List of works - Miguel A. Ciriano

1H-Pyrrolo[2,3-b]pyridine (HL) ligands in rhodium(I) and iridium(I) chemistry. Crystal and molecular structures of [Rh2(µ-L)2(nbd)2] and [Rh4(µ-Cl)2(µ-L)2(µ-CO)2(CO)2(nbd)2]

scholarly article by Luis Oro et al published 1985 in Dalton transactions RSC

2,2′-Bibenzimidazolate anions as bridging ligands in cationic heteronuclear gold(I)–rhodium(I) complexes. Crystal structure of [(Ph3P)2Au2(µ-bbzim)Rh(cod)][ClO4]·CHCl3

scholarly article by Rafael Usón et al published 1983 in Dalton transactions RSC

Activating a Peroxo Ligand for C-O Bond Formation

scientific article published on 16 January 2019

Aerobic Oxidation of Carbon Monoxide in a Tetrametallic Complex ⬇️

scientific article published on November 5, 2012

Bimetallic Reactivity of Dirhodium Compounds Leading to Functionalized Methylene-Bridged Compounds†

Complexes of rhodium(I) with 1,8-naphthyridine and related ligands. Crystal structure of [Rh2(µ-napy)2(nbd)2][ClO4]2·H2O

scholarly article by Antonio Tiripicchio et al published 1984 in Dalton transactions RSC

Connecting CC Bonds to Tetrairidium Chains ⬇️

scientific article published on February 28, 2013

Controlled Synthesis of Early-Late Zr-Ir-Rh Heterotrimetallic Compounds by Metal Exchange Reactions

scientific article published on 01 September 1999

Coordination features of a hybrid scorpionate/phosphane ligand exemplified with Iridium

scientific article published in January 2008

Crescent-shaped rhodium(I) complexes with bis(o-carboxymethylphenyl)triazenide

scientific article published in July 2004

Degradation and Oxidation of 1,1,1-Trichloroethane-Mediated Rhodium Compounds. A New Entry in the Synthesis of Bridging Vinylidene and .eta.1-Chlorovinyl Complexes

Deprotonation induced ligand-to-metal electron transfer: synthesis of a mixed-valence Rh(-I,I) dinuclear compound and its reaction with dioxygen

scientific article published on 11 April 2008

Developing Synthetic Approaches with Non-Innocent Metalloligands: Easy Access to IrI/Pd0 and IrI/Pd0/IrI Cores

scientific article published on 17 August 2011

Dinuclear rhodium and iridium complexes with mixed amido/methoxo and amido/hydroxo bridges

scientific article published in May 2002

Discrete Mixed-Valence Metal Chains: Iridium Pyridonate Blues The generous financial support from DGES and MCyT-PNI (Projects PB98-641 and BQU2000-1170) is gratefully acknowledged

scientific article published on 01 November 2001

Discrete iridium pyridonate chains with variable metal valence: nature and energetics of the Ir-Ir bonding from DFT calculations

scientific article

Early (Ti, Zr)-late (Rh, Ir) heteronuclear complexes with bridging sulphido ligands

Early−Late Heterotetranuclear Complexes (TiRh3) with Bridging Sulfido Ligands: Ligand Replacement Reactions and Catalytic Activity in Hydroformylation of Olefins

Formation of Diiridium(II) Complexes by Photoassisted Oxidative-Addition Reactions: Structure of a Stable Binuclear Iodo(iodomethyl)iridium(II) Complex

article

Formation of a bridging-imido d6 rhodium compound by nitrene capture. insertion and cycloaddition reactions

scientific article

Heteronuclear rhodium, palladium, platinum, and gold organoimido complexes from dinuclear organoamido rhodium precursors

scientific article published in February 2004

Heterotrinuclear angular aggregates of rhodium, iridium, palladium and Group 11 metals. X-Ray structure of the complex [(cod)2Rh2(µ3-C7H4NS2)2Ag(O2ClO2)](cod = cycloocta-1,5-diene)

scholarly article by Miguel A. Ciriano et al published 1991 in Dalton transactions RSC

