List of works - David Milstein

"Long-range" metal-ligand cooperation in H2 activation and ammonia-promoted hydride transfer with a ruthenium-acridine pincer complex

scientific article published on October 2010

A New Ligand System Based on a Bipyridine-Functionalized Calix[4]arene Backbone Leading to Mono- and Bimetallic Complexes ⬇️

scientific article published on May 19, 2003

A Reversible Liquid Organic Hydrogen Carrier System Based on Methanol-Ethylenediamine and Ethylene Urea

scientific article published on 06 March 2019

A novel liquid organic hydrogen carrier system based on catalytic peptide formation and hydrogenation

scientific article

Acceptorless Dehydrogenative Coupling Using Ammonia: Direct Synthesis of N-Heteroaromatics from Diols Catalyzed by Ruthenium

scientific article published on 17 September 2018

Activation of a carbon–carbon bond in solution by transition-metal insertion

scientific article published in Nature

Activation of dichloromethane by basic rhodium(I) and iridium(I) phosphine complexes. Synthesis and structures of fac-[Rh(PMe3)3Cl2(CH2PMe3)]Cl·CH2Cl2and trans-[Rh(Me2PCH2CH2PMe2)2Cl(CH2Cl)]Cl

scholarly article by Todd B. Marder et al published 1987 in Journal of the Chemical Society. Chemical communications

Activation of nitriles by metal ligand cooperation. Reversible formation of ketimido- and enamido-rhenium PNP pincer complexes and relevance to catalytic design

scientific article

Applications of acceptorless dehydrogenation and related transformations in chemical synthesis

scientific article published on July 2013

Aromatic vs aliphatic C-H bond activation by rhodium(I) as a function of agostic interactions: catalytic H/D exchange between olefins and methanol or water

scientific article

Benzyl Cation Stabilized by Metal Complexation. Relative Stability of Coordinated Methylene Arenium, π-Benzylic, and σ-Benzylic Structures

Bottom-Up Construction of a CO2-Based Cycle for the Photocarbonylation of Benzene, Promoted by a Rhodium(I) Pincer Complex

scientific article published on 11 July 2016

C-C Bond Formation of Benzyl Alcohols and Alkynes Using a Catalytic Amount of KOt Bu: Unusual Regioselectivity through a Radical Mechanism

scientific article published on 07 February 2019

C-H rather than O–H activation: synthesis and molecular structure of a cationic cis-hydrido-σ-acetylide complex of rhodium

scholarly article by Todd B. Marder et al published 1987 in Journal of the Chemical Society. Chemical communications

CO Oxidation by N2O Homogeneously Catalyzed by Ruthenium Hydride Pincer Complexes Indicating a New Mechanism

scientific article published on 05 June 2018

CO-Induced Methyl Migration in a Rhodium Thiophosphoryl Pincer Complex and Its Comparison with Phosphine-Based Complexes: The Divergent Effects of S and P Donor Ligands

Catalytic Hydrogenation of Thioesters, Thiocarbamates, and Thioamides

scientific article published on 17 December 2020

Catalytic Oxidative Deamination by Water with H2 Liberation

scientific article published on 25 November 2020

Catalytic System for the Heck Reaction of Fluorinated Haloaryls

Cationic, neutral, and anionic PNP Pd(II) and Pt(II) complexes: dearomatization by deprotonation and double-deprotonation of pincer systems

scientific article

Competitive C-I versus C-CN reductive elimination from a Rh(III) complex. Selectivity is controlled by the solvent

scientific article

Concept of the H(δ+)⋯ H(δ–) interaction. A low-temperature neutron diffraction study of cis-[IrH(OH)(PMe3)4]PF6

article

CC versus CH Activation and versus Agostic CC Interaction Controlled by Electron Density at the Metal Center ⬇️

scientific article published on September 22, 2003

DFT study of the structure and reactivity of the terminal Pt(IV)-oxo complex bearing no electron-withdrawing ligands

scientific article

Dimethylsulfoxide as a Ligand for RhI and IrI Complexes—Isolation, Structure, and Reactivity Towards XH Bonds (X=H, OH, OCH3) ⬇️

scientific article published on November 7, 2003

Direct Conversion of Alcohols into Alkenes by Dehydrogenative Coupling with Hydrazine/Hydrazone Catalyzed by Manganese

scientific article published on 19 August 2018

Direct Hydrogenation of Amides to Alcohols and Amines under Mild Conditions ⬇️

scientific article published on November 4, 2010

Direct Synthesis of Amides by Acceptorless Dehydrogenative Coupling of Benzyl Alcohols and Ammonia Catalyzed by a Manganese Pincer Complex: Unexpected Crucial Role of Base

scientific article published on 24 July 2019

Direct Synthesis of Amides by Dehydrogenative Coupling of Amines with either Alcohols or Esters: Manganese Pincer Complex as Catalyst.

