List of works - Alan S. Goldman

A mixed-valence chloride-bridged (pincer)Ir(III)-(diene)Ir(I) complex

scientific article published on 23 June 2007

Acid-catalyzed oxidative addition of a C-H bond to a square planar d⁸ iridium complex

scientific article published on 13 June 2014

Addition of C-C and C-H bonds by pincer-iridium complexes: a combined experimental and computational study.

scientific article published in November 2014

Addition of alkyl radicals to transition-metal-coordinated CO: calculation of the reaction of [Ru(CO)5] and related complexes and relevance to alkane carbonylation.

scientific article

Addition of ammonia to AlH3 and BH3. Why does only aluminum form 2:1 adducts?

scientific article published on 01 January 2000

Alkane metathesis by tandem alkane-dehydrogenation-olefin-metathesis catalysis and related chemistry.

scientific article published on 15 May 2012

Assessment of the Electronic Factors Determining the Thermodynamics of "Oxidative Addition" of C-H and N-H Bonds to Ir(I) Complexes

scientific article published on 23 December 2015

Bioinorganic chemistry: Bond breaking bacteria-style

scientific article published on 01 May 2009

Calculation of ionization energy, electron affinity, and hydride affinity trends in pincer-ligated d(8)-Ir((tBu4)PXCXP) complexes: implications for the thermodynamics of oxidative H2 addition

scientific article published on 18 November 2014

Carbon–carbon bonds get a break

scientific article published in Nature

Catalytic Dehydrogenative C-C Coupling by a Pincer-Ligated Iridium Complex

scientific article

Catalytic alkane metathesis by tandem alkane dehydrogenation-olefin metathesis

scientific article published on 01 April 2006

Catalytic cleavage of ether C-O bonds by pincer iridium complexes

scientific article published on 24 July 2014

Catalytic dehydroaromatization of n-alkanes by pincer-ligated iridium complexes

scientific article published on 19 December 2010

Catalytic ring expansion, contraction, and metathesis-polymerization of cycloalkanes.

scientific article

Catalytic synthesis of n-alkyl arenes through alkyl group cross-metathesis

scientific article published on 08 August 2013

Chlorination of (Phebox)Ir(mesityl)(OAc) by Thionyl Chloride.

scientific article published in June 2015

Cleavage of ether, ester, and tosylate C(sp3)-O bonds by an iridium complex, initiated by oxidative addition of C-H bonds. Experimental and computational studies.

scientific article published on 21 March 2013

Cleavage of sp3 C-O bonds via oxidative addition of C-H bonds.

scientific article published in November 2009

Combined computational and experimental study of substituent effects on the thermodynamics of H(2), CO, arene, and alkane addition to iridium.

scientific article

Dehydrogenation of Alkanes and Aliphatic Groups by Pincer-Ligated Metal Complexes.

scientific article published on 27 September 2017

Dehydrogenation of aliphatic polyolefins catalyzed by pincer-ligated iridium complexes

scientific article published on 27 May 2005

Dehydrogenation of n-Alkanes by Solid-Phase Molecular Pincer-Iridium Catalysts. High Yields of α-Olefin Product

scientific article

Dihydrogen/dihydride or tetrahydride? An experimental and computational investigation of pincer iridium polyhydrides

scientific article published on 01 February 2010

Dimerization of alkynes promoted by a pincer-ligated iridium complex. C-C reductive elimination inhibited by steric crowding

scientific article published on 01 January 2007

Distinct Thermodynamics for the Formation and Cleavage of N−H Bonds in Aniline and Ammonia. Directly-Observed Reductive Elimination of Ammonia from an Isolated Amido Hydride Complex ⬇️

scientific article published on November 12, 2003

Electrochemical C-H bond activation via cationic iridium hydride pincer complexes

scientific article published on 20 August 2019

Formation of Enamines via Catalytic Dehydrogenation by Pincer-Iridium Complexes

scientific article published on 10 February 2020

H2 Addition to Pincer Iridium Complexes Yielding trans-Dihydride Products: Unexpected Correlations of Bond Strength with Bond Length and Vibrational Frequencies

scientific article published on 12 June 2018

Large-Scale Selective Functionalization of Alkanes.

scientific article

Mechanism of alkane transfer-dehydrogenation catalyzed by a pincer-ligated iridium complex.

scientific article

Net oxidative addition of C(sp3)-F bonds to iridium via initial C-H bond activation

scientific article published on 01 June 2011

Olefin hydroaryloxylation catalyzed by pincer-iridium complexes

scientific article published on 27 September 2013

Olefin isomerization by iridium pincer catalysts. Experimental evidence for an η3-allyl pathway and an unconventional mechanism predicted by DFT calculations.

scientific article published on 2 August 2012

Oxidative addition of ammonia to form a stable monomeric amido hydride complex

scientific article

Polar molecules catalyze CO insertion into metal-alkyl bonds through the displacement of an agostic C-H bond

scientific article published on 12 February 2019

Preface for small-molecule activation: carbon-containing fuels

scientific article published on 01 June 2015

Selective Dehydrogenative Coupling of Ethylene to Butadiene via an Iridacyclopentane Complex.

scientific article published on 16 January 2018

Selective cleavage of the C-C bonds of aminoethyl groups, via a multistep pathway, by a pincer iridium complex.

