List of works - Christian Roussel

A forgotten chiral spiro compound revisited: 3,3'-dimethyl-3H,3'H-2,2'-spirobi[[1,3]benzothiazole]

scientific article published on 25 August 2015

A screening study of ChirBase molecular database to explore the expanded chiral pool derived from the application of chiral chromatography

scientific article

Access to N-thioalkenyl and N-(o-thio)aryl-benzimidazol-2-ones by ring opening of thiazolobenzimidazolium and benzimidazobenzothiazolium salts and C-O bond cleavage of an alkoxide.

scientific article published on 11 March 2015

Acid/base-triggered switching of circularly polarized luminescence and electronic circular dichroism in organic and organometallic helicenes

scientific article published on 21 November 2014

An approach to discriminating 25 commercial chiral stationary phases from structural data sets extracted from a molecular database ⬇️

scientific article published on September 1, 1997

An insight into the use of dimethylphenyl carbamate cyclofructan 7 chiral stationary phase in supercritical fluid chromatography: The basic comparison with HPLC ⬇️

scientific article published on April 27, 2013

An oxorhenium complex bearing a chiral cyclohexane-1-olato-2-thiolato ligand: Synthesis, stereochemistry, and theoretical study of parity violation vibrational frequency shifts

scientific article

Analysis of the major chiral compounds of Artemisia herba-alba essential oils (EOs) using reconstructed vibrational circular dichroism (VCD) spectra: En route to a VCD chiral signature of EOs.

scientific article published on 2 December 2015

Anisotropic organization and microscopic manipulation of self-assembling synthetic porphyrin microrods that mimic chlorosomes: bacterial light-harvesting systems.

scientific article published on 9 December 2011

Artemisia arborescens Essential Oil Composition, Enantiomeric Distribution, and Antimicrobial Activity from Different Wild Populations from the Mediterranean Area.

scientific article

Assembly of helicene-capped N,P,N,P,N-helicands within Cu(I) helicates: impacting chiroptical properties by ligand-ligand charge transfer

scientific article

Asymmetric 4-aryl-1,4-dihydropyridines potentiate mutant cystic fibrosis transmembrane conductance regulator (CFTR).

scientific article published on 27 August 2012

Atropisomerism and Axial Chirality in Heteroaromatic Compounds

Atropisomerism in a 10-Membered Ring with Multiple Chirality Axes: (3 Z,9 Z)-1,2,5,8-Dithiadiazecine-6,7(5 H,8 H)-dione Series

scientific article published on 13 June 2018

Atropisomerism in amidinoquinoxaline N-oxides: effect of the ring size and substituents on the enantiomerization barriers.

scientific article published on 27 January 2015

Atropisomerization in N-aryl-2(1H)-pyrimidin-(thi)ones: a ring-opening/rotation/ring-closure process in place of a classical rotation around the pivot bond

scientific article published on 11 December 2013

Attempts to separate (-)-α-thujone, (+)-β-thujone epimers from camphor enantiomers by enantioselective HPLC with polarimetric detection

scientific article published on 04 February 2013

Axial-to-central chirality transfer in cyclization processes ⬇️

scientific article published on 06 August 2013

Axially chiral Ni(II) complexes of α-amino acids: Separation of enantiomers and kinetics of racemization.

scientific article published on 23 January 2018

Aza[6]helicene Platinum Complexes: Chirality Control ofcis-transIsomerism

scientific article published on 17 April 2014

Bimetallic Gold(I) Complexes with Ethynyl-Helicene and Bis-Phosphole Ligands: Understanding the Role of Aurophilic Interactions in their Chiroptical Properties

scientific article published on 23 March 2016

CHIRBASE, a graphical molecular database on the separation of enantiomers by liquid-, supercritical fluid-, and gas chromatography

scientific article published on 01 January 1993

Chiral liquid chromatography contribution to the determination of the absolute configuration of enantiomers.

