Search filters

List of works by Pablo Espinet

1,2-Insertion and β-Elimination

14-Electron T-shaped [PdRXL] complexes: evidence or illusion? Mechanistic consequences for the stille reaction and related processes

scientific article published on 01 November 2002

19F NMR in organometallic chemistry

4-Pyridylisocyanide gold(i) and gold(i)-plus-silver(i) luminescent and mechanochromic materials: the silver role

scientific article published on 01 July 2019

A Convenient Quick Synthesis of SnBu2RCl Derivatives

A Critical Analysis of the Cyclic and Open Alternatives of the Transmetalation Step in the Stille Cross-Coupling Reaction

scientific article published on 01 November 2006

A DFT Study of the Effect of the Ligands in the Reductive Elimination from Palladium Bis(allyl) Complexes†

A deep tetranuclear metallo-cavitand with bis(aryl) palladium bridges

scientific article published on 20 May 2010

A warning on the use of radical traps as a test for radical mechanisms: they react with palladium hydrido complexes

scientific article published in September 2002

Acyl–Carbene and Methyl–Carbene Coupling via Migratory Insertion in Palladium Complexes

Alignment of Palladium Complexes into Columnar Liquid Crystals Driven by Peripheral Triphenylene Substituents

scientific article published on 17 March 2014

Alkynylisocyanide Gold Mesogens as Precursors of Gold Nanoparticles

scientific article published on 04 August 2011

Allylic Complexes of Palladium(II)

Anionic platinum complexes with 2-pyridylphosphines as ligands for rhodium: synthesis of zwitterionic Pt-Rh organometallic compounds

scientific article

Aryl palladium carbene complexes and carbene-aryl coupling reactions

scientific article published in February 2005

Asymmetric Negishi reaction for sterically hindered couplings: synthesis of chiral binaphthalenes

Azo Isocyanide Gold(I) Liquid Crystals, Highly Birefringent and Photosensitive in the Mesophase

scientific article published on 01 July 2009

Batch Stille Coupling with Insoluble and Recyclable Stannylated Polynorbornenes

Bimetallic catalysis using transition and Group 11 metals: an emerging tool for C-C coupling and other reactions

scientific article published on 20 January 2012

Binuclear mesogenic copper(i) isocyanide complexes with an unusual inorganic core formed by two tetrahedra sharing an edge

scientific article published in November 2002

Bis (pentafluorophenyl) complexes of palladium(II) and of platinum(II)

Bis(fluoromesityl) Palladium Complexes, Archetypes of Steric Crowding and Axial Protection byortho Effect− Evidence for Dissociative Substitution Processes− Observation of19F−19F Through-Space Couplings

Bis(pentafluorophenyl)-platinum(II) and -platinum(IV) complexes

C(C6F4PPh2-o)NMe a C,P-chelate and C,N-bridging ligand. Crystal structure of

C-C reductive elimination in palladium complexes, and the role of coupling additives. A DFT study supported by experiment

scientific article published in March 2009

Carbene and Carbonyl Transfer from [W(CO)5(carbene)] to Palladium, Affording Palladium(II) Carbene Acyl Complexes

scholarly article by Isabel Meana et al published August 2008 in Organometallics

Catalytic System for Heck Reactions Involving Insertion into Pd−(Perfluoro-organyl) Bonds

scientific article published on 01 November 2001

Catalytic System for the Heck Reaction of Fluorinated Haloaryls

Cationic (fluoromesityl)palladium(II) complexes

Cationic Intermediates in the Pd-Catalyzed Negishi Coupling. Kinetic and Density Functional Theory Study of Alternative Transmetalation Pathways in the Me–Me Coupling of ZnMe2andtrans-[PdMeCl(PMePh2)2]

scientific article published on 08 August 2011

Cationic palladium(II) complexes involving unprecedented O-coordination of acetylmethylenetriphenylphosphorane

Cationic pentafluorophenyl isonitrile complexes of palladium and their conversion to carbene and imidoyl complexes

