List of works - Marie-Noëlle Collomb

A Fully Delocalized Mixed-Valence Bis-μ(Thiolato) Dicopper Complex: A Structural and Functional Model of the Biological CuA Center

article

A bio-inspired switch based on cobalt(II) disulfide/cobalt(III) thiolate interconversion.

scientific article published on 9 April 2014

A combined high-field EPR and quantum chemical study on a weakly ferromagnetically coupled dinuclear Mn(iii) complex. A complete analysis of the EPR spectrum beyond the strong coupling limit

A computational mechanistic investigation of hydrogen production in water using the [Rh(III)(dmbpy)2Cl2](+)/[Ru(II)(bpy)3](2+)/ascorbic acid photocatalytic system.

scientific article published on April 2015

A copper thiolate centre for electron transfer: mononuclear vs. dinuclear complexes

scientific article published on 08 February 2012

A high-frequency and high-field EPR study of new azide and fluoride mononuclear Mn(III) complexes

scientific article published in October 2003

A multifrequency high-field EPR (9–285GHz) investigation of a series of dichloride mononuclear penta-coordinated Mn(II) complexes

An easy electrochemical procedure for tailoring thin films containing the [Fe(bpy)2(CH3CN)2]2+ and/or [Fe(bpy)3]2+-like cores (bpy=2,2′-bipyridine). Application to the design of a modified electrode with a supramolecular structure

article by Karine Gorgy et al published December 2001 in Electrochemistry Communications

An efficient Ru(II) -Rh(III) -Ru(II) polypyridyl photocatalyst for visible-light-driven hydrogen production in aqueous solution

scientific article published on 02 January 2014

An unusual stable mononuclear Mn(III) bis-terpyridine complex exhibiting Jahn-Teller compression: electrochemical synthesis, physical characterisation and theoretical study

scientific article

Binuclear manganese compounds of potential biological significance. 1. Syntheses and structural, magnetic, and electrochemical properties of dimanganese(II) and -(II,III) complexes of a bridging unsymmetrical phenolate ligand.

scientific article

Ca K-edge XAS as a probe of calcium centers in complex systems.

scientific article published on 10 December 2014

Calcium and heterometallic manganese-calcium complexes supported by tripodal pyridine-carboxylate ligands: structural, EPR and theoretical investigations

scientific article published in July 2015

Cobalt(II) Pentaaza-Macrocyclic Schiff Base Complex as Catalyst for Light-Driven Hydrogen Evolution in Water: Electrochemical Generation and Theoretical Investigation of the One-Electron Reduced Species

scientific article published on 25 June 2019

Cobalt(III) tetraaza-macrocyclic complexes as efficient catalyst for photoinduced hydrogen production in water: Theoretical investigation of the electronic structure of the reduced species and mechanistic insight.

scientific article

Definition of Magneto-Structural Correlations for the MnIIIon

Di(micro-oxo) binuclear manganese(III,IV) poly(bipyridyl) complexes bearing four ruthenium(II) photoactive units: synthesis, characterization, and photoinduced electron-transfer properties

scientific article published on 13 February 2007

EPR and magnetic properties of [Mn(μ-Cl)2(bpy)]n: An unusual ferromagnetic interaction in a Mn(II) chloro-bridged polymer

Efficient and limiting reactions in aqueous light-induced hydrogen evolution systems using molecular catalysts and quantum dots.

scientific article published on 14 May 2014

Efficient photocatalytic hydrogen production in water using a cobalt(III) tetraaza-macrocyclic catalyst: electrochemical generation of the low-valent Co(I) species and its reactivity toward proton reduction

scientific article published on 01 October 2013

Electrochemical Generation and Spectroscopic Characterization of the Key Rhodium(III) Hydride Intermediates of Rhodium Poly(bipyridyl) H2-Evolving Catalysts

scientific article published on 21 August 2018

Electrochemical and chemical formation of [Mn4(IV)O5(terpy)4(H2O)2]6+, in relation with the photosystem II oxygen-evolving center model [Mn2(III,IV)O2(terpy)2(H2O)2]3+

scientific article published on 01 October 2005

Electrochemical formation of bi- versus tetranuclear μ-oxo terpyridine manganese complexes in CH3CN. Influence of the terpyridine substituents

