List of works by Guy Bertrand

(CAAC)CuX-catalyzed hydroboration of terminal alkynes with pinacolborane directed by the X-ligand

(Phosphanyl)phosphaketenes as building blocks for novel phosphorus heterocycles.

scientific article published on 8 March 2017

1 H-1,2,3-Triazol-5-ylidenes: Readily Available Mesoionic Carbenes

scientific article published on 12 November 2018

1,3-Diborata-2,4-diphosphoniocyclobutane-1,3-diyls communicate through a para-phenylene linker

scientific article

31P NMR chemical shifts of carbene-phosphinidene adducts as an indicator of the π-accepting properties of carbenes

scientific article

A Facile Synthesis of Carbamoylsilanes, -boranes and -phosphane Oxides - Isolation of the First Uncomplexed Carbamoylborane

scientific article published on December 2006

A New Synthetic Method for the Preparation of Protonated-NHCs and Related Compounds

scientific article published on January 2006

A Ruthenium Catalyst for Olefin Metathesis Featuring an Anti-Bredt N-Heterocyclic Carbene Ligand

scientific article published on 9 February 2016

A Stable (Amino)(Phosphino)Carbene as bidentate ligand for Palladium and Nickel Complexes: Synthesis, Structure, and Catalytic Activity

scientific article published on January 2005

A cationic gold(I) complex as a general catalyst for the intermolecular hydroamination of alkynes: application to the one-pot synthesis of allenes from two alkynes and a sacrificial amine

scientific article published on January 2009

A crystalline monosubstituted carbene

scientific article published on 15 October 2018

A crystalline phosphinyl radical cation

scientific article published in August 2010

A crystalline singlet phosphinonitrene: a nitrogen atom-transfer agent

scientific article published in September 2012

A cyclic diaminocarbene with a pyramidalized nitrogen atom: a stable N-heterocyclic carbene with enhanced electrophilicity

scientific article published on 8 May 2012

A persistent (amino)(ferrocenyl)carbene().

scientific article published on January 2011

A rare example of a rearrangement involving four structural isomers: alpha-phosphinonitrile/C-phosphinoketenimine/1-aza-4- phosphabutadiene/1,2-dihydro-1,2-azaphosphete

scientific article published in December 2002

A rhodium(I)-oxygen adduct as a selective catalyst for one-pot sequential alkyne dimerization-hydrothiolation tandem reactions

scientific article published on 3 February 2016

A rigid cyclic (alkyl)(amino)carbene ligand leads to isolation of low-coordinate transition-metal complexes

scientific article published on November 2005

A stable acyclic ligand equivalent of an unstable 1,3-dithiol-5-ylidene

scientific article published on 6 April 2011

Activation of Si-H, B-H, and P-H bonds at a single nonmetal center

scientific article published in December 2010

Air-Stable (CAAC)CuCl and (CAAC)CuBH4 Complexes as Catalysts for the Hydrolytic Dehydrogenation of BH3NH3.

scientific article published on 20 March 2015

Allene formation by gold catalyzed cross-coupling of masked carbenes and vinylidenes

scholarly article

Amino-aryl-carbenes: alternative ligands for transition metals?

scientific article published in February 2004

An efficient synthetic route to stable bis(carbene)borylenes [(L1)(L2)BH].

scientific article

An unusual norcaradiene/tropylium rearrangement from a persistent amino-phosphonio-carbene

scientific article published in January 2007

Anionic 1,2,3-triazole-4,5-diylidene: a 1,2-dihapto ligand for the construction of bimetallic complexes

scientific article

Anti-Bredt N-heterocyclic carbene: an efficient ligand for the gold(I)-catalyzed hydroamination of terminal alkynes with parent hydrazine

scientific article published on 4 April 2013

Bicyclic (Alkyl)(amino)carbenes (BICAACs): Stable Carbenes More Ambiphilic than CAACs.

scientific article published on 25 May 2017

Bis(1,2,3-triazol-5-ylidenes) (i-bitz) as Stable 1,4-Bidentate Ligands Based on Mesoionic Carbenes (MICs).

scientific article published on January 2011

Bond activation with an apparently benign ethynyl dithiocarbamate Ar-C≡C-S-C(S)NR2.

scientific article published in October 2011

Borylene Complexes (BH)L2 and Nitrogen Cation Complexes (N+)L2: Isoelectronic Homologues of Carbones CL2