Columnar Mesophases in Hybrid Organic−Inorganic Supramolecular Aggregates: Liquid Crystals of Fe, Cr, Mo, and W at Room Temperature, Built from Triazines and Metalloacid Complexes

Comparing Protonolysis and Transmetalation Reactions: Microcalorimetric Studies of C-AuI Bonds in [AuRL] Complexes

scientific article published on 14 August 2018

Competition of Insertion and Transmetalation Pathways in the Reactions of Alkenylsilanes with Aryl Complexes of Palladium(II). An Experimental Study§

article

Complexes of Palladium(0)

Compounds with Palladium–Carbon σ-Bonds

scholarly article published 1982

Conformational Mobility in Chelated Square-Planar Rh, Ir, Pd, and Pt Complexes

article

Conformational preferences driven by the C-methyl substituent in chelated o-diphenylphosphino-alpha-methyl-N,N-dimethylbenzylamine rhodium complexes

scientific article

Cross Alkyl–Aryl versus Homo Aryl–Aryl Coupling in Palladium-Catalyzed Coupling of Alkyl–Gold(I) and Aryl–Halide

Crown-shaped tetrametallic imidoyl complexes of palladium. X-Ray crystal structure of [{[Pd2{µ-C(C6F5)NMe}2](µ-Cl)(µ-MeCO2)}2]

Cyclization versus Pd−H Elimination−Readdition: Skeletal Rearrangement of the Products of Pd−C6F5Addition to 1,4-Pentadienes

article

Cyclopalladated Complexes of Perylene Imine: Formation of Acetato-Bridged Dinuclear Complexes with 6,6- and 5,6-Membered Metallacycles

Cyclopalladated complexes of perylene imine: mononuclear complexes with five- or six-membered metallacycles

scientific article published on 28 June 2011

Cyclopentadienyl and Arene Complexes of Palladium(II)

Detection and reactivity of a palladium alkoxycarbene

scientific article published on 21 May 2012

Diamine-catalyzed addition of ZnEt2 to PhC(O)CF3 : two mechanisms and autocatalytic asymmetric enhancement

scientific article published on 15 September 2014

Diene Complexes of Palladium

Dimeric palladium complexes with bridging aryl groups: when are they stable?

scientific article published in December 2004

Dinuclear Gold(I) Isocyanide Complexes with Luminescent Properties, and Displaying Thermotropic Liquid Crystalline Behavior

scientific article published on 01 December 2006

Dinuclear azolato-bridged complexes of the nickel group metals with haloaryl ligands: a reinvestigation of their behavior in solution.

scientific article published in March 2000

Diverse behaviour of imidoyl bridges towards neutral nucleophiles: Bridge cleavage, isonitrile elimination, and formation of zwitterionic palladium complexes. X-ray structure of [(tmen)d&{;μ-C(C6F5)=NMe&};2dCl2]

Dramatic mechanistic switch in Sn/Au(I) group exchanges: transmetalation vs. oxidative addition.

scientific article published in March 2016

Dual Behavior of Cationic Palladium Pentafluorophenyl Complexes as Catalysts for the Homopolymerization of Acrylates and of Nonpolar Olefins

Effect of alkoxy chains on the mesomorphic properties of (p-alkoxy)tetrafluoroarylgold(I) isocyanide complexes

Effect of excess halide on the palladium-catalyzed insertion-triggered radical copolymerization of methyl acrylate and 1-hexene

Effect of microwave heating in the asymmetric addition of dimethylzinc to aldehydes

article

Effect of the Position and Number of Chiral Carbons on Ferroelectric Liquid Crystals from Multichain Mononuclearortho-Palladated Complexes

Efficient Synthesis of Chiral 1,1′-Binaphthalenes by the Asymmetric Suzuki–Miyaura Reaction: Dramatic Synthetic Improvement by Simple Purification of Naphthylboronic Acids

scientific article published on 01 December 2006

Efficient silylformylation of alkynes catalyzed by rhodium complexes with P,N donor ligands

