List of works - Manuel Martínez

A Detailed Kinetico-Mechanistic Investigation on the Palladium C-H Bond Activation in Azobenzenes and Their Monopalladated Derivatives

scientific article published on 16 November 2020

A Kinetico-Mechanistic Study on CuII Deactivators Employed in Atom Transfer Radical Polymerization.

scientific article published on 22 September 2016

A combined kinetico-mechanistic and computational study on the competitive formation of seven- versus five-membered platinacycles; the relevance of spectator halide ligands

scientific article published on 24 September 2015

A kinetico-mechanistic study on the C-H bond activation of primary benzylamines; cooperative and solid-state cyclopalladation on dimeric complexes.

scientific article published on September 2014

Activation volumes for cis-to-trans isomerisation reactions of azophenols: a clear mechanistic indicator?

scientific article published on 18 December 2017

Amino acids with fluorescent tetrazine ethers as bioorthogonal handles for peptide modification

scientific article published in 2022

Antisymbiotic Self-Assembly and Dynamic Behavior of Metallamacrocycles with Allylic Corners

scientific article published on 01 December 2010

Base-assisted synthesis of 4-pyridinate gold(i) metallaligands: a study of their use in self-assembly reactions

scientific article

Biologically active thiosemicarbazone Fe chelators and their reactions with ferrioxamine B and ferric EDTA; a kinetic study

scientific article published on 19 December 2011

Computational insights on the geometrical arrangements of Cu(II) with a mixed-donor N3S3 macrobicyclic ligand.

scientific article published on 19 December 2013

Copper(II) complexes of a hexadentate mixed-donor N3S3 macrobicyclic cage: facile rearrangements and interconversions

scientific article published in March 2010

Cyclopalladation and reactivity of amino esters through C-H bond activation: experimental, kinetic, and density functional theory mechanistic studies

scientific article published on 13 November 2013

Dinuclear Cyano-Bridged CoIII−FeIIComplexes as Precursors for Molecular Mixed-Valence Complexes of Higher Nuclearity

scientific article published in January 2006

Discrete dinuclear cyano-bridged complexes.

scientific article

Elucidating the mechanism of the Ley-Griffith (TPAP) alcohol oxidation.

scientific article

Exchange reactions of acetate ligands and electrophilic rhodium–carbon bond activation in orthometallated rhodium(II) compounds with trifluoroacetic acid. Crystal structure of [Rh2(O2CCF3)3{(C6H4)PPh2]·2CF3CO2H

article

Isomeric Distribution and Catalyzed Isomerization of Cobalt(III) Complexes with Pentadentate Macrocyclic Ligands. Importance of Hydrogen Bonding

scientific article published in October 2006

Isomerization processes on mixed ortho-metalated phosphine/succinimidato [Rh2(P(C5CH4)Ph2)2(OC4NH4O)2] complexes. A sliding movement of the succinimidato ligand

scientific article published on 01 October 2006

Kinetic studies on the oxidation of oxyhemoglobin by biologically active iron thiosemicarbazone complexes: relevance to iron-chelator-induced methemoglobinemia.

scientific article published on 8 December 2013

Kinetic study of formation of [Co(H2PO4)(H2O)5]2+ at various acidities and ionic strengths

Kinetico-Mechanistic Insight into the Platinum-Mediated C−C Coupling of Fluorinated Arenes

Kinetico-Mechanistic Studies of Nucleoside and Nucleotide Substitution Reactions of Co(III) Complexes of Fully Alkylated Cyclen.

scientific article

Kinetico-Mechanistic Studies on Intramolecular C–X Bond Activation (X = Br, Cl) of Amino-Imino Ligands on Pt(II) Compounds. Prevalence of a Concerted Mechanism in Nonpolar, Polar, and Ionic Liquid Media

Kinetico-mechanistic Studies on the Substitution Reactivity on the {Ru(II)(bpy)2} Core with Nucleosides and Nucleotides at Physiological pH

scientific article published on 21 June 2016

Kinetico-mechanistic Study on the Oxidation of Biologically Active Iron(II) Bis(thiosemicarbazone) Complexes by Air. Importance of NH···O2 Interactions As Established by Activation Volumes.

