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List of works by Fernando J. Lahoz

1H-Pyrrolo[2,3-b]pyridine (HL) ligands in rhodium(I) and iridium(I) chemistry. Crystal and molecular structures of [Rh2(µ-L)2(nbd)2] and [Rh4(µ-Cl)2(µ-L)2(µ-CO)2(CO)2(nbd)2]

scholarly article by Luis Oro et al published 1985 in Dalton transactions RSC

2-Pyridone-stabilized iridium silylene/silyl complexes: structure and QTAIM analysis

scientific article published on 24 November 2020

A C-H activation-CO(2)-carboxylation reaction sequence mediated by an 'Iridium(dppm)' species. Formation of the anionic ligand (Ph(2)P)(2)C-COOH.

scientific article published on 21 August 2008

A Hexanuclear Iridium Chain

scholarly article by Cristina Tejel et al published 3 February 2003 in Angewandte Chemie International Edition

A Trithiol Protio-Ligand and Its Fixation to the Periphery of a Carbosilane Dendrimer as Scaffolds for Polynuclear Rhodium and Iridium Complexes and Metallodendrimers

scholarly article by José A. Camerano et al published October 2005 in Organometallics

A Way to Novel Heterometallic Raft-like Clusters from Neutral Precursors

scientific article published in 1997

A flexible framework obtained from oxidative additions upon the binuclear complex [Ir2(µ-pz)(µ-SBut)(CO)2{P(OMe)3}2]: preparation and X-ray structures of [Ir2(µ-pz)(µ-SBut)(µ-L)(CO)2{P(OMe)3}2] and [Ir2(µ-pz)(µ-SBut)(µ-L)I2(CO)2-{P(OMe)3}2](H

article

Activation of a vinyl carbon–hydrogen bond in a tris(pyrazolyl)boratoiridium complex. The X-ray crystal structure of [IrH{HB(pz)3}(σ-C8H13)(η2-C8H14)]

Addition to Brønsted Acid/Base Driven Chemistry with Rhodathiaboranes: A Labile {SB9H9}-Thiodecaborane Fragment System

article

Additions and corrections

article published in 1988

Alkene C−H Activations at Dinuclear Complexes Promoted by Oxidation

scientific article published on 01 April 2002

Alkene hydrogenation on an 11-vertex rhodathiaborane with full cluster participation

scientific article

An iridium-mediated C-H activation/CO2-carboxylation reaction of 1,1-bisdiphenylphosphinomethane

scientific article published on 23 July 2010

Arene–Ruthenium Chemistry and Brønsted Acid Catalysis of a Chiral Phosphane-Hydroxyl Ligand

Asymmetric 1,3-dipolar cycloaddition reaction of α,β-unsaturated nitriles with nitrones catalyzed by chiral-at-metal rhodium or iridium complexes

scholarly article by Daniel Carmona et al published June 2009 in Tetrahedron: Asymmetry

Benzamidinatorhodium complexes. X-Ray structures of [Rh{CPh(NPh)2}(cod)] and [Rh2{µ-CPh(NPh)2}2(tfbb)2]

Benzene-1,2-dithiolate-induced assembly of reactive iridium fragments into tetranuclear octahydride complexes

scholarly article by M.Victoria Jiménez et al published April 2004 in Inorganica Chimica Acta

Bimetallic reactivity: unusual change in the coordination mode of the bridging ligands arising from an oxidative addition process

article

Binuclear dirhodium(I) complexes with phenyl(2-pyridyl)amido ligands. Crystal and molecular structure of [{Rh(μ-N,N′-PhNPy)(nbd)}2]·H2O (nbd = 2,5-norbomadiene)

Binuclear pentamethylcyclopentadienyl dirhodium complexes with pyrazolato and diphenylphosphido bridging ligands

Brønsted Acid/Base Driven Chemistry with Rhodathiaboranes: A Labile {SB9H9}–Thiadecaborane Fragment System

C-NH2 bond formation mediated by iridium complexes

scientific article published on 15 July 2014

Cationic Rhodium Complexes with Hemilabile Phosphine Ligands as Polymerization Catalyst for High Molecular Weight Stereoregular Poly(phenylacetylene)

