List of works - Guido Pampaloni

1,10-Phenanthroline-5,6-dione complexes of middle transition elements: Mono- and dinuclear derivatives

A crystallographic and spectroscopic study on the reactions of WCl6 with carbonyl compounds ⬇️

scientific article published on April 28, 2013

A crystallographically characterized salt of self-generated N-protonated tetraethylurea

scientific article published in January 2015

A structurally-characterized NbCl5-NHC adduct.

scientific article published on 24 March 2014

A systematic study on the activation of simple polyethers by MoCl5 and WCl6.

scientific article published on 7 May 2010

Arene Osmium Complexes with Ethacrynic Acid-Modified Ligands: Synthesis, Characterization, and Evaluation of Intracellular Glutathione S-Transferase Inhibition and Antiproliferative Activity

scholarly article by Gabriele Agonigi et al published 25 March 2016 in Organometallics

Bis(arylimino)pyridine derivatives of Group 4 metals: preparation, characterization and activity in ethylene polymerization

scientific article

Bis-conjugation of Bioactive Molecules to Cisplatin-like Complexes through (2,2'-Bipyridine)-4,4'-Dicarboxylic Acid with Optimal Cytotoxicity Profile Provided by the Combination Ethacrynic Acid/Flurbiprofen

scientific article published on 30 November 2020

Bypassing the Inertness of Aziridine/CO2 Systems to Access 5-Aryl-2-Oxazolidinones: Catalyst-Free Synthesis Under Ambient Conditions

scientific article published on 09 September 2020

C-N bond-forming self-condensation of amide promoted by MoCl5 at room temperature

scientific article published on 31 March 2011

Cationic Diiron and Diruthenium μ-Allenyl Complexes: Synthesis, X-Ray Structures and Cyclization Reactions with Ethyldiazoacetate/Amine Affording Unprecedented Butenolide- and Furaniminium-Substituted Bridging Carbene Ligands ⬇️

scientific article published on October 18, 2010

Conjugating Biotin to Ruthenium(II) Arene Units via Phosphine Ligand Functionalization

scientific article published in 2019

Controlled Dissociation of Iron and Cyclopentadienyl from a Diiron Complex with a Bridging C3 Ligand Triggered by One-Electron Reduction

scientific article published on 30 November 2018

Convenient synthesis of fluoride-alkoxides of Nb(V) and Ta(V): a spectroscopic, crystallographic and computational study

scientific article published on 01 November 2012

Converting Carbon Dioxide into Carbamato Derivatives ⬇️

scientific article published on October 1, 2003

Coordination Compounds of Niobium(IV) Oxide Dihalides Including the Synthesis and the Crystallographic Characterization of NHC Complexes

scientific article published on 15 April 2016

Coordination complexes of NbX5 (X = F, Cl) with (N,O)- and (O,O)-donor ligands and the first X-ray characterization of a neutral NbF5 adduct

scientific article published on 22 July 2013

Coordination complexes of niobium and tantalum pentahalides with a bulky NHC ligand

scientific article published on 01 April 2016

Decarbonylation of phenylacetic acids by high valent transition metal halides

scientific article published on 01 April 2019

Electron-transfer processes with substituted group 5 metal carbonyls. Synthesis, crystal and molecular structure of Ag3M3(CO)12(Me2PCH2CH2PMe2)3, M = Nb, Ta, the first structurally characterized carbonyl derivatives of niobium(0) and tantalum(0)

scholarly article by Fausto Calderazzo et al published February 1990 in Journal of Organometallic Chemistry

From 1,2-dialkoxyalkanes to 1,4-dioxanes. A transformation mediated by NbCl(5)via multiple C-O bond cleavage at room temperature.