scientific article

Kinetico-mechanistic information about alkene hydroamination with aniline in bromide-rich ionic media: importance of solvolysis

scientific article published on 17 May 2011

Kinetico-mechanistic insights on the assembling dynamics of allyl-cornered metallacycles: the Pt-Npy bond is the keystone

scientific article

Kinetico-mechanistic studies of substitution reactions on cross-bridged cyclen Co(III) complexes with nucleosides and nucleotides.

scientific article published on 12 October 2015

Kinetico-mechanistic studies of the acidolysis of Rh-C bonds in monocyclometallated dirhodium(II) acetato complexes; influence of electronic and steric effects.

scientific article published on 4 February 2011

Kinetico-mechanistic studies on methemoglobin generation by biologically active thiosemicarbazone iron(III) complexes

scientific article published on 9 December 2015

Kinetico-mechanistic studies on the formation of seven-membered [C,N]-platinacycles: the effect of methyl or fluoro substituents on the aryl ancillary ligands

scientific article published on 01 December 2015

Kinetico-mechanistic study of the thermal cis-to-trans isomerization of 4,4'-dialkoxyazoderivatives in nematic liquid crystals

scientific article published on 01 January 2010

Kineticomechanistic Study of the Redox pH Cycling Processes Occurring on a Robust Water-Soluble Cyanido-Bridged Mixed-Valence {CoIII/FeII}2 Square

scientific article published on 03 July 2018

Molecular Co(III)/Fe(II) cyano-bridged mixed-valence compounds with high nuclearities and diversity of Co(III) coordination environments: preparative and mechanistic aspects

scientific article published on 01 June 2009

NH2 As a Directing Group: From the Cyclopalladation of Amino Esters to the Preparation of Benzolactams by Palladium(II)-Catalyzed Carbonylation of N-Unprotected Arylethylamines

New insights in the formation of five- versus seven-membered platinacycles: a kinetico-mechanistic study.

scientific article published on 14 December 2012

Orthometalation reactions in trifluoroacetate dirhodium(II) compounds. Molecular structure of Rh2(O2CCF3)2[(C6H4)PPh2]2·(PPh3)2·2(C7H8)

Oxidation of Mixed-Valence CoIII/FeIIComplexes Reversed at High pH: A Kinetico-Mechanistic Study of Water Oxidation

scientific article published in November 2004

Photoactuation and thermal isomerisation mechanism of cyanoazobenzene-based liquid crystal elastomers

scientific article published on 01 May 2014

Polypyridyl-functionalizated alkynyl gold(i) metallaligands supported by tri- and tetradentate phosphanes

scientific article

Pressure and temperature effects on metal-to-metal charge transfer in cyano-bridged CoIII-FeII complexes

scientific article published on 17 March 2005

Proton-assisted air oxidation mechanisms of iron(ii) bis-thiosemicarbazone complexes at physiological pH: a kinetico-mechanistic study

scientific article published on 28 October 2019

Redox-Assisted Self-Assembly of a Water-Soluble Cyanido-Bridged Mixed Valence {Co(III) /Fe(II) }2 Square

scientific article

Regioselective orthopalladation of (Z)-2-aryl-4-arylidene-5(4H)-oxazolones: scope, kinetico-mechanistic, and density functional theory studies of the C-H bond activation

scientific article published on 01 August 2011

Reversible rearrangements of Cu(II) cage complexes: solvent and anion influences

scientific article published on 01 November 2012

Self-Assembly and Properties of a Discrete Water-Soluble Prussian Blue Analogue FeII/CoIII Cube: Confinement of a Water Molecule in Aqueous Solution

scientific article published on 13 January 2020

Sensitive and Selective Chromogenic Sensing of Carbon Monoxide via Reversible Axial CO Coordination in Binuclear Rhodium Complexes

scientific article published on 09 September 2011

Substitution reactions on cyclometalated Pt(IV) complexes. Associative tuning by fluoro ligands and fluorinated substituents

scientific article

Synthesis, structure, and substitution mechanism of new Ru(II) complexes containing 1,4,7-trithiacyclononane and 1,10-phenanthroline ligands

scientific article

Tailoring mixed-valence CoIII/FeII complexes for their potential use as sensitizers in dye sensitized solar cells