Cationic rhodium(I) complexes with diolefin and substituted pyridine N-oxides as ligands

Chemical evidence of polynuclear intermediates in a ligand redistribution equilibrium between dinuclear rhodium complexes. X-ray structure of [Rh2(μ-bzta)2(CO)3(PPh3)] (bzta = benzothiazole-2-thiolate)

scholarly article by Miguel A. Ciriano et al published August 1993 in Journal of Organometallic Chemistry

Chiral Brønsted Acid Catalysts. Activation of Methyl 3,3,3-Trifluoropyruvate by Hydroxymethylpyridine-Containing Half-Sandwich Complexes

Chiral Half-Sandwich Ruthenium(II) Complexes as Catalysts in 1,3-Dipolar Cycloaddition Reactions of Nitrones with Methacrolein

Chiral Octahedral Phosphano–Oxazoline Iridium(III) Complexes as Catalysts in Asymmetric Cycloaddition Reactions

scholarly article by Daniel Carmona et al published 20 February 2013 in Organometallics

Chiral Phosphinooxazoline−Ruthenium(II) and −Osmium(II) Complexes as Catalysts in Diels−Alder Reactions

scholarly article by Daniel Carmona et al published March 2006 in Organometallics

Chiral iridium(III) α-amino acidato complexes (RIr,SN,SC)- and (SIr,SN,SC)-[(η5-C5Me5)Ir(L-prolinate)(CCCMe3)]

scholarly article by Daniel Carmona et al published July 1993 in Tetrahedron: Asymmetry

Chiral pyridylamino-ruthenium(II) complexes: synthesis, structure and catalytic properties in Diels-Alder reactions

scientific article published on 14 May 2008

Cluster activation via cyclometallation. Formation of the cyclometallated triosmium carbonyl cluster [Os3H2(CO)9{P(C6H4)Ph}] and its reactions with phosphorus donor ligands. The X-ray crystal structures of [Os3H2(CO)9{P(C6H4)Ph}] and [Os3H(CO)9{P(OMe

Complete Characterization of a Chiral Lewis Acid−Product Complex for the Enantioselective Diels−Alder Reaction between Methacrolein and Cyclopentadiene: Mechanistic Considerations

Corrigendum to “Synthesis and structure of chiral-at-metal complexes with the ligand (S)-2-[(Sp)-2-(diphenylphosphino)ferrocenyl]-4-isopropyloxazoline” [J. Organomet. Chem. 691 (2006) 5560–5566]

scholarly article published in Journal of Organometallic Chemistry

Crescent-shaped rhodium(I) complexes with bis(o-carboxymethylphenyl)triazenide

scientific article published in July 2004

C−C Formation and C−O Cleavage Reactions on Hemilabile Arene−Phosphine Ligands in Route to η5-Cyclohexadienyl Iridium Compounds§

scholarly article by M. Victoria Jiménez et al published August 2008 in Organometallics

C−H Activation and C−C Coupling Reactions in 2-Vinylpyridine Cationic Complexes of Iridium

scholarly article by Janeth Navarro et al published April 2004 in Organometallics

C−H Bond Activations by New Labile η6-Arene Complexes of Iridium

scholarly article by Francisco Torres et al published November 1999 in Journal of the American Chemical Society

Di- and tetra-nuclear mixed-valence complexes of rhodium(III,I) and rhodium(III)–iridium(I) with the 2,2′-bi-imidazolate(2–) anion (bim) as bridging ligand. Crystal structure of [{(η-C5Me5)[P(OEt)3]Rh(bim)Rh(nbd)}2][ClO4]2

scholarly article by Luis Oro et al published 1986 in Dalton transactions RSC

Diastereoselective Synthesis of Chiral Octahedral Iridium(III) Phosphano–Oxazoline Complexes

scholarly article by Daniel Carmona et al published 20 February 2013 in Organometallics

Dimer species in aqueous solutions of m–phenylenediamine-N,N,N′,N′-tetra-acetic acid (m-H4pdta) with copper(II) and of pyridine-2,6-diamine-N,N,N′,N′-tetra-acetic acid (2,6-H4pydta) with nickel(II). X-Ray crystal structures of Na4[Cu2(m-pdt

scholarly article by Alfredo Mederos et al published 1990 in Dalton transactions RSC