Enthalpy of ligand substitution in cis organopalladium complexes with monodentate ligands

scientific article published on 27 August 2009

Experimental Study of the Mechanism of the Palladium-Catalyzed Aryl–Alkyl Negishi Coupling Using Hybrid Phosphine–Electron-Withdrawing Olefin Ligands

Experimental study of speciation and mechanistic implications when using chelating ligands in aryl-alkynyl Stille coupling

scientific article published on 07 August 2020

Exploring the Scope of Nitrogen Acyclic Carbenes (NACs) in Gold-Catalyzed Reactions

Feasibility of Storing Latent Heat with Liquid Crystals. Proof of Concept at Lab Scale

Ferroelectric liquid crystal behavior in platinum orthometallated complexes

Final Analysis: Is Gold a Catalyst in Cross-Coupling Reactions in the Absence of Palladium?

article published in 2011

Fluorene-based stannylated polymers and their use as recyclable reagents in the Stille reaction

Fluorescent perylenylpyridine complexes: an experimental and theoretical study

scientific article published on 18 September 2020

Fluorinated vs Nonfluorinated PR2(biaryl) Ligands and Their [AuCl(L)] Complexes: Synthesis, X-ray Structures, and Computational Study of Weak Interactions. Bond, No Bond, and Beyond

scientific article published on 29 October 2020

Fluorophobic Effect in Metallomesogens – The Synthesis and Mesomorphism of Ag, Au, Cu, Fe, Pd, and Pt Fluorous Isocyanide Complexes

Formation of Trinuclear Palladium Orthometalated Complexes with Unprecedented Asymmetrical (μ3-S)(μ3-X) Bridges (X = OH, SR, O2CR) from μ2-Hydroxo Dimeric Complexes and CS2†

scientific article published on 01 February 2004

Formation of a Vinyliminium Palladium Complex by C−C Coupling in Vinylcarbene Palladium Aryl Complexes

scholarly article by Ana C. Albéniz et al published February 2006 in Organometallics

Functional isocyanide metal complexes as building blocks for supramolecular materials: hydrogen-bonded liquid crystals

scientific article published on 7 June 2007

Genuine Examples of Tetrahedral Tetradentate Sulfide Ligand Bridging Four Pd Atoms: Controlled Formation of [(μ4-S){(μ2-X)Pd2(C∧N)2}2] (X = OH or Cl; HC∧N =p-C2H5OC6H4CHNC6H4-p-C2H5) Complexes

scientific article published on 10 February 2007

Gold Liquid Crystals Displaying Luminescence in the Mesophase and Short F⋅⋅⋅F Interactions in the Solid State

scientific article published on 01 February 2005

Gold(I) complexes with hydrogen-bond supported heterocyclic carbenes as active catalysts in reactions of 1,6-enynes

scientific article

Gold(I)-carbenes derived from 4-pyridylisocyanide complexes: supramolecular macrocycles supported by hydrogen bonds, and luminescent behavior

scientific article

H-Bonded adducts of [2,4,6-{(C10H21O)3C6H2NH}3C3N3] with [LnM{PPh2(C6H4CO2H)}] displaying columnar mesophases at room temperature

scientific article published in October 2014

Heterometallic Complexes by Transmetalation of Alkynyl Groups from Copper or Silver to Allyl Palladium Complexes: Demetalation Studies and Alkynyl Homocoupling

article published in 2013

Higher fluorescence in platinum(iv) orthometallated complexes of perylene imine compared with their platinum(ii) or palladium(ii) analogues

scientific article published on 01 September 2015

Highly Enantioselective Addition of Dialkylzinc to Trifluoroacetophenones, Catalyzed by 1,2-Diamines. Synthesis of Key Fragments of Inhibitors of the Enzyme 11β-HSD1 and Kinetic Analysis of the Process†

