List of works - Keary M Engle

A Transient-Directing-Group Strategy Enables Enantioselective Reductive Heck Hydroarylation of Alkenes

scientific article published on 20 March 2020

Activation of diverse carbon-heteroatom and carbon-carbon bonds via palladium(II)-catalysed β-X elimination

An Initiation Kinetics Prediction Model Enables Rational Design of Ruthenium Olefin Metathesis Catalysts Bearing Modified Chelating Benzylidenes

scientific article published on 10 April 2018

An S(N)Ar approach to sterically hindered ortho-alkoxybenzaldehydes for the synthesis of olefin metathesis catalysts.

scientific article published on 31 March 2015

Asymmetric Electrophilic Fluorocyclization with Carbon Nucleophiles

scientific article published on 22 July 2013

Bystanding F+ oxidants enable selective reductive elimination from high-valent metal centers in catalysis

scientific article published on 24 January 2011

C(alkenyl)-H Activation via Six-Membered Palladacycles: Catalytic 1,3-Diene Synthesis

scientific article published on 23 April 2018

Cascade CuH-Catalysed Conversion of Alkynes to Enantioenriched 1,1-Disubstituted Products

scientific article published on 02 December 2019

Catalytic Carbo- and Aminoboration of Alkenyl Carbonyl Compounds via 5- and 6-Membered Palladacycles.

scientific article published on 31 January 2018

Catalytic Hydrotrifluoromethylation of Unactivated Alkenes

scientific article published on 07 February 2013

Catalytic Intermolecular Carboamination of Unactivated Alkenes via Directed Aminopalladation.

scientific article published on 20 July 2017

Catalytic, Enantioselective Synthesis of Allenyl Boronates

scientific article published on 21 March 2018

Catalytic, Enantioselective α-Alkylation of Azlactones with Nonconjugated Alkenes by Directed Nucleopalladation

scientific article published on 27 February 2019

Catalytic, Regioselective Hydrocarbofunctionalization of Unactivated Alkenes with Diverse C-H Nucleophiles

scientific article published on 6 October 2016

Constructing multiply substituted arenes using sequential palladium(II)-catalyzed C-H olefination

scientific article

Contrasting two- and three-dimensional crystal properties of isomeric dialkyl phthalates

scientific article published on 15 November 2007

Coordination diversity in hydrogen-bonded homoleptic fluoride-alcohol complexes modulates reactivity

scientific article published on 22 June 2015

Copper-Catalyzed Chan-Lam Cyclopropylation of Phenols and Azaheterocycles

Cross-coupling of C(sp)-H Bonds with Organometallic Reagents via Pd(II)/Pd(0) Catalysis**

scientific article

Developing ligands for palladium(II)-catalyzed C-H functionalization: intimate dialogue between ligand and substrate

scientific article published on 03 May 2013

Direct Access to Versatile Electrophiles via Catalytic Oxidative Cyanation of Alkenes

scientific article published in 2018

Directed nickel-catalyzed 1,2-dialkylation of alkenyl carbonyl compounds.

scientific article published on 16 May 2018

Directed, Palladium(II)-Catalyzed Enantioselective anti-Carboboration of Alkenyl Carbonyl Compounds

scientific article published on 13 March 2019

Directed, Palladium(II)-Catalyzed Intermolecular Aminohydroxylation of Alkenes Using a Mild Oxidation System

scientific article published on 11 June 2018

Directed, Regiocontrolled Hydroamination of Unactivated Alkenes via Protodepalladation.

scientific article published on 19 April 2016

Heterocycle Formation via Palladium-Catalyzed C-H Functionalization

scientific article

Hydrogen-Bonded Homoleptic Fluoride-Diarylurea Complexes: Structure, Reactivity and Coordinating Power

scientific article published on 8 September 2016

In Situ Catalyst Modification in Atom Transfer Radical Reactions with Ruthenium Benzylidene Complexes

scientific article

Integrating Allyl Electrophiles into Nickel-Catalyzed Conjunctive Cross-Coupling

scientific article published on 20 January 2020

Large-periodicity two-dimensional crystals by cocrystallization

scientific article

Ligand-accelerated C-H activation reactions: evidence for a switch of mechanism

scientific article published on October 2010

Ligand-accelerated cross-coupling of C(sp2)-H bonds with arylboron reagents

scientific article published on 21 October 2011

Ligand-enabled meta-C-H activation using a transient mediator

scientific article

Ligand-enabled reactivity and selectivity in a synthetically versatile aryl C-H olefination

scientific article

Mechanistic rationalization of unusual kinetics in Pd-catalyzed C-H olefination

scientific article published on 29 February 2012

Ni(COD)(DQ): An Air-Stable 18-Electron Nickel(0)-Olefin Precatalyst

scientific article published on 17 February 2020

Nickel-Catalyzed 1,2-Diarylation of Alkenyl Carboxylates: A Gateway to 1,2,3-Trifunctionalized Building Blocks