Dimetallic Dioxygen Activation Leading to a Doubly Oxygen-Bridged Dirhodium Complex

Dinuclear pentafluorophenyl compounds of rhodium(III) with anionic bridging ligands. Molecular structures of [P(CH2Ph)Ph3]2[{Rh(C6F5)3}2(µ-SCN)2] and [P(CH2Ph)Ph3]2[{Rh(C6F5)3}2(µ-CO3)]

scholarly article by María P. García et al published 1995 in Dalton transactions RSC

Dinuclear pyridine-4-thiolate-bridged rhodium and iridium complexes as ditopic building blocks in molecular architecture

scientific article published on 17 January 2014

Dinuclear rhodium and iridium complexes with mixed amido/methoxo and amido/hydroxo bridges

scientific article published in May 2002

Diolefin and carbonyl rhodium(I) and iridium(I) complexes with phosphine sulphide ligands. Crystal structure of [Rh(COD)(Et2P(S)(S)PEt2)]ClO4

scholarly article by Carmen Claver et al published September 1989 in Journal of Organometallic Chemistry

Effects of the Heterocycle and Its Substituents on Structure and Fluxionality in Rhodium(I) and Iridium(I) Complexes with the Hindered Thiolates 6-tert-Butylpyridine-2-thiolate and 1-Alkyl-4-tert-butylimidazole-2-thiolate (alkyl = methyl andtert-buty

scholarly article by Valentín Miranda-Soto et al published August 2006 in Organometallics

Enantioselective 1,3-dipolar cycloaddition of nitrones to methacrolein catalyzed by (eta5-C5Me5)M{(R)-prophos} containing complexes (M = Rh, Ir; (R)-prophos = 1,2-bis(diphenylphosphino)propane): on the origin of the enantioselectivity

scientific article published in September 2005

Enantioselective Catalytic Diels–Alder Reactions with Enones As Dienophiles

Enantioselective Diels–Alder Reactions Catalyzed by Well-Defined Arene–Ruthenium Complexes. Relationship between Catalyst Structure and Enantioselectivity

Enantioselective catalysts based on the chiral fragment (η5-C5Me5)Ir(Prophos) for Diels–Alder reactions

Evidence for enhancement of catalysis by a second metal in heterobinuclear complexes: X-ray structure of [H(CO)(PPh3)2Ru(bim)Rh(cod)](bim = 2,2′-bi-imidazolato, cod = cyclo-octa-1,5-diene)

Flexible Building Blocks for Transition Metal Early−Late Chemistry. Synthesis of Heterobimetallic Tetranuclear Metallomacrocycles

Grafting of Copper(I)-NHC Species on MCM-41: Homogeneous versus Heterogeneous Catalysis

Half-Sandwich Complexes of Osmium(II) with l-α-Amino Carboxylate Ligands as Asymmetric Transfer Hydrogenation Catalysts. On the Origin of the Enantioselectivity

scholarly article by Daniel Carmona et al published 22 March 2012 in Organometallics

Half-sandwich complexes of iridium and ruthenium containing cysteine-derived ligands

scientific article published on 23 December 2016

Half-sandwich complexes of osmium containing guanidine-derived ligands

scientific article published on 25 September 2020

Half-sandwich organometallic complexes with stereogenic metal centres: Synthesis and characterization of diastereomeric [(ηn-ring)M(Aa)X] (Aa = α-amino carboxylate) compounds

Half-sandwich rhodium (and iridium) complexes as enantioselective catalysts for the 1,3-dipolar cycloaddition of 3,4-dihydroisoquinoline N-oxide to methacrylonitrile

scientific article published in January 2007

Heterobinuclear IrRh, RuRh and Rulr complexes with pyrazolate bridging ligands: reactivity towards chelating diphosphines; crystal structure of [(C5Me5)Ir(µ-pz)2(µ-CO)-Ir(CO)(dppen)]BPh4·0.5MeOH [pz = pyrazolate, dppen =cis-1,2-bis(diphenylphosphi

