List of works - Takeaki Iwamoto

1,4-Dehydrogenation with a Two-Coordinate Cyclic (Alkyl)(amino)silylene

scientific article published on 24 June 2019

A Potassium Diboryllithate: Synthesis, Bonding Properties, and the Deprotonation of Benzene

scientific article

A Pt(0) complex with cyclic (alkyl)(amino)silylene and 1,3-divinyl-1,1,3,3-tetramethyldisiloxane ligands: synthesis, molecular structure, and catalytic hydrosilylation activity.

scientific article published in July 2017

A Tetrasilicon Analogue of Bicyclo[1.1.0]but-1(3)-ene Containing a Si=Si Double Bond with an Inverted Geometry

scientific article published on 21 February 2019

A Two-Coordinate Cyclic (Alkyl)(amino)silylene: Balancing Thermal Stability and Reactivity

scientific article published on 15 November 2016

A heavy analogue of the smallest bridgehead alkene stabilized by a base

scientific article published on 04 November 2014

A stable dialkylphosphinyl radical

scientific article published on 28 July 2011

A stable fused bicyclic disilene as a model for silicon surface.

scientific article

A stable silicon-based allene analogue with a formally sp-hybridized silicon atom.

scientific article

A two-coordinate palladium complex with two dialkylphosphinyl ligands

scientific article published on 24 October 2012

An Isolable Potassium Salt of a Borasilene-Chloride Adduct.

scientific article published on 22 March 2017

An Isolable Silicon Analogue of a Ketone that Contains an Unperturbed Si=O Double Bond

scientific article published on 18 June 2019

Anthryl-substituted 3-silylene-2-silaaziridine obtained by isomerization of disilacyclopropanimine: an exocyclic silene showing a distinct intramolecular charge transfer transition

scientific article published on 15 July 2013

Benzodisilacyclobutadienes: 8π-Electron Systems with an Antiaromatic Silicon Ring

scientific article

Cleavage of Two Hydrogen Molecules by Boryldisilenes

scientific article published on 09 May 2018

Concise synthesis of halogenated chrysenes ([4]phenacenes) that favor pi-stack packing in single crystals

scientific article published on 01 September 2009

Dearomative cycloadditions of a silylene with pyrazine and quinoxaline

scientific article published on 01 August 2018

Design of chiral bis-phosphoric acid catalyst derived from (R)-3,3'-di(2-hydroxy-3-arylphenyl)binaphthol: catalytic enantioselective Diels-Alder reaction of α,β-unsaturated aldehydes with amidodienes

scientific article published on 11 November 2011

Excited-state reactions of an isolable silylene with aromatic compounds.

scientific article

Facile Skeletal Rearrangement of Polycyclic Disilenes with Bicyclo[1.1.1]pentasilanyl Groups

scientific article published on 10 July 2018

Facile synthesis and bridgehead-functionalization of bicyclo[3.3.3]pentasiloxanes.

scientific article published on 12 December 2017

Fourteen-electron bis(dialkylsilylene)palladium and twelve-electron bis(dialkylsilyl)palladium complexes

scientific article published on 01 January 2008

Fused Tricyclic Disilenes with Highly Strained SiSi Double Bonds: Addition of a SiSi Single Bond to a SiSi Double Bond

article

Heteroaryldisilenes: heteroaryl groups serve as electron acceptors for Si[double bond, length as m-dash]Si double bonds in intramolecular charge transfer transitions

scientific article published on 01 August 2017

High performance global exploration of isomers and isomerization channels on quantum chemical potential energy surface of H5 C2 NO2

scientific article published on 04 November 2020

Interconversion between a planar 1,3-dichlorobicyclo[1.1.0]tetrasilane and a (chloro)(chlorosilyl)cyclotrisilene

scientific article published on 14 November 2020

Isolable 2,3-disila-1,3-butadiene from a double sila-Peterson reaction

scientific article published on 01 July 2014

Isolation and Characterization of Radical Anions Derived from a Boryl-Substituted Diphosphene.

scientific article published on 11 January 2017

Ligand dependence of pi-complex character in disilene-palladium complexes.