scientific article published on 9 June 2008

Interaction of niobium and tantalum pentahalides with O-donors: coordination chemistry and activation reactions ⬇️

scientific article published on 09 November 2011

Iron(III) N,N-Dialkylcarbamate-Catalyzed Formation of Cyclic Carbonates from CO2 and Epoxides under Ambient Conditions by Dynamic CO2 Trapping as Carbamato Ligands

scientific article published on 12 July 2018

Is bond stretch isomerism in mononuclear transition metal complexes a real issue? The misleading case of the MoCl5/tetrahydropyran reaction system

scientific article

Ligand-interchange reactions between M(IV) (M = Ti, V) oxide bis-acetylacetonates and halides of high-valent group 4 and 5 metals. A synthetic and electrochemical study

scientific article published on 01 October 2013

Long-lived radical cation salts obtained by interaction of monocyclic arenes with niobium and tantalum pentahalides at room temperature: EPR and DFT studies

scientific article published on 20 August 2013

Long-lived radical cations of monocyclic arenes at room temperature obtained by NbF5 acting as an oxidizing agent and counterion precursor

scientific article published on 01 July 2010

Low-temperature syntheses of vanadium(III) and molybdenum(IV) bromides by halide exchange

MoCl5 as an effective chlorinating agent towards α-amino acids: synthesis of α-ammonium-acylchloride salts and α-amino-acylchloride complexes.

scientific article

Modifying bis(triflimide) ionic liquids by dissolving early transition metal carbamates

scientific article published in February 2018

Mono-, Di- and Tetra-iron Complexes with Selenium or Sulphur Functionalized Vinyliminium Ligands: Synthesis, Structural Characterization and Antiproliferative Activity

scientific article published on 03 April 2020

Novel highly active niobium catalysts for ring opening metathesis polymerization of norbornene.

scientific article published on 27 July 2009

Olefin Trifluoroacetato Derivatives of Copper(I) and Their Olefin/CO Exchange Reactions

article published in 2005

One-electron redox reactions involving chromium(0) and molybdenum(0) bis-1,3,5-trimethylbenzene derivatives

Oxidative Dimerization of Triarylamines Promoted by WCl6, Including the Solid State Isolation and the Crystallographic Characterization of a Triphenylammonium Salt

scientific article published on 23 December 2015

Oxido-molybdenum complexes obtained by Cl/O interchange between MoCl5 and carboxylic acids: a crystallographic, spectroscopic and computational study

scientific article published on 01 November 2014

Perfluorofluorenyl anions and their use as co-catalysts in the zirconocene-promoted polymerization of olefins

Reactivity of bis(η6-arene) derivatives of titanium, vanadium and niobium with fulvenes bearing electron-withdrawing substituents

scholarly article by Lucia Calucci et al published November 2005 in Journal of Organometallic Chemistry

Reactivity of niobium(v) and tantalum(v) halides with carbonyl compounds: synthesis of simple coordination adducts, C-H bond activation, C=O protonation, and halide transfer.

scientific article published on 6 August 2007

Recent Advances in the Chemistry of Metal Carbamates

scientific article published on 07 August 2020

Redox reactions of vanadium(0) and niobium(0) bis(mesitylene) (mes) derivatives with metal carbonyl halides of Group 7. The crystal and molecular structure of [mes(CO)2Nb(μ-I)2Re(CO)3], a metal-metal bonded heterobimetallic complex

scholarly article by Fausto Calderazzo et al published December 1993 in Journal of Organometallic Chemistry

Redox reactions with bis(η6-arene) derivatives of early transition metals

Ring opening polymerization of rac-lactide by group 4 tetracarbamato complexes: activation, propagation and role of the metal

scientific article published on 01 February 2013

Stabilization of Niobium(0) and Tantalum(0) in Mixed Metal Clusters containing Silver Atoms

scholarly article by Fausto Calderazzo et al published April 1989 in Angewandte Chemie. International edition in English

Straightforward formation of carbocations from tertiary carboxylic acids via CO release at room temperature

scientific article published on 07 December 2018

Structures and unusual rearrangements of coordination adducts of MX(5) (M = Nb, Ta; X = F, Cl) with simple diethers. A crystallographic, spectroscopic, and computational study

scientific article

Synproportionation reactions between copper(II) trihalogenoacetates Cu(CX3CO2)2, X = F, Cl or Br, and copper in the presence of carbon monoxide

Synthesis and Antiproliferative Activity of New Ruthenium Complexes with Ethacrynic-Acid-Modified Pyridine and Triphenylphosphine Ligands