Excited-state spectroscopic investigations of multinuclear complexes based on [Ru(bpy)3](2+) moieties connected to 2,2'-bipyridine and 2,2';6',2''-terpyridine ligands.

scientific article

Experimental and computational investigation of thiolate alkylation in Ni(II) and Zn(II) complexes: role of the metal on the sulfur nucleophilicity

scientific article

Factors influencing mononuclear versus multinuclear coordination in a series of potentially hexadentate acyclic N6 ligands: the roles of flexibility and chelate ring size

scientific article published on 16 September 2011

High-field EPR investigation of a series of mononuclear Mn(II) complexes doped into Zn(II) hosts

High-spin chloro mononuclear MnIII complexes: a multifrequency high-field EPR study

scientific article published in March 2005

How Accurately Can Extended X-ray Absorption Spectra Be Predicted from First Principles? Implications for Modeling the Oxygen-Evolving Complex in Photosystem II.

scientific article published on 9 September 2015

Influence of mixed thiolate/thioether versus dithiolate coordination on the accessibility of the uncommon +I and +III oxidation states for the nickel ion: an experimental and computational study

scientific article

Intramolecular Electron Transfers Thwart Bistability in a Pentanuclear Iron Complex

scientific article published on 2 June 2016

Investigation of a Neat versus Magnetically Diluted Powdered Mononuclear MnII Complex by High-Field and High-Frequency EPR Spectroscopy

Investigation of the Zero-Field Splitting in Six- and Seven-Coordinate Mononuclear MnII Complexes with N/O-Based Ligands by Combining EPR Spectroscopy and Quantum Chemistry

scholarly article by Jordi Rich et al published 22 June 2010 in European Journal of Inorganic Chemistry

Long-Lived Charge Separated State in NiO-Based p-Type Dye-Sensitized Solar Cells with Simple Cyclometalated Iridium Complexes

scientific article published on 16 June 2014

Manganese K-Edge X-Ray Absorption Spectroscopy as a Probe of the Metal–Ligand Interactions in Coordination Compounds

Manganese Kβ X-ray emission spectroscopy as a probe of metal-ligand interactions

scientific article published on August 2011

Mn(II) complexes containing the polypyridylic chiral ligand (-)-pinene[5,6]bipyridine. Catalysts for oxidation reactions

scientific article published on 19 August 2009

Mononuclear Mn(III) and Mn(IV) bis-terpyridine complexes: electrochemical formation and spectroscopic characterizations

scientific article

Multifrequency high-field EPR investigation of a mononuclear manganese(iv) complex

Multireversible Redox Processes in Pentanuclear Bis(Triple-Helical) Manganese Complexes Featuring an Oxo-Centered triangular {MnII2MnIII(μ3-O)}5+or {MnIIMnIII2(μ3-O)}6+Core Wrapped by Two {MnII2(bpp)3}−

scientific article published on 03 August 2011

New linear high-valent tetranuclear manganese-oxo cluster relevant to the oxygen-evolving complex of photosystem II with oxo, hydroxo, and aqua coordinated to a single Mn(IV).

scientific article published in December 2005

Origin of the zero-field splitting in mononuclear octahedral dihalide MnII complexes: an investigation by multifrequency high-field electron paramagnetic resonance and density functional theory

scientific article

Photoredox vs. energy transfer in a Ru(II)-Fe(II) supramolecular complex built with an heteroditopic bipyridine-terpyridine ligand

scientific article published on 23 November 2007

Redox-Induced μ-Acetato and μ-Oxo Core Interconversions in Dinuclear Manganese Tris(2-methylpyridyl)amine (tpa) Complexes: Isolation and Characterization of [Mn2III(μ-O)(μ-O2CCH3)(tpa)2]3+