Hydrogen Bonding and Isomerism Arising from the Coordination Modes of Bridging Benzimidazole-2-thiolate Ligands in Tetranuclear Rhodium Complexes

scientific article published on 01 August 1998

Inner-Sphere Oxygen Activation Promoting Outer-Sphere Nucleophilic Attack on Olefins

scientific article published on 01 October 2019

Intervalent bis(mu-aziridinato)M(II)--M(I) complexes (M=Rh,Ir): delocalized metallo-radicals or delocalized aminyl radicals?

scientific article

Ligand oxidation of a deprotonated bis(picolyl)amine Ir(I)(cod) complex

scientific article published in January 2008

Ligand-centred reactivity of bis(picolyl)amine iridium: sequential deprotonation, oxidation and oxygenation of a "non-innocent" ligand

scientific article

Nucleophilicity and P-C Bond Formation Reactions of a Terminal Phosphanido Iridium Complex

scientific article published on 22 December 2015

Oxidation of Substrates by an Iridium Dioxygen Complex: Intramolecular Oxidation of Carbon Monoxide and Activation of a Carbonyl Group by Attack of a Heterocyclic Nitrogen

scholarly article by Miguel A. Ciriano et al published October 1995 in Organometallics

Oxidative-Addition Reactions of Diiodine to Dinuclear Rhodium Pyrazolate Complexes

article

Peripheral SH-functionalisation of carbosilane dendrimers including the synthesis of the model compound dimethylbis(propanethiol)silane and their interaction with rhodium complexes

scientific article published on 28 July 2005

Preparation and X-ray structure of a trinuclear rhodium complex with the polydentate 1,8-naphthyridine-2-one (onapy) ligand: [Rh3(μ3-onapy)2(CO)2(cod)2](ClO4)·1.5C2H4Cl2

scholarly article by Antonio Tiripicchio et al published January 1986 in Inorganica Chimica Acta

Protonation reactions of dinuclear pyrazolato iridium(I) complexes

scientific article published in July 2003

Pseudo-Tetrahedral Rhodium and Iridium Complexes: Catalytic Synthesis of E-Enynes

scientific article published on 05 November 2018

Reactions of Phosphine Ligands with Iridium Complexes Leading to C(sp3)−H Bond Activation

scholarly article by Cristina Tejel et al published March 2005 in Organometallics

Reactions of bis(ethylene)(tertiary phosphine)platinum complexes with phenylethynyl derivatives of titanium and silicon; crystal structure of (µ-dimethylsilanediyl)(σ-phenylethynyl)[µ-(1-σ:1–2-η-phenylethynyl)]-bis(tricyclohexylphosphine)dipla

scholarly article by Miguel A. Ciriano et al published 1979 in Dalton transactions RSC

Reactions of dimethyldivinylsilane, dimethyldivinyltin and allyltrimethyltin with diethylene (tertiary) phosphine)platinum complexes

Reactions of triorganosilanes with tris-µ-(t-butyl isocyanide)-tris(t-butyl isocyanide)-triangulo-triplatinum: crystal structure of the complex [{Pt(CH:NBut)(SiMePh2)(CNBut)}2]

Reversible C−H Bond Activation of a Bifunctional Phosphine Bridging Ligand across Two Unbonded Metal Centers

Rhodium Complexes Promoting C-O Bond Formation in Reactions with Oxygen: The Role of Superoxo Species

scientific article published on 28 January 2017

Rhodium Complexes in P-C Bond Formation: Key Role of a Hydrido Ligand

scientific article published on 24 December 2020

Rhodium Complexes in P-H Bond Activation Reactions

scientific article published on 08 November 2019

Rhodium and Iridium Pyrazolato Blues

scientific article published on 01 June 1998

Rhodium, iridium and gold complexes of the short-bite ligand 1-benzyl-2-imidazolyldiphenylphosphine

scholarly article by Cristina Tejel et al published April 2003 in Inorganica Chimica Acta