article

Highly fluorescent complexes with 3-isocyanoperylene and N-(2,5-di-tert-butylphenyl)-9-isocyano-perylene-3,4-dicarboximide

scientific article published on 01 July 2014

Highly fluorescent complexes with gold, palladium or platinum linked to perylene through a tetrafluorophenyl group

scientific article published on 01 May 2013

Highly fluorescent platinum(II) organometallic complexes of perylene and perylene monoimide, with Pt σ-bonded directly to the perylene core

scientific article published on October 2010

In Situ Generation of ArCu from CuF2 Makes Coupling of Bulky Aryl Silanes Feasible and Highly Efficient

scientific article published on 19 February 2016

Insertion of MeNC into PdC6Cl5 bonds. Bridged and terminal N-methylpentachlorobenzimidoylpalladium(II) complexes

Insertion of mercury into iron–halogen bonds. X-Ray structure of [(p-MeC6H4NC)5Fe → HgI2]

Insertion reactions of 1,4-diisocyanobenzene in binuclear Pd(I) complexes

Insights into the mechanism of the Negishi reaction: ZnRX versus ZnR2 reagents

scientific article

Ionic metallomesogens derived from silver(I) bis-amine complexes: Structure and mesogenic behavior

Is there any bona fide example of O–H⋯F–C bond in solution? The cases of HOC(CF3)2(4-X-2,6-C6H2(CF3)2) (X = Si(i-Pr)3, CF3)

scientific article published on 15 August 2007

Isocyano-Triphenylene Complexes of Gold, Copper, Silver, and Platinum. Coordination Features and Mesomorphic Behavior

Liquid Crystals Based on Gold Compounds

Liquid crystalline behaviour in gold(i) and silver(i) ionic isocyanide complexes: smectic and columnar mesophases

Liquid crystalline salen manganese(iii) complexes. Mesomorphic and catalytic behaviour

scientific article published on 03 May 2011

Liquid crystals based on pseudohalogold(i) isocyanide complexes

Liquid-crystalline self-organization of isocyanide-containing dendrimers induced by coordination to gold(I) fragments

scientific article published in February 2010

Luminescence and mesogenic properties in crown-ether-isocyanide or carbene gold(I) complexes: luminescence in solution, in the solid, in the mesophase, and in the isotropic liquid state

scientific article

Luminescent gold(I) metallo-acids and their hydrogen bonded supramolecular liquid crystalline derivatives with decyloxystilbazole as hydrogen acceptor

scientific article

Luminescent goldI carbenes from 2-pyridylisocyanide complexes: structural consequences of intramolecular versus intermolecular hydrogen-bonding interactions

scientific article published in February 2008

MeNC Insertion into Pd–C6F5bonds: bis(µ-imidoyl-C,N)palladium complexes, a novel type of imidoyl co-ordination in palladium chemistry. Single-crystal X-ray structure of [Pd2{µ-C(C6F5)N(Me)}2Cl2(SC4H8)2]

Mechanism of the Stille Reaction. 1. The Transmetalation Step. Coupling of R1I and R2SnBu3Catalyzed bytrans-[PdR1IL2] (R1= C6Cl2F3; R2= Vinyl, 4-Methoxyphenyl; L = AsPh3)

article by Arturo L. Casado & Pablo Espinet published September 1998 in Journal of the American Chemical Society

Mechanism of the Stille Reaction. 2. Couplings of Aryl Triflates with Vinyltributyltin. Observation of Intermediates. A More Comprehensive Scheme

scientific article published in 2000

Mechanism of the rhodium-catalyzed asymmetric isomerization of allylamines to enamines

scientific article published in January 2008

Mesogenic Nickel and Palladium Complexes with Pincer Ligands Derived from Pyridine-2,6-bis(thiocarboxylic) Acid

scholarly article by Pablo Espinet et al published February 2004 in Chemistry of Materials

Mesogens based on palladium orthometallated complexes with carboxylato bridges: tuning and shaping a non-planar molecule