Heterodinuclear Iridium Cyclooctadiene Complexes with the [(η5-C5H5)Fe(η6-(1,1-di(2-propenyl)-3-butenyl)benzene)]+Ligand

scholarly article by Silvia Marcén et al published January 2002 in Organometallics

Heterogeneous catalysts based on supported Rh–NHC complexes: synthesis of high molecular weight poly(silyl ether)s by catalytic hydrosilylation

Heteronuclear and heterovalent diphenylphosphido-bridged complexes of rhodium, iridium and ruthenium. Crystal structure of [(C5Me5)ClRh(μ-Cl)(μ-PPh2)Rh(COD)] · Et2O (COD = 1,5-cyclooctadiene)

scholarly article by Montserrat Esteban et al published January 1991 in Journal of Organometallic Chemistry

Homo- and hetero-binuclear complexes containing the anion [Rh(C5Me5){PO(OMe)2}2(pyrazolate)]–as ligand. Crystal structure of [(C5Me5)Rh{µ-PO(OMe)2}2(µ-C3H3N2)-Ru(C6H6)]ClO4·CH2Cl2

Hydridorhodathiaboranes: Synthesis, Characterization, and Reactivity

Hydroxo–Rhodium–N-Heterocyclic Carbene Complexes as Efficient Catalyst Precursors for Alkyne Hydrothiolation

Iridium(I) Complexes with Hemilabile N-Heterocyclic Carbenes: Efficient and Versatile Transfer Hydrogenation Catalysts

scholarly article by M. Victoria Jiménez et al published 24 October 2011 in Organometallics

Labile Rhodium(I)–N-Heterocyclic Carbene Complexes

Metal as Source of Chirality in Octahedral Complexes with Tripodal Tetradentate Ligands

scientific article

Metal–Nitroalkene and aci-Nitro Intermediates in Catalytic Enantioselective Friedel–Crafts Reactions of Indoles with trans-β-Nitrostyrenes

Methylene- and diamidonaphthalene-bridged diiridium(III) complexes

Mn2+as a probe in RbCaF3: local order parameter of the structural phase transition measured by ENDOR

Modification of [8,8,8-(H)(PPh3)2-9-(Py)-nido-8,7-RhSB9H9], Py = NC5H5, with Monodentate Phosphines: Reactivity and Mechanistic Insights

Mononuclear rhodium and iridium compounds with pyridyl-pyrazole ligands

scholarly article by Ana P. Martínez et al published March 2005 in Inorganica Chimica Acta

NH3-promoted ligand lability in eleven-vertex rhodathiaboranes

scientific article

Novelgem-Dithiolato-Bridged Rhodium Hydroformylation Catalysts: Bridging the Gap in Dinuclear Rhodium Thiolate Chemistry

scholarly article by Marc A. F. Hernandez-Gruel et al published December 2007 in European Journal of Inorganic Chemistry

ONO Dianionic Pincer-Type Ligand Precursors for the Synthesis of σ,π-Cyclooctenyl Iridium(III) Complexes: Formation Mechanism and Coordination Chemistry

scholarly article by Duc Hanh Nguyen et al published 8 November 2013 in Organometallics

Optically active pseudoctahedral rhodium(III), iridium(III), and ruthenium(II) complexes with α-amino acidato ligands. Crystal structures of RIrSCSN- and SIrSCSN-[(C5Me5)Ir(pro)Cl] · H2O (Hpro = l-proline)

scholarly article by Daniel Carmona et al published October 1990 in Journal of Organometallic Chemistry