scientific article

Direct Synthesis of Pyrroles by Dehydrogenative Coupling of Diols and Amines Catalyzed by Cobalt Pincer Complexes

scientific article published on 12 October 2016

Direct Synthesis of Symmetrical Azines from Alcohols and Hydrazine Catalyzed by a Ruthenium Pincer Complex: Effect of Hydrogen Bonding

scientific article

Direct conversion of alcohols to acetals and H(2) catalyzed by an acridine-based ruthenium pincer complex

scientific article published in March 2009

Direct coupling of alcohols to form esters and amides with evolution of H2 using in situ formed ruthenium catalysts

Direct deamination of primary amines by water to produce alcohols

scientific article published on 25 April 2013

Direct observation of reductive elimination of MeX (X = Cl, Br, I) from Rh(III) complexes: mechanistic insight and the importance of sterics

scientific article

Direct synthesis of amides from alcohols and amines with liberation of H2.

scientific article

Direct synthesis of pyridines and quinolines by coupling of γ-amino-alcohols with secondary alcohols liberating H2 catalyzed by ruthenium pincer complexes

scientific article published in July 2013

Direct synthesis of pyrroles by dehydrogenative coupling of β-aminoalcohols with secondary alcohols catalyzed by ruthenium pincer complexes

scientific article published on 6 March 2013

Discovery of the First Metallaquinone

scientific article published in 2000

Effect of CO on the oxidative addition of arene C-H bonds by cationic rhodium complexes

scientific article published in January 2010

Efficient hydrogenation of biomass-derived cyclic di-esters to 1,2-diols

scientific article published on 31 October 2011

Efficient hydrogenation of organic carbonates, carbamates and formates indicates alternative routes to methanol based on CO2 and CO.

scientific article published on 22 July 2011

Evidence for a terminal Pt(iv)-oxo complex exhibiting diverse reactivity

scientific article published in Nature

Exclusive C–C Oxidative Addition in a Rhodium Thiophosphoryl Pincer Complex and Computational Evidence for an η3-C–C–H Agostic Intermediate

article

Facile Conversion of Alcohols into Esters and Dihydrogen Catalyzed by New Ruthenium Complexes

scholarly article by Jing Zhang et al published August 2005 in Journal of the American Chemical Society

Formal loss of an H radical by a cobalt complex via metal-ligand cooperation

scientific article

Formamides as Isocyanate Surrogates: A Mechanistically Driven Approach to the Development of Atom-Efficient, Selective Catalytic Syntheses of Ureas, Carbamates, and Heterocycles

scientific article published on 01 October 2019

Formation of η2C−H Agostic Rhodium Arene Complexes and Their Relevance to Electrophilic Bond Activation

scholarly article by Arkadi Vigalok et al published December 1998 in Journal of the American Chemical Society

General Synthesis of Amino Acid Salts from Amino Alcohols and Basic Water Liberating H2.

scientific article published on 10 May 2016

Highly Efficient Process for Production of Biofuel from Ethanol Catalyzed by Ruthenium Pincer Complexes

scientific article published on 11 July 2016

Hydrogenation and Hydrosilylation of Nitrous Oxide Homogeneously Catalyzed by a Metal Complex

scientific article published on 12 April 2017

Hydrogenation and dehydrogenation iron pincer catalysts capable of metal-ligand cooperation by aromatization/dearomatization

scientific article published on 16 June 2015

Imidazole synthesis by transition metal free, base-mediated deaminative coupling of benzylamines and nitriles

scientific article published on 23 November 2017

In vivo magnetic resonance imaging of the estrogen receptor in an orthotopic model of human breast cancer

scientific article published on 31 October 2011

Interplay between solvent and counteranion stabilization of highly unsaturated rhodium(III) complexes: facile unsaturation-induced dearomatization

scientific article

Iron pincer complex catalyzed, environmentally benign, E-selective semi-hydrogenation of alkynes

scientific article

Iron-Catalyzed Mild and Selective Hydrogenative Cross-Coupling of Nitriles and Amines To Form Secondary Aldimines

scientific article published on 12 January 2017

Manganese Catalyzed Hydrogenation of Carbamates and Urea Derivatives

scientific article published on 07 August 2019

Manganese Catalyzed Hydrogenation of Organic Carbonates to Methanol and Alcohols

scientific article published on 07 August 2018

Manganese Catalyzed α-Olefination of Nitriles by Primary Alcohols

scientific article published on 9 August 2017

Manganese-Catalyzed Environmentally Benign Dehydrogenative Coupling of Alcohols and Amines to Form Aldimines and H2: A Catalytic and Mechanistic Study.