Rhodium-Rhodium Bonds in Edge-Sharing Coplanar Dinuclear Complexes Generous financial support from DGES (Projects PB98-641, PB95-318, and PB94-1186) and a fellowship (to M.S.) are gratefully acknowledged

scientific article published on 01 July 2000

Stepwise Construction of Polynuclear Complexes of Rhodium and Iridium Assisted by Benzimidazole-2-thiol. NMR and X-ray Diffraction Studies

scientific article published on 01 July 1996

Stereoselective oxidative additions of iodoalkanes and activated alkynes to a sulfido-bridged heterotrinuclear early-late (TiIr2) complex

scientific article published in June 2003

Structural and dynamic studies on amido-bridged rhodium and iridium complexes

scientific article published in July 2002

Structures, Reactivity, and Catalytic Activity of Dithiolato-Bridged Heterobimetallic MRh (M = Pt, Pd) Complexes

article published in 2002

Synthesis and characterization of an unusual tetranuclear rhodium complex; X-ray molecular structure of [Rh4(µ-Cl)2(µ-az)2(µ-CO)2(CO)2(nbd)2](az = 7-azaindolate; nbd = norborna-2,5-diene)

scholarly article by Luis Oro et al published 1984 in Journal of the Chemical Society. Chemical communications

Synthesis of bis-µ-diorganosilanediyl-af-dihydridobis(triorganophosphine)diplatinum complexes: crystal and molecular structure of [{PtH(µ-SiMe2)[P(C6H11)3]}2]

Synthesis of mixed-metal trinuclear complexes. X-Ray crystal structure of [(cod)2Rh2(µ3-C7H4NS2)2AgO2ClO2](cod = cyclo-octa-1,5-diene; C7H4NS2= benzothiazole-2-thiolate)

Synthesis of trans-di-µ-hydridobis(silyl)bis(trialkylphosphine)di-platinum complexes: crystal and molecular structure of di-µ-hydrido-bis(tricyclohexylphosphine)bis(triethylsilyl)diplatinum

Terminal phosphanido rhodium complexes mediating catalytic P-P and P-C bond formation

scientific article

Tetranuclear Complexes as Intermediates in Transannular Oxidative-Addition Reactions. Structure of the First Tetrairidium Linear Cluster

article

Tetranuclear [Rh4(mu-PyS2)2(diolefin)4] complexes as building blocks for new inorganic architectures: synthesis of coordination polymers and heteropolynuclear complexes with electrophilic d8 and d10 metal fragments

scientific article published in February 2004

The unexpected formal insertion of a carbonyl group into a heterocyclic NIr bond

Three-Coordinate Rhodium Complexes in Low Oxidation States

scientific article published on 19 February 2020

Trinuclear angular aggregates of rhodium: synthesis and crystal structures of [Rh3(µ3-SC5H4N)2(CO)6][ClO4](SC5H4N = pyridine-2-thiolate) and [Rh3(µ3-C7H4NS2)2(CO)2(PPh3)2(tfbb)][ClO4](C7H4NS2= benzothiazole-2-thiolate, tfbb = tetrafluorobenzobarrel

scholarly article by Miguel A. Ciriano et al published 1990 in Dalton transactions RSC

Trinuclear iridium and rhodium complexes: the solution to a puzzle involving the multiple coordination possibilities of 1,8-naphthyridine-2-one ligands

scholarly article by B.Eva Villaroya et al published September 1996 in Inorganica Chimica Acta

Unprecedented hybrid scorpionate/phosphine ligand able to be anchored to carbosilane dendrimers

scientific article published in December 2005

List of works by Miguel A. Ciriano

1H-Pyrrolo[2,3-b]pyridine (HL) ligands in rhodium(I) and iridium(I) chemistry. Crystal and molecular structures of [Rh2(µ-L)2(nbd)2] and [Rh4(µ-Cl)2(µ-L)2(µ-CO)2(CO)2(nbd)2]

2,2′-Bibenzimidazolate anions as bridging ligands in cationic heteronuclear gold(I)–rhodium(I) complexes. Crystal structure of [(Ph3P)2Au2(µ-bbzim)Rh(cod)][ClO4]·CHCl3

Activating a Peroxo Ligand for C-O Bond Formation

Aerobic Oxidation of Carbon Monoxide in a Tetrametallic Complex ⬇️

Bimetallic Reactivity of Dirhodium Compounds Leading to Functionalized Methylene-Bridged Compounds†

Complexes of rhodium(I) with 1,8-naphthyridine and related ligands. Crystal structure of [Rh2(µ-napy)2(nbd)2][ClO4]2·H2O

Connecting CC Bonds to Tetrairidium Chains ⬇️

Controlled Synthesis of Early-Late Zr-Ir-Rh Heterotrimetallic Compounds by Metal Exchange Reactions