Mesomorphic Mixtures of Metal Isocyanide Complexes, Including Smectic C Mesophases at Room Temperature and Liquid Crystalline “Molecular Alloys”

Mesomorphic trigonal bipyramidal iron(0) isocyanide complexes

Microwave assisted asymmetric Suzuki-Miyaura and Negishi cross-coupling reactions: synthesis of chiral binaphthalenes

Molecular and Merrifield supported chiral diamines for enantioselective addition of ZnR2 (R = Me, Et) to ketones

article

Mono- and dinuclear luminescent 1,1′-biisoquinoline gold(I) complexes

Mononuclear, dinuclear, and hexanuclear goldI complexes with (aza-15-crown-5)dithiocarbamate

scientific article published in February 2008

Monoolefin and Acetylene Complexes of Palladium

Neutral Organometallic Palladium(II) Aquo Complexes

Neutral and Cationic Complexes with P-Bonded 2-Pyridylphosphines as N-Donor Ligands toward Rhodium. Electrical Charge vs Steric Hindrance on the Conformational Control

scientific article published on 01 August 2006

Neutral and anionic pentafluorophenyl complexes of palladium and platinum(II) and their reactivity towards amines

New organometallic liquid crystals I. Orthopalladated imine derivatives

Nitrogen Acyclic Gold(I) Carbenes: Excellent and Easily Accessible Catalysts in Reactions of 1,6-Enynes

Observation of a Hidden Intermediate in the Stille Reaction. Study of the Reversal of the Transmetalation Step

scientific article published on 18 July 2008

Observation of the direct products of migratory insertion in aryl palladium carbene complexes and their subsequent hydrolysis

scientific article published on 01 July 2002

On the requirements of the precursor complex for olefin insertion: reactivity of cis- and trans-Pd(C6F5)(L)2+ with dienes

Organometallic Nucleophiles and Pd: What Makes ZnMe2 Different? Is Au Like Zn?

Oxidative addition of methyl iodide to bis(phenyl)(chelate)platinum(II) complexes

article

Palladium Catalysts for Norbornene Polymerization. A Study by NMR and Calorimetric Methods

Palladium Complexes Derived from Reactions with Acetylenes

Palladium Round Trip in the Negishi Coupling of trans-[PdMeCl(PMePh2)2] with ZnMeCl: An Experimental and DFT Study of the Transmetalation Step

scientific article (publication date: 7 July 2010)

Palladium(I) and Cluster Complexes

Palladium(II) allylic complexes by carbene transmetalation and migratory insertion reactions: Synthesis and side reactions

Palladium(II) complexes of 3,3′-, 5,5′-, and 7,7′-dimethyl-2,2′-biindazole

Palladium(II) metallomesogens of crown ether derivatized imines, and their sodium adducts

Palladium-Based System for the Polymerization of Acrylates. Scope and Mechanism

Palladium: Introduction and General Principles

Pd–H elimination reactions in palladium(ii) allylic complexes

scientific article published on 06 July 2007

Pentafluorophenyl complexes of palladium and platinum containing chelating and bridging Fe(C5H4PPh2)2 or Fe(C5H4SPh)2

Pentafluorophenyl complexes of palladium and platinum containing chelating, unidentate, or bridging Ph2PCH2PPh2ligands

Pentamethylcyclopentadienyl-rhodium and -iridium complexes XXV. Rhodium complexes derived from m- and p-dihydroxybenzenes

scholarly article by Pablo Espinet & Peter M. Maitlis published October 1979 in Journal of Organometallic Chemistry

Pentamethylcyclopentadienyl-rhodium and -iridium complexes. Part 22. Blue five-co-ordinate rhodium(III) complexes derived from catechol and related compounds

scholarly article by Pablo Espinet et al published 1979 in Dalton transactions RSC