Reversible apical coordination of imidazole between the Ni(III) and Ni(II) oxidation states of a dithiolate complex: a process related to the Ni superoxide dismutase

scientific article published in July 2010

Seven Reversible Redox Processes in a Self-Assembled Cobalt Pentanuclear Bis(triple-stranded helicate): Structural, Spectroscopic, and Magnetic Characterizations in the CoICoII4, CoII5, and CoII3CoIII2 Redox States

scientific article published on 24 June 2020

Structural characterization and electronic properties determination by high-field and high-frequency EPR of a series of five-coordinated Mn(II) complexes

scientific article published in October 2004

Structural, spectroscopic and redox properties of a mononuclear CoII thiolate complex – the reactivity toward S-alkylation: an experimental and theoretical study

scientific article published on 01 October 2012

Synthesis and structural characterization of five-, six-, and seven-coordinate mononuclear manganese(II) complexes with N-tridentate ligands

article published in 2004

Synthesis, Characterization, and Photocatalytic H2-Evolving Activity of a Family of [Co(N4Py)(X)](n+) Complexes in Aqueous Solution.

scientific article

Synthesis, structure, spectroscopy and reactivity of new heterotrinuclear water oxidation catalysts

article published in 2016

Systematic Theoretical Study of the Zero-Field Splitting in Coordination Complexes of Mn(III). Density Functional Theory versus Multireference Wave Function Approaches

Tetranuclear Polypyridyl Complexes of RuII and FeII: Synthesis, Electrochemical, Photophysical and Photochemical Behaviour

Trinuclear terpyridine frustrated spin system with a Mn(IV)3O4 core: synthesis, physical characterization, and quantum chemical modeling of its magnetic properties

scientific article published in November 2009

Two new terpyridine dimanganese complexes: a manganese(III,III) complex with a single unsupported oxo bridge and a manganese(III,IV) complex with a dioxo bridge. Synthesis, structure, and redox properties.

scientific article published in March 2002

Understanding the Zero-Field Splitting of Mononuclear Manganese(II) Complexes from Combined EPR Spectroscopy and Quantum Chemistry

scholarly article by Carole Duboc et al published 14 November 2009 in Applied Magnetic Resonance

Visible-Light-Driven Generation of High-Valent Oxo-Bridged Dinuclear and Tetranuclear Manganese Terpyridine Entities Linked to Photoactive Ruthenium Units of Relevance to Photosystem II

scholarly article by Carmen E Castillo et al published 19 September 2012 in European Journal of Inorganic Chemistry

[Rh(III)(dmbpy)2Cl2]+ as a highly efficient catalyst for visible-light-driven hydrogen production in pure water: comparison with other rhodium catalysts.

scientific article

List of works by Marie-Noëlle Collomb

A Fully Delocalized Mixed-Valence Bis-μ(Thiolato) Dicopper Complex: A Structural and Functional Model of the Biological CuA Center

A bio-inspired switch based on cobalt(II) disulfide/cobalt(III) thiolate interconversion.

A combined high-field EPR and quantum chemical study on a weakly ferromagnetically coupled dinuclear Mn(iii) complex. A complete analysis of the EPR spectrum beyond the strong coupling limit

A computational mechanistic investigation of hydrogen production in water using the [Rh(III)(dmbpy)2Cl2](+)/[Ru(II)(bpy)3](2+)/ascorbic acid photocatalytic system.

A copper thiolate centre for electron transfer: mononuclear vs. dinuclear complexes

A high-frequency and high-field EPR study of new azide and fluoride mononuclear Mn(III) complexes

A multifrequency high-field EPR (9–285GHz) investigation of a series of dichloride mononuclear penta-coordinated Mn(II) complexes

An easy electrochemical procedure for tailoring thin films containing the [Fe(bpy)2(CH3CN)2]2+ and/or [Fe(bpy)3]2+-like cores (bpy=2,2′-bipyridine). Application to the design of a modified electrode with a supramolecular structure

An efficient Ru(II) -Rh(III) -Ru(II) polypyridyl photocatalyst for visible-light-driven hydrogen production in aqueous solution

An unusual stable mononuclear Mn(III) bis-terpyridine complex exhibiting Jahn-Teller compression: electrochemical synthesis, physical characterisation and theoretical study

Binuclear manganese compounds of potential biological significance. 1. Syntheses and structural, magnetic, and electrochemical properties of dimanganese(II) and -(II,III) complexes of a bridging unsymmetrical phenolate ligand.