scientific article published in May 2004

Chiral oxorhenium(V) complexes as candidates for the experimental observation of molecular parity violation: a structural, synthetic and theoretical study

scientific article

Chiroptical Detectors for the Study of Unusual Phenomena in Chiral Chromatography ⬇️

scientific article published on January 1, 2013

Chiroptical properties of carbo[6]helicene derivatives bearing extended π-conjugated cyano substituents

scientific article published in August 2013

Chromatographic resolution, solution and crystal phase conformations, and absolute configuration of tert-butyl(dimethylamino)phenylphosphine-borane complex

scientific article published on 01 July 2006

Combining Organocatalysis with Central-to-Axial Chirality Conversion: Atroposelective Hantzsch-Type Synthesis of 4-Arylpyridines.

scientific article

Controlling chirality and optical properties of artificial antenna systems with self-assembling porphyrins

scientific article published on 01 May 2003

Data mining and enantiophore studies on chiral stationary phases used in HPLC separation

scientific article

Diastereo- and Enantioselective Synthesis of Organometallic Bis(helicene)s by a Combination of CH Activation and Dynamic Isomerization

scientific article published on 31 October 2013

Electronic and chiroptical properties of chiral cycloiridiated complexes bearing helicenic NHC ligands

scientific article published on 29 June 2016

Enantiomers of dimethyl [(2E)-1,3-diphenylprop-2-en-1-yl]propanedioate resulting from allylic alkylation reaction: Elution order on major high-performance liquid chromatography chiral columns ⬇️

scientific article published on September 15, 2012

Enantiophore modeling in 3D-QSAR. A data mining application on Whelk-O1 chiral stationary phase

scientific article

Enantiorecognition on solid chiral selectors using microbatch technology: an example of limitation in case of strong association in the racemate

scientific article published in July 2005

Enantioselective Syntheses of Furan Atropisomers by an Oxidative Central-to-Axial Chirality Conversion Strategy.

scientific article published on 20 January 2017

Ethylenedithio-tetrathiafulvalene-helicenes: electroactive helical precursors with switchable chiroptical properties.

scientific article published on 12 August 2013

From Hetero- to Homochiral Bis(metallahelicene)s Based on a PtIII−PtIIIBonded Scaffold: Isomerization, Structure, and Chiroptical Properties

scientific article published on 24 February 2011

Geometric enantiomerism in cyclic compounds: chiral dibrominated 1,3-dioxanes

scientific article published on 24 September 2010

HPLC on chiral support with polarimetric detection: application to conglomerate discovery

scientific article published on 01 June 2007

HPLC separation and VCD spectroscopy of chiral pyrazoles derived from (5R)-dihydrocarvone

Helicene-grafted vinyl- and carbene-osmium complexes: an example of acid-base chiroptical switching

scientific article

Inherently chiral phosphonatocavitands as artificial chemo- and enantio-selective receptors of natural ammoniums

scientific article published on 25 May 2011

Isolation of the major chiral compounds from Bubonium graveolens essential oil by HPLC and absolute configuration determination by VCD.

scientific article

Metallahelicenes: Easily Accessible Helicene Derivatives with Large and Tunable Chiroptical Properties

scientific article published on 01 January 2010

Metal−Bis(helicene) Assemblies Incorporating π-Conjugated Phosphole-Azahelicene Ligands: Impacting Chiroptical Properties by Metal Variation

scientific article published on 01 March 2009

Mimics of the self-assembling chlorosomal bacteriochlorophylls: regio- and stereoselective synthesis and stereoanalysis of acyl(1-hydroxyalkyl)porphyrins

scientific article published in October 2009

Mining Chromatographic Enantioseparation Data Using Matched Molecular Pair Analysis.

scientific article

Modeling and predicting chiral stationary phase enantioselectivity: An efficient random forest classifier using an optimally balanced training dataset and an aggregation strategy

scientific article published on 30 January 2018

Multifunctional and reactive enantiopure organometallic helicenes: tuning chiroptical properties by structural variations of mono- and bis(platinahelicene)s

scientific article published on 3 November 2011

N-C Axially Chiral Anilines: Electronic Effect on Barrier to Rotation and A Remote Proton Brake.