scientific article published on 25 March 2016

Manganese-Catalyzed Hydrogenation of Esters to Alcohols.

scientific article published on 30 October 2016

Manganese-Catalyzed N-Formylation of Amines by Methanol Liberating H2 : A Catalytic and Mechanistic Study.

scientific article

Mechanism of the Manganese-Pincer-Catalyzed Acceptorless Dehydrogenative Coupling of Nitriles and Alcohols

scientific article published on 29 January 2019

Mechanism of the Methylene Transfer Reaction. C−C Activation and Reductive Elimination in One System. A DFT Study

Mechanistic studies of the rhodium-catalysed cyclization of α,ω-alkynoci acids to alkylidene lactones. Crystals structures of two iridium model catalytic intermediates

scholarly article by Todd B. Marder et al published 1987 in Journal of the Chemical Society. Chemical communications

Metal-ligand cooperation

scientific article published on 07 September 2015

Metal-ligand cooperation by aromatization-dearomatization: a new paradigm in bond activation and "green" catalysis

scientific article published on 8 July 2011

Metal-ligand cooperation in the trans addition of dihydrogen to a pincer Ir(I) complex: a DFT study

scientific article published on 28 September 2009

Metal-stabilized phenoxonium cation

scientific article published in December 2003

Metallacarbenes from diazoalkanes: an experimental and computational study of the reaction mechanism

scientific article

Mononuclear Rh(II) PNP-type complexes. Structure and reactivity

scientific article published on 29 September 2007

N-Substituted Hydrazones by Manganese-Catalyzed Coupling of Alcohols with Hydrazine: Borrowing Hydrogen and Acceptorless Dehydrogenation in One System

scientific article published on 8 January 2018

NO˙ disproportionation by a {RhNO}9 pincer-type complex.

scientific article

New ligand systems incorporating two and three 4,4'-bipyridine units. Characterization of bi- and trimetallic rhodium and iridium complexes

scientific article published in November 2004

Novel Azine Reactivity: Facile NN Bond Cleavage, CH Activation, and NN Coupling Mediated by RhI ⬇️

scientific article published on April 29, 2003

Nucleophilic de-coordination and electrophilic regeneration of "hemilabile" pincer-type complexes: formation of anionic dialkyl, diaryl, and dihydride Pt(II) complexes bearing no stabilizing pi-acceptors

scientific article

Oxidation of Alkenes by Water with H2 Liberation

scientific article published on 19 March 2020

Oxidative addition of water and aliphatic alcohols by IrCl(trialkylphosphine)(3).

scientific article published in September 2002

Oxidative addition of water to novel Ir(I) complexes stabilized by dimethyl sulfoxide ligands

scientific article published in January 2002

Pi-accepting-pincer rhodium complexes: an unusual coordination mode of PCP-type systems

scientific article published in April 2005

Pyridine-Based PCP-Ruthenium Complexes: Unusual Structures and Metal-Ligand Cooperation

scientific article published on 30 April 2019

Pyridine-based SNS-iridium and -rhodium sulfide complexes, including d8-d8 metal-metal interactions in the solid state

scientific article published on 14 May 2008

Reactivity of rhodium-triflate complexes with diphenylsilane: evidence for silylene intermediacy in stoichiometric and catalytic reactions

scientific article

Reductive Cleavage of CO2 by Metal-Ligand-Cooperation Mediated by an Iridium Pincer Complex.

scientific article published on 28 April 2016

Reversible Aromaticity Transfer in a Bora-Cycle: Boron-Ligand Cooperation.

scientific article published on 15 September 2016

Rhodaoxetane: synthesis, structure, and theoretical evaluation

Ru(0) and Ru(II) nitrosyl pincer complexes: structure, reactivity, and catalytic activity

scientific article published on 18 September 2013

Ruthenium Dihydrogen Complex for C–H Activation: Catalytic H/D Exchange under Mild Conditions