Oxidative addition of I2, MeI, and CH2I2to the naphthalene-1,8-diamide bridged complex [Ir2{µ-1,8-(NH)2C10H6}(CO)2(PPh3)2]. X-Ray crystal structure of [Ir2I2(µ-CH2){µ-1,8-(NH)2C10H6}(CO)2(PPh3)2]·CH2Cl2

article

Oxidative-addition reactions of Mel or CH2I2to [M2(µ-pz)(µ-SBut)(CO)2{P(OMe)3}2](M = Rh or Ir) complexes. X-Ray structure of [Ir2(µ-pz)(µ-SBut)(µ-CH2)I2(CO)2{P(OMe)3}2](pz = pyrazolate)

article

P-H activation of secondary phosphanes on a parent amido diiridium complex

scientific article published in January 2014

Pentamethylcyclopentadienyl-iridium(iii) complexes with pyridylamino ligands: synthesis and applications as asymmetric catalysts for Diels–Alder reactions

scientific article published on 01 May 2007

Pentamethylcyclopentadienylrhodium complexes with the pyridazine ligand. Molecular structure of [{Rh(C5Me5)}2(µ-Cl)2(µ-pydz)][ClO4]2·H2O (pydz = pyridazine)

Postsynthetic modifications of [2,2,2-(H)(PPh3)2-closo-2,1-RhSB8H8] with Lewis bases: cluster modular tuning

scientific article published on 4 May 2016

Preparation and X-ray structure of a trinuclear rhodium complex with the polydentate 1,8-naphthyridine-2-one (onapy) ligand: [Rh3(μ3-onapy)2(CO)2(cod)2](ClO4)·1.5C2H4Cl2

scholarly article by Antonio Tiripicchio et al published January 1986 in Inorganica Chimica Acta

Preparation, X-ray structural analysis, and method of interconversion of two isomeric forms of [Os6(CO)16{P(OMe)3}2]

Proton-assisted hydrogen activation on polyhedral cations

scientific article published on 10 February 2013

Rational design of efficient rhodium catalysts for the anti-Markovnikov oxidative amination of styrene

scientific article published on 24 June 2010

Reactions of 11-vertex rhodathiaboranes with HCl: synthesis and reactivity of new Cl-ligated clusters

scientific article

Reactions of Diamidonaphthalene-Bridged Diiridium Tetrahydrides with Alkynes: Hydrogenation, Vinylidene Formation, and Catalytic C−C Coupling

Reactivity of [TiM 2 ] (M = Rh, Ir) and [TiIr 3 ] early-late heterobimetallic sulfido-bridged clusters

Reactivity of binuclear heterobridged iridium complexes with SnCl2

scholarly article by M. Teresa Pinillos et al published 1992 in Dalton transactions RSC

Reactivity of rhodium(III) complexes containing chelating pentachlorophenyl ligands. Molecular structures of fac-[Rh(C6Cl5)3(py)] and mer-[Rh(C6Cl5)3(tBuNC)3]

Reactivity of the Chiral Metallic Brønsted Acid [(η6-p-MeC6H4iPr)Ru(κ3P,O,O′-POH)][SbF6]2 (POH = (SC1,RC2)-Ph2PC(Ph)HC(OH)HCH2OMe) toward Aldimines

Reversible Activation of Water by an Air- and Moisture-Stable Frustrated Rhodium Nitrogen Lewis Pair

scientific article published on 20 August 2019

Reversible CO2Fixation by Iridium(I) Complexes Containing Me2PhP as Ligand

scholarly article by Jens Langer et al published 12 April 2010 in Organometallics

Reversible Opening of the Triangular Structure of a Sulfido-Bridged ZrRh2Early−Late Heterobimetallic Complex Induced by Bis-(diphenylphosphino)methane

Rhodium complexes of the binucleating ligands pyridine-2-thiolate and benzothiazole-2-thiolate. Crystal structures of [{Rh(µ-SC5H4N)(CO)2}2] and [{Rh(µ-SC5H4N)(tfbb)}2]·Me2CO (tfbb = tetrafluorobenzobarrelene)

scholarly article by Miguel A. Ciriano et al published 1989 in Dalton transactions RSC

Rhodium(I) Complexes with Hemilabile N-Heterocyclic Carbenes: Efficient Alkyne Hydrosilylation Catalysts

Rhodium(I) Complexes with Hemilabile Phosphines: Rational Design for Efficient Oxidative Amination Catalysts

Rhodium(I)-N-Heterocyclic Carbene Catalyst for Selective Coupling of N-Vinylpyrazoles with Alkynes via C–H Activation

article

Rhodium?tetranuclear complexes as building blocks for the construction of coordination polymers: chiroselectivity in the formation of [ClCuRh4(µ-PyS2)2(cod)4]n (H2PyS2= 2,6-dimercaptopyridine)

