List of works - Daniel García-Vivó

9-Borabicyclo[3.3.1]nonane: a metal-free catalyst for the hydroboration of carbodiimides

scientific article published on 01 March 2019

Acetonitrile Adduct [MoReCp(μ-H)(μ-PCy2)(CO)5(NCMe)]: A Surrogate of an Unsaturated Heterometallic Hydride Complex

scientific article published on 10 January 2018

Activation of H-H and H-O bonds at phosphorus with diiron complexes bearing pyramidal phosphinidene ligands.

scientific article published in March 2012

C-C and C-N Couplings Following Hydride Addition on Isocyanide Cyclopolyenyl Dimolybdenum Complexes to Give Tethered Aldimine and Aminocarbene Derivatives

scientific article published on 04 August 2017

Carbene- and Carbyne-like Behavior of the Mo−P Multiple Bond in a Dimolybdenum Complex Inducing Trigonal-Pyramidal Coordination of a Phosphinidene Ligand

scientific article published on 04 July 2007

Carbodiimides as catalysts for the reduction of CO2 with boranes

scientific article published on 01 May 2018

Chemistry of CS2- and SCNPh-adducts of the pyramidal phosphinidene-bridged complex [Mo2Cp(μ-κ1:κ1,η5-PC5H4)(CO)2(η6-HMes*)(PMe3)].

scientific article published on 27 February 2017

Chemistry of the oxophosphinidene ligand. 1. Electronic structure of the anionic complexes [MCp{P(O)R}(CO)(2)](-) (M = Mo, W; R = 2,4,6-C(6)H(2)(t)Bu(3)) and their reactions with H(+) and C-based electrophiles.

scientific article

Coordination and Dehydrogenation of Diphosphine-Borane Ph2PCH2PPh2·BH3 at a Heterometallic MoRe Center to Give an Agostic Boryl-Bridged Derivative

scientific article published on 12 November 2019

Cyclopentadienyl and related complexes of the group 6 elements having metal–metal triple bonds: Synthesis, structure, bonding and reactivity

Dehydrogenation, Methyl Elimination and Insertion Reactions of the Agostic Methyl-Bridged Complex [Mo2 Cp2 (μ-κ1 :η2 -CH3 )(μ-Pt Bu2 )(μ-CO)]

scientific article published on 30 May 2018

Dimolybdenum cyclopentadienyl complexes with bridging chalcogenophosphinidene ligands.

scientific article published on 3 July 2012

E-H Bond Activation and Insertion Processes in the Reactions of the Unsaturated Hydride [W2Cp2(μ-H)(μ-PPh2)(NO)2].

scientific article published on 7 February 2018

Efficient Synthesis and Multisite Reactivity of a Phosphinidene-Bridged Mo-Re Complex. A Platform Combining Nucleophilic and Electrophilic Features

scientific article published on 06 July 2020

Electronic Structure and Multisite Basicity of the Pyramidal Phosphinidene-Bridged Dimolybdenum Complex [Mo2(η5-C5H5)(μ-κ1:κ1,η5-PC5H4)(η6-C6H3tBu3)(CO)2(PMe3)]

scientific article published on 08 October 2015

Exploiting σ/π Coordination Isomerism to Prepare Homologous Organoalkali Metal (Li, Na, K) Monomers with Identical Ligand Sets

article

Group 4 initiators for the stereoselective ROP of rac-β-butyrolactone and its copolymerization with rac-lactide

scientific article published on 20 October 2011

Hydride, gold(i) and related derivatives of the unsaturated ditungsten anion [W2Cp2(μ-PCy2)(μ-CO)2](-).

scientific article published in November 2014

Hydrogen Atom Transfer Reactions of the Unsaturated Hydroxycarbyne Complex [W2Cp2(μ-COH)(μ-PPh2)2]BF4

Insertion and C–C coupling processes in reactions of the unsaturated hydride [W2Cp2(H)(μ-PCy2)(CO)2] with alkynes

scientific article published on 01 March 2016

Insertion reactions of small unsaturated molecules in the N-B bonds of boron guanidinates

scientific article published on 24 July 2017

Insertion, coupling and elimination processes in the reactions of the unsaturated alkyl-bridged complexes [Mo₂(η⁵-C₅H₅)₂(μ-CH₂R)(μ-PCy₂)(CO)₂] (R = H, Ph) with isocyanides and secondary phosphines.