Selective C−C vs C−H Bond Activation by Rhodium(I) PCP Pincer Complexes. A Computational Study

scholarly article by Andreas Sundermann et al published July 2000 in Journal of the American Chemical Society

Selective Hydrogenation of Cyclic Imides to Diols and Amines and Its Application in the Development of a Liquid Organic Hydrogen Carrier.

scientific article published on 8 June 2018

Selective ortho C-h activation of haloarenes by an Ir(I) system

scientific article published in April 2003

Self-oxidation of a phenolate complex to a bimetallic stilbene quinone

scientific article published in November 2004

Structure of Estradiol Metal Chelate and Estrogen Receptor Complex: The Basis for Designing a New Class of Selective Estrogen Receptor Modulators

scientific article

Synthesis and Reactivity of Cationic Boron Complexes Distorted by Pyridine-based Pincer Ligands: Isolation of a Photochemical Hofmann-Martius-type Intermediate

scientific article published on 03 February 2020

Synthesis and Reactivity of the Methylene Arenium Form of a Benzyl Cation, Stabilized by Complexation

scientific article published in 2006

Synthesis and molecular structures of a rhoda-lactone and its alkylation product; insertion of a pendant alkyne into a rhodium–hydrogen bond

article published in 1988

Synthesis and reactivity of iron complexes with a new pyrazine-based pincer ligand, and application in catalytic low-pressure hydrogenation of carbon dioxide

scientific article

Synthesis of Cyclic Imides by Acceptorless Dehydrogenative Coupling of Diols and Amines Catalyzed by a Manganese Pincer Complex.

scientific article

Synthesis of amides from esters and amines with liberation of H2 under neutral conditions

scientific article published on 19 January 2011

Synthesis, structure and reactivity of NO+, NO˙ and NO- pincer PCN-Rh complexes

scientific article published on 14 May 2020

Synthesis, structure, and reactivity of rhodium and iridium complexes of the chelating bis-sulfoxide tBuSOC2H4SOtBu. Selective O-H activation of 2-hydroxy-isopropyl-pyridine

scientific article published on 18 June 2008

Template Catalysis by Metal-Ligand Cooperation. C-C Bond Formation via Conjugate Addition of Non-activated Nitriles under Mild, Base-free Conditions Catalyzed by a Manganese Pincer Complex

scientific article published on 10 May 2016

Template catalysis by manganese pincer complexes: oxa- and aza-Michael additions to unsaturated nitriles

scientific article published on 07 August 2019

The Ferraquinone-Ferrahydroquinone Couple: Combining Quinonic and Metal-Based Reactivity

scientific article published on 31 January 2017

The first fully characterized neutral and cationic rhodium(I)-complexes containing DMSO as the only dative ligand; S-, O- and bridging S,O-bidentate binding modes

scientific article

Transfer of methylene groups promoted by metal complexation

scientific article published in Nature

Unprecedented iron-catalyzed selective hydrogenation of activated amides to amines and alcohols.

scientific article published on 22 March 2016

Why Does the Tetrakis(trimethylphosphine)iridium(III) Hydridochloride Cation Adopt the Sterically and Electronically UnfavorableCisGeometry?

scholarly article by Ofer Blum et al published October 2000 in Organometallics

Z-Selective (Cross-)Dimerization of Terminal Alkynes Catalyzed by an Iron Complex.

scientific article published on 21 April 2016

orthoC−H Activation of Haloarenes and Anisole by an Electron-Rich Iridium(I) Complex: Mechanism and Origin of Regio- and Chemoselectivity. An Experimental and Theoretical Study

scholarly article by Eyal Ben-Ari et al published June 2006 in Organometallics

sp3 C–H and sp2 C–H agostic ruthenium complexes: a combined experimental and theoretical study

article published in 2004

List of works by David Milstein

"Long-range" metal-ligand cooperation in H2 activation and ammonia-promoted hydride transfer with a ruthenium-acridine pincer complex

A New Ligand System Based on a Bipyridine-Functionalized Calix[4]arene Backbone Leading to Mono- and Bimetallic Complexes ⬇️

A Reversible Liquid Organic Hydrogen Carrier System Based on Methanol-Ethylenediamine and Ethylene Urea

A novel liquid organic hydrogen carrier system based on catalytic peptide formation and hydrogenation

Acceptorless Dehydrogenative Coupling Using Ammonia: Direct Synthesis of N-Heteroaromatics from Diols Catalyzed by Ruthenium