Ca K-edge XAS as a probe of calcium centers in complex systems.

Calcium and heterometallic manganese-calcium complexes supported by tripodal pyridine-carboxylate ligands: structural, EPR and theoretical investigations

Cobalt(II) Pentaaza-Macrocyclic Schiff Base Complex as Catalyst for Light-Driven Hydrogen Evolution in Water: Electrochemical Generation and Theoretical Investigation of the One-Electron Reduced Species

Cobalt(III) tetraaza-macrocyclic complexes as efficient catalyst for photoinduced hydrogen production in water: Theoretical investigation of the electronic structure of the reduced species and mechanistic insight.

Definition of Magneto-Structural Correlations for the MnIIIon

Di(micro-oxo) binuclear manganese(III,IV) poly(bipyridyl) complexes bearing four ruthenium(II) photoactive units: synthesis, characterization, and photoinduced electron-transfer properties

EPR and magnetic properties of [Mn(μ-Cl)2(bpy)]n: An unusual ferromagnetic interaction in a Mn(II) chloro-bridged polymer

Efficient and limiting reactions in aqueous light-induced hydrogen evolution systems using molecular catalysts and quantum dots.

Efficient photocatalytic hydrogen production in water using a cobalt(III) tetraaza-macrocyclic catalyst: electrochemical generation of the low-valent Co(I) species and its reactivity toward proton reduction

Electrochemical Generation and Spectroscopic Characterization of the Key Rhodium(III) Hydride Intermediates of Rhodium Poly(bipyridyl) H2-Evolving Catalysts

Electrochemical and chemical formation of [Mn4(IV)O5(terpy)4(H2O)2]6+, in relation with the photosystem II oxygen-evolving center model [Mn2(III,IV)O2(terpy)2(H2O)2]3+

Electrochemical formation of bi- versus tetranuclear μ-oxo terpyridine manganese complexes in CH3CN. Influence of the terpyridine substituents

Excited-state spectroscopic investigations of multinuclear complexes based on [Ru(bpy)3](2+) moieties connected to 2,2'-bipyridine and 2,2';6',2''-terpyridine ligands.

Experimental and computational investigation of thiolate alkylation in Ni(II) and Zn(II) complexes: role of the metal on the sulfur nucleophilicity

Factors influencing mononuclear versus multinuclear coordination in a series of potentially hexadentate acyclic N6 ligands: the roles of flexibility and chelate ring size

High-field EPR investigation of a series of mononuclear Mn(II) complexes doped into Zn(II) hosts

High-spin chloro mononuclear MnIII complexes: a multifrequency high-field EPR study

How Accurately Can Extended X-ray Absorption Spectra Be Predicted from First Principles? Implications for Modeling the Oxygen-Evolving Complex in Photosystem II.

Influence of mixed thiolate/thioether versus dithiolate coordination on the accessibility of the uncommon +I and +III oxidation states for the nickel ion: an experimental and computational study

Intramolecular Electron Transfers Thwart Bistability in a Pentanuclear Iron Complex

Investigation of a Neat versus Magnetically Diluted Powdered Mononuclear MnII Complex by High-Field and High-Frequency EPR Spectroscopy

Investigation of the Zero-Field Splitting in Six- and Seven-Coordinate Mononuclear MnII Complexes with N/O-Based Ligands by Combining EPR Spectroscopy and Quantum Chemistry

Long-Lived Charge Separated State in NiO-Based p-Type Dye-Sensitized Solar Cells with Simple Cyclometalated Iridium Complexes

