List of works - Alison J. Frontier

A general method for the catalytic nazarov cyclization of heteroaromatic compounds

scientific article published on 01 November 2006

A highly reactive dicationic iridium(III) catalyst for the polarized Nazarov cyclization reaction

scientific article

A macrocyclic β-iodoallenolate intermediate is key: synthesis of the ABD core of phomactin A.

scientific article

A potent, orally bioavailable benzazepinone growth hormone secretagogue.

scientific article published in May 1998

Beta-iodoallenolates as springboards for annulation reactions

scientific article published on 01 October 2009

Beyond the Divinyl Ketone: Innovations in the Generation and Nazarov Cyclization of Pentadienyl Cation Intermediates.

scientific article published on June 2013

Cascade cyclizations of acyclic and macrocyclic alkynones: studies toward the synthesis of phomactin A.

scientific article published on 10 June 2013

Cationic Cascade for Building Complex Polycyclic Molecules from Simple Precursors: Diastereoselective Installation of Three Contiguous Stereogenic Centers in a One-Pot Process

scientific article published on 20 December 2018

Cationic cyclizations and rearrangements promoted by a heterogeneous gold catalyst.

scientific article published on 16 January 2014

Conjugate Addition-Initiated Nazarov Cyclization ⬇️

scientific article published on July 22, 2011

Correction to "One-Pot Double-Annulation Strategy for the Synthesis of Unusual Fused Bis-Heterocycles"

scientific article published on 29 June 2020

Correction to "Stereochemical Relay through a Cationic Intermediate: Helical Preorganization Dictates Direction of Conrotation in the halo-Nazarov Cyclization"

scientific article published on 07 July 2020

Cyclization Cascades Initiated by 1,6-Conjugate Addition ⬇️

scientific article published on September 28, 2012

Development of a Nazarov cyclization/Wagner-Meerwein rearrangement sequence for the stereoselective synthesis of spirocycles

scientific article published on 08 June 2007

Diastereoselective Construction of Densely Functionalized 1-Halocyclopentenes Using an Alkynyl Halo-Prins/Halo-Nazarov Cyclization Strategy

scientific article published on 24 October 2017

Dicationic Palladium(II) Complexes as Active Lewis Acid Catalysts for Polarized Nazarov Cyclization

scientific article

Divergent reaction pathways of a cationic intermediate: rearrangement and cyclization of 2-substituted furyl and benzofuryl enones catalyzed by iridium(III)

scientific article published on 15 February 2011

Efficient catalysis of Nazarov cyclization using a cationic iridium complex possessing adjacent labile coordination sites.

scientific article

Enantioselective Nazarov Cyclization Catalyzed by a Cinchona Alkaloid Derivative.

scientific article published on June 2015

Experimental and theoretical studies on the Nazarov cyclization/Wagner-Meerwein rearrangement sequence

scientific article

Flavaglines target primitive leukemia cells and enhance anti-leukemia drug activity.

scientific article

Gold (III) Chloride-Catalyzed 6-endo-trig Oxa-Michael Addition Reactions for Diastereoselective Synthesis of Fused Tetrahydropyranones.

scientific article published on July 2013

Leveraging the Halo-Nazarov Cyclization for the Chemodivergent Assembly of Functionalized Haloindenes and Indanones

scientific article published on 22 March 2019

Nazarov Cyclization/Internal Redox Cyclization Sequence for the Synthesis of N-Heterocyclic Bridged Ring Systems

scientific article published on 21 September 2016

New Twists in Nazarov Cyclization Chemistry

scientific article published on 13 August 2020

No acid required: 4π and 6π electrocyclization reactions of dienyl diketones for the synthesis of cyclopentenones and 2H-Pyrans.

scientific article

Noncanonical Cation-π Cyclizations of Alkylidene β-Ketoesters: Synthesis of Spiro-fused and Bridged Bicyclic Ring Systems

scientific article published on 14 March 2019

One-Pot Double-Annulation Strategy for the Synthesis of Unusual Fused Bis-Heterocycles

scientific article published on 15 May 2020

Oxidation-Initiated Nazarov Cyclization of Vinyl Alkoxyallenes ⬇️

scientific article published on December 14, 2010

Polarizing the Nazarov cyclization: efficient catalysis under mild conditions.

scientific article published in November 2003

Polarizing the Nazarov cyclization: the impact of dienone substitution pattern on reactivity and selectivity.

scientific article published in January 2008

Reagent control of [1,2]-Wagner-Meerwein shift chemoselectivity following the Nazarov cyclization: application to the total synthesis of enokipodin B

scientific article published on 21 February 2013

Stereochemical Relay through a Cationic Intermediate: Helical Preorganization Dictates Direction of Conrotation in the halo-Nazarov Cyclization

scientific article published on 30 April 2020

Stereoselective synthesis of pyrrolidine derivatives via reduction of substituted pyrroles

scientific article published on 26 October 2007

Studies toward the AB ring system of the tetrapetalone natural products

scientific article

Synthesis, characterization, and catalytic properties of new electrophilic iridium(III) complexes containing the (R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl ligand.