scientific article published on 4 April 2014

Low-temperature N-O bond cleavage in nitrosyl ligands induced by the unsaturated dimolybdenum anion [Mo2(eta(5)-C5H5)2(mu-PPh2)(mu-CO)2]-.

scientific article published in October 2009

Mild N–O Bond Cleavage Reactions of a Pyramidalized Nitrosyl Ligand Bridging a Dimolybdenum Center

scientific article published on 03 November 2015

Mild P-P bond cleavage in the methyldiphosphenyl complex [Mo2Cp2(μ-PCy2)(μ-κ(2):κ(2)-P2Me)(CO)2] to give novel phosphide-bridged trinuclear derivatives

scientific article published on 10 October 2014

Mild P4Activation To Give an Anionic Diphosphorus Complex with a Dual Binding Ability at a Single P Site

scientific article published on 27 January 2011

Monomerizing alkali-metal 3,5-dimethylbenzyl salts with tris(N, N-dimethyl-2-aminoethyl)amine (Me6TREN): structural and bonding implications

scientific article

N-O Bond Activation and Cleavage Reactions of the Nitrosyl-Bridged Complexes [M2Cp2(μ-PCy2)(μ-NO)(NO)2] (M = Mo, W)

scientific article published on 21 November 2018

Nucleophilic behaviour of dioxo- and thiooxophosphorane complexes [MoCp(CO)2{E,P-EP(O)(2,4,6-C6H2tBu3)}]−(E = O, S)

scientific article published on 01 November 2014

One-step synthesis and P-H bond cleavage reactions of the phosphanyl complex syn-[MoCp{PH(2,4,6-C6H2tBu3)}(CO)2] to give heterometallic phosphinidene-bridged derivatives

scientific article published on 01 October 2019

P-N and N-Mo Bond Formation Processes in the Reactions of a Pyramidal Phosphinidene-Bridged Dimolybdenum Complex with Diazoalkanes and Organic Azides

scientific article published on 21 May 2020

Phosphinidene-Bridged MoMn Derivatives of the Thiophosphinidene Complex [Mo2Cp2(μ-κ2:κ1,η6-SPMes)(CO)2] (Mes = 2,4,6-C6H2tBu3).

scientific article

Phosphinidene-bridged binuclear complexes

article published in 2017

Polyamine-Stabilized Sodium Aryloxides: Simple Initiators for the Ring-Opening Polymerization ofrac-Lactide

scientific article published on 16 March 2011

Proton induced P–H and Mo–H bond activation at the phosphide bridged dimolybdenum complexes [Mo2Cp2(µ-H)(µ-PHR)(CO)4] (R = Cy, 2,4,6-C6H2R′3; R′ = H, Me,tBu)

scientific article published on 15 November 2004

Reactions of the Tetrafluoroborate Complex [Mo2Cp2(κ2-F2BF2)(μ-PPh2)2(CO)]BF4 with Mono- and Bidentate Ligands Having E–H bonds (E = O, S, Se, N, P)

scientific article published on 20 June 2012

Reactions of the Unsaturated Ditungsten Complexes [W2Cp2(μ-PPh2)2(CO)x] (x = 1, 2) with Nitric Oxide: Stereoselective Carbonyl Displacement and Oxygen-Transfer Reactions of a Nitrite Ligand

scientific article published on 16 April 2014

Reactions of the Unsaturated Hydroxo Complex [W2Cp2(OH)(μ-PPh2)2(CO)]BF4 with Mono- and Bidentate Ligands Having E–H bonds (E = O, S, N)

scientific article published on 18 September 2012

Reactions of the unsaturated complex [Mo(2)(eta(5)-C(5)H(5))(2)(mu-PEt(2))(2)(CO)(2)] with [Au(PR(3))](+) cations: kinetic preference of the Mo-P bonds as the site of attack of the gold(I) electrophile.