Borylenes: An Emerging Class of Compounds

scientific article published on 3 June 2017

C-F bond activation with an apparently benign ethynyl dithiocarbamate, and subsequent fluoride transfer reactions

scientific article published on 7 September 2012

C-phosphanyl-C-chloroiminium salts as electrophilic carbene synthetic equivalents

scientific article published in October 2002

CO fixation to stable acyclic and cyclic alkyl amino carbenes: stable amino ketenes with a small HOMO-LUMO gap.

scientific article published on May 2006

Carbene activation of P4 and subsequent derivatization

scientific article published in January 2007

Carbene-Stabilized Main Group Radicals and Radical Ions

scientific article published on August 2013

Carbenes Introduction

article

Carbodicarbenes, carbon(0) derivatives, can dimerize

scientific article

Catenation of two singlet diradicals: synthesis of a stable tetraradical (tetraradicaloid).

scientific article

Chemistry. Soluble allotropes of main-group elements

scientific article published in August 2008

Chemistry. The modest undressing of a silicon center.

scientific article

Comparative reactivity of different types of stable cyclic and acyclic mono- and diamino carbenes with simple organic substrates.

scientific article published on 24 March 2014

Cross-coupling reactions between stable carbenes

scientific article published on 18 May 2014

Crystalline 1H-1,2,3-triazol-5-ylidenes: new stable mesoionic carbenes (MICs).

scientific article

Crystalline Monomeric Allenyl/Propargyl Radical

scientific article published on 18 October 2017

Crystalline, Lewis base-free, cationic phosphoranimines (iminophosphonium salts).

scientific article published on 12 September 2013

Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments

scientific article

Cyclic (Alkyl)- and (Aryl)-(amino)carbene Coinage Metal Complexes and Their Applications

scientific article published on 02 April 2020

Cyclic (Amino)(aryl)carbenes (CAArCs) as Strong σ-Donating and π-Accepting Ligands for Transition Metals

scientific article

Cyclic (alkyl)(amino)carbenes (CAACs): stable carbenes on the rise

scientific article published on 17 December 2014

Cyclic (amino)[bis(ylide)]carbene as an anionic bidentate ligand for transition-metal complexes

scientific article published on 19 April 2008

Cyclic C-amino phosphorus ylides as a source of bidentate heteroditopic ligands (phosphine/aminocarbene) for transition metals

scientific article published on November 2006

Cyclic alkyl amino carbene (CAAC) ruthenium complexes as remarkably active catalysts for ethenolysis

scientific article published on 17 December 2014

Deprotonation of a borohydride: synthesis of a carbene-stabilized boryl anion

scientific article published on 13 June 2013

Ein kationisches 1,3-Diphospha-2,4-dipallada(II)-tricyclo[1.1.1]pentan-Derivat: das erste strukturell charakterisierte pyramidale μ2-Phosphiniden

article published in 1995

Electronic structure of .lambda.5-phosphaacetylene and corresponding triplet methylenes

article published in 1991

Eliminating nonradiative decay in Cu(I) emitters: >99% quantum efficiency and microsecond lifetime

scientific article published on 08 February 2019

Evidence for the coexistence of two bond-stretch isomers in solution

scientific article published in September 2004

Experimental and computational studies of anti-Bredt amidinium salts

scientific article published on 17 September 2013

Exploring the reactivity of white phosphorus with electrophilic carbenes: synthesis of a P4 cage and P8 clusters

scientific article

Facile preparation of homo- and hetero-dimetallic complexes with a 4-phosphino-substituted NHC ligand. Toward the design of multifunctional catalysts ⬇️

scientific article

Facile splitting of hydrogen and ammonia by nucleophilic activation at a single carbon center.

scientific article

First example of prototropism in iminobis(phosphines) induced by phosphorus alkylation

Generalization of the Copper to Late-Transition-Metal Transmetallation to Carbenes beyond N-Heterocyclic Carbenes

scientific article published on 30 May 2016

Gold-catalyzed hydroamination of alkynes and allenes with parent hydrazine

scientific article

Gold-catalyzed hydroarylation of alkenes with dialkylanilines

scientific article published on 19 September 2014

Gold-catalyzed intermolecular Markovnikov hydroamination of allenes with secondary amines

scientific article published on August 2009

Grubbs and Hoveyda-Type Ruthenium Complexes Bearing a Cyclic Bent-Allene

scientific article published on August 2011

Highly Ambiphilic Room Temperature Stable Six-Membered Cyclic (Alkyl)(amino)carbenes

scientific article published on 13 July 2018

Homogeneous catalytic hydroamination of alkynes and allenes with ammonia

scientific article published on January 2008

Insights into the carbene-initiated aggregation of [Fe(cot)(2)].