Activation of a carbon–carbon bond in solution by transition-metal insertion

Activation of dichloromethane by basic rhodium(I) and iridium(I) phosphine complexes. Synthesis and structures of fac-[Rh(PMe3)3Cl2(CH2PMe3)]Cl·CH2Cl2and trans-[Rh(Me2PCH2CH2PMe2)2Cl(CH2Cl)]Cl

Activation of nitriles by metal ligand cooperation. Reversible formation of ketimido- and enamido-rhenium PNP pincer complexes and relevance to catalytic design

Applications of acceptorless dehydrogenation and related transformations in chemical synthesis

Aromatic vs aliphatic C-H bond activation by rhodium(I) as a function of agostic interactions: catalytic H/D exchange between olefins and methanol or water

Benzyl Cation Stabilized by Metal Complexation. Relative Stability of Coordinated Methylene Arenium, π-Benzylic, and σ-Benzylic Structures

Bottom-Up Construction of a CO2-Based Cycle for the Photocarbonylation of Benzene, Promoted by a Rhodium(I) Pincer Complex

C-C Bond Formation of Benzyl Alcohols and Alkynes Using a Catalytic Amount of KOt Bu: Unusual Regioselectivity through a Radical Mechanism

C-H rather than O–H activation: synthesis and molecular structure of a cationic cis-hydrido-σ-acetylide complex of rhodium

CO Oxidation by N2O Homogeneously Catalyzed by Ruthenium Hydride Pincer Complexes Indicating a New Mechanism

CO-Induced Methyl Migration in a Rhodium Thiophosphoryl Pincer Complex and Its Comparison with Phosphine-Based Complexes: The Divergent Effects of S and P Donor Ligands

Catalytic Hydrogenation of Thioesters, Thiocarbamates, and Thioamides

Catalytic Oxidative Deamination by Water with H2 Liberation

Catalytic System for the Heck Reaction of Fluorinated Haloaryls

Cationic, neutral, and anionic PNP Pd(II) and Pt(II) complexes: dearomatization by deprotonation and double-deprotonation of pincer systems

Competitive C-I versus C-CN reductive elimination from a Rh(III) complex. Selectivity is controlled by the solvent

Concept of the H(δ+)⋯ H(δ–) interaction. A low-temperature neutron diffraction study of cis-[IrH(OH)(PMe3)4]PF6

CC versus CH Activation and versus Agostic CC Interaction Controlled by Electron Density at the Metal Center ⬇️

DFT study of the structure and reactivity of the terminal Pt(IV)-oxo complex bearing no electron-withdrawing ligands

Dimethylsulfoxide as a Ligand for RhI and IrI Complexes—Isolation, Structure, and Reactivity Towards XH Bonds (X=H, OH, OCH3) ⬇️

Direct Conversion of Alcohols into Alkenes by Dehydrogenative Coupling with Hydrazine/Hydrazone Catalyzed by Manganese

Direct Hydrogenation of Amides to Alcohols and Amines under Mild Conditions ⬇️

Direct Synthesis of Amides by Acceptorless Dehydrogenative Coupling of Benzyl Alcohols and Ammonia Catalyzed by a Manganese Pincer Complex: Unexpected Crucial Role of Base

Direct Synthesis of Amides by Dehydrogenative Coupling of Amines with either Alcohols or Esters: Manganese Pincer Complex as Catalyst.

Direct Synthesis of Pyrroles by Dehydrogenative Coupling of Diols and Amines Catalyzed by Cobalt Pincer Complexes

Direct Synthesis of Symmetrical Azines from Alcohols and Hydrazine Catalyzed by a Ruthenium Pincer Complex: Effect of Hydrogen Bonding

Direct conversion of alcohols to acetals and H(2) catalyzed by an acridine-based ruthenium pincer complex

Direct coupling of alcohols to form esters and amides with evolution of H2 using in situ formed ruthenium catalysts

Direct deamination of primary amines by water to produce alcohols

Direct observation of reductive elimination of MeX (X = Cl, Br, I) from Rh(III) complexes: mechanistic insight and the importance of sterics

Direct synthesis of amides from alcohols and amines with liberation of H2.

Direct synthesis of pyridines and quinolines by coupling of γ-amino-alcohols with secondary alcohols liberating H2 catalyzed by ruthenium pincer complexes

Direct synthesis of pyrroles by dehydrogenative coupling of β-aminoalcohols with secondary alcohols catalyzed by ruthenium pincer complexes

Discovery of the First Metallaquinone

Effect of CO on the oxidative addition of arene C-H bonds by cationic rhodium complexes

Efficient hydrogenation of biomass-derived cyclic di-esters to 1,2-diols

Efficient hydrogenation of organic carbonates, carbamates and formates indicates alternative routes to methanol based on CO2 and CO.