scientific article published in October 2009

Reactivity of N-Phosphinoguanidines of the Formula (HNR)(Ph2PNR)C(NAr) toward Main Group Metal Alkyls: Facile Ligand Rearrangement from N-Phosphinoguanidinates to Phosphinimine-Amidinates

scientific article published on 01 October 2020

Reactivity of the Anionic Diphosphorus Complex [Mo2Cp2(μ-PCy2)(CO)2(μ-κ2:κ2-P2)]− Toward ER3X Electrophiles (E = C to Pb): Insights into the Multisite Donor Ability and Dynamics of the P2 Ligand

scientific article published on 24 September 2012

Reactivity of the Anionic Diphosphorus Complex [Mo2Cp2(μ-PCy2)(μ-κ2:κ2-P2)(CO)2]− toward Phosphorus- and Transition Metal-Based Electrophiles

scientific article published on 09 July 2013

Reply to the ‘Comment on “Hydride, gold(i) and related derivatives of the unsaturated ditungsten anion [W2Cp2(μ-PCy2)(μ-CO)2]−”’ by M. Green, Dalton Transactions, 2018, 47, DOI: 10.1039/C8DT00044A

scientific article published on 01 May 2018

Selective Three-Component Coupling for CO2 Chemical Fixation to Boron Guanidinato Compounds

scientific article published on 27 June 2018

Stepwise hydrogenation of an arylthiophosphinidene isocyanide complex to give tethered aldimine and aminocarbene functions

scientific article published on 01 August 2013

Structural and Chemical Effects of the PtBu2 Bridge at Unsaturated Dimolybdenum Complexes Having Hydride and Hydrocarbyl Ligands.

scientific article

Structural diversity in polyamine Lewis base stabilised lithium aryloxides.

scientific article published on 6 August 2010

Structure and dynamics of heterometallic clusters derived from addition of metal carbonyl fragments to the unsaturated hydride [W2Cp2(μ-H)(μ-PPh2)(NO)2].

scientific article published on 25 October 2017

Symmetrization in a Phosphinidene-Bridged Complex To Give a Diphosphanediyl Derivative with Metal-Centered Reactivity

scientific article published on 06 December 2011

Synthesis and DFT Study of a Diphenylsilanone-Bridged Dimolybdenum Complex

scientific article

Terminal vs. bridging coordination of CO and NO ligands after decarbonylation of [W2Cp2(μ-PR2)(CO)3(NO)] complexes (R = Ph, Cy). An experimental and computational study.

scientific article

The doubly-bonded ditungsten anion [W2Cp2(μ-PPh2)(NO)2](-): an entry to the chemistry of unsaturated nitrosyl complexes.

scientific article published in August 2016

Tris(2-dimethylaminoethyl)amine: a simple new tripodal polyamine ligand for Group 1 metals.

scientific article published on 5 August 2010

Unprecedented participation of a four-coordinate hydrogen atom in the cubane core of lithium and sodium phenolates.

scientific article published in December 2013

Unusual ligand rearrangement: from N-phosphinoguanidinato to phosphinimine-amidinato compounds

scientific article published on 01 February 2019

Well-controlled synthesis of boronic-acid functionalised poly(lactide)s: a versatile platform for biocompatible polymer conjugates and sensors

scholarly article in RSC Advances, vol. 2 no. 14, 2012

List of works by Daniel García-Vivó

9-Borabicyclo[3.3.1]nonane: a metal-free catalyst for the hydroboration of carbodiimides

Acetonitrile Adduct [MoReCp(μ-H)(μ-PCy2)(CO)5(NCMe)]: A Surrogate of an Unsaturated Heterometallic Hydride Complex

Activation of H-H and H-O bonds at phosphorus with diiron complexes bearing pyramidal phosphinidene ligands.

C-C and C-N Couplings Following Hydride Addition on Isocyanide Cyclopolyenyl Dimolybdenum Complexes to Give Tethered Aldimine and Aminocarbene Derivatives

Carbene- and Carbyne-like Behavior of the Mo−P Multiple Bond in a Dimolybdenum Complex Inducing Trigonal-Pyramidal Coordination of a Phosphinidene Ligand

Carbodiimides as catalysts for the reduction of CO2 with boranes

Chemistry of CS2- and SCNPh-adducts of the pyramidal phosphinidene-bridged complex [Mo2Cp(μ-κ1:κ1,η5-PC5H4)(CO)2(η6-HMes*)(PMe3)].

Chemistry of the oxophosphinidene ligand. 1. Electronic structure of the anionic complexes [MCp{P(O)R*}(CO)(2)](-) (M = Mo, W; R* = 2,4,6-C(6)H(2)(t)Bu(3)) and their reactions with H(+) and C-based electrophiles.