scientific article published on January 2011

Intercepting a Transient Phosphino-Arsinidene

scientific article published on 05 June 2018

Intramolecular "hydroiminiumation and -amidiniumation" of alkenes: a convenient, flexible, and scalable route to cyclic iminium and imidazolinium salts

scientific article published on 5 April 2007

Intramolecular "hydroiminiumation" of alkenes: application to the synthesis of conjugate acids of cyclic alkyl amino carbenes (CAACs).

scientific article published in January 2007

Ionic-type reactivity of 1,3-dibora-2,4-diphosphoniocyclobutane-1,3-diyls: regio- and stereoselective addition of hydracids

scientific article published in September 2009

Isolation of Au-, Co-η1PCO and Cu-η2PCO complexes, conversion of an Ir-η1PCO complex into a dimetalladiphosphene, and an interaction-free PCO anion.

scientific article published on 4 January 2016

Isolation of a C5-deprotonated imidazolium, a crystalline "abnormal" N-heterocyclic carbene

scientific article

Isolation of a Lewis base stabilized parent phosphenium (PH2(+)) and related species

scientific article

Isolation of a carbene-stabilized phosphorus mononitride and its radical cation (PN+*).

scientific article published in August 2010

Isolation of bicyclopropenylidenes: derivatives of the smallest member of the fulvalene family

scientific article

Isolation of bis(copper) key intermediates in Cu-catalyzed azide-alkyne "click reaction".

scientific article

Isolation of bridging and terminal coinage metal-nitrene complexes

scientific article

Isolation of crystalline carbene-stabilized P(2)-radical cations and P(2)-dications

scientific article published on 11 April 2010

Isolation of cyclopropenylidene-lithium adducts: the Weiss-Yoshida reagent

scientific article published in October 2006

Isolation of neutral mononuclear copper complexes stabilized by two cyclic (alkyl)(amino)carbenes

scientific article published on 17 April 2014

Kinetic Selectivity of Olefin Metathesis Catalysts Bearing Cyclic (Alkyl)(Amino)Carbenes

scientific article published on January 2008

L3 C3 P3 : Tricarbontriphosphide Tricyclic Radicals and Cations Stabilized by Cyclic (alkyl)(amino)carbenes

scientific article

L3 C3 P3 : Tricarbontriphosphide Tricyclic Radicals and Cations Stabilized by Cyclic (alkyl)(amino)carbenes

Mesoionic Carbene-Gold(I) Catalyzed Bis-Hydrohydrazination of Alkynes with Parent Hydrazine

scientific article

Mesoionic thiazol-5-ylidenes as ligands for transition metal complexes

scientific article published on 30 August 2011

Modular Approach to Kekulé Diradicaloids Derived from Cyclic (Alkyl)(amino)carbenes.

scientific article published on 31 January 2018

Mono- and diaminocarbenes from chloroiminium and -amidinium salts: synthesis of metal-free bis(dimethylamino)carbene

scientific article (publication date: 4 February 2004)

NHC-CAAC Heterodimers with Three Stable Oxidation States.

scientific article published on 15 September 2016

NHC-mediated aggregation of P4: isolation of a P12 cluster

scientific article published on 31 October 2007

Nonmetal-mediated fragmentation of P4: isolation of P1 and P2 bis(carbene) adducts.

scientific article published in January 2009

On the electronic structures of the 1,3-diboracyclobutane-1,3-diyls and their valence isomers with a B2E2 skeleton (E=N, P, As).

scientific article published in August 2003

One-, two-, and three-electron reduction of a cyclic alkyl(amino)carbene-SbCl₃ adduct

scientific article published on 24 June 2014

Optically Pure C1-Symmetric Cyclic(alkyl)(amino)carbene Ruthenium Complexes for Asymmetric Olefin Metathesis

scientific article published on 13 November 2020

Organic Mixed Valence Compounds Derived from Cyclic (Alkyl)(amino)carbenes.

scientific article published on 17 January 2018

Organometallics Roundtable 2011

article

Oxidative addition at a carbene center: synthesis of an iminoboryl-CAAC adduct

scientific article

Palladium-oxygen and palladium-arene interactions in complexes derived from biaryl aminocarbenes: comparison with biaryl phosphanes

scientific article published on January 2008

Persistent (amino)(silyl)carbenes

scientific article

Persistent phosphinyl radicals featuring a bulky amino substituent and the 2,6-bis(trifluoromethyl)phenyl group

scientific article published in October 2004

Photolytic rearrangement of phosphorus azide : evidence for a transient metaphosphonimidate.