Evidence for a terminal Pt(iv)-oxo complex exhibiting diverse reactivity

Exclusive C–C Oxidative Addition in a Rhodium Thiophosphoryl Pincer Complex and Computational Evidence for an η3-C–C–H Agostic Intermediate

Facile Conversion of Alcohols into Esters and Dihydrogen Catalyzed by New Ruthenium Complexes

Formal loss of an H radical by a cobalt complex via metal-ligand cooperation

Formamides as Isocyanate Surrogates: A Mechanistically Driven Approach to the Development of Atom-Efficient, Selective Catalytic Syntheses of Ureas, Carbamates, and Heterocycles

Formation of η2C−H Agostic Rhodium Arene Complexes and Their Relevance to Electrophilic Bond Activation

General Synthesis of Amino Acid Salts from Amino Alcohols and Basic Water Liberating H2.

Highly Efficient Process for Production of Biofuel from Ethanol Catalyzed by Ruthenium Pincer Complexes

Hydrogenation and Hydrosilylation of Nitrous Oxide Homogeneously Catalyzed by a Metal Complex

Hydrogenation and dehydrogenation iron pincer catalysts capable of metal-ligand cooperation by aromatization/dearomatization

Imidazole synthesis by transition metal free, base-mediated deaminative coupling of benzylamines and nitriles

In vivo magnetic resonance imaging of the estrogen receptor in an orthotopic model of human breast cancer

Interplay between solvent and counteranion stabilization of highly unsaturated rhodium(III) complexes: facile unsaturation-induced dearomatization

Iron pincer complex catalyzed, environmentally benign, E-selective semi-hydrogenation of alkynes

Iron-Catalyzed Mild and Selective Hydrogenative Cross-Coupling of Nitriles and Amines To Form Secondary Aldimines

Manganese Catalyzed Hydrogenation of Carbamates and Urea Derivatives

Manganese Catalyzed Hydrogenation of Organic Carbonates to Methanol and Alcohols

Manganese Catalyzed α-Olefination of Nitriles by Primary Alcohols

Manganese-Catalyzed Environmentally Benign Dehydrogenative Coupling of Alcohols and Amines to Form Aldimines and H2: A Catalytic and Mechanistic Study.

Manganese-Catalyzed Hydrogenation of Esters to Alcohols.

Manganese-Catalyzed N-Formylation of Amines by Methanol Liberating H2 : A Catalytic and Mechanistic Study.

Mechanism of the Manganese-Pincer-Catalyzed Acceptorless Dehydrogenative Coupling of Nitriles and Alcohols

Mechanism of the Methylene Transfer Reaction. C−C Activation and Reductive Elimination in One System. A DFT Study

Mechanistic studies of the rhodium-catalysed cyclization of α,ω-alkynoci acids to alkylidene lactones. Crystals structures of two iridium model catalytic intermediates

Metal-ligand cooperation

Metal-ligand cooperation by aromatization-dearomatization: a new paradigm in bond activation and "green" catalysis

Metal-ligand cooperation in the trans addition of dihydrogen to a pincer Ir(I) complex: a DFT study

Metal-stabilized phenoxonium cation

Metallacarbenes from diazoalkanes: an experimental and computational study of the reaction mechanism

Mononuclear Rh(II) PNP-type complexes. Structure and reactivity

N-Substituted Hydrazones by Manganese-Catalyzed Coupling of Alcohols with Hydrazine: Borrowing Hydrogen and Acceptorless Dehydrogenation in One System

NO˙ disproportionation by a {RhNO}9 pincer-type complex.

New ligand systems incorporating two and three 4,4'-bipyridine units. Characterization of bi- and trimetallic rhodium and iridium complexes

Novel Azine Reactivity: Facile NN Bond Cleavage, CH Activation, and NN Coupling Mediated by RhI ⬇️

Nucleophilic de-coordination and electrophilic regeneration of "hemilabile" pincer-type complexes: formation of anionic dialkyl, diaryl, and dihydride Pt(II) complexes bearing no stabilizing pi-acceptors

Oxidation of Alkenes by Water with H2 Liberation

Oxidative addition of water and aliphatic alcohols by IrCl(trialkylphosphine)(3).