Manganese K-Edge X-Ray Absorption Spectroscopy as a Probe of the Metal–Ligand Interactions in Coordination Compounds

Manganese Kβ X-ray emission spectroscopy as a probe of metal-ligand interactions

Mn(II) complexes containing the polypyridylic chiral ligand (-)-pinene[5,6]bipyridine. Catalysts for oxidation reactions

Mononuclear Mn(III) and Mn(IV) bis-terpyridine complexes: electrochemical formation and spectroscopic characterizations

Multifrequency high-field EPR investigation of a mononuclear manganese(iv) complex

Multireversible Redox Processes in Pentanuclear Bis(Triple-Helical) Manganese Complexes Featuring an Oxo-Centered triangular {MnII2MnIII(μ3-O)}5+or {MnIIMnIII2(μ3-O)}6+Core Wrapped by Two {MnII2(bpp)3}−

New linear high-valent tetranuclear manganese-oxo cluster relevant to the oxygen-evolving complex of photosystem II with oxo, hydroxo, and aqua coordinated to a single Mn(IV).

Origin of the zero-field splitting in mononuclear octahedral dihalide MnII complexes: an investigation by multifrequency high-field electron paramagnetic resonance and density functional theory

Photoredox vs. energy transfer in a Ru(II)-Fe(II) supramolecular complex built with an heteroditopic bipyridine-terpyridine ligand

Redox-Induced μ-Acetato and μ-Oxo Core Interconversions in Dinuclear Manganese Tris(2-methylpyridyl)amine (tpa) Complexes: Isolation and Characterization of [Mn2III(μ-O)(μ-O2CCH3)(tpa)2]3+

Reversible apical coordination of imidazole between the Ni(III) and Ni(II) oxidation states of a dithiolate complex: a process related to the Ni superoxide dismutase

Seven Reversible Redox Processes in a Self-Assembled Cobalt Pentanuclear Bis(triple-stranded helicate): Structural, Spectroscopic, and Magnetic Characterizations in the CoICoII4, CoII5, and CoII3CoIII2 Redox States

Structural characterization and electronic properties determination by high-field and high-frequency EPR of a series of five-coordinated Mn(II) complexes

Structural, spectroscopic and redox properties of a mononuclear CoII thiolate complex – the reactivity toward S-alkylation: an experimental and theoretical study

Synthesis and structural characterization of five-, six-, and seven-coordinate mononuclear manganese(II) complexes with N-tridentate ligands

Synthesis, Characterization, and Photocatalytic H2-Evolving Activity of a Family of [Co(N4Py)(X)](n+) Complexes in Aqueous Solution.

Synthesis, structure, spectroscopy and reactivity of new heterotrinuclear water oxidation catalysts

Systematic Theoretical Study of the Zero-Field Splitting in Coordination Complexes of Mn(III). Density Functional Theory versus Multireference Wave Function Approaches

Tetranuclear Polypyridyl Complexes of RuII and FeII: Synthesis, Electrochemical, Photophysical and Photochemical Behaviour

Trinuclear terpyridine frustrated spin system with a Mn(IV)3O4 core: synthesis, physical characterization, and quantum chemical modeling of its magnetic properties

Two new terpyridine dimanganese complexes: a manganese(III,III) complex with a single unsupported oxo bridge and a manganese(III,IV) complex with a dioxo bridge. Synthesis, structure, and redox properties.

Understanding the Zero-Field Splitting of Mononuclear Manganese(II) Complexes from Combined EPR Spectroscopy and Quantum Chemistry

Visible-Light-Driven Generation of High-Valent Oxo-Bridged Dinuclear and Tetranuclear Manganese Terpyridine Entities Linked to Photoactive Ruthenium Units of Relevance to Photosystem II

[Rh(III)(dmbpy)2Cl2]+ as a highly efficient catalyst for visible-light-driven hydrogen production in pure water: comparison with other rhodium catalysts.