List of works - Matthew J. Gaunt

A General Carbonyl Alkylative Amination Process for Tertiary Amine Synthesis

A Highly Para-Selective Copper(II)-Catalyzed Direct Arylation of Aniline and Phenol Derivatives

scientific article published on 01 January 2011

A Practical and Efficient Synthesis of the C-16−C-28 Spiroketal Fragment (CD) of the Spongistatins

scientific article published in 2003

A concise and scalable strategy for the total synthesis of dictyodendrin B based on sequential C-H functionalization

scientific article published on 23 February 2015

A counteranion triggered arylation strategy using diaryliodonium fluorides.

scientific article

A general carbonyl alkylative amination for tertiary amine synthesis

scientific article published on 08 April 2020

A general catalytic β-C-H carbonylation of aliphatic amines to β-lactams

scientific article published on 01 November 2016

A meta-selective copper-catalyzed C-H bond arylation

scientific article

A protein functionalization platform based on selective reactions at methionine residues

scientific article published in Nature

A steric tethering approach enables palladium-catalysed C-H activation of primary amino alcohols.

scientific article

Addition of Dithiols to Bis-Ynones: Development of a Versatile Platform for the Synthesis of Polyketide Natural Products

article

An Intramolecular Organocatalytic Cyclopropanation Reaction

scientific article published on 01 May 2004

An enantioselective organocatalytic oxidative dearomatization strategy

scientific article published on 01 January 2008

Callipeltosides A, B and C: Total Syntheses and Structural Confirmation

scientific article published on 31 July 2015

Carboxylate-Assisted Oxidative Addition to Aminoalkyl PdII Complexes: C(sp3 )-H Arylation of Alkylamines by Distinct PdII /PdIV Pathway

scientific article published on 24 May 2019

Catalytic C(sp3)-H bond activation in tertiary alkylamines

scientific article published on 20 December 2019

Chemical synthesis of Aspidosperma alkaloids inspired by the reverse of the biosynthesis of the rhazinilam family of natural products

scientific article published on 22 August 2012

Cobalt-catalysed C-H carbonylative cyclisation of aliphatic amides

scientific article

Continuous-Flow Synthesis and Derivatization of Aziridines through Palladium-Catalyzed C(sp(3) )-H Activation.

scientific article published on 15 June 2016

Convenient preparation of trans-arylalkenes via palladium(II)-catalyzed isomerization of cis-arylalkenes

scientific article

Copper(II)-catalyzed meta-selective direct arylation of α-aryl carbonyl compounds

scientific article published on 22 October 2010

Copper-Catalyzed Oxy-Alkenylation of Homoallylic Alcohols to Generate Functional syn-1,3-Diol Derivatives

scientific article published on 27 May 2015

Copper-catalyzed alkene arylation with diaryliodonium salts

scientific article published on 19 June 2012

Copper-catalyzed arylative Meyer-Schuster rearrangement of propargylic alcohols to complex enones using diaryliodonium salts

scientific article published on 22 April 2013

Copper-catalyzed carboarylation of alkynes via vinyl cations

scientific article published on 15 August 2013

Copper-catalyzed electrophilic carbofunctionalization of alkynes to highly functionalized tetrasubstituted alkenes

scientific article published on 29 March 2013

Copper-catalyzed intramolecular electrophilic carbofunctionalization of allylic amides

scientific article published on 15 July 2013

Correction to "Palladium-Catalyzed Enantioselective C-H Activation of Aliphatic Amines Using Chiral Anionic BINOL-Phosphoric Acid Ligands".

