List of works - Geoffrey Cloke

A Dichromium(II) Bis(η8-pentalene) Double-Sandwich Complex with a Spin Equilibrium: Synthetic, Structural, Magnetic, and Theoretical Studies

Activation and reduction of diethyl ether by low valent uranium: formation of the trimetallic, mixed valence uranium oxo species [U(CpRR')(mu-I)2]3(mu3-O) (CpRR' = C5Me5, C5Me4H, C5H4SiMe3).

scientific article published in January 2008

Alkylpalladium N-Heterocyclic Carbene Complexes: Synthesis, Reactivity, and Catalytic Properties

Axial coordination of NHC ligands on dirhodium(II) complexes: generation of a new family of catalysts.

scientific article

Bis(pentalene)di-titanium: a bent double-sandwich complex with a very short Ti-Ti bond

scientific article published in October 2013

Bis(η-heteroarene) titanium complexes derived from 2,4,6-tri-tert-butylpyridine and 2,4,6-tri-tert-butylphosphorin: Conformational preference in solution and redox activity

scholarly article by Polly Arnold et al published February 1997 in Journal of Organometallic Chemistry

Bonding in Complexes of Bis(pentalene)dititanium, Ti2(C8H6)2.

scientific article

C-H and H-H activation at a di-titanium centre

scientific article

Computational insight into the reductive oligomerisation of CO at uranium(III) mixed-sandwich complexes

scientific article published on 21 March 2012

Correction: C-H and H-H activation at a di-titanium centre

scientific article published on 5 February 2018

Development of a practical Buchwald-Hartwig amine arylation protocol using a conveniently prepared (NHC)Pd(R-allyl)Cl catalyst

scientific article published on 6 June 2008

Direct detection of individual bis(arene) rotational isomers in the gas phase by mass-analyzed threshold ionization spectroscopy

scientific article published on 01 January 2007

Ethene Activation and Catalytic Hydrogenation by a Low-Valent Uranium Pentalene Complex

scientific article published on 24 December 2019

Facile conversion of CO/H2 into methoxide at a uranium(III) center

scientific article published on 15 June 2011

Formation of cyanates in low-valent uranium chemistry: a synergistic experimental/theoretical study

scientific article published on 28 April 2014

Group 4 metal compounds incorporating the amide ligand, [N(SiMe2{C6H4-2-OMe})2](-).

scientific article

Mechanistic studies on the reductive cyclooligomerisation of CO by U(III) mixed sandwich complexes; the molecular structure of [(U(eta-C8H6{Si(i)Pr3-1,4}2)(eta-Cp*)]2(mu-eta1:eta1-C2O2).

scientific article published on 26 September 2008

Metal Vapor Synthesis as a Straightforward Route to Group 10 Homoleptic Carbene Complexes

Mixed sandwich thorium complexes incorporating bis(tri-isopropylsilyl)cyclooctatetraenyl and pentamethylcyclopentadienyl ligands: synthesis, structure and reactivity

scientific article published in February 2015

Mn2 bis(pentalene): a mixed-spin bimetallic with two extremes of bonding within the same molecule

scientific article published in December 2006

New horizons in organo-f-block chemistry

scientific article published on 28 June 2010

Reductive coupling of carbon monoxide by U(III) complexes--a computational study

scientific article published on 15 August 2011

Reductive cyclotetramerization of CO to squarate by a U(III) complex: the X-ray crystal structure of [(U (eta-C8H6{SiiPr3-1,4}2)(eta-C5Me4H)]2(mu-eta2: eta2-C4O4).

scientific article published in August 2006

Reductive cyclotrimerization of carbon monoxide to the deltate dianion by an organometallic uranium complex

scientific article published in February 2006

Reductive deoxygenation of CO2 by a bimetallic titanium bis(pentalene) complex

scientific article published on 01 March 2014

Reductive disproportionation of carbon dioxide to carbonate and squarate products using a mixed-sandwich U(iii) complex

scientific article (publication date: 2008)

Reversible binding and reduction of dinitrogen by a uranium(III) pentalene complex

scientific article published in August 2002

Single-molecule magnet properties of a monometallic dysprosium pentalene complex

scientific article published on 01 June 2018

Stabilization of low-oxidation-state early transition-metal complexes bearing 1,2,4-triphosphacyclopentadienyl ligands: structure of [[Sc(P3C2tBu2)2]2]; ScII or mixed oxidation state?

scientific article

Steric control of redox events in organo-uranium chemistry: synthesis and characterisation of U(v) oxo and nitrido complexes

scientific article published on 11 April 2016

Structural studies of group 1 metal 4-azapentalenyl complexes

scientific article published on 8 March 2005

Studies on high-temperature amination reactions of aromatic chlorides using discrete palladium-N-heterocyclic carbene (NHC) complexes and in situ palladium/imidazolium salt protocols

scientific article published in January 2003

Syntheses, structural studies, photoelectron spectra and density functional theory calculations of the "pseudo" tetraphospha-metallocenes [M(eta-P2C3Bu(t)3)(2)], (M = Ni, Pd, Pt).