scientific article published on 24 January 2018

NH-type of chiral Ni(II) complexes of glycine Schiff base: design, structural evaluation, reactivity and synthetic applications

scientific article published on 01 February 2014

Nanoscopic imaging of meso-tetraalkylporphyrins prepared in high yields enabled by Montmorrilonite K10 and 3A molecular sieves

scientific article published on 09 July 2013

New 1,4-dihydropyridines endowed with NO-donor and calcium channel agonist properties

scientific article published on May 2004

New route to 3-alkylthiazolo[3,2-a]benzimidazole derivatives.

scientific article published on 28 February 2005

New selective phosphodiesterase 4D inhibitors differently acting on long, short, and supershort isoforms

scientific article published in November 2009

Non-racemic atropisomeric (thio)ureas as neutral enantioselective anion receptors for amino-acid derivatives: origin of smaller Kass with thiourea than urea derivatives

article

Novel phenyl(thio)ureas bearing (thio)oxothiazoline group as potential BACE-1 inhibitors: synthesis and biological evaluation

scientific article

Resolution and absolute configuration of some α-aminoacetals: en route to enantiopure N-protected α-aminoaldehydes

scientific article published on 21 October 2011

Resolution of some 4-benzofurazanyl and 4-benzofuroxanyl 1,4-dihydropyridine derivatives by chiral HPLC on Whelk-o1 and some polysaccharide chiral stationary phases

scientific article published on 01 January 1999

Reviewing mobile phases used on Chiralcel OD through an application of data mining tools to CHIRBASE database.

scientific article published in January 2001

Rhenium complexes bearing phosphole–pyridine chelates: simple molecules with large chiroptical properties

scientific article published on 24 May 2012

Ridge-tile-like chiral topology: synthesis, resolution, and complete chiroptical characterization of enantiomers of edge-sharing binuclear square planar complexes of Ni(II) bearing achiral ligands

scientific article published on August 2010

Ruthenium-Grafted Vinylhelicenes: Chiroptical Properties and Redox Switching

scientific article published on 6 October 2015

Ruthenium-Vinylhelicenes: Remote Metal-Based Enhancement and Redox Switching of the Chiroptical Properties of a Helicene Core

scientific article published on 25 June 2012

Self-disproportionation of enantiomers via achiral chromatography: a warning and an extra dimension in optical purifications.

scientific article published on 19 April 2012

Separation of atropisomeric 1,4,5,6-tetrahydropyrimidinium salts by chiral HPLC and determination of their enantiomerization barriers.

scientific article published in April 2005

Static and dynamic properties of 1,1'-bi-2-naphthol and its conjugated acids and bases

scientific article published on 18 September 2014

Steric Scale of Common Substituents from Rotational Barriers of N-(o-Substituted aryl)thiazoline-2-thione Atropisomers.

scientific article published on 13 September 2017

Straightforward access to mono- and bis-cycloplatinated helicenes that display circularly polarized phosphorescence using crystallization resolution methods

scientific article

Structural characterization of artificial self-assembling porphyrins that mimic the natural chlorosomal bacteriochlorophylls c, d, and e.

scientific article published in April 2005

Subtle chirality in oxo- and sulfidorhenium(v) complexes

scientific article published on 13 July 2009

Synthesis and Structural Properties of Aza[n]helicene Platinum Complexes: Control of Cis and Trans Stereochemistry.

scientific article

Synthesis and absolute configuration assignment of 5-amino-1,3,5-triphenyl-pentane-1,3-diol stereoisomers.

scientific article published in January 2005

Synthesis and chiral recognition ability of helical polyacetylenes bearing helicene pendants

Synthesis and vibrational circular dichroism of enantiopure chiral oxorhenium(V) complexes containing the hydrotris(1-pyrazolyl)borate ligand

scientific article published in December 2006

Synthesis and voltage-clamp studies of methyl 1,4-dihydro-2, 6-dimethyl-5-nitro-4-(benzofurazanyl)pyridine-3-carboxylate racemates and enantiomers and of their benzofuroxanyl analogues.

