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List of works by Jacques Maddaluno

"On water" reaction of deactivated anilines with 4-methoxy-3-buten-2-one, an effective butynone surrogate

scientific article published on 18 November 2016

1-(Phenylthio)- and 1-(phenylsulfoxide)-4-alkoxy-butadienes, a new class of chiral dienes

1H Pure Shift DOSY: a handy tool to evaluate the aggregation and solvation of organolithium derivatives

article by G. Hamdoun et al published 2014 in Chemical Communications

2D 7Li Ultrafast CT-COSY: a new tool for the rapid measurement of tiny homonuclear lithium scalar couplings

scientific article published on 5 December 2016

3-Aminopyrrolidine lithium amide in enantioselective addition of organolithium compounds onto aromatic aldehydes

article

3-Aminopyrrolidine lithium amides as chiral ligands for alkyllithium derivatives: Synthesis, NMR analysis, and computational study of their mixed aggregates

article

6Li NMR Study of the Equilibrium between Methyllithium andn-Butyllithium in THF. Influence of a Third Partner, a Chiral Lithium Amide

A Combined 1 H/6 Li NMR DOSY Strategy Finally Uncovers the Structure of Isopropyllithium in THF.

scientific article published on 13 July 2017

A Concise Route to α′-Methoxy-γ-pyrones and Verticipyrone Based Upon the Desymmetrization of α,α′-Dimethoxy-γ-pyrone

scientific article published on 01 October 2010

A DFT Theoretical Analysis of Aldehyde Condensation Pathways onto Methyllithium, Lithium Dimethylamide, and Their Aggregates

article

A DFT theoretical study of the condensation of aggregates of sp2 organolithium compounds on formaldehyde

scientific article published in September 2005

A Domino Knoevenagel/1,6-Heteroelectrocyclization Sequence to Access Phosphono-2H-thiopyrans

A Lithium Amide Protected Against Protonation in the Gas Phase: Unexpected Effect of LiCl

scientific article published on 4 June 2015

A NMR and theoretical study of the aggregates between alkyllithium and chiral lithium amides: control of the topology through a single asymmetric center

scientific article

A case of anti carbolithiation of alkynes resulting from intramolecular lithium coordination

scientific article published in January 2008

A convenient route to 1-benzyl 3-aminopyrrolidine and 3-aminopiperidine

article published in 2001

A quantum mechanical study on carbocation formation energy in (poly)ethylenic compounds

Access to Silylated Pyrazole Derivatives by Palladium-Catalyzed C-H Activation of a TMS group

scientific article

Access to Tri- and Tetracyclic Structures by Thermally Promoted and High-Pressure-Promoted [4+2] Cycloadditions of 2-, 3- or 4-Vinyl-Substituted Binuclear Heterocycles

Accurate measurement of effective Li-Li scalar coupling constants: the NMR missing link for alkyllithium aggregates

scientific article published on 27 November 2020

Adamantyl aziridines via aza-Michael initiated ring closure (aza-MIRC) reaction

Advances in the Chemistry of Chiral Lithium Amides

Alkoxy-3 acroleines : equivalents du dialdehyde malonique

Alkyllithium Mixed Aggregates: Dynamic Behavior and Comprehensive Analysis of NMR 2J7Li–7Li Spin–Spin Coupling

An Organocatalytic Access to Spiro[4.5]decanes and Spiro[4.6]undecanes Containing Aminolactones and 3-Aminopyrrolidines

An ab initio study of the interaction of DNA fragments with methyllithium

article

An organocatalytic route to 2-heteroarylmethylene decorated N-arylpyrroles.

scientific article published on 24 July 2013

Anionic access to silylated and germylated binuclear heterocycles

scientific article published on 3 July 2014

Are sp lithiated carbons more nucleophilic than sp2 or sp3 ones? A comparative DFT study of the condensation of propynyllithium aggregates on formaldehyde

scientific article published in March 2010

Aza-Michael access to fluoroalkylidene analogues of biomolecules

scientific article

Base or nucleophile? DFT finally elucidates the origin of the selectivity between the competitive reactions triggered by MeLi or LDA on propanal

Benefits of a Dual Chemical and Physical Activation: Direct aza-Michael Addition of Anilines Promoted by Solvent Effect under High Pressure

article

Carbolithiation of Chloro-Substituted Alkynes: A New Access to Vinyl Carbenoids

article published in 2014

Catalytic enantioselective nucleophilic addition of organolithium derivatives: pitfalls and opportunities

article

Central alpha 1 adrenoceptor subtypes in narcolepsy-cataplexy: a disorder of REM sleep

scientific article published in June 1989

Chiral 3-aminopyrrolidines as a rigid diamino scaffold for organocatalysis and organometallic chemistry