Pentamethylcyclopentadienyl-rhodium and -iridium complexes. Part 26. Dicationic η5-aniline and η6-anisole complexes

scholarly article by Pablo Espinet et al published 1980 in Dalton transactions RSC

Perylenecarboxydiimide-gold(I) organometallic dyes. Optical properties and Langmuir films

Phenylbis(2- pyridyl)phosphine: P- vs. N,N′-coordination in carbonylmolybdenum-(O) and -(II) complexes

Phosphine-pyridyl and related ligands in synthesis and catalysis

article published in 1999

Phosphines with Tethered Electron-Withdrawing Olefins as Ligands for Efficient Pd-Catalyzed Aryl-Alkyl Coupling

Photoisomerizable metallomesogens and soft crystals based on orthopalladated complexes

scientific article published on October 2010

Photosensitive azobispyridine gold(i) and silver(i) complexes

scientific article published on 31 January 2011

Polymer [Pd(CH2SO2C6H4Me)2]n, a precursor to remarkably stable Pd organometallics.

scientific article

Polymerization of Acrylates by Neutral Palladium Complexes. Isolation of Complexes at the Initial Steps

Polynuclear platinum–silver, –copper, and –gold acetylide complexes. Molecular structure of [Pt2Ag4(CCBut)8]

Predominance of bridging coordination in luminescent 1,1′-biisoquinoline silver(I) derivatives

Preparation of Halo- or Pseudohalo Methyl Bis (Phenyl)(Chelate) Platinum(IV) Complexes

Promoting Difficult Carbon-Carbon Couplings: Which Ligand Does Best?

scientific article published on 16 September 2016

Protection of the Gold(I) Catalyst by AsPh3in Reactions of Enynes

Quantitative Evaluation of the Factors Contributing to the “Copper Effect” in the Stille Reaction

Ranking Ligands by Their Ability to Ease (C<sub>6</sub>F<sub>5</sub>)<sub>2</sub>Ni<sup>II</sup>L → Ni<sup>0</sup>L + (C<sub>6</sub>F<sub>5</sub>)<sub>2</sub> Coupling versus Hydrolysis: Outstanding Activity of PEWO Ligands

scientific article published on 08 December 2020

Reactions of [Pd(C6F5)2(CNR)2] with [PdCl2(NCPh)2]. Insertion of p-MeC6H4NC into Pd-C6F5 bonds

Reactivity of cis-[Pd4(μ-X)4μ-C(C6F5)NMe4] (X  Cl, Br, 1) towards neutral bidentate ligands

Reactivity of tetra-n-butylammonium di-µ-chloro-bis[bis(pentafluorophenyl)palladate(II)]. A general method for the synthesis of cis isomers of neutral and anionic palladium(II) complexes

RhI Ar/AuI Ar' Transmetalation: A Case of Group Exchange Pivoting on the Formation of M-M' Bonds through Oxidative Insertion

scientific article published on 07 February 2019

Rhodium Complexes with the Chelating and Binucleating Ligands P(CH2CH2Py)nPh3-n(Py = 2-Pyridyl;n= 1, 2): Structures and Fluxional Behavior

scientific article published on 01 February 2000

Room-temperature columnar mesophases in triazine-gold thiolate metal-organic supramolecular aggregates

scientific article

Selective Deposition of Gold Nanoparticles on or Inside Carbon Nanotubes and Their Catalytic Activity for Preferential Oxidation of CO

Selective Green Coupling of Alkynyltins and Allylic Halides to Trienynes via a Tandem Double Stille Reaction

Self-Organization of Dendritic Supermolecules, Based on Isocyanide–Gold(I), –Copper(I), –Palladium(II), and –Platinum(II) Complexes, into Micellar Cubic Mesophases

scientific article published on 01 January 2008

Single-bridged halide or pseudohalide complexes of palladium(II)

Single-bridged pseudohalide complexes

article published in 1979

Solvent-Induced Reduction of Palladium-Aryls, a Potential Interference in Pd Catalysis