scientific article published on 18 December 2008

Synthesis and reactivity of alkyl-palladium N-heterocyclic carbene complexes.

scientific article

Synthesis of an [(NHC)2 Pd(SiMe3 )2 ] Complex and Catalytic cis-Bis(silyl)ations of Alkynes with Unactivated Disilanes.

scientific article published on 9 April 2015

Synthetic and structural studies on amine coordination to Pd-N-heterocyclic carbene complexes

scientific article published on 21 July 2009

Synthetic, structural, and mechanistic studies on the oxidative addition of aromatic chlorides to a palladium (N-heterocyclic carbene) complex: relevance to catalytic amination

scientific article published in August 2003

The First Example of a Formal Scandium(I) Complex: Synthesis and Molecular Structure of a 22-Electron Scandium Triple Decker Incorporating the Novel 1,3,5-Triphosphabenzene Ring

article

The Reductive Activation of CO2 Across a Ti=Ti Double Bond: Synthetic, Structural, and Mechanistic Studies

scientific article

The experimental determination of Th(iv)/Th(iii) redox potentials in organometallic thorium complexes

scientific article published on 11 June 2019

The first stable scandocene: synthesis and characterisation of bis(η-2,4,5-tri-tert-butyl-1,3-diphosphacyclopentadienyl)scandium(II)

scholarly article by Polly Arnold et al published 1998 in Chemical Communications

The first structurally authenticated zerovalent heteroarene complex of a lanthanide; synthesis and X-ray structure of bis(2,4,6-tri-tert-butyl- phosphorin)holmium(O)

The organometallic chemistry of pentalene

Trigonal Prismatic Structure of Tris(butadiene)molybdenum and Related Complexes Revisited: Diolefin or Metallacyclopentene Coordination?

Trimerisation of carbon suboxide at a di-titanium centre to form a pyrone ring system.

scientific article

Tuning the Reactivity of Dirhodium(II) Complexes with Axial N-Heterocyclic Carbene Ligands: The Arylation of Aldehydes

scientific article published on 01 January 2007

U(III)-induced reductive co-coupling of NO and CO to form U(IV) cyanate and oxo derivates.

scientific article published on August 2010

Unusual reactivity of a nickel N-heterocyclic carbene complex: tert-butyl group cleavage and silicone grease activation

scientific article published in November 2004

Vibrational and electronic structure of the dinuclear bis(mu-nitrido) vanadium(v) complex [V(N{N"}2)(mu-N)]2: spectroscopic properties of the M2(mu-N)2 diamond core

scientific article published on 15 February 2005

Yttrium complexes incorporating the chelating diamides [ArN(CH2)xNAr]2- (Ar = C6H3-2,6-iPr2, x= 2, 3) and their unusual reaction with phenylsilane

scientific article published on 10 March 2004

Zero kinetic energy spectroscopy: mass-analyzed threshold ionization spectra of chromium sandwich complexes with alkylbenzenes, (η(6)-RPh)(2)Cr (R = Me, Et, i-Pr, t-Bu).

scientific article published on October 2010

Zero oxidation state compounds of scandium, yttrium, and the lanthanides

scholarly article by Geoffrey Cloke published 1993 in Chemical Society Reviews

η-Arene complexes of scandium(0) and scandium(II)

scholarly article by Geoffrey Cloke et al published 1991 in Journal of the Chemical Society. Chemical communications

List of works by Geoffrey Cloke

A Dichromium(II) Bis(η8-pentalene) Double-Sandwich Complex with a Spin Equilibrium: Synthetic, Structural, Magnetic, and Theoretical Studies

Activation and reduction of diethyl ether by low valent uranium: formation of the trimetallic, mixed valence uranium oxo species [U(CpRR')(mu-I)2]3(mu3-O) (CpRR' = C5Me5, C5Me4H, C5H4SiMe3).

Alkylpalladium N-Heterocyclic Carbene Complexes: Synthesis, Reactivity, and Catalytic Properties

Axial coordination of NHC ligands on dirhodium(II) complexes: generation of a new family of catalysts.

Bis(pentalene)di-titanium: a bent double-sandwich complex with a very short Ti-Ti bond

Bis(η-heteroarene) titanium complexes derived from 2,4,6-tri-tert-butylpyridine and 2,4,6-tri-tert-butylphosphorin: Conformational preference in solution and redox activity

Bonding in Complexes of Bis(pentalene)dititanium, Ti2(C8H6)2.

C-H and H-H activation at a di-titanium centre

Computational insight into the reductive oligomerisation of CO at uranium(III) mixed-sandwich complexes

Correction: C-H and H-H activation at a di-titanium centre

Development of a practical Buchwald-Hartwig amine arylation protocol using a conveniently prepared (NHC)Pd(R-allyl)Cl catalyst

Direct detection of individual bis(arene) rotational isomers in the gas phase by mass-analyzed threshold ionization spectroscopy

Ethene Activation and Catalytic Hydrogenation by a Low-Valent Uranium Pentalene Complex

Facile conversion of CO/H2 into methoxide at a uranium(III) center

Formation of cyanates in low-valent uranium chemistry: a synergistic experimental/theoretical study

Group 4 metal compounds incorporating the amide ligand, [N(SiMe2{C6H4-2-OMe})2](-).