Sequential C-H activation and dinuclear insertion of ethylene promoted by a diiridium complex

scientific article published in February 2002

Some reactions of [Os3(µ-H)3(CO)9(µ3-CX)](X = OMe or Cl): the formation of C–N and C–P bonds

Square-planar rhodium(I) complexes partnered with [arachno-6-SB(9)H(12)]- : a route toward the synthesis of new rhodathiaboranes and organometallic/thiaborane salts

scientific article

Stepwise construction of [Os6(CO)18(µ6-P)]–, a hexanuclear osmium cluster monoanion with trigonal-prismatic co-ordination for phosphorus: X-ray crystal structures of [Os6(µ-H)2(CO)20(MeCN)(µ3-PH)] and [PPh3Me][Os6(CO)18(µ6-P)]

scholarly article by Stephen B. Colbran et al published 1988 in Dalton transactions RSC

Stepwise synthesis of [Os3(CO)8(R2C2)(R′2C2)] from [Os3(CO)10(R2C2)] under mild conditions, x-ray crystal structure of [Os3(CO)8(Ph2C2)2]; a bis(alkyne) without an osmacyclopentaidiene ring

Stereoselective oxidative additions of iodoalkanes and activated alkynes to a sulfido-bridged heterotrinuclear early-late (TiIr2) complex

scientific article published in June 2003

Stereospecific control of the metal-centred chirality of rhodium(iii) and iridium(iii) complexes bearing tetradentate CNN'P ligands

scientific article published on 26 May 2017

Steric Effects in the Oxidative Addition of MeI to a Sulfido-Bridged ZrRh2 Early–Late Heterobimetallic Compound

Structural and dynamic studies on amido-bridged rhodium and iridium complexes

scientific article published in July 2002

Syntheses and Reactivity of Functionalized (η5-Tetramethylcyclopentadienyl) Rhenium Complexes: Molecular Structures of (η5:η2-C5Me4CH2CH2CHCH2)Re(CO)2and (η5-C5Me4CH2-2-C4H3S)Re(CO)2(PMe3)

scholarly article by Fernando Godoy et al published November 2003 in Organometallics

Synthesis and Characterisation of New Iridium Complexes with the (4S)-2-[2-(Diphenylphosphanyl)phenyl]-4-isopropyl-1,3-oxazoline Ligand That Catalyse Asymmetric Michael Reactions

scholarly article by Daniel Carmona et al published May 2005 in European Journal of Inorganic Chemistry

Synthesis and Reactivity of Mononuclear (Pentachlorophenyl)rhodium(II) Complexes. Structural Relevance of Rhodium−o-Chlorine Secondary Bonding

scholarly article by María P. García et al published March 1997 in Organometallics

Synthesis and Stereochemistry of Half-Sandwich Alkynyl Amino Acidate Complexes of Rhodium(III), Iridium(III), and Ruthenium(II)

scholarly article by Daniel Carmona et al published June 2000 in Organometallics

Synthesis and catalytic activity of heterodinuclear Ru-Ir and Ru-Rh complexes. Crystal structure of [H(CO)(PPh3)2Ru(μ-Cl)(μ-pz)Ir(TFB)] (pz = pyrazolate, TFB = tetrafluorobenzobarrelene)

Synthesis and catalytic activity of well-defined Co(<scp>i</scp>) complexes based on NHC–phosphane pincer ligands

scientific article published in 2023

Synthesis and characterisation of the tetranuclear phosphinidene clusters [Os3MH2(CO)12(PR)](M = Os, R = Ph or cyclo-C6H11; M = Ru, R = cyclo-C6H11) and the crystal and molecular structure of [Os4(µ-H)2(CO)12(µ3-PC6H11)]

Synthesis and characterization of Ru(II), Rh(III) and Ir(III) complexes of the “Daniphos” ligands and their application in the hydrogen transfer catalysis

Synthesis and characterization of an unusual tetranuclear rhodium complex; X-ray molecular structure of [Rh4(µ-Cl)2(µ-az)2(µ-CO)2(CO)2(nbd)2](az = 7-azaindolate; nbd = norborna-2,5-diene)

scholarly article by Luis Oro et al published 1984 in Journal of the Chemical Society. Chemical communications