Synthesis and characterization of chromium(I) bis(η6-toluene) derivatives containing sterically demanding anions

Synthesis and reactivity of Haloacetato derivatives of iron(II) including the crystal and the molecular structure of [Fe(CF3COOH)2(micro-CF3COO)2]n

scientific article published on 13 March 2007

Synthesis and structural characterization of iron(II) derivatives of heterocyclic tridentate amines

article published in 2003

Synthesis of Nanocrystalline TiOF2 Embedded in a Carbonaceous Matrix from TiF4 and D-Fructose.

scientific article published on 29 January 2016

Synthesis of a highly reactive form of WO2Cl2, its conversion into nanocrystalline mono-hydrated WO3 and coordination compounds with tetramethylurea.

scientific article published on 6 September 2016

Synthesis of chromium(0) and molybdenum(0) bis (η6-arene) derivatives and their monoelectronic oxidation to [M(η6-arene)2]+cations

scientific article published on 22 June 2006

Synthesis of copper(I) bis(3,5-dimethylpyrazolyl)methane olefin complexes and their reactivity towards carbon monoxide

Synthesis of di- and tetranuclear oxido-molybdenum(V) complexes containing p-toluenesulfonates as ligands: a joint spectroscopic, crystallographic and computational study

scientific article published on 30 May 2014

Synthesis of α-amino acidato derivatives of niobium and tantalum pentahalides and their conversion into iminium salts

scientific article published on 06 April 2015

Synthesis, Characterization, and Olefin/CO Exchange Reactions of Copper(I) Derivatives Containing Bidentate Oxygen Ligands

Synthesis, X-ray characterization, and reactivity of α-aminoacidato ethoxide complexes of niobium(V) and tantalum(V)

scientific article published on 12 March 2013

Synthesis, characterization and olefin/CO exchange reactions of pyrazolylborato complexes of copper(i)

scientific article published on 04 May 2006

Synthesis, characterization and reactivity of tetracyclopentadienylniobium(IV), a precursor to organometallic derivatives of niobium(IV)

scholarly article by Fausto Calderazzo et al published July 2001 in Journal of Organometallic Chemistry

Synthesis, characterization, and reactivity of manganese(II) and iron(II) trifluoroacetates. Crystal and molecular structure of two linkage isomers of polynuclear [Mn(CF 3 COO) 2 (THF) 2 ] n

scholarly article by Fausto Calderazzo et al published 2001 in Canadian Journal of Chemistry

Synthesis, reactivity and structures of mono- and dihaloacetato complexes of copper(I) and copper(II)

Synthesis, variable temperature NMR investigations and solid state characterization of novel octafluorofluorene compounds

article published in 2009

Tetrahydrofuran and 1,2-dimethoxyethane derivatives of vanadium(II) and vanadium(III)

scholarly article by Guido Pampaloni & Ulli Englert published March 1995 in Inorganica Chimica Acta

Tetrasubstituted Selenophenes from the Stepwise Assembly of Molecular Fragments on a Diiron Frame and Final Cleavage of a Bridging Alkylidene

scientific article published on 18 November 2020

The chlorinating behaviour of WCl₆ towards α-aminoacids

scientific article published on 01 May 2015

The interaction of molybdenum pentachloride with O- and S-heterocycles

scientific article published on 11 October 2013

The interaction of molybdenum pentachloride with carbonyl compounds.

scientific article published on 4 December 2012

The reactivity of 1,1-dialkoxyalkanes with niobium and tantalum pentahalides. Formation of coordination compounds, C-H and C-C bond activation and the X-ray structure of the stable carboxonium species [Me(2)C=CHC(=OMe)Me][NbCl(5)(OMe)].

scientific article published on 10 August 2009

The reactivity of molybdenum pentachloride with ethers: routes to the synthesis of Mo(IV)Cl4 adducts, Mo(V) chlorido-alkoxides and Mo(V) oxydo-chlorides

scientific article published on 5 September 2013

Tribenzylamine C-H activation and intermolecular hydrogen transfer promoted by WCl6.