scientific article published on April 1999

Synthesis of p-toluenesulfinic esters of cellulose and beta-cyclodextrin

scientific article published on 01 March 1996

Synthesis of some novel organic nitrates and comparative in vitro study of their vasodilator profile

scientific article

Synthesis, chiral HPLC resolution and configuration assignment of 1-phenylglyceryl trinitrate stereomers

scientific article published on 01 June 2006

Synthesis, chiral separation, and absolute configuration of bis-(N-aryl) atropisomeric triads: 1,2-bis-[4-methyl-2-(thi)oxo-2,3-dihydrothiazol-3-yl]-benzene

scientific article published on 01 January 2009

Systematic evaluation of new chiral stationary phases for supercritical fluid chromatography using a standard racemate library

scientific article

The gear effect. III. A simple model for steric induced modification of syn-anti equilibrium in nucleotides

scientific article published on 01 February 1973

Theoretical reassessment of Whelk-O1 as an enantioselective receptor for 1-(4-halogeno-phenyl)-1-ethylamine derivatives

scientific article published on 01 January 2004

Toward structure-based predictive tools for the selection of chiral stationary phases for the chromatographic separation of enantiomers

scientific article published on 20 May 2016

Vibrational and electronic circular dichroism studies on the axially chiral pyridine-N-oxide: trans-2,6-di-ortho-tolyl-3,4,5-trimethylpyridine-N-oxide

scholarly article by Florina Teodorescu et al published October 2015 in Tetrahedron: Asymmetry

XRD and VCD: a marriage of love or convenience? Honeymoon around a cyclic urea derivative

scientific article published on 13 June 2012

enantio-Enriched CPL-active helicene-bipyridine-rhenium complexes

scientific article published on March 2015

List of works by Christian Roussel

A forgotten chiral spiro compound revisited: 3,3'-dimethyl-3H,3'H-2,2'-spirobi[[1,3]benzothiazole]

A screening study of ChirBase molecular database to explore the expanded chiral pool derived from the application of chiral chromatography

Access to N-thioalkenyl and N-(o-thio)aryl-benzimidazol-2-ones by ring opening of thiazolobenzimidazolium and benzimidazobenzothiazolium salts and C-O bond cleavage of an alkoxide.

Acid/base-triggered switching of circularly polarized luminescence and electronic circular dichroism in organic and organometallic helicenes

An approach to discriminating 25 commercial chiral stationary phases from structural data sets extracted from a molecular database ⬇️

An insight into the use of dimethylphenyl carbamate cyclofructan 7 chiral stationary phase in supercritical fluid chromatography: The basic comparison with HPLC ⬇️

An oxorhenium complex bearing a chiral cyclohexane-1-olato-2-thiolato ligand: Synthesis, stereochemistry, and theoretical study of parity violation vibrational frequency shifts

Analysis of the major chiral compounds of Artemisia herba-alba essential oils (EOs) using reconstructed vibrational circular dichroism (VCD) spectra: En route to a VCD chiral signature of EOs.

Anisotropic organization and microscopic manipulation of self-assembling synthetic porphyrin microrods that mimic chlorosomes: bacterial light-harvesting systems.

Artemisia arborescens Essential Oil Composition, Enantiomeric Distribution, and Antimicrobial Activity from Different Wild Populations from the Mediterranean Area.

Assembly of helicene-capped N,P,N,P,N-helicands within Cu(I) helicates: impacting chiroptical properties by ligand-ligand charge transfer

Asymmetric 4-aryl-1,4-dihydropyridines potentiate mutant cystic fibrosis transmembrane conductance regulator (CFTR).

Atropisomerism and Axial Chirality in Heteroaromatic Compounds

Atropisomerism in a 10-Membered Ring with Multiple Chirality Axes: (3 Z,9 Z)-1,2,5,8-Dithiadiazecine-6,7(5 H,8 H)-dione Series

Atropisomerism in amidinoquinoxaline N-oxides: effect of the ring size and substituents on the enantiomerization barriers.