scientific article published on 12 December 2019

Nickel-Catalyzed 1,2-Diarylation of Simple Alkenyl Amides

scientific article published on 17 December 2018

Nickel-Catalyzed β,γ-Dicarbofunctionalization of Alkenyl Carbonyl Compounds via Conjunctive Cross-Coupling

scientific article published on 24 July 2017

Nickel-catalyzed intermolecular oxidative Heck arylation driven by transfer hydrogenation

scientific article published on 05 November 2019

Organic chemistry: Precision pruning of molecules

scientific article published on 11 May 2016

Origins of initiation rate differences in ruthenium olefin metathesis catalysts containing chelating benzylidenes

scientific article published on 21 April 2015

Palladium(0)-Catalyzed Directed syn-1,2-Carboboration and -Silylation: Alkene Scope, Applications in Dearomatization, and Stereocontrol by a Chiral Auxiliary

scientific article published on 08 October 2019

Palladium(II)-Catalyzed Directed anti-Hydrochlorination of Unactivated Alkynes with HCl.

scientific article

Palladium(II)-catalyzed C-H activation/C-C cross-coupling reactions: versatility and practicality

scientific article published on January 2009

Palladium(ii)-catalyzed γ-selective hydroarylation of alkenyl carbonyl compounds with arylboronic acids

scientific article published on 06 September 2018

Pd(0)/PR3-catalyzed intermolecular arylation of sp3 C-H bonds

scientific article published on July 2009

Pd(II)-catalyzed enantioselective C-H activation of cyclopropanes

scientific article published on 21 November 2011

Pd(II)-catalyzed hydroxyl-directed C-H olefination enabled by monoprotected amino acid ligands

scientific article

Pd(II)-catalyzed olefination of sp3 C-H bonds

scientific article

Practical Intermolecular Hydroarylation of Terminal Alkenes via Reductive Heck Coupling

Protodepalladation as a Strategic Elementary Step in Catalysis

scientific article published on 29 October 2018

Recent applications of chiral phosphoric acids in palladium catalysis

scientific article published on 07 January 2020

Regioselective Hydroamination Using a Directed Nucleopalladation/Protodepalladation Strategy

Sequential C–H Functionalization Reactions for the Enantioselective Synthesis of Highly Functionalized 2,3-Dihydrobenzofurans

scientific article published on 25 April 2013

Synthesis of Stereodefined 1,1-Diborylalkenes via Copper-Catalyzed Diboration of Terminal Alkynes

scientific article published on 23 June 2020

Synthesis of Substituted Dihydrobenzofurans via Tandem SNAr/5-Exo-Trig Cyclization

scientific article published on 08 April 2015

Transition metal-catalyzed C-H activation reactions: diastereoselectivity and enantioselectivity

scientific article published on October 2009

Transition-Metal-Catalyzed 1,2-Carboboration of Alkenes: Strategies, Mechanisms, and Stereocontrol

scientific article published on 10 September 2019

Tridentate Directing Groups Stabilize 6-Membered Palladacycles in Catalytic Alkene Hydrofunctionalization

scientific article published on 3 October 2017

Trifluoromethylation of Allylsilanes under Copper Catalysis

scientific article published on 12 June 2012

Trifluoromethylation of Allylsilanes under Photoredox Catalysis

scientific article published on 06 March 2013

Weak coordination as a powerful means for developing broadly useful C-H functionalization reactions

scientific article

Z-Selective Cross-Metathesis and Homodimerization of 3E-1,3-Dienes: Reaction Optimization, Computational Analysis, and Synthetic Applications

scientific article published on 30 September 2016

β,γ-Vicinal Dicarbofunctionalization of Alkenyl Carbonyl Compounds via Directed Nucleopalladation

scientific article

List of works by Keary M Engle

A Transient-Directing-Group Strategy Enables Enantioselective Reductive Heck Hydroarylation of Alkenes

Activation of diverse carbon-heteroatom and carbon-carbon bonds via palladium(II)-catalysed β-X elimination

An Initiation Kinetics Prediction Model Enables Rational Design of Ruthenium Olefin Metathesis Catalysts Bearing Modified Chelating Benzylidenes

An S(N)Ar approach to sterically hindered ortho-alkoxybenzaldehydes for the synthesis of olefin metathesis catalysts.

Asymmetric Electrophilic Fluorocyclization with Carbon Nucleophiles

Bystanding F+ oxidants enable selective reductive elimination from high-valent metal centers in catalysis

C(alkenyl)-H Activation via Six-Membered Palladacycles: Catalytic 1,3-Diene Synthesis

Cascade CuH-Catalysed Conversion of Alkynes to Enantioenriched 1,1-Disubstituted Products

Catalytic Carbo- and Aminoboration of Alkenyl Carbonyl Compounds via 5- and 6-Membered Palladacycles.

Catalytic Hydrotrifluoromethylation of Unactivated Alkenes

Catalytic Intermolecular Carboamination of Unactivated Alkenes via Directed Aminopalladation.