scientific article published on 13 March 2014

Trifluoromethyl-Substituted Bis(pyrazolyl)methanes as Ligands for Copper and Silver: Synthesis and Spectroscopic and Structural Characterization

Vanadium(v) oxoanions in basic water solution: a simple oxidative system for the one pot selective conversion of l-proline to pyrroline-2-carboxylate.

scientific article published on 24 October 2017

Versatile coordination of acetazolamide to ruthenium(ii) p-cymene complexes and preliminary cytotoxicity studies

scientific article published on 01 July 2018

Zirconium(II)- and Hafnium(II)-Assisted Reductive Coupling of Coordinated Carbonyl Groups Leading to Ketenylidene Complexes of Zirconium(IV) and Hafnium(IV)

scholarly article by Fausto Calderazzo et al published April 1996 in Chemistry—A European Journal

[Nb{B(?6-C6H5)2(C6H5)2}(?2-H3CC2CH3)]: the First Compound with Bent Tetraphenylborate as 12-Electron Donor Ligand

[Zr3Cp2(O2CNiPr2)6(?-O)(?-CCO)], the First Crystallographically Established Ketenylidene Complex; A Model for CO Reductive Cleavage on Metal Surfaces

α-Diimine homologues of cisplatin: synthesis, speciation in DMSO/water and cytotoxicity

α-Diimines as Versatile, Derivatizable Ligands in Ruthenium(II) p-Cymene Anticancer Complexes

article published in 2018

List of works by Guido Pampaloni

1,10-Phenanthroline-5,6-dione complexes of middle transition elements: Mono- and dinuclear derivatives

A crystallographic and spectroscopic study on the reactions of WCl6 with carbonyl compounds ⬇️

A crystallographically characterized salt of self-generated N-protonated tetraethylurea

A structurally-characterized NbCl5-NHC adduct.

A systematic study on the activation of simple polyethers by MoCl5 and WCl6.

Arene Osmium Complexes with Ethacrynic Acid-Modified Ligands: Synthesis, Characterization, and Evaluation of Intracellular Glutathione S-Transferase Inhibition and Antiproliferative Activity

Bis(arylimino)pyridine derivatives of Group 4 metals: preparation, characterization and activity in ethylene polymerization

Bis-conjugation of Bioactive Molecules to Cisplatin-like Complexes through (2,2'-Bipyridine)-4,4'-Dicarboxylic Acid with Optimal Cytotoxicity Profile Provided by the Combination Ethacrynic Acid/Flurbiprofen

Bypassing the Inertness of Aziridine/CO2 Systems to Access 5-Aryl-2-Oxazolidinones: Catalyst-Free Synthesis Under Ambient Conditions

C-N bond-forming self-condensation of amide promoted by MoCl5 at room temperature

Cationic Diiron and Diruthenium μ-Allenyl Complexes: Synthesis, X-Ray Structures and Cyclization Reactions with Ethyldiazoacetate/Amine Affording Unprecedented Butenolide- and Furaniminium-Substituted Bridging Carbene Ligands ⬇️

Conjugating Biotin to Ruthenium(II) Arene Units via Phosphine Ligand Functionalization

Controlled Dissociation of Iron and Cyclopentadienyl from a Diiron Complex with a Bridging C3 Ligand Triggered by One-Electron Reduction

Convenient synthesis of fluoride-alkoxides of Nb(V) and Ta(V): a spectroscopic, crystallographic and computational study

Converting Carbon Dioxide into Carbamato Derivatives ⬇️

Coordination Compounds of Niobium(IV) Oxide Dihalides Including the Synthesis and the Crystallographic Characterization of NHC Complexes

Coordination complexes of NbX5 (X = F, Cl) with (N,O)- and (O,O)-donor ligands and the first X-ray characterization of a neutral NbF5 adduct

Coordination complexes of niobium and tantalum pentahalides with a bulky NHC ligand

Decarbonylation of phenylacetic acids by high valent transition metal halides

Electron-transfer processes with substituted group 5 metal carbonyls. Synthesis, crystal and molecular structure of Ag3M3(CO)12(Me2PCH2CH2PMe2)3, M = Nb, Ta, the first structurally characterized carbonyl derivatives of niobium(0) and tantalum(0)

From 1,2-dialkoxyalkanes to 1,4-dioxanes. A transformation mediated by NbCl(5)via multiple C-O bond cleavage at room temperature.