Speciation of ZnMe2, ZnMeCl, and ZnCl2 in Tetrahydrofuran (THF), and Its Influence on Mechanism Calculations of Catalytic Processes

Stable Nickel Catalysts for Fast Norbornene Polymerization: Tuning Reactivity

scholarly article by Juan A. Casares et al published October 2005 in European Journal of Inorganic Chemistry

Stannylated polynorbornenes as new reagents for a clean Stille reaction

scientific article published in January 2008

Stille Coupling of Alkynyl Stannane and Aryl Iodide, a Many-Pathways Reaction: The Importance of Isomerization

article published in 2011

Stille coupling involving bulky groups feasible with gold cocatalyst

scientific article published on 22 January 2013

Striking Increase in Hole Mobility upon Metal Coordination to Triphenylene Schiff Base Semiconducting Multicolumnar Mesophases

scientific article published on 10 July 2020

Striking ligand-disproportionative Cl/aryl scrambling in a simple Au(III) system. Solvent role, driving forces and mechanisms

scientific article published on 09 December 2020

Strong Metallophilic Interactions in the Palladium Arylation by Gold Aryls

scientific article published on 04 April 2012

Structural Switching in Luminescent Polynuclear Gold Imidoyl Complexes by Intramolecular Hydrogen Bonding

Structural and dynamic studies in solution of anionic dinuclear azolato-bridged palladium(II) complexes

Structural studies of mesogenic orthopalladated imine derivatives

Study of Pd-elimination under carbonylation conditions: Regioselective formation of esters

article published in 1998

Study of the Replacement of Weak Ligands on Square-Planar Organometallic Nickel(II) Complexes. Organo-Nickel Aquacomplexes

scientific article published on 01 February 2007

Supramolecular Aggregates in Fluid Phases: Mesomorphicortho-Palladated Complexes with Substituted Crown Ethers and Their Potassium Adducts

Supramolecular aggregates of metallo–organic acids with stilbazoles. Formation of columnar mesophases and Langmuir films

article

Supramolecular coordination polymers of silver(I) with 2-isocyanopyridine or 1,2-phenylenediisocyanide

Supramolecular organization in copper(i) isocyanide complexes: copper(i) liquid crystals from a simple molecular structure

Synergistic π–π and Pt–Pt interactions in luminescent hybrid inorganic/organic dual columnar liquid crystals

Syntheses and reactivity of pentachlorophenylpalladium(I) derivatives. Molecular structure of Pd2(μ-dppm)2(C6Cl5)2

Synthesis and Characterization of Gold(I) Complexes with 9-(4-Isocyanophenyl)carbazole or 9-Ethyl-3-isocyanocarbazole Ligands

Synthesis and catalytic activity of gold chiral nitrogen acyclic carbenes and gold hydrogen bonded heterocyclic carbenes in cyclopropanation of vinyl arenes and in intramolecular hydroalkoxylation of allenes

scientific article published on November 2010

Synthesis and characterization of cis-bis[(p-tolylsulfonyl)methyl]palladium(II) complexes

Synthesis and phase behaviour of mesomorphic transition-metal complexes of alkoxydithiobenzoates

Synthesis and properties of crown ether isocyanide silver(I) derivatives: X-ray structure of a self-assembled 22-membered diargentacycle

Synthesis and reactivity of binuclear perhalogenophenyl derivatives of platinum(I). Molecular structure of [Pt2(C6F5)2(CO)2(PPh3)2]·0.4CHCl3

Synthesis and reactivity of neutral and cationic pentafluorophenyl platinum(I) derivatives

Synthesis and reactivity of palladium complexes with N,N′-di-p-tolyl-formamidine, -triazene or -formamidinato ligands. Insertion of CNC6H4Me-p, CS2 or CO2 into a PdN bond

Synthesis and structure of neutral and cationic pentahaloarylpalladium(II) isonitrile complexes