The role of hydroxo-bridged dinuclear species and the influence of "innocent" buffers in the reactivity of cis-[Co(III)(cyclen)(H₂O)₂]³⁺ and [Co(III)(tren)(H₂O)₂]³⁺ complexes with biologically relevant ligands at physiological pH.

scientific article published in July 2014

Tungsten and molybdenum incomplete cuboidal clusters; kinetico-mechanistic studies and association in dimers

scientific article published on 30 August 2013

Tuning the metal-to-metal charge transfer energy of cyano-bridged dinuclear complexes

scientific article

pH-Driven preparation of two related platinum(ii) complexes exhibiting distinct cytotoxic properties

scientific article

List of works by Manuel Martínez

A Detailed Kinetico-Mechanistic Investigation on the Palladium C-H Bond Activation in Azobenzenes and Their Monopalladated Derivatives

A Kinetico-Mechanistic Study on CuII Deactivators Employed in Atom Transfer Radical Polymerization.

A combined kinetico-mechanistic and computational study on the competitive formation of seven- versus five-membered platinacycles; the relevance of spectator halide ligands

A kinetico-mechanistic study on the C-H bond activation of primary benzylamines; cooperative and solid-state cyclopalladation on dimeric complexes.

Activation volumes for cis-to-trans isomerisation reactions of azophenols: a clear mechanistic indicator?

Amino acids with fluorescent tetrazine ethers as bioorthogonal handles for peptide modification

Antisymbiotic Self-Assembly and Dynamic Behavior of Metallamacrocycles with Allylic Corners

Base-assisted synthesis of 4-pyridinate gold(i) metallaligands: a study of their use in self-assembly reactions

Biologically active thiosemicarbazone Fe chelators and their reactions with ferrioxamine B and ferric EDTA; a kinetic study

Computational insights on the geometrical arrangements of Cu(II) with a mixed-donor N3S3 macrobicyclic ligand.

Copper(II) complexes of a hexadentate mixed-donor N3S3 macrobicyclic cage: facile rearrangements and interconversions

Cyclopalladation and reactivity of amino esters through C-H bond activation: experimental, kinetic, and density functional theory mechanistic studies

Dinuclear Cyano-Bridged CoIII−FeIIComplexes as Precursors for Molecular Mixed-Valence Complexes of Higher Nuclearity

Discrete dinuclear cyano-bridged complexes.

Elucidating the mechanism of the Ley-Griffith (TPAP) alcohol oxidation.

Exchange reactions of acetate ligands and electrophilic rhodium–carbon bond activation in orthometallated rhodium(II) compounds with trifluoroacetic acid. Crystal structure of [Rh2(O2CCF3)3{(C6H4)PPh2]·2CF3CO2H

Isomeric Distribution and Catalyzed Isomerization of Cobalt(III) Complexes with Pentadentate Macrocyclic Ligands. Importance of Hydrogen Bonding

Isomerization processes on mixed ortho-metalated phosphine/succinimidato [Rh2(P(C5CH4)Ph2)2(OC4NH4O)2] complexes. A sliding movement of the succinimidato ligand

Kinetic studies on the oxidation of oxyhemoglobin by biologically active iron thiosemicarbazone complexes: relevance to iron-chelator-induced methemoglobinemia.

Kinetic study of formation of [Co(H2PO4)(H2O)5]2+ at various acidities and ionic strengths

Kinetico-Mechanistic Insight into the Platinum-Mediated C−C Coupling of Fluorinated Arenes

Kinetico-Mechanistic Studies of Nucleoside and Nucleotide Substitution Reactions of Co(III) Complexes of Fully Alkylated Cyclen.

Kinetico-Mechanistic Studies on Intramolecular C–X Bond Activation (X = Br, Cl) of Amino-Imino Ligands on Pt(II) Compounds. Prevalence of a Concerted Mechanism in Nonpolar, Polar, and Ionic Liquid Media

Kinetico-mechanistic Studies on the Substitution Reactivity on the {Ru(II)(bpy)2} Core with Nucleosides and Nucleotides at Physiological pH

Kinetico-mechanistic Study on the Oxidation of Biologically Active Iron(II) Bis(thiosemicarbazone) Complexes by Air. Importance of NH···O2 Interactions As Established by Activation Volumes.