Chiral Lithium Amides: Tuning Asymmetric Synthesis on the Basis of Structural Parameters

scientific article published on 20 December 2016

Combining high pressure and catalysis: pinacol- or catecholborane hydroboration of functionalized olefins†

article

Compact transition state and asymmetric induction: a theoretical ab initio SCF-CI study of enamine addition to carbonyl compounds

article

Conjugate-elimination on unsaturated acetals: A one-step route to functionalized 1,3-dienes

article by Jacques Maddaluno et al published November 1995 in Tetrahedron Letters

Conjugated elimination versus [1,2]-Wittig rearrangement of unsaturated diox(ol)anes

Convergent Asymmetric Synthesis of (+)-Aureothin Employing an Oxygenase-Mediated Resolution Step

scientific article published on 16 July 2012

Desymmetrization of a meso-allylic acetal by enantioselective conjugate elimination

scientific article published on 7 February 2008

Diastereoselective construction of substituted tetrahydropyrans using an intramolecular oxy-Michael strategy

Diastereoselective organocatalytic Mannich access to azacyclic system en route to lyconadin A

Diastereoselective syntheses of new analogues of the farnesyltransferase inhibitor RPR 130401.

scientific article

Diels–Alder Reactions of Symmetrically 1,4-Disubstituted Dienes: Theoretical Study on the Influence of the Configuration of the Double Bonds on the Regio- and Endoselectivity

Diels–Alder cycloadditions of functionalized (Z)-1-benzylidene-2-methylene cyclohexanes: the beneficial effect of high pressure

Dimerization of Aryl Sulfonates by in situ Generated Nickel(0)

scholarly article by Muriel Durandetti & Jacques Maddaluno published 29 September 2015 in Synlett

Direct Access to Cumbersome Aminated Quaternary Centers by Hyperbaric Aza-Michael Additions

article

Direct Carboxylation of Aryl Tosylates by CO2 Catalyzed by In situ-Generated Ni(0).

scientific article

Direct Syn Addition of Two Silicon Atoms to a C≡C Triple Bond by Si-Si Bond Activation: Access to Reactive Disilylated Olefins

scientific article published on 23 January 2017

Domino alkylation/oxa-Michael of 1,3-cyclohexanediones: Steering the C/O-chemoselectivity to reach tetrahydrobenzofuranones

article

Dynamics of the Lithium Amide/Alkyllithium Interactions: Mixed Dimers and Beyond

article

Effects of high pressure on Friedel-Crafts benzoylation

Efficient Deracemization of Pipecolic Acid Amides through Enantioselective Protonation of Their Lithium Enolates: Insights into the Origin of the Transferred Proton

Efficient Organocatalytic Hetero-Diels-Alder Reactions of Activated Ketones under High Pressure for Direct Access to δ-Lactones¹

Efficient Synthesis of New Phosphono-Substituted Dihydrothiopyrans via Hetero Diels–Alder Reaction, under Thermal and High Pressure Conditions

article published in 2000

Enantioselective Alkynylation of Aldehydes by Mixed Aggregates of 3-Aminopyrrolidine Lithium Amides and Lithium Acetylides

article published in 2015

Enantioselective Conjugate Addition of a Lithium Ester Enolate Catalyzed by Chiral Lithium Amides

article

Enantioselective Hydroxyvinylation with Lithioethenes

Enantioselective conjugate addition of a lithium ester enolate catalyzed by chiral lithium amides: a possible intermediate characterized

scientific article published in May 2009

Enantioselective protonation and alkylation of non-covalent mixed aggregates of chiral 3-aminopyrrolidine lithium amides

Evidence for multiple [3H]prazosin binding sites in canine brain membranes.

scientific article published in May 1989

First substoichiometric version of the catalytic enantioselective addition of an alkyllithium to an aldehyde

article

First-principles molecular dynamics evaluation of thermal effects on the NMR (1)J(Li,C) spin-spin coupling

scientific article published in January 2007

Flexible Total Synthesis of (±)-Aureothin, a Potent Antiproliferative Agent

scientific article published on 23 May 2016

Formal enantioselective synthesis of aplykurodinone-1.