Mechanistic studies on the reductive cyclooligomerisation of CO by U(III) mixed sandwich complexes; the molecular structure of [(U(eta-C8H6{Si(i)Pr3-1,4}2)(eta-Cp*)]2(mu-eta1:eta1-C2O2).

Metal Vapor Synthesis as a Straightforward Route to Group 10 Homoleptic Carbene Complexes

Mixed sandwich thorium complexes incorporating bis(tri-isopropylsilyl)cyclooctatetraenyl and pentamethylcyclopentadienyl ligands: synthesis, structure and reactivity

Mn2 bis(pentalene): a mixed-spin bimetallic with two extremes of bonding within the same molecule

New horizons in organo-f-block chemistry

Reductive coupling of carbon monoxide by U(III) complexes--a computational study

Reductive cyclotetramerization of CO to squarate by a U(III) complex: the X-ray crystal structure of [(U (eta-C8H6{SiiPr3-1,4}2)(eta-C5Me4H)]2(mu-eta2: eta2-C4O4).

Reductive cyclotrimerization of carbon monoxide to the deltate dianion by an organometallic uranium complex

Reductive deoxygenation of CO2 by a bimetallic titanium bis(pentalene) complex

Reductive disproportionation of carbon dioxide to carbonate and squarate products using a mixed-sandwich U(iii) complex

Reversible binding and reduction of dinitrogen by a uranium(III) pentalene complex

Single-molecule magnet properties of a monometallic dysprosium pentalene complex

Stabilization of low-oxidation-state early transition-metal complexes bearing 1,2,4-triphosphacyclopentadienyl ligands: structure of [[Sc(P3C2tBu2)2]2]; ScII or mixed oxidation state?

Steric control of redox events in organo-uranium chemistry: synthesis and characterisation of U(v) oxo and nitrido complexes

Structural studies of group 1 metal 4-azapentalenyl complexes

Studies on high-temperature amination reactions of aromatic chlorides using discrete palladium-N-heterocyclic carbene (NHC) complexes and in situ palladium/imidazolium salt protocols

Syntheses, structural studies, photoelectron spectra and density functional theory calculations of the "pseudo" tetraphospha-metallocenes [M(eta-P2C3Bu(t)3)(2)], (M = Ni, Pd, Pt).

Synthesis and reactivity of alkyl-palladium N-heterocyclic carbene complexes.

Synthesis of an [(NHC)2 Pd(SiMe3 )2 ] Complex and Catalytic cis-Bis(silyl)ations of Alkynes with Unactivated Disilanes.

Synthetic and structural studies on amine coordination to Pd-N-heterocyclic carbene complexes

Synthetic, structural, and mechanistic studies on the oxidative addition of aromatic chlorides to a palladium (N-heterocyclic carbene) complex: relevance to catalytic amination

The First Example of a Formal Scandium(I) Complex: Synthesis and Molecular Structure of a 22-Electron Scandium Triple Decker Incorporating the Novel 1,3,5-Triphosphabenzene Ring

The Reductive Activation of CO2 Across a Ti=Ti Double Bond: Synthetic, Structural, and Mechanistic Studies

The experimental determination of Th(iv)/Th(iii) redox potentials in organometallic thorium complexes

The first stable scandocene: synthesis and characterisation of bis(η-2,4,5-tri-tert-butyl-1,3-diphosphacyclopentadienyl)scandium(II)

The first structurally authenticated zerovalent heteroarene complex of a lanthanide; synthesis and X-ray structure of bis(2,4,6-tri-tert-butyl- phosphorin)holmium(O)

The organometallic chemistry of pentalene

Trigonal Prismatic Structure of Tris(butadiene)molybdenum and Related Complexes Revisited: Diolefin or Metallacyclopentene Coordination?

Trimerisation of carbon suboxide at a di-titanium centre to form a pyrone ring system.

Tuning the Reactivity of Dirhodium(II) Complexes with Axial N-Heterocyclic Carbene Ligands: The Arylation of Aldehydes

U(III)-induced reductive co-coupling of NO and CO to form U(IV) cyanate and oxo derivates.

Unusual reactivity of a nickel N-heterocyclic carbene complex: tert-butyl group cleavage and silicone grease activation

Vibrational and electronic structure of the dinuclear bis(mu-nitrido) vanadium(v) complex [V(N{N"}2)(mu-N)]2: spectroscopic properties of the M2(mu-N)2 diamond core

Yttrium complexes incorporating the chelating diamides [ArN(CH2)xNAr]2- (Ar = C6H3-2,6-iPr2, x= 2, 3) and their unusual reaction with phenylsilane

Zero kinetic energy spectroscopy: mass-analyzed threshold ionization spectra of chromium sandwich complexes with alkylbenzenes, (η(6)-RPh)(2)Cr (R = Me, Et, i-Pr, t-Bu).

Zero oxidation state compounds of scandium, yttrium, and the lanthanides

η-Arene complexes of scandium(0) and scandium(II)