List of works - Rajendra S. Ghadwal

A Modular Access to Divinyldiphosphenes with a Strikingly Small HOMO-LUMO Energy Gap

scientific article published on 20 May 2019

A Phosphorus Analogue of p-Quinodimethane with a Planar P4 Ring: A Metal-Free Diphosphorus Source

scientific article published on 04 February 2019

A dimer of silaisonitrile with two-coordinate silicon atoms

scientific article published on 13 May 2011

A début for base stabilized monoalkylsilylenes

A facile route to functionalized N-heterocyclic carbenes (NHCs) with NHC base-stabilized dichlorosilylene

scientific article published on July 2010

Ambiphilicity of dichlorosilylene in a single molecule

scientific article published on 01 January 2010

An access to base-stabilized three-membered silicon heterocycles

scientific article published in 2012

Carbon-based two electron σ-donor ligands beyond classical N-heterocyclic carbenes.

scientific article

Classical N-Heterocyclic Carbenes Derived Crystalline Radicals

scientific article published on 21 February 2018

Convenient Access to Monosilicon Epoxides with Pentacoordinate Silicon

scientific article published on 01 May 2010

Crystalline Divinyldiarsene Radical Cations and Dications

scientific article published on 23 October 2019

Crystalline Divinyldiarsenes and Cleavage of the As=As Bond

scientific article published on 20 May 2019

Dichlorosilylene: A High Temperature Transient Species to an Indispensable Building Block ⬇️

scientific article published on November 27, 2012

Diphosphene radical cations and dications with a π-conjugated C2P2C2-framework

scientific article published on 01 August 2019

Diradical Character Enhancement by Spacing: N-Heterocyclic Carbene Analogues of Müller's Hydrocarbon

scientific article published on 18 October 2018

Direct functionalization of white phosphorus with anionic dicarbenes and mesoionic carbenes: facile access to 1,2,3-triphosphol-2-ides

scientific article published on 18 October 2019

Donor-acceptor stabilized silaformyl chloride

scientific article published on 11 July 2012

Donor-acceptor-stabilized silicon analogue of an acid anhydride.

scientific article

Double N–H bond activation of N,N′-bis-substituted hydrazines with stable N-heterocyclic silylene

article

Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom

scientific article published on 01 December 2019

Facile Access to Transition-Metal-Carbonyl Complexes with an Amidinate-Stabilized Chlorosilylene Ligand

article

Facile Access to the Functionalized N-Donor Stabilized Silylenes PhC(NtBu)2SiX (X = PPh2, NPh2, NCy2, NiPr2, NMe2, N(SiMe3)2, OtBu)

Facile access to silyl-functionalized N-heterocyclic olefins with HSiCl3

scientific article published on 01 October 2013

Facile routes to abnormal-NHC-cobalt(ii) complexes.

scientific article published on 2 June 2017

Free radical reactivity of mono- and dichlorosilylene with muonium

scientific article published on 09 September 2011

Isolation of Elusive Electrophilic Phosphinidene Complexes with π-Donor N-Heterocyclic Vinyl Substituents

scientific article published on 16 April 2020

Isolation of a Ge(I) Diradicaloid and Dihydrogen Splitting

scientific article published on 29 December 2020

Isolation of singlet carbene derived 2-arsa-1,3-butadiene radical cations and dications

scientific article published on 01 March 2020

Kekulé diradicaloids derived from a classical N-heterocyclic carbene.

scientific article published on 24 April 2018

Lewis Base Stabilized Dichlorosilylene

scientific article published on 01 January 2009

Lewis base mediated dismutation of trichlorosilane

scientific article published in 2012

Lewis-Base-Stabilized Dichlorosilylene: A Two-Electron σ-Donor Ligand

scientific article published on 01 February 2010

Mixed valence η6-arene cobalt(I) and cobalt(II) compound.

scientific article

Mono- and di-cationic hydrido boron compounds

scientific article published on 01 August 2015

N-Heterocyclic Carbene Analogues of Thiele and Chichibabin Hydrocarbons

scientific article published on 18 April 2018

N-Heterocyclic Carbene Stabilized Dichlorosilylene Transition-Metal Complexes of V(I), Co(I), and Fe(0)

scientific article published on 5 September 2011

N-Heterocyclic Vinylidene-Stabilized Phosphorus Biradicaloid

scientific article published on 30 May 2017

Neutral Penta- and Hexacoordinate N-Heterocyclic Carbene Complexes Derived from SiX4(X = F, Br)

article

Neutral pentacoordinate silicon fluorides derived from amidinate, guanidinate, and triazapentadienate ligands and base-induced disproportionation of Si2Cl6 to stable silylenes

scientific article published on 02 December 2010

Nickel-catalysed direct C2-arylation of N-heterocyclic carbenes.

scientific article

Normal-to-abnormal rearrangement of an N-heterocyclic carbene with a silylene transition metal complex

scientific article published on 01 June 2017

Palladium-catalyzed direct C2-arylation of an N-heterocyclic carbene: an atom-economic route to mesoionic carbene ligands

scientific article published on 29 January 2015

Reaction of N-heterocyclic silylenes with thioketone: formation of silicon-sulfur three (Si-C-S)- and five (Si-C-C-C-S)-membered ring systems

scientific article published on 30 January 2013

Reactions of StableN-Heterocyclic Silylenes with Ketones and 3,5-Di-tert-butyl-o-benzoquinone

Reactivity Studies of a Stable N-Heterocyclic Silylene with Triphenylsilanol and Pentafluorophenol

Selective functionalization of a bis-silylene

scientific article published on 01 July 2013

Silylene-Functionalized N-Heterocyclic Carbene (Si-NHC).