scientific article published in May 2010

Tandem Nazarov cyclization-michael addition sequence catalyzed by an Ir(III) complex

scientific article published on 01 April 2006

Total Synthesis of (±)-Rocaglamide via Oxidation-Initiated Nazarov Cyclization ⬇️

scientific article published on January 26, 2012

Total synthesis of (+/-)-merrilactone A

scientific article published on 08 December 2007

Total synthesis of (+/-)-merrilactone A via catalytic Nazarov cyclization

scientific article published on 01 January 2007

Tuning Mechanism through Buffer Dependence of Hydrogen Evolution Catalyzed by a Cobalt Mini-enzyme

scientific article published on 19 March 2020

Understanding the fate of the oxyallyl cation following Nazarov electrocyclization: sequential Wagner-Meerwein migrations and the synthesis of spirocyclic cyclopentenones

scientific article

Using Nazarov electrocyclization to stage chemoselective [1,2]-migrations: stereoselective synthesis of functionalized cyclopentenones.

scientific article published on 26 September 2011

List of works by Alison J. Frontier

A general method for the catalytic nazarov cyclization of heteroaromatic compounds

A highly reactive dicationic iridium(III) catalyst for the polarized Nazarov cyclization reaction

A macrocyclic β-iodoallenolate intermediate is key: synthesis of the ABD core of phomactin A.

A potent, orally bioavailable benzazepinone growth hormone secretagogue.

Beta-iodoallenolates as springboards for annulation reactions

Beyond the Divinyl Ketone: Innovations in the Generation and Nazarov Cyclization of Pentadienyl Cation Intermediates.

Cascade cyclizations of acyclic and macrocyclic alkynones: studies toward the synthesis of phomactin A.

Cationic Cascade for Building Complex Polycyclic Molecules from Simple Precursors: Diastereoselective Installation of Three Contiguous Stereogenic Centers in a One-Pot Process

Cationic cyclizations and rearrangements promoted by a heterogeneous gold catalyst.

Conjugate Addition-Initiated Nazarov Cyclization ⬇️

Correction to "One-Pot Double-Annulation Strategy for the Synthesis of Unusual Fused Bis-Heterocycles"

Correction to "Stereochemical Relay through a Cationic Intermediate: Helical Preorganization Dictates Direction of Conrotation in the halo-Nazarov Cyclization"

Cyclization Cascades Initiated by 1,6-Conjugate Addition ⬇️

Development of a Nazarov cyclization/Wagner-Meerwein rearrangement sequence for the stereoselective synthesis of spirocycles

Diastereoselective Construction of Densely Functionalized 1-Halocyclopentenes Using an Alkynyl Halo-Prins/Halo-Nazarov Cyclization Strategy

Dicationic Palladium(II) Complexes as Active Lewis Acid Catalysts for Polarized Nazarov Cyclization

Divergent reaction pathways of a cationic intermediate: rearrangement and cyclization of 2-substituted furyl and benzofuryl enones catalyzed by iridium(III)

Efficient catalysis of Nazarov cyclization using a cationic iridium complex possessing adjacent labile coordination sites.

Enantioselective Nazarov Cyclization Catalyzed by a Cinchona Alkaloid Derivative.

Experimental and theoretical studies on the Nazarov cyclization/Wagner-Meerwein rearrangement sequence

Flavaglines target primitive leukemia cells and enhance anti-leukemia drug activity.

Gold (III) Chloride-Catalyzed 6-endo-trig Oxa-Michael Addition Reactions for Diastereoselective Synthesis of Fused Tetrahydropyranones.

Leveraging the Halo-Nazarov Cyclization for the Chemodivergent Assembly of Functionalized Haloindenes and Indanones

Nazarov Cyclization/Internal Redox Cyclization Sequence for the Synthesis of N-Heterocyclic Bridged Ring Systems

New Twists in Nazarov Cyclization Chemistry

No acid required: 4π and 6π electrocyclization reactions of dienyl diketones for the synthesis of cyclopentenones and 2H-Pyrans.

Noncanonical Cation-π Cyclizations of Alkylidene β-Ketoesters: Synthesis of Spiro-fused and Bridged Bicyclic Ring Systems

One-Pot Double-Annulation Strategy for the Synthesis of Unusual Fused Bis-Heterocycles

Oxidation-Initiated Nazarov Cyclization of Vinyl Alkoxyallenes ⬇️

Polarizing the Nazarov cyclization: efficient catalysis under mild conditions.

Polarizing the Nazarov cyclization: the impact of dienone substitution pattern on reactivity and selectivity.

Reagent control of [1,2]-Wagner-Meerwein shift chemoselectivity following the Nazarov cyclization: application to the total synthesis of enokipodin B

Stereochemical Relay through a Cationic Intermediate: Helical Preorganization Dictates Direction of Conrotation in the halo-Nazarov Cyclization

Stereoselective synthesis of pyrrolidine derivatives via reduction of substituted pyrroles

Studies toward the AB ring system of the tetrapetalone natural products

Synthesis, characterization, and catalytic properties of new electrophilic iridium(III) complexes containing the (R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl ligand.

Tandem Nazarov cyclization-michael addition sequence catalyzed by an Ir(III) complex

Total Synthesis of (±)-Rocaglamide via Oxidation-Initiated Nazarov Cyclization ⬇️

Total synthesis of (+/-)-merrilactone A

Total synthesis of (+/-)-merrilactone A via catalytic Nazarov cyclization

Tuning Mechanism through Buffer Dependence of Hydrogen Evolution Catalyzed by a Cobalt Mini-enzyme

Understanding the fate of the oxyallyl cation following Nazarov electrocyclization: sequential Wagner-Meerwein migrations and the synthesis of spirocyclic cyclopentenones

Using Nazarov electrocyclization to stage chemoselective [1,2]-migrations: stereoselective synthesis of functionalized cyclopentenones.