scientific article published on 23 May 2013

Formylation of amines through catalyst- and solvent-free transamidation reaction

Handy access to chiral N,N′-disubstituted 3-aminopyrrolidines

article

Heterocyclic lithium amides as chiral ligands for an enantioselective hydroxyalkylation with n-BuLi

scientific article published on 17 June 2008

Heterocyclization by catalytic carbonickelation of alkynes: a domino sequence involving vinylnickels

High pressure promoted aza-Michael addition of primary and secondary amines to α-substituted acrylates

article

Improved Asymmetric Synthesis of 8-Arylmenthols

Influence of freezer storage time on cerebral biogenic amine and metabolite concentrations and receptor ligand binding characteristics

scientific article published on 01 May 1988

Influence of the Acetylenic Substituent on the Intramolecular Carbolithiation of Alkynes

Influence of the acetylenic substituent on the intramolecular carbolithiation of alkynes: a DFT theoretical study

scientific article published on 16 September 2013

Influence of the correlation, aggregation, and solvation on ab initio computed Li-C, Li-N, and Li-Li NMR coupling constants

scientific article published in February 2003

Intramolecular Carbolithiation of Alkynes:anti Selectivity

Intramolecular Carbolithiation of Heterosubstituted Alkynes: An Experimental and Theoretical Study

Intramolecular Sila-Matteson Rearrangement: A General Access to Silylated Heterocycles

scientific article published in 2012

Intramolecular carbonickelation of alkenes

scientific article published on 12 April 2013

Introduction to chemical warfare agents, relevant simulants and modern neutralisation methods

scientific article published on 19 June 2019

Is the Elimination of Lithium Alkoxide Easier from a Vinyllithium or from an Alkyllithium? A DFT Study of the Aromatization of 3-Vinylidene-2,3-dihydrobenzofurans to Benzofurans

article by Catherine Fressigné et al published 19 December 2008 in European Journal of Organic Chemistry

Lithium Amide Protected against Hydrolysis by Aggregated Lithium Halides: An MS + DFT Investigation.

scientific article published on 11 July 2017

Mass Spectrometric Characterization of Limulus polyphemus Hemocyanin

scientific article published in 1999

MeLi + LiCl in THF: one heterodimer and no tetramers

scientific article published on September 2010

Measurement of phenylacetic acid in cerebrospinal fluid and plasma using combined gas chromatography/electron capture chemical ionization mass spectrometry

scientific article published on 01 September 1988

Metal-free aerobic C–H oxidation of cyclic enones

Michael addition of 1,3-dicarbonyl compounds catalyzed by iron oxide nanoparticles

article

Molecular Mechanics/Continuum Reaction Field/Quantum Mechanics Study of the Intramolecular Diels−Alder Reaction of 2-Furfuryl Derivatives

scholarly article by Claude Giessner-Prettre et al published March 1997 in Journal of Organic Chemistry

Multinuclear NMR Study of the Aggregates between Methyllithium and Lithium Bromide in Toluene

NMR studies of a ternary complex reagent of lithium ester enolate, chiral diether, and lithium diisopropylamide in an asymmetric Michael reaction

New approaches to bicyclic vinyl heterocycles from propargylic acetals

scientific article published in January 2005

New carbanionic access to 3-vinylindoles and 3-vinylbenzofurans

scientific article published in August 2002

New pluses in carbanion chemistry

Nonempirical calculations on dicopper(1+)-dioxygen: a possible model for oxyhemocyanin and oxytyrosinase active sites

One-Pot Regio- and Stereoselective Synthesis of α′-Methoxy-γ-pyrones: Biological Evaluation as Mitochondrial Respiratory Complex Inhibitors

scientific article published on 27 October 2011

Organocatalytic Asymmetric Hetero-Diels-Alder Reaction of Oxindoles under High Pressure¹

Organoytterbium ate complexes extend the value of cyclobutenediones as isoprene equivalents

scientific article published on 23 October 2013

Origin of the Detrimental Effect of Lithium Halides on an Enantioselective Nucleophilic Alkylation of Aldehydes

Oxidative Neutralization of Mustard-Gas Simulants in an On-Board Flow Device with In-Line NMR Monitoring

scientific article

Palladium-Mediated N-Arylation of Heterocyclic Diamines: Insights into the Origin of an Unusual Chemoselectivity

scholarly article by Noemi Cabello-Sanchez et al published March 2007 in Journal of Organic Chemistry