Coordination features of a hybrid scorpionate/phosphane ligand exemplified with Iridium

Crescent-shaped rhodium(I) complexes with bis(o-carboxymethylphenyl)triazenide

Degradation and Oxidation of 1,1,1-Trichloroethane-Mediated Rhodium Compounds. A New Entry in the Synthesis of Bridging Vinylidene and .eta.1-Chlorovinyl Complexes

Deprotonation induced ligand-to-metal electron transfer: synthesis of a mixed-valence Rh(-I,I) dinuclear compound and its reaction with dioxygen

Developing Synthetic Approaches with Non-Innocent Metalloligands: Easy Access to IrI/Pd0 and IrI/Pd0/IrI Cores

Dinuclear rhodium and iridium complexes with mixed amido/methoxo and amido/hydroxo bridges

Discrete Mixed-Valence Metal Chains: Iridium Pyridonate Blues The generous financial support from DGES and MCyT-PNI (Projects PB98-641 and BQU2000-1170) is gratefully acknowledged

Discrete iridium pyridonate chains with variable metal valence: nature and energetics of the Ir-Ir bonding from DFT calculations

Early (Ti, Zr)-late (Rh, Ir) heteronuclear complexes with bridging sulphido ligands

Early−Late Heterotetranuclear Complexes (TiRh3) with Bridging Sulfido Ligands: Ligand Replacement Reactions and Catalytic Activity in Hydroformylation of Olefins

Formation of Diiridium(II) Complexes by Photoassisted Oxidative-Addition Reactions: Structure of a Stable Binuclear Iodo(iodomethyl)iridium(II) Complex

Formation of a bridging-imido d6 rhodium compound by nitrene capture. insertion and cycloaddition reactions

Heteronuclear rhodium, palladium, platinum, and gold organoimido complexes from dinuclear organoamido rhodium precursors

Heterotrinuclear angular aggregates of rhodium, iridium, palladium and Group 11 metals. X-Ray structure of the complex [(cod)2Rh2(µ3-C7H4NS2)2Ag(O2ClO2)](cod = cycloocta-1,5-diene)

Hydrogen Bonding and Isomerism Arising from the Coordination Modes of Bridging Benzimidazole-2-thiolate Ligands in Tetranuclear Rhodium Complexes

Inner-Sphere Oxygen Activation Promoting Outer-Sphere Nucleophilic Attack on Olefins

Intervalent bis(mu-aziridinato)M(II)--M(I) complexes (M=Rh,Ir): delocalized metallo-radicals or delocalized aminyl radicals?

Ligand oxidation of a deprotonated bis(picolyl)amine Ir(I)(cod) complex

Ligand-centred reactivity of bis(picolyl)amine iridium: sequential deprotonation, oxidation and oxygenation of a "non-innocent" ligand

Nucleophilicity and P-C Bond Formation Reactions of a Terminal Phosphanido Iridium Complex

Oxidation of Substrates by an Iridium Dioxygen Complex: Intramolecular Oxidation of Carbon Monoxide and Activation of a Carbonyl Group by Attack of a Heterocyclic Nitrogen

Oxidative-Addition Reactions of Diiodine to Dinuclear Rhodium Pyrazolate Complexes

Peripheral SH-functionalisation of carbosilane dendrimers including the synthesis of the model compound dimethylbis(propanethiol)silane and their interaction with rhodium complexes

Preparation and X-ray structure of a trinuclear rhodium complex with the polydentate 1,8-naphthyridine-2-one (onapy) ligand: [Rh3(μ3-onapy)2(CO)2(cod)2](ClO4)·1.5C2H4Cl2

Protonation reactions of dinuclear pyrazolato iridium(I) complexes

Pseudo-Tetrahedral Rhodium and Iridium Complexes: Catalytic Synthesis of E-Enynes

Reactions of Phosphine Ligands with Iridium Complexes Leading to C(sp3)−H Bond Activation

Reactions of bis(ethylene)(tertiary phosphine)platinum complexes with phenylethynyl derivatives of titanium and silicon; crystal structure of (µ-dimethylsilanediyl)(σ-phenylethynyl)[µ-(1-σ:1–2-η-phenylethynyl)]-bis(tricyclohexylphosphine)dipla