scientific article published on 31 May 2017

Cu(II)-catalyzed direct and site-selective arylation of indoles under mild conditions

scientific article published on 11 June 2008

Cu-Catalyzed Cascades to Carbocycles: Union of Diaryliodonium Salts with Alkenes or Alkynes Exploiting Remote Carbocations

scientific article published on 12 June 2014

Development of β-keto 1,3-dithianes as versatile intermediates for organic synthesis

article

Diastereoselective C-H carbonylative annulation of aliphatic amines: a rapid route to functionalized γ-lactams

scientific article published on 31 July 2018

Dithiane additions to vinyl epoxides: steric control over the SN2 and SN2' manifolds

scientific article published in December 2002

Double Conjugate Addition of Dithiols to Propargylic Carbonyl Systems To Generate Protected 1,3-Dicarbonyl Compounds

article

Enantioselective Catalytic Intramolecular Cyclopropanation using Modified Cinchona Alkaloid Organocatalysts

scholarly article by Carin C. C. Johansson et al published 11 September 2006 in Angewandte Chemie International Edition

Enantioselective Copper-Catalyzed Arylation-Driven Semipinacol Rearrangement of Tertiary Allylic Alcohols with Diaryliodonium Salts

scientific article published on 22 June 2017

Enantioselective Cu-Catalyzed Arylation of Secondary Phosphine Oxides with Diaryliodonium Salts toward the Synthesis of P-Chiral Phosphines

scientific article published on 30 September 2016

Enantioselective Organocatalytic Cyclopropanation via Ammonium Ylides

scholarly article by Charles D. Papageorgiou et al published 6 September 2004 in Angewandte Chemie International Edition

Enantioselective and Regiodivergent Copper-Catalyzed Electrophilic Arylation of Allylic Amides with Diaryliodonium Salts

scientific article

Enantioselective organocatalysis

scientific article

Enantioselective α-arylation of N-acyloxazolidinones with copper(II)-bisoxazoline catalysts and diaryliodonium salts

scientific article published on 17 August 2011

Gram-scale enantioselective formal synthesis of morphine through an ortho-para oxidative phenolic coupling strategy

scientific article published on 6 October 2014

Highlights from the 38th ESF/EUCHEM Conference on Stereochemistry, Bürgenstock, Switzerland, April/May 2003

scholarly article by Matthew J Gaunt & Guy C Lloyd-Jones published 1 September 2003 in Chemical Communications

Ligand-Enabled Catalytic C-H Arylation of Aliphatic Amines by a Four-Membered-Ring Cyclopalladation Pathway.

scientific article published on 5 November 2015

Ligand-assisted palladium-catalyzed C-H alkenylation of aliphatic amines for the synthesis of functionalized pyrrolidines

scientific article published on 23 February 2017

Mechanistic Insights into the Palladium-Catalyzed Aziridination of Aliphatic Amines by C-H Activation

scientific article published on 14 August 2015

Mechanistic investigation into the C(sp3)-H acetoxylation of morpholinones

scientific article published on 01 October 2018

Metals are not the only catalysts ⬇️

scientific article published on February 10, 2011

Mild aerobic oxidative palladium (II) catalyzed C-H bond functionalization: regioselective and switchable C-H alkenylation and annulation of pyrroles

scientific article published in March 2006

Multicomponent linchpin couplings. Reaction of dithiane anions with terminal epoxides, epichlorohydrin, and vinyl epoxides: efficient, rapid, and stereocontrolled assembly of advanced fragments for complex molecule synthesis

scientific article published in November 2003

Multicomponent synthesis of tertiary alkylamines by photocatalytic olefin-hydroaminoalkylation

scientific article published in Nature

New Strategies for the Transition-Metal Catalyzed Synthesis of Aliphatic Amines

scientific article published on 17 February 2020

Novel anti-Markovnikov regioselectivity in the Wacker reaction of styrenes

scientific article

Organic chemistry: Nickel steps towards selectivity

scientific article published in Nature

Organic-Catalyst-Mediated Cyclopropanation Reaction

article

Organocatalytic C-H bond arylation of aldehydes to bis-heteroaryl ketones

scientific article published on 27 February 2013

Organocatalytic sigmatropic reactions: development of a [2,3] Wittig rearrangement through secondary amine catalysis

scientific article published on 01 March 2006

Oxidative Dearomatization and Organocatalytic Desymmetrization

Oxidative Pd(II)-catalyzed C-H bond amination to carbazole at ambient temperature

scientific article

Palladium(II)-catalyzed C-H bond arylation of electron-deficient arenes at room temperature

scientific article published on 22 December 2010

Palladium-Catalyzed Enantioselective C-H Activation of Aliphatic Amines Using Chiral Anionic BINOL-Phosphoric Acid Ligands.