Synthesis and characterization of new 10- and 12-vertex CO-ligated metallathiaboranes

Synthesis and characterization of the alkoxycarbonyl complexes [(C5Me5)M(µ-pz)(µ-I)2Rhl(CO2R)(CO)](M = Rh, R = Me or Et; M = Ir, R = Me; pz = pyrazolate). Molecular structure of [(C5Me5)Ir(µ-pz)(µ-I)2Rhl(CO2Me)(CO)]

article published in 1990

Synthesis and molecular structure of [[(HBpz(3))Rh(PPh(3))(mu-Cl)(2)](2)Ag]BF(4) (Hpz = pyrazole), a heterotrinuclear Rh(2)Ag compound with square-planar silver(I).

scientific article published in May 2002

Synthesis and reactivity at the Ir-MeTpm platform: from κ1-N coordination to κ3-N-based organometallic chemistry

scientific article published on 01 May 2019

Synthesis and structure of chiral-at-metal complexes with the ligand (S)-2-[(Sp)-2-(diphenylphosphino)ferrocenyl]-4-isopropyloxazoline

Synthesis of [M(η2-C2Ph2)(CO)(PiPr3)2] (MOs or Ru) and X-ray crystal structure of the osmium derivative

scholarly article by Jesús Espuelas et al published April 1994 in Journal of Organometallic Chemistry

Synthesis of a Square-Planar Rhodium Alkylidene N-Heterocyclic Carbene Complex and Its Reactivity Toward Alkenes

Synthesis of mononuclear complexes of Ru and Os and heterobimetallic M–M′(M = Ru or Os; M′= Rh, Ir, or Au) compounds with pyrazolate or imidazolate type ligands. X-Ray crystal structure of [(Ph3P)2(OC)HRu(µ-bim)Rh(cod)](bim = dianion of 2,2′

Synthesis of tetranuclear rhodium and iridium complexes directed by 6-mercaptopyridin-2-ol: electrochemical behavior, chemical oxidation, and coordination chemistry

scientific article

Synthesis of transition-metal complexes with heterodifunctional ligands derived of NH(PPh2)2. Crystal structure of [(η5-C5Me5)RhCl{η2-P,Se-Ph2PNP(Se)Ph2}]·CH2Cl2

Synthesis, Characterization, Properties, and Asymmetric Catalytic Diels−Alder Reactions of Chiral-at-Metal Phosphinooxazoline-Rhodium(III) and −Iridium(III) Complexes§

scholarly article by Daniel Carmona et al published November 2002 in Organometallics

Synthesis, Molecular Structure and Catalytic Activity of Six-Coordinate Chloro(hydrido)- and Dihydridoruthenium(II) and -osmium(II) Complexes with the Chiral Ligands PiPr2NH(Me)Ph, (S,S)-Chiraphos and (S,S,)-Diop

scholarly article by Christoph Schlünken et al published June 2004 in European Journal of Inorganic Chemistry

Synthesis, Molecular Structure, and Reactivity of Iridium(I) and Iridium(III) Complexes Formed by Coordination and C−H Activation of the Substituted Arenes C6H5CH2CH2PiPr2and C6H5OCH2CH2PtBu2

scholarly article by Giuseppe Canepa et al published May 2003 in Organometallics

Synthesis, Reactivity, and Catalytic Activity of Triangular ZrM2(M = Rh, Ir) Early−Late Heterobimetallic Complexes

Synthesis, characterization and molecular structure of the hydroperoxo complex [(η5C5Me5)Ir(µ-pz)3Rh(OOH)(dppe)][BF4]; Hpz = pyrazole, dppe β 1,2-bis(diphenylphosphino)ethane

Synthesis, reactivity and catalytic activity of [RuH(η1-OCMe2)(CO)2(PPri3)2]BF4

Synthesis, structural characterization, and ligand replacement reactions of gem-dithiolato-bridged rhodium and iridium complexes

scientific article published on 29 May 2008

Synthesis, structure, and kinetic studies on [RuCl2(NCCH3)2(cod)]