Palladium-mediated arylation of 3-aminopiperidines and 3-aminopyrrolidines

scientific article published in December 2004

Ph2P(BH3)Li: From Ditopicity to Dual Reactivity

scientific article published in 2011

Probing solvent effects on mixed aggregates associating a chiral lithium amide and n-BuLi by NMR: from structure to reactivity

scientific article published in October 2014

Probing the Origins of Asymmetric Induction by 3-Aminopyrrolidine Lithium Amides Complexes: A6Li/1H/13C NMR Study

scientific article published in 1997

Putting pressure on elusive polymorphs and solvates

article

Pyrrolidinic and piperidinic ring fission by conjugate elimination

article

Revisiting the structure of (LiCH3)n aggregates using Car-Parrinello molecular dynamics

scientific article published in April 2006

Ring fission of chiral cyclic acetals plus intramolecular [4 + 2] cycloaddition: a sequential access to medium-size lactones. Application to the synthesis of carbasugars

scientific article published on 4 March 2005

Selective monoalkylation of amines with light electrophiles using a flow microreactor system

article

Selective monomethylation of primary amines with simple electrophiles

article by Thomas Lebleu et al published 2014 in Chemical Communications

Selectivity Controls in the [4+2] Cycloadditions of 1-Oxygenated Dienes

Semiempirical calculations of the dispersion contribution to the proton chemical shift

Shuffling lithiated mixed aggregates: NMR and Car-Parrinello molecular dynamics reveal an unexpected associative pathway

scientific article published on 21 November 2008

Solvent effects in the aza-Michael addition of anilines

article

Solvent effects on the mixed aggregates of chiral 3-aminopyrrolidine lithium amides and alkyllithiums

article

Spin-driven activation of dioxygen in various metalloenzymes and their inspired models

Stereocontrolled access to polyenol ethers by conjugate elimination/ring fission reactions

Stereocontrolled synthesis and cycloaddition of 1,2,4-trioxygenated 1,3-dienes

scientific article (publication date: 3 March 2006)

Stereoselective access to heteroarylmethylene-substituted pyrrolidines: fully organocatalytic Mannich-hydroamination reactions.

scientific article published in February 2013

Structure of the Mixed Aggregates between a Chiral Lithium Amide and Phenyllithium or Vinyllithium

Structure-Selectivity Relationship in Alkyllithium−Aldehyde Condensations Using 3-Aminopyrrolidine Lithium Amides as Chiral Auxiliaries

article

Study of the docking of competitive inhibitors at a model of tyrosinase active site: insights from joint broken-symmetry/Spin-Flip DFT computations and ELF topological analysis

scientific article

Synthesis and Diels-Alder reactivity of functionalized aminodienes and bis-dienes

Synthesis and antimicrobial activities of two novel amino sugars derived from chloraloses

scientific article published on 4 April 2010

Synthesis of oxa-bridged analogues of farnesyltransferase inhibitor RPR 115135.

scientific article published in June 2001

Synthesis of α,β-unsaturated dioxanes, dioxolanes and dioxepanes by trans-acetalisation of dimethylacetals with meso or C2-symmetrical 1,2-, 1,3- and 1,4-diols

article published in 2004

Synthesis, separation and structure determination of atropisomeric ketimines: precursors of new potential chiral ligands and phase-transfer catalysts

Synthetic Applications of the Nickel-Catalyzed Cyclization of Alkynes Combined with Addition Reactions in a Domino Process

article

Tandem Cycloadditions of Functionalized Bis-Dienes. An Orthogonal Route to New Dipseudoglycals

article published in 1999

Tandem aza-Michael additions under high pressure: a shortcut to the azanorbornyl skeleton

article

Theoretical Evidence of Electrophilic Superoxides in Models of Oxyhemocyanin/Oxytyrosinase Active Sites. Influence of the Ligand's Arrangement

article

Theoretical study of oxyhemocyanin active site: a possible insight on the first step of phenol oxidation by tyrosinase.

scientific article published in July 1992

Theoretical study of phenol and 2-aminophenol docking at a model of the tyrosinase active site

article published in 2003

Thermal and hyperbaric addition ofN,N- andN,O- binucleophiles on cycloalkylidenic bromo esters

article

Thermal/hyperbaric heterocycloaddition of 1,4-dialkoxy-1,3-dienes: the de novo (E,Z) way to sugars

scientific article published in November 2002

Total synthesis of spiromastilactone A

scientific article published on 01 April 2019

Unexpected behavior of dienol thio ethers gives versatile access to a large set of functionalized dienes

Utilisation d'alkoxyacetates chiraux - equivalents de l'hydroxyacetaldehyde - en aldolisation stereocontrolee approche enantio et diastereoselective de polyols vicinaux

Why Are Monomeric Lithium Amides Planar?

article

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