scientific article published on 9 January 2017

Palladium-catalysed C–H activation of aliphatic amines to give strained nitrogen heterocycles

scientific article published in Nature

Palladium-catalyzed intermolecular alkenylation of indoles by solvent-controlled regioselective C-H functionalization

scientific article published on 01 May 2005

Pd-catalyzed C-H bond functionalization on the indole and pyrrole nucleus.

scientific article published on January 2010

Rapid Generation of Complex Molecular Architectures by a Catalytic Enantioselective Dearomatization Strategy

scientific article published on 9 November 2015

Rapid Syntheses of (-)-FR901483 and (+)-TAN1251C Enabled by Complexity-Generating Photocatalytic Olefin Hydroaminoalkylation

scientific article published on 30 December 2019

Recent developments in natural product synthesis using metal-catalysed C-H bond functionalisation

scientific article published on 10 March 2011

Recent developments in the use of catalytic asymmetric ammonium enolates in chemical synthesis

scientific article published on December 2007

Selective Chemical Functionalization at N6-Methyladenosine Residues in DNA Enabled by Visible-Light-Mediated Photoredox Catalysis

scientific article published on 11 December 2020

Selective Palladium(II)-Catalyzed Carbonylation of Methylene β-C-H Bonds in Aliphatic Amines

scientific article published on 14 July 2017

Selective Reductive Elimination at Alkyl Pd(IV) via Dissociative Ligand Ionization Enables Catalytic C(sp3)-H Amination to Azetidines

scientific article published on 30 January 2018

Streamlined Synthesis of C(sp3)-Rich N-Heterospirocycles Enabled by Visible-Light-Mediated Photocatalysis

scientific article published on 17 May 2019

Synthesis and Reactivity of Stable Alkyl-Pd(IV) Complexes Relevant to Monodentate N-directed C(sp3)-H Functionalization Processes

scientific article published on 22 July 2020

Synthesis of rhazinicine by a metal-catalyzed C-H bond functionalization strategy

scientific article published on 01 January 2008

Synthesis of the C-1−C-28 ABCD Unit of Spongistatin 1

scientific article published in 2003

Synthesis of the EF Fragment of Spongistatin 1

The total synthesis of K-252c (staurosporinone) via a sequential C-H functionalisation strategy

scientific article

The α-tertiary amine motif drives remarkable selectivity for Pd-catalyzed carbonylation of β-methylene C-H bonds.

scientific article

Total Synthesis of Spongistatin 1: A Synthetic Strategy Exploiting Its Latent Pseudo-Symmetry

scholarly article by Matthew Ball et al published 26 August 2005 in Angewandte Chemie International Edition

List of works by Matthew J. Gaunt

A General Carbonyl Alkylative Amination Process for Tertiary Amine Synthesis

A Highly Para-Selective Copper(II)-Catalyzed Direct Arylation of Aniline and Phenol Derivatives

A Practical and Efficient Synthesis of the C-16−C-28 Spiroketal Fragment (CD) of the Spongistatins

A concise and scalable strategy for the total synthesis of dictyodendrin B based on sequential C-H functionalization

A counteranion triggered arylation strategy using diaryliodonium fluorides.