scientific article (publication date: 1980)

Protonolysis of a ruthenium-carbene bond and applications in olefin metathesis

scientific article

Reactions of phosphorus electrophiles with [(.eta.5-C5Me5)Fe(CO)2]-; spectroscopic evidence for a phosphinidene complex

Reactivity of cyclic (alkyl)(amino)carbenes (CAACs) and bis(amino)cyclopropenylidenes (BACs) with heteroallenes: comparisons with their N-heterocyclic carbene (NHCs) counterparts

scientific article published on November 2009

Readily Available Primary Aminoboranes as Powerful Reagents for Aldimine Synthesis

scientific article published on 06 February 2019

Readily available onio-substituted methyleneiminium salts: single precursors for a variety of aminocarbenes

scientific article published in August 2004

Realizing Metal-Free Carbene-Catalyzed Carbonylation Reactions with CO

scientific article published on 15 October 2020

Rearrangement of biaryl monoaminocarbenes via concerted asynchronous insertion into aromatic C-H bonds

scientific article published on 3 September 2008

Recently reported crystalline isothiazole carbenes: myth or reality

scientific article (publication date: 2007)

Reductive Elimination at Carbon under Steric Control

scientific article published on 14 June 2019

Reluctance of 4-chloro-5-metalla-1,3,2-diazaborolines to undergo metal halide beta-elimination: an opportunity for C-functionalization of 1,3,2-diazaborolines

scientific article published on 9 October 2008

Serendipitous discovery of the catalytic hydroammoniumation and methylamination of alkynes

scientific article published on January 2010

Sigma-bond stretching: a static approach for a dynamic process

scientific article published in February 2004

Singlet diradicals: from transition states to crystalline compounds

scientific article

Spectroscopic Evidence for a Monomeric Copper(I) Hydride and Crystallographic Characterization of a Monomeric Silver(I) Hydride

scientific article

Stability and electronic properties of imidazole-based mesoionic carbenes.

scientific article published on 7 June 2011

Stable Bis(diisopropylamino)cyclopropenylidene (BAC) as Ligand for Transition Metal Complexes

scientific article published on March 2008

Stable cyclic (alkyl)(amino)carbenes as rigid or flexible, bulky, electron-rich ligands for transition-metal catalysts: a quaternary carbon atom makes the difference

scientific article

Stable cyclic carbenes and related species beyond diaminocarbenes

scientific article

Stable four-pi-electron, four-membered heterocyclic cations and carbenes

scholarly article

Stable optically pure phosphino(silyl)carbenes: reagents for highly enantioselective cyclopropanation reactions

scientific article published in April 2004

Stable planar six-pi-electron six-membered N-heterocyclic carbenes with tunable electronic properties

scientific article

Stereoselective Synthesis of Phosphoranyl Aryloxiranes through the Addition of a Nucleophilic Stable Carbene to Aromatic Aldehydes ⬇️

scientific article published on October 3, 2003

Synthesis and characterization of a neutral tricoordinate organoboron isoelectronic with amines

scientific article

Synthesis and ligand properties of a persistent, all-carbon four-membered-ring allene

scientific article

Synthesis and ligand properties of stable five-membered-ring allenes containing only second-row elements

scientific article published in January 2008

Synthesis and reactivity of a CAAC-aminoborylene adduct: a hetero-allene or an organoboron isoelectronic with singlet carbenes

scientific article published on 29 September 2014

Synthesis and reactivity of olefin metathesis catalysts bearing cyclic (alkyl)(amino)carbenes

scientific article published on January 2007

Synthesis and rearrangement of diphosphorus analogues of amidinium salts

scientific article published in March 2002

Synthesis of 4- and 4,5-functionalized imidazol-2-ylidenes from a single 4,5-unsubstituted imidazol-2-ylidene

scientific article

Synthesis of Highly Stable 1,3-Diaryl-1H-1,2,3-triazol-5-ylidenes and their Applications in Ruthenium-Catalyzed Olefin Metathesis

scientific article published on March 2011

Synthesis of a Carbodicyclopropenylidene: A Carbodicarbene based Solely on Carbon.

scientific article published on 30 March 2016

Synthesis of a Cationic 1,3-Diphospha-2,4-dipallada(II)tricyclo[1.1.1]pentane Derivative: The First Structurally Characterized Pyramidalμ2-Phosphinidene