Temperature Dual Enantioselective Control in a Rhodium-Catalyzed Michael-Type Friedel-Crafts Reaction: A Mechanistic Explanation.

scientific article published on 27 June 2016

Tetra- and tri-nuclear rhodiumpalladium complexes with the 1,2,4-triazolate ligand. Crystal structure of (η3-C3H5)2Pd2Rh2(μ3-tz)2Cl2(CO)4

scholarly article by Antonio Tiripicchio et al published June 1985 in Inorganica Chimica Acta

Tetranuclear Complexes as Intermediates in Transannular Oxidative-Addition Reactions. Structure of the First Tetrairidium Linear Cluster

article

Tetranuclear [Rh4(mu-PyS2)2(diolefin)4] complexes as building blocks for new inorganic architectures: synthesis of coordination polymers and heteropolynuclear complexes with electrophilic d8 and d10 metal fragments

scientific article published in February 2004

The Anions [Cptt2Zr(μ-S)2M(CO)2]-(M = Rh, Ir) as Versatile Precursors for the Synthesis of Sulfido-Bridged Early−Late Heterotrimetallic (ELHT) Compounds†

The Stepwise Reaction of Rhodium and Iridium Complexes of formula [MCl2(κ4C,N,N',P-L)] with Silver Cations: A Case of trans-Influence and Chiral Self-Recognition

scientific article

The complete characterization of a rhodium Lewis acid-dipolarophile complex as an intermediate for the enantioselective catalytic 1,3-dipolar cycloaddition of C,N-diphenylnitrone to methacrolein

scientific article published in March 2004

The rhodium and iridium co-ordination chemistry of the hemilabile hybrid ligand 1-(2′-pyridyl)-3-dimethylamino-2-propen-1-one

scholarly article by Ana P Martı́nez et al published April 2003 in Inorganica Chimica Acta

The unexpected synthesis of rhodium(I) complexes with the 1-(2′-pyridyl)-3-oxo-1-propenoxide anionic ligand

scholarly article by Ana P. Martı́nez et al published April 2002 in Inorganic Chemistry Communications

Trans Additions of Silanes to 1-Alkynes Catalyzed by Ruthenium Complexes: Role of in Situ Formed Polynuclear Aggregates

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Trinuclear aggregates of rhodium and iridium supported by thiolate bridges: synthesis and crystal structure

scholarly article by Miguel A. Ciriano et al published 1992 in Dalton transactions RSC

Trinuclear angular aggregates of rhodium: synthesis and crystal structures of [Rh3(µ3-SC5H4N)2(CO)6][ClO4](SC5H4N = pyridine-2-thiolate) and [Rh3(µ3-C7H4NS2)2(CO)2(PPh3)2(tfbb)][ClO4](C7H4NS2= benzothiazole-2-thiolate, tfbb = tetrafluorobenzobarrel

scholarly article by Miguel A. Ciriano et al published 1990 in Dalton transactions RSC

Trinuclear iridium and rhodium complexes: the solution to a puzzle involving the multiple coordination possibilities of 1,8-naphthyridine-2-one ligands

scholarly article by B.Eva Villaroya et al published September 1996 in Inorganica Chimica Acta

Tris(pentafluorophenyl) neutral and anionic five-co-ordinate complexes of rhodium(III). Crystal structures of [Rh(C6F5)3(PEt3)2] and [Rh(C6F5)3(AsPh3)2]

Unsaturated Iridium(III) Complexes Supported by a Quinolato–Carboxylato ONO Pincer-Type Ligand: Synthesis, Reactivity, and Catalytic C–H Functionalization

scholarly article by Duc Hanh Nguyen et al published 8 November 2013 in Organometallics

Zwitterionic Rhodium and Iridium Complexes Based on a Carboxylate Bridge-Functionalized Bis-N-heterocyclic Carbene Ligand: Synthesis, Structure, Dynamic Behavior, and Reactivity.

scientific article published on 6 April 2018

[CpTi(μ3-S)3{Rh(tfbb)}3]: An early-late heterometallic complex as molecular model for the deactivation of metal sulphide catalysts

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