Kinetico-mechanistic information about alkene hydroamination with aniline in bromide-rich ionic media: importance of solvolysis

Kinetico-mechanistic insights on the assembling dynamics of allyl-cornered metallacycles: the Pt-Npy bond is the keystone

Kinetico-mechanistic studies of substitution reactions on cross-bridged cyclen Co(III) complexes with nucleosides and nucleotides.

Kinetico-mechanistic studies of the acidolysis of Rh-C bonds in monocyclometallated dirhodium(II) acetato complexes; influence of electronic and steric effects.

Kinetico-mechanistic studies on methemoglobin generation by biologically active thiosemicarbazone iron(III) complexes

Kinetico-mechanistic studies on the formation of seven-membered [C,N]-platinacycles: the effect of methyl or fluoro substituents on the aryl ancillary ligands

Kinetico-mechanistic study of the thermal cis-to-trans isomerization of 4,4'-dialkoxyazoderivatives in nematic liquid crystals

Kineticomechanistic Study of the Redox pH Cycling Processes Occurring on a Robust Water-Soluble Cyanido-Bridged Mixed-Valence {CoIII/FeII}2 Square

Molecular Co(III)/Fe(II) cyano-bridged mixed-valence compounds with high nuclearities and diversity of Co(III) coordination environments: preparative and mechanistic aspects

NH2 As a Directing Group: From the Cyclopalladation of Amino Esters to the Preparation of Benzolactams by Palladium(II)-Catalyzed Carbonylation of N-Unprotected Arylethylamines

New insights in the formation of five- versus seven-membered platinacycles: a kinetico-mechanistic study.

Orthometalation reactions in trifluoroacetate dirhodium(II) compounds. Molecular structure of Rh2(O2CCF3)2[(C6H4)PPh2]2·(PPh3)2·2(C7H8)

Oxidation of Mixed-Valence CoIII/FeIIComplexes Reversed at High pH: A Kinetico-Mechanistic Study of Water Oxidation

Photoactuation and thermal isomerisation mechanism of cyanoazobenzene-based liquid crystal elastomers

Polypyridyl-functionalizated alkynyl gold(i) metallaligands supported by tri- and tetradentate phosphanes

Pressure and temperature effects on metal-to-metal charge transfer in cyano-bridged CoIII-FeII complexes

Proton-assisted air oxidation mechanisms of iron(ii) bis-thiosemicarbazone complexes at physiological pH: a kinetico-mechanistic study

Redox-Assisted Self-Assembly of a Water-Soluble Cyanido-Bridged Mixed Valence {Co(III) /Fe(II) }2 Square

Regioselective orthopalladation of (Z)-2-aryl-4-arylidene-5(4H)-oxazolones: scope, kinetico-mechanistic, and density functional theory studies of the C-H bond activation

Reversible rearrangements of Cu(II) cage complexes: solvent and anion influences

Self-Assembly and Properties of a Discrete Water-Soluble Prussian Blue Analogue FeII/CoIII Cube: Confinement of a Water Molecule in Aqueous Solution

Sensitive and Selective Chromogenic Sensing of Carbon Monoxide via Reversible Axial CO Coordination in Binuclear Rhodium Complexes

Substitution reactions on cyclometalated Pt(IV) complexes. Associative tuning by fluoro ligands and fluorinated substituents

Synthesis, structure, and substitution mechanism of new Ru(II) complexes containing 1,4,7-trithiacyclononane and 1,10-phenanthroline ligands

Tailoring mixed-valence CoIII/FeII complexes for their potential use as sensitizers in dye sensitized solar cells

The role of hydroxo-bridged dinuclear species and the influence of "innocent" buffers in the reactivity of cis-[Co(III)(cyclen)(H₂O)₂]³⁺ and [Co(III)(tren)(H₂O)₂]³⁺ complexes with biologically relevant ligands at physiological pH.

Tungsten and molybdenum incomplete cuboidal clusters; kinetico-mechanistic studies and association in dimers

Tuning the metal-to-metal charge transfer energy of cyano-bridged dinuclear complexes

pH-Driven preparation of two related platinum(ii) complexes exhibiting distinct cytotoxic properties