Reactions of dimethyldivinylsilane, dimethyldivinyltin and allyltrimethyltin with diethylene (tertiary) phosphine)platinum complexes

Reactions of triorganosilanes with tris-µ-(t-butyl isocyanide)-tris(t-butyl isocyanide)-triangulo-triplatinum: crystal structure of the complex [{Pt(CH:NBut)(SiMePh2)(CNBut)}2]

Reversible C−H Bond Activation of a Bifunctional Phosphine Bridging Ligand across Two Unbonded Metal Centers

Rhodium Complexes Promoting C-O Bond Formation in Reactions with Oxygen: The Role of Superoxo Species

Rhodium Complexes in P-C Bond Formation: Key Role of a Hydrido Ligand

Rhodium Complexes in P-H Bond Activation Reactions

Rhodium and Iridium Pyrazolato Blues

Rhodium, iridium and gold complexes of the short-bite ligand 1-benzyl-2-imidazolyldiphenylphosphine

Rhodium-Rhodium Bonds in Edge-Sharing Coplanar Dinuclear Complexes Generous financial support from DGES (Projects PB98-641, PB95-318, and PB94-1186) and a fellowship (to M.S.) are gratefully acknowledged

Stepwise Construction of Polynuclear Complexes of Rhodium and Iridium Assisted by Benzimidazole-2-thiol. NMR and X-ray Diffraction Studies

Stereoselective oxidative additions of iodoalkanes and activated alkynes to a sulfido-bridged heterotrinuclear early-late (TiIr2) complex

Structural and dynamic studies on amido-bridged rhodium and iridium complexes

Structures, Reactivity, and Catalytic Activity of Dithiolato-Bridged Heterobimetallic MRh (M = Pt, Pd) Complexes

Synthesis and characterization of an unusual tetranuclear rhodium complex; X-ray molecular structure of [Rh4(µ-Cl)2(µ-az)2(µ-CO)2(CO)2(nbd)2](az = 7-azaindolate; nbd = norborna-2,5-diene)

Synthesis of bis-µ-diorganosilanediyl-af-dihydridobis(triorganophosphine)diplatinum complexes: crystal and molecular structure of [{PtH(µ-SiMe2)[P(C6H11)3]}2]

Synthesis of mixed-metal trinuclear complexes. X-Ray crystal structure of [(cod)2Rh2(µ3-C7H4NS2)2AgO2ClO2](cod = cyclo-octa-1,5-diene; C7H4NS2= benzothiazole-2-thiolate)

Synthesis of trans-di-µ-hydridobis(silyl)bis(trialkylphosphine)di-platinum complexes: crystal and molecular structure of di-µ-hydrido-bis(tricyclohexylphosphine)bis(triethylsilyl)diplatinum

Terminal phosphanido rhodium complexes mediating catalytic P-P and P-C bond formation

Tetranuclear Complexes as Intermediates in Transannular Oxidative-Addition Reactions. Structure of the First Tetrairidium Linear Cluster

Tetranuclear [Rh4(mu-PyS2)2(diolefin)4] complexes as building blocks for new inorganic architectures: synthesis of coordination polymers and heteropolynuclear complexes with electrophilic d8 and d10 metal fragments

The unexpected formal insertion of a carbonyl group into a heterocyclic NIr bond

Three-Coordinate Rhodium Complexes in Low Oxidation States

Trinuclear angular aggregates of rhodium: synthesis and crystal structures of [Rh3(µ3-SC5H4N)2(CO)6][ClO4](SC5H4N = pyridine-2-thiolate) and [Rh3(µ3-C7H4NS2)2(CO)2(PPh3)2(tfbb)][ClO4](C7H4NS2= benzothiazole-2-thiolate, tfbb = tetrafluorobenzobarrel

Trinuclear iridium and rhodium complexes: the solution to a puzzle involving the multiple coordination possibilities of 1,8-naphthyridine-2-one ligands

Unprecedented hybrid scorpionate/phosphine ligand able to be anchored to carbosilane dendrimers

[CpTi(μ3-S)3{Rh(tfbb)}3]: An early-late heterometallic complex as molecular model for the deactivation of metal sulphide catalysts