Interaction of niobium and tantalum pentahalides with O-donors: coordination chemistry and activation reactions ⬇️

Iron(III) N,N-Dialkylcarbamate-Catalyzed Formation of Cyclic Carbonates from CO2 and Epoxides under Ambient Conditions by Dynamic CO2 Trapping as Carbamato Ligands

Is bond stretch isomerism in mononuclear transition metal complexes a real issue? The misleading case of the MoCl5/tetrahydropyran reaction system

Ligand-interchange reactions between M(IV) (M = Ti, V) oxide bis-acetylacetonates and halides of high-valent group 4 and 5 metals. A synthetic and electrochemical study

Long-lived radical cation salts obtained by interaction of monocyclic arenes with niobium and tantalum pentahalides at room temperature: EPR and DFT studies

Long-lived radical cations of monocyclic arenes at room temperature obtained by NbF5 acting as an oxidizing agent and counterion precursor

Low-temperature syntheses of vanadium(III) and molybdenum(IV) bromides by halide exchange

MoCl5 as an effective chlorinating agent towards α-amino acids: synthesis of α-ammonium-acylchloride salts and α-amino-acylchloride complexes.

Modifying bis(triflimide) ionic liquids by dissolving early transition metal carbamates

Mono-, Di- and Tetra-iron Complexes with Selenium or Sulphur Functionalized Vinyliminium Ligands: Synthesis, Structural Characterization and Antiproliferative Activity

Novel highly active niobium catalysts for ring opening metathesis polymerization of norbornene.

Olefin Trifluoroacetato Derivatives of Copper(I) and Their Olefin/CO Exchange Reactions

One-electron redox reactions involving chromium(0) and molybdenum(0) bis-1,3,5-trimethylbenzene derivatives

Oxidative Dimerization of Triarylamines Promoted by WCl6, Including the Solid State Isolation and the Crystallographic Characterization of a Triphenylammonium Salt

Oxido-molybdenum complexes obtained by Cl/O interchange between MoCl5 and carboxylic acids: a crystallographic, spectroscopic and computational study

Perfluorofluorenyl anions and their use as co-catalysts in the zirconocene-promoted polymerization of olefins

Reactivity of bis(η6-arene) derivatives of titanium, vanadium and niobium with fulvenes bearing electron-withdrawing substituents

Reactivity of niobium(v) and tantalum(v) halides with carbonyl compounds: synthesis of simple coordination adducts, C-H bond activation, C=O protonation, and halide transfer.

Recent Advances in the Chemistry of Metal Carbamates

Redox reactions of vanadium(0) and niobium(0) bis(mesitylene) (mes) derivatives with metal carbonyl halides of Group 7. The crystal and molecular structure of [mes(CO)2Nb(μ-I)2Re(CO)3], a metal-metal bonded heterobimetallic complex

Redox reactions with bis(η6-arene) derivatives of early transition metals

Ring opening polymerization of rac-lactide by group 4 tetracarbamato complexes: activation, propagation and role of the metal

Stabilization of Niobium(0) and Tantalum(0) in Mixed Metal Clusters containing Silver Atoms

Straightforward formation of carbocations from tertiary carboxylic acids via CO release at room temperature

Structures and unusual rearrangements of coordination adducts of MX(5) (M = Nb, Ta; X = F, Cl) with simple diethers. A crystallographic, spectroscopic, and computational study

Synproportionation reactions between copper(II) trihalogenoacetates Cu(CX3CO2)2, X = F, Cl or Br, and copper in the presence of carbon monoxide

Synthesis and Antiproliferative Activity of New Ruthenium Complexes with Ethacrynic-Acid-Modified Pyridine and Triphenylphosphine Ligands

Synthesis and characterization of chromium(I) bis(η6-toluene) derivatives containing sterically demanding anions

Synthesis and reactivity of Haloacetato derivatives of iron(II) including the crystal and the molecular structure of [Fe(CF3COOH)2(micro-CF3COO)2]n

Synthesis and structural characterization of iron(II) derivatives of heterocyclic tridentate amines

Synthesis of Nanocrystalline TiOF2 Embedded in a Carbonaceous Matrix from TiF4 and D-Fructose.