A general carbonyl alkylative amination for tertiary amine synthesis

A general catalytic β-C-H carbonylation of aliphatic amines to β-lactams

A meta-selective copper-catalyzed C-H bond arylation

A protein functionalization platform based on selective reactions at methionine residues

A steric tethering approach enables palladium-catalysed C-H activation of primary amino alcohols.

Addition of Dithiols to Bis-Ynones: Development of a Versatile Platform for the Synthesis of Polyketide Natural Products

An Intramolecular Organocatalytic Cyclopropanation Reaction

An enantioselective organocatalytic oxidative dearomatization strategy

Callipeltosides A, B and C: Total Syntheses and Structural Confirmation

Carboxylate-Assisted Oxidative Addition to Aminoalkyl PdII Complexes: C(sp3 )-H Arylation of Alkylamines by Distinct PdII /PdIV Pathway

Catalytic C(sp3)-H bond activation in tertiary alkylamines

Chemical synthesis of Aspidosperma alkaloids inspired by the reverse of the biosynthesis of the rhazinilam family of natural products

Cobalt-catalysed C-H carbonylative cyclisation of aliphatic amides

Continuous-Flow Synthesis and Derivatization of Aziridines through Palladium-Catalyzed C(sp(3) )-H Activation.

Convenient preparation of trans-arylalkenes via palladium(II)-catalyzed isomerization of cis-arylalkenes

Copper(II)-catalyzed meta-selective direct arylation of α-aryl carbonyl compounds

Copper-Catalyzed Oxy-Alkenylation of Homoallylic Alcohols to Generate Functional syn-1,3-Diol Derivatives

Copper-catalyzed alkene arylation with diaryliodonium salts

Copper-catalyzed arylative Meyer-Schuster rearrangement of propargylic alcohols to complex enones using diaryliodonium salts

Copper-catalyzed carboarylation of alkynes via vinyl cations

Copper-catalyzed electrophilic carbofunctionalization of alkynes to highly functionalized tetrasubstituted alkenes

Copper-catalyzed intramolecular electrophilic carbofunctionalization of allylic amides

Correction to "Palladium-Catalyzed Enantioselective C-H Activation of Aliphatic Amines Using Chiral Anionic BINOL-Phosphoric Acid Ligands".

Cu(II)-catalyzed direct and site-selective arylation of indoles under mild conditions

Cu-Catalyzed Cascades to Carbocycles: Union of Diaryliodonium Salts with Alkenes or Alkynes Exploiting Remote Carbocations

Development of β-keto 1,3-dithianes as versatile intermediates for organic synthesis

Diastereoselective C-H carbonylative annulation of aliphatic amines: a rapid route to functionalized γ-lactams

Dithiane additions to vinyl epoxides: steric control over the SN2 and SN2' manifolds

Double Conjugate Addition of Dithiols to Propargylic Carbonyl Systems To Generate Protected 1,3-Dicarbonyl Compounds

Enantioselective Catalytic Intramolecular Cyclopropanation using Modified Cinchona Alkaloid Organocatalysts

Enantioselective Copper-Catalyzed Arylation-Driven Semipinacol Rearrangement of Tertiary Allylic Alcohols with Diaryliodonium Salts

Enantioselective Cu-Catalyzed Arylation of Secondary Phosphine Oxides with Diaryliodonium Salts toward the Synthesis of P-Chiral Phosphines

Enantioselective Organocatalytic Cyclopropanation via Ammonium Ylides

Enantioselective and Regiodivergent Copper-Catalyzed Electrophilic Arylation of Allylic Amides with Diaryliodonium Salts

Enantioselective organocatalysis

Enantioselective α-arylation of N-acyloxazolidinones with copper(II)-bisoxazoline catalysts and diaryliodonium salts

Gram-scale enantioselective formal synthesis of morphine through an ortho-para oxidative phenolic coupling strategy

Highlights from the 38th ESF/EUCHEM Conference on Stereochemistry, Bürgenstock, Switzerland, April/May 2003

Ligand-Enabled Catalytic C-H Arylation of Aliphatic Amines by a Four-Membered-Ring Cyclopalladation Pathway.