scientific article published on 15 November 2005

Naphtho- and anthra-disilacyclobutadienes

scientific article published on 17 November 2020

Near-IR absorbing nickel(II) porphyrinoids prepared by regioselective insertion of silylenes into antiaromatic nickel(II) norcorrole

scientific article published on 28 January 2014

New isolable dialkylsilylene and its isolable dimer that equilibrate in solution.

scientific article published on 3 December 2012

Palladium and platinum η(2) -disilyne complexes bearing an isolable dialkyldisilyne as a ligand

scientific article published on 8 November 2013

Pentasila-1,4-diene: Homoconjugation between Si═Si Double Bonds via a SiMe(2) Unit.

scientific article

Persilastaffanes: design, synthesis, structure, and conjugation between silicon cages

scientific article published on 07 December 2011

Persistent Dialkylsilanone Generated by Dehydrobromination of Dialkylbromosilanol

scientific article

Persistent antimony- and bismuth-centered radicals in solution

scientific article published on 27 July 2014

Persistent four-coordinate iron-centered radical stabilized by π-donation.

scientific article published on 25 September 2015

Probing the reactivity of a stable silene using muonium

scientific article published on 01 January 2008

Radical anion of isolable dialkylsilylene.

scientific article published in March 2003

Reactions of a tetrasilabicyclo[1.1.0]but-1(3)-ene with carbon tetrachloride and methanol

scientific article published on 15 May 2019

Stable Push-Pull Disilene: Substantial Donor-Acceptor Interactions through the Si═Si Double Bond.

scientific article published in December 2017

Synthesis and structures of (dialkylsilylene)bis(phosphine)-nickel, palladium, and platinum complexes and (η(6)-arene)(dialkylsilylene)nickel complexes

scientific article published on 31 August 2010

Synthesis, properties, and reactions of a series of stable dialkyl-substituted silicon-chalcogen doubly bonded compounds

scientific article published in December 2006

Synthesis, structure, and bonding of stable dialkylsilaketenimines.

scientific article published in April 2006

Tethered 1,2-Si-Group Migrations in Radical-Mediated Ring Enlargements of Cyclic Alkoxysilanes: An EPR Spectroscopic and Computational Investigation.

scientific article published on 05 June 2017

The first 1,3-disilabicyclo[1.1.0]butane with long-bridge silicon-silicon bond.

scientific article published in December 2001

The singlet excited state of a stable dialkylsilylene is responsible for its photoreactions

scientific article published on 01 August 2004

Thermal and photochemical cleavage of Si=Si double bond in tetrasila-1,3-diene

scientific article published on 11 August 2007

Transformation of azulenes to bicyclic [4]dendralene and heptafulvene derivatives via photochemical cycloaddition of dialkylsilylene.

scientific article

List of works by Takeaki Iwamoto

1,4-Dehydrogenation with a Two-Coordinate Cyclic (Alkyl)(amino)silylene

A Potassium Diboryllithate: Synthesis, Bonding Properties, and the Deprotonation of Benzene

A Pt(0) complex with cyclic (alkyl)(amino)silylene and 1,3-divinyl-1,1,3,3-tetramethyldisiloxane ligands: synthesis, molecular structure, and catalytic hydrosilylation activity.

A Tetrasilicon Analogue of Bicyclo[1.1.0]but-1(3)-ene Containing a Si=Si Double Bond with an Inverted Geometry

A Two-Coordinate Cyclic (Alkyl)(amino)silylene: Balancing Thermal Stability and Reactivity

A heavy analogue of the smallest bridgehead alkene stabilized by a base

A stable dialkylphosphinyl radical

A stable fused bicyclic disilene as a model for silicon surface.

A stable silicon-based allene analogue with a formally sp-hybridized silicon atom.

A two-coordinate palladium complex with two dialkylphosphinyl ligands

An Isolable Potassium Salt of a Borasilene-Chloride Adduct.