scientific article

Stabilization of low valent silicon fluorides in the coordination sphere of transition metals

scientific article published on 18 January 2012

Stable silaimines with three- and four-coordinate silicon atoms

scientific article published on 04 October 2012

Synthesis and Structure of [{PhC(NtBu)2}2Ge2(μ-S)2Cl2] and a Germanium Dithiocarboxylate Analogue

Synthesis and structural investigation of R2Si (R = Me, Ph) bridged di-N-heterocyclic carbenes

scientific article published on 01 September 2014

The Viability of C5-Protonated- and C4,C5-Ditopic Carbanionic Abnormal NHCs: A New Dimension in NHC Chemistry.

scientific article published on 24 January 2018

List of works by Rajendra S. Ghadwal

A Modular Access to Divinyldiphosphenes with a Strikingly Small HOMO-LUMO Energy Gap

A Phosphorus Analogue of p-Quinodimethane with a Planar P4 Ring: A Metal-Free Diphosphorus Source

A dimer of silaisonitrile with two-coordinate silicon atoms

A début for base stabilized monoalkylsilylenes

A facile route to functionalized N-heterocyclic carbenes (NHCs) with NHC base-stabilized dichlorosilylene

Ambiphilicity of dichlorosilylene in a single molecule

An access to base-stabilized three-membered silicon heterocycles

Carbon-based two electron σ-donor ligands beyond classical N-heterocyclic carbenes.

Classical N-Heterocyclic Carbenes Derived Crystalline Radicals

Convenient Access to Monosilicon Epoxides with Pentacoordinate Silicon

Crystalline Divinyldiarsene Radical Cations and Dications

Crystalline Divinyldiarsenes and Cleavage of the As=As Bond

Dichlorosilylene: A High Temperature Transient Species to an Indispensable Building Block ⬇️

Diphosphene radical cations and dications with a π-conjugated C2P2C2-framework

Diradical Character Enhancement by Spacing: N-Heterocyclic Carbene Analogues of Müller's Hydrocarbon

Direct functionalization of white phosphorus with anionic dicarbenes and mesoionic carbenes: facile access to 1,2,3-triphosphol-2-ides

Donor-acceptor stabilized silaformyl chloride

Donor-acceptor-stabilized silicon analogue of an acid anhydride.

Double N–H bond activation of N,N′-bis-substituted hydrazines with stable N-heterocyclic silylene

Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom

Facile Access to Transition-Metal-Carbonyl Complexes with an Amidinate-Stabilized Chlorosilylene Ligand

Facile Access to the Functionalized N-Donor Stabilized Silylenes PhC(NtBu)2SiX (X = PPh2, NPh2, NCy2, NiPr2, NMe2, N(SiMe3)2, OtBu)

Facile access to silyl-functionalized N-heterocyclic olefins with HSiCl3

Facile routes to abnormal-NHC-cobalt(ii) complexes.

Free radical reactivity of mono- and dichlorosilylene with muonium

Isolation of Elusive Electrophilic Phosphinidene Complexes with π-Donor N-Heterocyclic Vinyl Substituents

Isolation of a Ge(I) Diradicaloid and Dihydrogen Splitting

Isolation of singlet carbene derived 2-arsa-1,3-butadiene radical cations and dications

Kekulé diradicaloids derived from a classical N-heterocyclic carbene.

Lewis Base Stabilized Dichlorosilylene

Lewis base mediated dismutation of trichlorosilane

Lewis-Base-Stabilized Dichlorosilylene: A Two-Electron σ-Donor Ligand

Mixed valence η6-arene cobalt(I) and cobalt(II) compound.

Mono- and di-cationic hydrido boron compounds

N-Heterocyclic Carbene Analogues of Thiele and Chichibabin Hydrocarbons

N-Heterocyclic Carbene Stabilized Dichlorosilylene Transition-Metal Complexes of V(I), Co(I), and Fe(0)

N-Heterocyclic Vinylidene-Stabilized Phosphorus Biradicaloid

Neutral Penta- and Hexacoordinate N-Heterocyclic Carbene Complexes Derived from SiX4(X = F, Br)

Neutral pentacoordinate silicon fluorides derived from amidinate, guanidinate, and triazapentadienate ligands and base-induced disproportionation of Si2Cl6 to stable silylenes

Nickel-catalysed direct C2-arylation of N-heterocyclic carbenes.

Normal-to-abnormal rearrangement of an N-heterocyclic carbene with a silylene transition metal complex

Palladium-catalyzed direct C2-arylation of an N-heterocyclic carbene: an atom-economic route to mesoionic carbene ligands

Reaction of N-heterocyclic silylenes with thioketone: formation of silicon-sulfur three (Si-C-S)- and five (Si-C-C-C-S)-membered ring systems

Reactions of StableN-Heterocyclic Silylenes with Ketones and 3,5-Di-tert-butyl-o-benzoquinone

Reactivity Studies of a Stable N-Heterocyclic Silylene with Triphenylsilanol and Pentafluorophenol

Selective functionalization of a bis-silylene

Silylene-Functionalized N-Heterocyclic Carbene (Si-NHC).

Stabilization of low valent silicon fluorides in the coordination sphere of transition metals

Stable silaimines with three- and four-coordinate silicon atoms

Synthesis and Structure of [{PhC(NtBu)2}2Ge2(μ-S)2Cl2] and a Germanium Dithiocarboxylate Analogue

Synthesis and structural investigation of R2Si (R = Me, Ph) bridged di-N-heterocyclic carbenes

The Viability of C5-Protonated- and C4,C5-Ditopic Carbanionic Abnormal NHCs: A New Dimension in NHC Chemistry.