scientific article published in June 2005

Synthesis and characterization of carbazolide-based iridium PNP pincer complexes. Mechanistic and computational investigation of alkene hydrogenation: evidence for an Ir(III)/Ir(V)/Ir(III) catalytic cycle

scientific article published on 29 April 2014

β-Hydride Elimination and C-H Activation by an Iridium Acetate Complex, Catalyzed by Lewis Acids. Alkane Dehydrogenation Cocatalyzed by Lewis Acids and [2,6-Bis(4,4-dimethyloxazolinyl)-3,5-dimethylphenyl]iridium.

scientific article published on 18 April 2017

List of works by Alan S. Goldman

A mixed-valence chloride-bridged (pincer)Ir(III)-(diene)Ir(I) complex

Acid-catalyzed oxidative addition of a C-H bond to a square planar d⁸ iridium complex

Addition of C-C and C-H bonds by pincer-iridium complexes: a combined experimental and computational study.

Addition of alkyl radicals to transition-metal-coordinated CO: calculation of the reaction of [Ru(CO)5] and related complexes and relevance to alkane carbonylation.

Addition of ammonia to AlH3 and BH3. Why does only aluminum form 2:1 adducts?

Alkane metathesis by tandem alkane-dehydrogenation-olefin-metathesis catalysis and related chemistry.

Assessment of the Electronic Factors Determining the Thermodynamics of "Oxidative Addition" of C-H and N-H Bonds to Ir(I) Complexes

Bioinorganic chemistry: Bond breaking bacteria-style

Calculation of ionization energy, electron affinity, and hydride affinity trends in pincer-ligated d(8)-Ir((tBu4)PXCXP) complexes: implications for the thermodynamics of oxidative H2 addition

Carbon–carbon bonds get a break

Catalytic Dehydrogenative C-C Coupling by a Pincer-Ligated Iridium Complex

Catalytic alkane metathesis by tandem alkane dehydrogenation-olefin metathesis

Catalytic cleavage of ether C-O bonds by pincer iridium complexes

Catalytic dehydroaromatization of n-alkanes by pincer-ligated iridium complexes

Catalytic ring expansion, contraction, and metathesis-polymerization of cycloalkanes.

Catalytic synthesis of n-alkyl arenes through alkyl group cross-metathesis

Chlorination of (Phebox)Ir(mesityl)(OAc) by Thionyl Chloride.

Cleavage of ether, ester, and tosylate C(sp3)-O bonds by an iridium complex, initiated by oxidative addition of C-H bonds. Experimental and computational studies.

Cleavage of sp3 C-O bonds via oxidative addition of C-H bonds.

Combined computational and experimental study of substituent effects on the thermodynamics of H(2), CO, arene, and alkane addition to iridium.

Dehydrogenation of Alkanes and Aliphatic Groups by Pincer-Ligated Metal Complexes.

Dehydrogenation of aliphatic polyolefins catalyzed by pincer-ligated iridium complexes

Dehydrogenation of n-Alkanes by Solid-Phase Molecular Pincer-Iridium Catalysts. High Yields of α-Olefin Product

Dihydrogen/dihydride or tetrahydride? An experimental and computational investigation of pincer iridium polyhydrides

Dimerization of alkynes promoted by a pincer-ligated iridium complex. C-C reductive elimination inhibited by steric crowding

Distinct Thermodynamics for the Formation and Cleavage of N−H Bonds in Aniline and Ammonia. Directly-Observed Reductive Elimination of Ammonia from an Isolated Amido Hydride Complex ⬇️

Electrochemical C-H bond activation via cationic iridium hydride pincer complexes

Formation of Enamines via Catalytic Dehydrogenation by Pincer-Iridium Complexes

H2 Addition to Pincer Iridium Complexes Yielding trans-Dihydride Products: Unexpected Correlations of Bond Strength with Bond Length and Vibrational Frequencies

Large-Scale Selective Functionalization of Alkanes.

Mechanism of alkane transfer-dehydrogenation catalyzed by a pincer-ligated iridium complex.

Net oxidative addition of C(sp3)-F bonds to iridium via initial C-H bond activation

Olefin hydroaryloxylation catalyzed by pincer-iridium complexes

Olefin isomerization by iridium pincer catalysts. Experimental evidence for an η3-allyl pathway and an unconventional mechanism predicted by DFT calculations.

Oxidative addition of ammonia to form a stable monomeric amido hydride complex

Polar molecules catalyze CO insertion into metal-alkyl bonds through the displacement of an agostic C-H bond

Preface for small-molecule activation: carbon-containing fuels

Selective Dehydrogenative Coupling of Ethylene to Butadiene via an Iridacyclopentane Complex.

Selective cleavage of the C-C bonds of aminoethyl groups, via a multistep pathway, by a pincer iridium complex.

Synthesis and characterization of carbazolide-based iridium PNP pincer complexes. Mechanistic and computational investigation of alkene hydrogenation: evidence for an Ir(III)/Ir(V)/Ir(III) catalytic cycle

β-Hydride Elimination and C-H Activation by an Iridium Acetate Complex, Catalyzed by Lewis Acids. Alkane Dehydrogenation Cocatalyzed by Lewis Acids and [2,6-Bis(4,4-dimethyloxazolinyl)-3,5-dimethylphenyl]iridium.