Atropisomerization in N-aryl-2(1H)-pyrimidin-(thi)ones: a ring-opening/rotation/ring-closure process in place of a classical rotation around the pivot bond

Attempts to separate (-)-α-thujone, (+)-β-thujone epimers from camphor enantiomers by enantioselective HPLC with polarimetric detection

Axial-to-central chirality transfer in cyclization processes ⬇️

Axially chiral Ni(II) complexes of α-amino acids: Separation of enantiomers and kinetics of racemization.

Aza[6]helicene Platinum Complexes: Chirality Control ofcis-transIsomerism

Bimetallic Gold(I) Complexes with Ethynyl-Helicene and Bis-Phosphole Ligands: Understanding the Role of Aurophilic Interactions in their Chiroptical Properties

CHIRBASE, a graphical molecular database on the separation of enantiomers by liquid-, supercritical fluid-, and gas chromatography

Chiral liquid chromatography contribution to the determination of the absolute configuration of enantiomers.

Chiral oxorhenium(V) complexes as candidates for the experimental observation of molecular parity violation: a structural, synthetic and theoretical study

Chiroptical Detectors for the Study of Unusual Phenomena in Chiral Chromatography ⬇️

Chiroptical properties of carbo[6]helicene derivatives bearing extended π-conjugated cyano substituents

Chromatographic resolution, solution and crystal phase conformations, and absolute configuration of tert-butyl(dimethylamino)phenylphosphine-borane complex

Combining Organocatalysis with Central-to-Axial Chirality Conversion: Atroposelective Hantzsch-Type Synthesis of 4-Arylpyridines.

Controlling chirality and optical properties of artificial antenna systems with self-assembling porphyrins

Data mining and enantiophore studies on chiral stationary phases used in HPLC separation

Diastereo- and Enantioselective Synthesis of Organometallic Bis(helicene)s by a Combination of CH Activation and Dynamic Isomerization

Electronic and chiroptical properties of chiral cycloiridiated complexes bearing helicenic NHC ligands

Enantiomers of dimethyl [(2E)-1,3-diphenylprop-2-en-1-yl]propanedioate resulting from allylic alkylation reaction: Elution order on major high-performance liquid chromatography chiral columns ⬇️

Enantiophore modeling in 3D-QSAR. A data mining application on Whelk-O1 chiral stationary phase

Enantiorecognition on solid chiral selectors using microbatch technology: an example of limitation in case of strong association in the racemate

Enantioselective Syntheses of Furan Atropisomers by an Oxidative Central-to-Axial Chirality Conversion Strategy.

Ethylenedithio-tetrathiafulvalene-helicenes: electroactive helical precursors with switchable chiroptical properties.

From Hetero- to Homochiral Bis(metallahelicene)s Based on a PtIII−PtIIIBonded Scaffold: Isomerization, Structure, and Chiroptical Properties

Geometric enantiomerism in cyclic compounds: chiral dibrominated 1,3-dioxanes

HPLC on chiral support with polarimetric detection: application to conglomerate discovery

HPLC separation and VCD spectroscopy of chiral pyrazoles derived from (5R)-dihydrocarvone

Helicene-grafted vinyl- and carbene-osmium complexes: an example of acid-base chiroptical switching

Inherently chiral phosphonatocavitands as artificial chemo- and enantio-selective receptors of natural ammoniums

Isolation of the major chiral compounds from Bubonium graveolens essential oil by HPLC and absolute configuration determination by VCD.

Metallahelicenes: Easily Accessible Helicene Derivatives with Large and Tunable Chiroptical Properties

Metal−Bis(helicene) Assemblies Incorporating π-Conjugated Phosphole-Azahelicene Ligands: Impacting Chiroptical Properties by Metal Variation

Mimics of the self-assembling chlorosomal bacteriochlorophylls: regio- and stereoselective synthesis and stereoanalysis of acyl(1-hydroxyalkyl)porphyrins

Mining Chromatographic Enantioseparation Data Using Matched Molecular Pair Analysis.