Ligand-assisted palladium-catalyzed C-H alkenylation of aliphatic amines for the synthesis of functionalized pyrrolidines

Mechanistic Insights into the Palladium-Catalyzed Aziridination of Aliphatic Amines by C-H Activation

Mechanistic investigation into the C(sp3)-H acetoxylation of morpholinones

Metals are not the only catalysts ⬇️

Mild aerobic oxidative palladium (II) catalyzed C-H bond functionalization: regioselective and switchable C-H alkenylation and annulation of pyrroles

Multicomponent linchpin couplings. Reaction of dithiane anions with terminal epoxides, epichlorohydrin, and vinyl epoxides: efficient, rapid, and stereocontrolled assembly of advanced fragments for complex molecule synthesis

Multicomponent synthesis of tertiary alkylamines by photocatalytic olefin-hydroaminoalkylation

New Strategies for the Transition-Metal Catalyzed Synthesis of Aliphatic Amines

Novel anti-Markovnikov regioselectivity in the Wacker reaction of styrenes

Organic chemistry: Nickel steps towards selectivity

Organic-Catalyst-Mediated Cyclopropanation Reaction

Organocatalytic C-H bond arylation of aldehydes to bis-heteroaryl ketones

Organocatalytic sigmatropic reactions: development of a [2,3] Wittig rearrangement through secondary amine catalysis

Oxidative Dearomatization and Organocatalytic Desymmetrization

Oxidative Pd(II)-catalyzed C-H bond amination to carbazole at ambient temperature

Palladium(II)-catalyzed C-H bond arylation of electron-deficient arenes at room temperature

Palladium-Catalyzed Enantioselective C-H Activation of Aliphatic Amines Using Chiral Anionic BINOL-Phosphoric Acid Ligands.

Palladium-catalysed C–H activation of aliphatic amines to give strained nitrogen heterocycles

Palladium-catalyzed intermolecular alkenylation of indoles by solvent-controlled regioselective C-H functionalization

Pd-catalyzed C-H bond functionalization on the indole and pyrrole nucleus.

Rapid Generation of Complex Molecular Architectures by a Catalytic Enantioselective Dearomatization Strategy

Rapid Generation of Complex Molecular Architectures by a Catalytic Enantioselective Dearomatization Strategy

Rapid Syntheses of (-)-FR901483 and (+)-TAN1251C Enabled by Complexity-Generating Photocatalytic Olefin Hydroaminoalkylation

Recent developments in natural product synthesis using metal-catalysed C-H bond functionalisation

Recent developments in the use of catalytic asymmetric ammonium enolates in chemical synthesis

Selective Chemical Functionalization at N6-Methyladenosine Residues in DNA Enabled by Visible-Light-Mediated Photoredox Catalysis

Selective Palladium(II)-Catalyzed Carbonylation of Methylene β-C-H Bonds in Aliphatic Amines

Selective Reductive Elimination at Alkyl Pd(IV) via Dissociative Ligand Ionization Enables Catalytic C(sp3)-H Amination to Azetidines

Streamlined Synthesis of C(sp3)-Rich N-Heterospirocycles Enabled by Visible-Light-Mediated Photocatalysis

Synthesis and Reactivity of Stable Alkyl-Pd(IV) Complexes Relevant to Monodentate N-directed C(sp3)-H Functionalization Processes

Synthesis of rhazinicine by a metal-catalyzed C-H bond functionalization strategy

Synthesis of the C-1−C-28 ABCD Unit of Spongistatin 1

Synthesis of the EF Fragment of Spongistatin 1

The total synthesis of K-252c (staurosporinone) via a sequential C-H functionalisation strategy

The α-tertiary amine motif drives remarkable selectivity for Pd-catalyzed carbonylation of β-methylene C-H bonds.