Synthesis of a room-temperature-stable dimeric copper(I) hydride

scientific article published on 13 October 2010

Synthesis of a simplified version of stable bulky and rigid cyclic (alkyl)(amino)carbenes, and catalytic activity of the ensuing gold(I) complex in the three-component preparation of 1,2-dihydroquinoline derivatives

scientific article published in June 2009

Synthesis of allenylidene lithium and silver complexes, and subsequent transmetalation reactions

scientific article published in January 2009

Synthesis of an extremely bent acyclic allene (a "carbodicarbene"): a strong donor ligand

scientific article published in January 2008

Synthesis of carbenes through substitution reactions at a carbene center

scientific article

Synthesis of extended polyphosphacumulenes

scientific article

Synthesis of phosphaformamidines and phosphaformamidinates

scientific article published on July 2007

Synthesis of transient and stable C-amino phosphorus ylides and their fragmentation into transient and stable carbenes

scientific article published on January 2006

Synthesis, reactivity, and ligand properties of a stable alkyl carbene

scientific article published in July 2004

The Advantages of Cyclic Over Acyclic Carbenes To Access Isolable Capto-Dative C-Centered Radicals.

scientific article published on 19 January 2017

The Deprotonated Iminophosphoraneo-C6H4PPh2P=NSiMe3 as a Novel Chelating Ligand in Organocopper(I) and -zinc(II) Chemistry

The Dramatic Influence of Diamidoamine Ligands on the Structure and Reactivity of Low-Valent Tin and Bismuth Derivatives

The Janus Face of the X Ligand in the Copper-Catalyzed Azide-Alkyne Cycloaddition

scientific article published on 27 November 2015

The debut of chiral cyclic (alkyl)(amino)carbenes (CAACs) in enantioselective catalysis

scientific article published on 06 July 2019

The existence of two short-bond isomers for bicyclo[1.1.0]butane derivatives based on boron and phosphorus

scientific article published in January 2008

The stable pentamethylcyclopentadienyl cation remains unknown

scientific article published in July 2002

Thermal valence isomerization of 2,3-diborata-1,4-diphosphoniabuta-1,3-dienes to bicyclo[1.1.0]butanes and cyclobutane-1,3-diyls

scientific article published in January 2007

Toward phenanthridin-2-ylidene: electrophilicity versus acidity in planar-constrained C-aryl iminium salts

scientific article published on January 2006

Transient azomethine-ylides from a stable amino-carbene and an aldiminium salt

scientific article

Transient palladadiphosphanylcarbenes: singlet carbenes with an "inverse" electronic configuration (p(pi)2 instead of sigma2) and unusual transannular metal-carbene interactions (piC-->Pd donation and sigmaPd-->C back-donation).

scientific article published on January 2007

Transition-Metal-like Behavior of Main Group Elements: Ligand Exchange at a Phosphinidene

scientific article

Transmetalation Reaction of Dimethylzinc and (Bis(2-pyridyl)methyl)lithium

article published in 2000

Trinuclear gold clusters supported by cyclic (alkyl)(amino)carbene ligands: mimics for gold heterogeneous catalysts

scientific article published in July 2014

Tuning electronic structure through halide modulation of mesoionic carbene cobalt complexes

scientific article published on 01 February 2020

Tuning the nucleophilicity in cyclopropenylidenes

scientific article published on January 2008

Umpolung of electrophilic terminal phosphinidene complexes by interaction with nucleophilic carbenes.

scientific article published in August 2009

Understanding the Activity and Enantioselectivity of Acetyl-Protected Aminoethyl Quinoline Ligands in Palladium-Catalyzed β-C(sp3)-H Bond Arylation Reactions

scientific article published on 11 October 2019

What Are the Radical Intermediates in Oxidative N-Heterocyclic Carbene Organocatalysis?

scientific article published on 31 December 2018

Ynamides: stable ligand equivalents of unstable oxazol-4-ylidenes (novel mesoionic carbenes).

scientific article

[Bis(diisopropylamino)phosphino]trimethylsilylcarbene: A Stable Nucleophilic Carbene

scholarly article by Alai Igau et al published May 1989 in Angewandte Chemie International Edition

nido-Five-vertex clusters: in and out of boron chemistry

scientific article

β- and α-Hydride abstraction in Gold(I) alkyl complexes

scientific article

λ3-Phosphinocarbenes λ5-phosphaacetylenes

scientific article (publication date: December 1994)

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