Coordination and Dehydrogenation of Diphosphine-Borane Ph2PCH2PPh2·BH3 at a Heterometallic MoRe Center to Give an Agostic Boryl-Bridged Derivative

Cyclopentadienyl and related complexes of the group 6 elements having metal–metal triple bonds: Synthesis, structure, bonding and reactivity

Dehydrogenation, Methyl Elimination and Insertion Reactions of the Agostic Methyl-Bridged Complex [Mo2 Cp2 (μ-κ1 :η2 -CH3 )(μ-Pt Bu2 )(μ-CO)]

Dimolybdenum cyclopentadienyl complexes with bridging chalcogenophosphinidene ligands.

E-H Bond Activation and Insertion Processes in the Reactions of the Unsaturated Hydride [W2Cp2(μ-H)(μ-PPh2)(NO)2].

Efficient Synthesis and Multisite Reactivity of a Phosphinidene-Bridged Mo-Re Complex. A Platform Combining Nucleophilic and Electrophilic Features

Electronic Structure and Multisite Basicity of the Pyramidal Phosphinidene-Bridged Dimolybdenum Complex [Mo2(η5-C5H5)(μ-κ1:κ1,η5-PC5H4)(η6-C6H3tBu3)(CO)2(PMe3)]

Exploiting σ/π Coordination Isomerism to Prepare Homologous Organoalkali Metal (Li, Na, K) Monomers with Identical Ligand Sets

Group 4 initiators for the stereoselective ROP of rac-β-butyrolactone and its copolymerization with rac-lactide

Hydride, gold(i) and related derivatives of the unsaturated ditungsten anion [W2Cp2(μ-PCy2)(μ-CO)2](-).

Hydrogen Atom Transfer Reactions of the Unsaturated Hydroxycarbyne Complex [W2Cp2(μ-COH)(μ-PPh2)2]BF4

Insertion and C–C coupling processes in reactions of the unsaturated hydride [W2Cp2(H)(μ-PCy2)(CO)2] with alkynes

Insertion reactions of small unsaturated molecules in the N-B bonds of boron guanidinates

Insertion, coupling and elimination processes in the reactions of the unsaturated alkyl-bridged complexes [Mo₂(η⁵-C₅H₅)₂(μ-CH₂R)(μ-PCy₂)(CO)₂] (R = H, Ph) with isocyanides and secondary phosphines.

Low-temperature N-O bond cleavage in nitrosyl ligands induced by the unsaturated dimolybdenum anion [Mo2(eta(5)-C5H5)2(mu-PPh2)(mu-CO)2]-.

Mild N–O Bond Cleavage Reactions of a Pyramidalized Nitrosyl Ligand Bridging a Dimolybdenum Center

Mild P-P bond cleavage in the methyldiphosphenyl complex [Mo2Cp2(μ-PCy2)(μ-κ(2):κ(2)-P2Me)(CO)2] to give novel phosphide-bridged trinuclear derivatives

Mild P4Activation To Give an Anionic Diphosphorus Complex with a Dual Binding Ability at a Single P Site

Monomerizing alkali-metal 3,5-dimethylbenzyl salts with tris(N, N-dimethyl-2-aminoethyl)amine (Me6TREN): structural and bonding implications

N-O Bond Activation and Cleavage Reactions of the Nitrosyl-Bridged Complexes [M2Cp2(μ-PCy2)(μ-NO)(NO)2] (M = Mo, W)

Nucleophilic behaviour of dioxo- and thiooxophosphorane complexes [MoCp(CO)2{E,P-EP(O)(2,4,6-C6H2tBu3)}]−(E = O, S)

One-step synthesis and P-H bond cleavage reactions of the phosphanyl complex syn-[MoCp{PH(2,4,6-C6H2tBu3)}(CO)2] to give heterometallic phosphinidene-bridged derivatives

P-N and N-Mo Bond Formation Processes in the Reactions of a Pyramidal Phosphinidene-Bridged Dimolybdenum Complex with Diazoalkanes and Organic Azides

Phosphinidene-Bridged MoMn Derivatives of the Thiophosphinidene Complex [Mo2Cp2(μ-κ2:κ1,η6-SPMes*)(CO)2] (Mes* = 2,4,6-C6H2tBu3).