Modeling and predicting chiral stationary phase enantioselectivity: An efficient random forest classifier using an optimally balanced training dataset and an aggregation strategy

Multifunctional and reactive enantiopure organometallic helicenes: tuning chiroptical properties by structural variations of mono- and bis(platinahelicene)s

N-C Axially Chiral Anilines: Electronic Effect on Barrier to Rotation and A Remote Proton Brake.

NH-type of chiral Ni(II) complexes of glycine Schiff base: design, structural evaluation, reactivity and synthetic applications

Nanoscopic imaging of meso-tetraalkylporphyrins prepared in high yields enabled by Montmorrilonite K10 and 3A molecular sieves

New 1,4-dihydropyridines endowed with NO-donor and calcium channel agonist properties

New route to 3-alkylthiazolo[3,2-a]benzimidazole derivatives.

New selective phosphodiesterase 4D inhibitors differently acting on long, short, and supershort isoforms

Non-racemic atropisomeric (thio)ureas as neutral enantioselective anion receptors for amino-acid derivatives: origin of smaller Kass with thiourea than urea derivatives

Novel phenyl(thio)ureas bearing (thio)oxothiazoline group as potential BACE-1 inhibitors: synthesis and biological evaluation

Resolution and absolute configuration of some α-aminoacetals: en route to enantiopure N-protected α-aminoaldehydes

Resolution of some 4-benzofurazanyl and 4-benzofuroxanyl 1,4-dihydropyridine derivatives by chiral HPLC on Whelk-o1 and some polysaccharide chiral stationary phases

Reviewing mobile phases used on Chiralcel OD through an application of data mining tools to CHIRBASE database.

Rhenium complexes bearing phosphole–pyridine chelates: simple molecules with large chiroptical properties

Ridge-tile-like chiral topology: synthesis, resolution, and complete chiroptical characterization of enantiomers of edge-sharing binuclear square planar complexes of Ni(II) bearing achiral ligands

Ruthenium-Grafted Vinylhelicenes: Chiroptical Properties and Redox Switching

Ruthenium-Vinylhelicenes: Remote Metal-Based Enhancement and Redox Switching of the Chiroptical Properties of a Helicene Core

Self-disproportionation of enantiomers via achiral chromatography: a warning and an extra dimension in optical purifications.

Separation of atropisomeric 1,4,5,6-tetrahydropyrimidinium salts by chiral HPLC and determination of their enantiomerization barriers.

Static and dynamic properties of 1,1'-bi-2-naphthol and its conjugated acids and bases

Steric Scale of Common Substituents from Rotational Barriers of N-(o-Substituted aryl)thiazoline-2-thione Atropisomers.

Straightforward access to mono- and bis-cycloplatinated helicenes that display circularly polarized phosphorescence using crystallization resolution methods

Structural characterization of artificial self-assembling porphyrins that mimic the natural chlorosomal bacteriochlorophylls c, d, and e.

Subtle chirality in oxo- and sulfidorhenium(v) complexes

Synthesis and Structural Properties of Aza[n]helicene Platinum Complexes: Control of Cis and Trans Stereochemistry.

Synthesis and absolute configuration assignment of 5-amino-1,3,5-triphenyl-pentane-1,3-diol stereoisomers.

Synthesis and chiral recognition ability of helical polyacetylenes bearing helicene pendants

Synthesis and vibrational circular dichroism of enantiopure chiral oxorhenium(V) complexes containing the hydrotris(1-pyrazolyl)borate ligand

Synthesis and voltage-clamp studies of methyl 1,4-dihydro-2, 6-dimethyl-5-nitro-4-(benzofurazanyl)pyridine-3-carboxylate racemates and enantiomers and of their benzofuroxanyl analogues.

Synthesis of p-toluenesulfinic esters of cellulose and beta-cyclodextrin

Synthesis of some novel organic nitrates and comparative in vitro study of their vasodilator profile