Synthesis of (NBu4)2[Pd2(μ-Br)2(C6X5)2Br2] (X=F, Cl), new and more versatile precursors of pentahalophenyl derivatives of palladium(II)

article published in 1989

Synthesis of gold-(I) and -(III) complexes with carbonyl-stabilized phosphorus ylides. Crystal structure of [{Au(PPh3)}2{µ-C(PPh3)CO2Et}]ClO4

Synthesis of heterobimetallic complexes containing cobalt–platinum or rhodium–platinum dative bonds. Molecular structure of [(η5-C5H5)(CO)2Rh→Pt(C6F5)2(CO)]

scholarly article by Rafael Usón et al published 1988 in Dalton transactions RSC

Synthesis of mono- and polynuclear perhalophenyl palladium-platinum acetylide complexes. Molecular structure of (NBu4)2[Pt2Ag2(C6F5)4(CCPh4] · 4CH2Cl2

scholarly article by Pablo Espinet et al published February 1991 in Journal of Organometallic Chemistry

Synthesis of neutral and cationic pentafluorophenylpalladium(I) derivatives. Insertion versus coordination of isocyanides in binuclear palladium(I) complexes

article published in 1983

Synthesis, crystal structure and second-order nonlinear optical properties of the trinuclear palladium orthometalated complex [(μ3-S)(μ3-OH)Pd3(C^N)3] (HC^N=p-–C6H4–CHN–C6H4–NO2-p)

Terminal pentafluorobenzimidoylpalladium(II) complexes. X-ray structure of trans-[Pd{C(C6F5)NMe}Cl(CNMe)2]

Tetrameric and Polymeric Cyano-Bridged Complexes of Palladium(II)

scholarly article by R. Usón et al published January 1983 in Synthesis and Reactivity in Inorganic, Metal Organic, and Nano Metal Chemistry

The Amide Group as Modulator of Crystalline and Liquid Crystalline Structures in Isocyano-Alkylanilide Silver(I) Complexes

The Negishi Catalysis: Full Study of the Complications in the Transmetalation Step and Consequences for the Coupling Products

The Origin of Hindered Rotation around the Pt−N Bond in Platinum Amides

scientific article published on 01 August 2001

The Stille Reaction, 38 Years Later

The decisive role of ligand metathesis in Au/Pd bimetallic catalysis

scientific article published on 11 July 2013

The effect of polyether terminal chains in the liquid crystalline behavior of ortho-palladated complexes

The mechanisms of the Stille reaction

scientific article

The oxidative dimerization of arylamido complexes of platinum revisited: protonation/deprotonation or oxidation/reduction?

The role of amide ligands in the stabilization of Pd(II) tricoordinated complexes: is the Pd–NR2 bond order single or higher?

Tin in Organic Synthesis

Transition metal liquid crystals: advanced materials within the reach of the coordination chemist

Triphenylene-Imidazolium Salts and Their NHC Metal Complexes, Materials with Segregated Multicolumnar Mesophases.

scientific article published on 2 April 2018

Tris- and tetra-perhalogenoaryl metallates of cobalt(II), nickel(II), palladium(II), and platinum(II)

scholarly article by Rafael Uson et al published 1977 in Journal of the Chemical Society. Chemical communications

Twist-Grain Boundary Phase and Blue Phases in Isocyanide Gold(I) Complexes

Unlikeliness of Pd-Free Gold(I)-Catalyzed Sonogashira Coupling Reactions

scientific article published in 2010

Versatile Route to Functionalized Vinylic Addition Polynorbornenes

article

When are tricoordinated PdII species accessible? Stability trends and mechanistic consequences

scientific article

[Pd(Fmes)2(tmeda)]: a case of intermittent C-H···F-C hydrogen-bond interaction in solution.

scientific article published in February 2013

[Pd(Fmes)I{NMe2(CH2-o-C6H4-I)-N,I}], a palladium(II) complex with I− and organic iodide as trans ligands

article published in 2003

Paulina is supported by:

About Paulina

Help