Synthesis of a highly reactive form of WO2Cl2, its conversion into nanocrystalline mono-hydrated WO3 and coordination compounds with tetramethylurea.

Synthesis of chromium(0) and molybdenum(0) bis (η6-arene) derivatives and their monoelectronic oxidation to [M(η6-arene)2]+cations

Synthesis of copper(I) bis(3,5-dimethylpyrazolyl)methane olefin complexes and their reactivity towards carbon monoxide

Synthesis of di- and tetranuclear oxido-molybdenum(V) complexes containing p-toluenesulfonates as ligands: a joint spectroscopic, crystallographic and computational study

Synthesis of α-amino acidato derivatives of niobium and tantalum pentahalides and their conversion into iminium salts

Synthesis, Characterization, and Olefin/CO Exchange Reactions of Copper(I) Derivatives Containing Bidentate Oxygen Ligands

Synthesis, X-ray characterization, and reactivity of α-aminoacidato ethoxide complexes of niobium(V) and tantalum(V)

Synthesis, characterization and olefin/CO exchange reactions of pyrazolylborato complexes of copper(i)

Synthesis, characterization and reactivity of tetracyclopentadienylniobium(IV), a precursor to organometallic derivatives of niobium(IV)

Synthesis, characterization, and reactivity of manganese(II) and iron(II) trifluoroacetates. Crystal and molecular structure of two linkage isomers of polynuclear [Mn(CF 3 COO) 2 (THF) 2 ] n

Synthesis, reactivity and structures of mono- and dihaloacetato complexes of copper(I) and copper(II)

Synthesis, variable temperature NMR investigations and solid state characterization of novel octafluorofluorene compounds

Tetrahydrofuran and 1,2-dimethoxyethane derivatives of vanadium(II) and vanadium(III)

Tetrasubstituted Selenophenes from the Stepwise Assembly of Molecular Fragments on a Diiron Frame and Final Cleavage of a Bridging Alkylidene

The chlorinating behaviour of WCl₆ towards α-aminoacids

The interaction of molybdenum pentachloride with O- and S-heterocycles

The interaction of molybdenum pentachloride with carbonyl compounds.

The reactivity of 1,1-dialkoxyalkanes with niobium and tantalum pentahalides. Formation of coordination compounds, C-H and C-C bond activation and the X-ray structure of the stable carboxonium species [Me(2)C=CHC(=OMe)Me][NbCl(5)(OMe)].

The reactivity of molybdenum pentachloride with ethers: routes to the synthesis of Mo(IV)Cl4 adducts, Mo(V) chlorido-alkoxides and Mo(V) oxydo-chlorides

Tribenzylamine C-H activation and intermolecular hydrogen transfer promoted by WCl6.

Trifluoromethyl-Substituted Bis(pyrazolyl)methanes as Ligands for Copper and Silver: Synthesis and Spectroscopic and Structural Characterization

Vanadium(v) oxoanions in basic water solution: a simple oxidative system for the one pot selective conversion of l-proline to pyrroline-2-carboxylate.

Versatile coordination of acetazolamide to ruthenium(ii) p-cymene complexes and preliminary cytotoxicity studies

Zirconium(II)- and Hafnium(II)-Assisted Reductive Coupling of Coordinated Carbonyl Groups Leading to Ketenylidene Complexes of Zirconium(IV) and Hafnium(IV)

[Nb{B(?6-C6H5)2(C6H5)2}(?2-H3CC2CH3)]: the First Compound with Bent Tetraphenylborate as 12-Electron Donor Ligand

[Zr3Cp2(O2CNiPr2)6(?-O)(?-CCO)], the First Crystallographically Established Ketenylidene Complex; A Model for CO Reductive Cleavage on Metal Surfaces

α-Diimine homologues of cisplatin: synthesis, speciation in DMSO/water and cytotoxicity