Phosphinidene-bridged binuclear complexes

Polyamine-Stabilized Sodium Aryloxides: Simple Initiators for the Ring-Opening Polymerization ofrac-Lactide

Proton induced P–H and Mo–H bond activation at the phosphide bridged dimolybdenum complexes [Mo2Cp2(µ-H)(µ-PHR)(CO)4] (R = Cy, 2,4,6-C6H2R′3; R′ = H, Me,tBu)

Reactions of the Tetrafluoroborate Complex [Mo2Cp2(κ2-F2BF2)(μ-PPh2)2(CO)]BF4 with Mono- and Bidentate Ligands Having E–H bonds (E = O, S, Se, N, P)

Reactions of the Unsaturated Ditungsten Complexes [W2Cp2(μ-PPh2)2(CO)x] (x = 1, 2) with Nitric Oxide: Stereoselective Carbonyl Displacement and Oxygen-Transfer Reactions of a Nitrite Ligand

Reactions of the Unsaturated Hydroxo Complex [W2Cp2(OH)(μ-PPh2)2(CO)]BF4 with Mono- and Bidentate Ligands Having E–H bonds (E = O, S, N)

Reactions of the unsaturated complex [Mo(2)(eta(5)-C(5)H(5))(2)(mu-PEt(2))(2)(CO)(2)] with [Au(PR(3))](+) cations: kinetic preference of the Mo-P bonds as the site of attack of the gold(I) electrophile.

Reactivity of N-Phosphinoguanidines of the Formula (HNR)(Ph2PNR)C(NAr) toward Main Group Metal Alkyls: Facile Ligand Rearrangement from N-Phosphinoguanidinates to Phosphinimine-Amidinates

Reactivity of the Anionic Diphosphorus Complex [Mo2Cp2(μ-PCy2)(CO)2(μ-κ2:κ2-P2)]− Toward ER3X Electrophiles (E = C to Pb): Insights into the Multisite Donor Ability and Dynamics of the P2 Ligand

Reactivity of the Anionic Diphosphorus Complex [Mo2Cp2(μ-PCy2)(μ-κ2:κ2-P2)(CO)2]− toward Phosphorus- and Transition Metal-Based Electrophiles

Reply to the ‘Comment on “Hydride, gold(i) and related derivatives of the unsaturated ditungsten anion [W2Cp2(μ-PCy2)(μ-CO)2]−”’ by M. Green, Dalton Transactions, 2018, 47, DOI: 10.1039/C8DT00044A

Selective Three-Component Coupling for CO2 Chemical Fixation to Boron Guanidinato Compounds

Stepwise hydrogenation of an arylthiophosphinidene isocyanide complex to give tethered aldimine and aminocarbene functions

Structural and Chemical Effects of the PtBu2 Bridge at Unsaturated Dimolybdenum Complexes Having Hydride and Hydrocarbyl Ligands.

Structural diversity in polyamine Lewis base stabilised lithium aryloxides.

Structure and dynamics of heterometallic clusters derived from addition of metal carbonyl fragments to the unsaturated hydride [W2Cp2(μ-H)(μ-PPh2)(NO)2].

Symmetrization in a Phosphinidene-Bridged Complex To Give a Diphosphanediyl Derivative with Metal-Centered Reactivity

Synthesis and DFT Study of a Diphenylsilanone-Bridged Dimolybdenum Complex

Terminal vs. bridging coordination of CO and NO ligands after decarbonylation of [W2Cp2(μ-PR2)(CO)3(NO)] complexes (R = Ph, Cy). An experimental and computational study.

The doubly-bonded ditungsten anion [W2Cp2(μ-PPh2)(NO)2](-): an entry to the chemistry of unsaturated nitrosyl complexes.

Tris(2-dimethylaminoethyl)amine: a simple new tripodal polyamine ligand for Group 1 metals.

Unprecedented participation of a four-coordinate hydrogen atom in the cubane core of lithium and sodium phenolates.

Unusual ligand rearrangement: from N-phosphinoguanidinato to phosphinimine-amidinato compounds

Well-controlled synthesis of boronic-acid functionalised poly(lactide)s: a versatile platform for biocompatible polymer conjugates and sensors

Chemistry of the oxophosphinidene ligand. 1. Electronic structure of the anionic complexes [MCp{P(O)R}(CO)(2)](-) (M = Mo, W; R = 2,4,6-C(6)H(2)(t)Bu(3)) and their reactions with H(+) and C-based electrophiles.

Phosphinidene-Bridged MoMn Derivatives of the Thiophosphinidene Complex [Mo2Cp2(μ-κ2:κ1,η6-SPMes)(CO)2] (Mes = 2,4,6-C6H2tBu3).