An Isolable Silicon Analogue of a Ketone that Contains an Unperturbed Si=O Double Bond

Anthryl-substituted 3-silylene-2-silaaziridine obtained by isomerization of disilacyclopropanimine: an exocyclic silene showing a distinct intramolecular charge transfer transition

Benzodisilacyclobutadienes: 8π-Electron Systems with an Antiaromatic Silicon Ring

Cleavage of Two Hydrogen Molecules by Boryldisilenes

Concise synthesis of halogenated chrysenes ([4]phenacenes) that favor pi-stack packing in single crystals

Dearomative cycloadditions of a silylene with pyrazine and quinoxaline

Design of chiral bis-phosphoric acid catalyst derived from (R)-3,3'-di(2-hydroxy-3-arylphenyl)binaphthol: catalytic enantioselective Diels-Alder reaction of α,β-unsaturated aldehydes with amidodienes

Excited-state reactions of an isolable silylene with aromatic compounds.

Facile Skeletal Rearrangement of Polycyclic Disilenes with Bicyclo[1.1.1]pentasilanyl Groups

Facile synthesis and bridgehead-functionalization of bicyclo[3.3.3]pentasiloxanes.

Fourteen-electron bis(dialkylsilylene)palladium and twelve-electron bis(dialkylsilyl)palladium complexes

Fused Tricyclic Disilenes with Highly Strained SiSi Double Bonds: Addition of a SiSi Single Bond to a SiSi Double Bond

Heteroaryldisilenes: heteroaryl groups serve as electron acceptors for Si[double bond, length as m-dash]Si double bonds in intramolecular charge transfer transitions

High performance global exploration of isomers and isomerization channels on quantum chemical potential energy surface of H5 C2 NO2

Interconversion between a planar 1,3-dichlorobicyclo[1.1.0]tetrasilane and a (chloro)(chlorosilyl)cyclotrisilene

Isolable 2,3-disila-1,3-butadiene from a double sila-Peterson reaction

Isolation and Characterization of Radical Anions Derived from a Boryl-Substituted Diphosphene.

Ligand dependence of pi-complex character in disilene-palladium complexes.

Naphtho- and anthra-disilacyclobutadienes

Near-IR absorbing nickel(II) porphyrinoids prepared by regioselective insertion of silylenes into antiaromatic nickel(II) norcorrole

New isolable dialkylsilylene and its isolable dimer that equilibrate in solution.

Palladium and platinum η(2) -disilyne complexes bearing an isolable dialkyldisilyne as a ligand

Pentasila-1,4-diene: Homoconjugation between Si═Si Double Bonds via a SiMe(2) Unit.

Persilastaffanes: design, synthesis, structure, and conjugation between silicon cages

Persistent Dialkylsilanone Generated by Dehydrobromination of Dialkylbromosilanol

Persistent antimony- and bismuth-centered radicals in solution

Persistent four-coordinate iron-centered radical stabilized by π-donation.

Probing the reactivity of a stable silene using muonium

Radical anion of isolable dialkylsilylene.

Reactions of a tetrasilabicyclo[1.1.0]but-1(3)-ene with carbon tetrachloride and methanol

Stable Push-Pull Disilene: Substantial Donor-Acceptor Interactions through the Si═Si Double Bond.

Synthesis and structures of (dialkylsilylene)bis(phosphine)-nickel, palladium, and platinum complexes and (η(6)-arene)(dialkylsilylene)nickel complexes

Synthesis, properties, and reactions of a series of stable dialkyl-substituted silicon-chalcogen doubly bonded compounds

Synthesis, structure, and bonding of stable dialkylsilaketenimines.

Tethered 1,2-Si-Group Migrations in Radical-Mediated Ring Enlargements of Cyclic Alkoxysilanes: An EPR Spectroscopic and Computational Investigation.

The first 1,3-disilabicyclo[1.1.0]butane with long-bridge silicon-silicon bond.

The singlet excited state of a stable dialkylsilylene is responsible for its photoreactions

Thermal and photochemical cleavage of Si=Si double bond in tetrasila-1,3-diene

Transformation of azulenes to bicyclic [4]dendralene and heptafulvene derivatives via photochemical cycloaddition of dialkylsilylene.