Catalytic, Enantioselective Synthesis of Allenyl Boronates

Catalytic, Enantioselective α-Alkylation of Azlactones with Nonconjugated Alkenes by Directed Nucleopalladation

Catalytic, Regioselective Hydrocarbofunctionalization of Unactivated Alkenes with Diverse C-H Nucleophiles

Constructing multiply substituted arenes using sequential palladium(II)-catalyzed C-H olefination

Contrasting two- and three-dimensional crystal properties of isomeric dialkyl phthalates

Coordination diversity in hydrogen-bonded homoleptic fluoride-alcohol complexes modulates reactivity

Copper-Catalyzed Chan-Lam Cyclopropylation of Phenols and Azaheterocycles

Cross-coupling of C(sp)-H Bonds with Organometallic Reagents via Pd(II)/Pd(0) Catalysis**

Developing ligands for palladium(II)-catalyzed C-H functionalization: intimate dialogue between ligand and substrate

Direct Access to Versatile Electrophiles via Catalytic Oxidative Cyanation of Alkenes

Directed nickel-catalyzed 1,2-dialkylation of alkenyl carbonyl compounds.

Directed, Palladium(II)-Catalyzed Enantioselective anti-Carboboration of Alkenyl Carbonyl Compounds

Directed, Palladium(II)-Catalyzed Intermolecular Aminohydroxylation of Alkenes Using a Mild Oxidation System

Directed, Regiocontrolled Hydroamination of Unactivated Alkenes via Protodepalladation.

Heterocycle Formation via Palladium-Catalyzed C-H Functionalization

Hydrogen-Bonded Homoleptic Fluoride-Diarylurea Complexes: Structure, Reactivity and Coordinating Power

In Situ Catalyst Modification in Atom Transfer Radical Reactions with Ruthenium Benzylidene Complexes

Integrating Allyl Electrophiles into Nickel-Catalyzed Conjunctive Cross-Coupling

Large-periodicity two-dimensional crystals by cocrystallization

Ligand-accelerated C-H activation reactions: evidence for a switch of mechanism

Ligand-accelerated cross-coupling of C(sp2)-H bonds with arylboron reagents

Ligand-enabled meta-C-H activation using a transient mediator

Ligand-enabled reactivity and selectivity in a synthetically versatile aryl C-H olefination

Mechanistic rationalization of unusual kinetics in Pd-catalyzed C-H olefination

Ni(COD)(DQ): An Air-Stable 18-Electron Nickel(0)-Olefin Precatalyst

Nickel-Catalyzed 1,2-Diarylation of Alkenyl Carboxylates: A Gateway to 1,2,3-Trifunctionalized Building Blocks

Nickel-Catalyzed 1,2-Diarylation of Simple Alkenyl Amides

Nickel-Catalyzed β,γ-Dicarbofunctionalization of Alkenyl Carbonyl Compounds via Conjunctive Cross-Coupling

Nickel-catalyzed intermolecular oxidative Heck arylation driven by transfer hydrogenation

Organic chemistry: Precision pruning of molecules

Origins of initiation rate differences in ruthenium olefin metathesis catalysts containing chelating benzylidenes

Palladium(0)-Catalyzed Directed syn-1,2-Carboboration and -Silylation: Alkene Scope, Applications in Dearomatization, and Stereocontrol by a Chiral Auxiliary

Palladium(II)-Catalyzed Directed anti-Hydrochlorination of Unactivated Alkynes with HCl.

Palladium(II)-catalyzed C-H activation/C-C cross-coupling reactions: versatility and practicality

Palladium(ii)-catalyzed γ-selective hydroarylation of alkenyl carbonyl compounds with arylboronic acids

Pd(0)/PR3-catalyzed intermolecular arylation of sp3 C-H bonds

Pd(II)-catalyzed enantioselective C-H activation of cyclopropanes

Pd(II)-catalyzed hydroxyl-directed C-H olefination enabled by monoprotected amino acid ligands

Pd(II)-catalyzed olefination of sp3 C-H bonds

Practical Intermolecular Hydroarylation of Terminal Alkenes via Reductive Heck Coupling

Protodepalladation as a Strategic Elementary Step in Catalysis

Recent applications of chiral phosphoric acids in palladium catalysis

Regioselective Hydroamination Using a Directed Nucleopalladation/Protodepalladation Strategy

Sequential C–H Functionalization Reactions for the Enantioselective Synthesis of Highly Functionalized 2,3-Dihydrobenzofurans

Synthesis of Stereodefined 1,1-Diborylalkenes via Copper-Catalyzed Diboration of Terminal Alkynes

Synthesis of Substituted Dihydrobenzofurans via Tandem SNAr/5-Exo-Trig Cyclization

Transition metal-catalyzed C-H activation reactions: diastereoselectivity and enantioselectivity

Transition-Metal-Catalyzed 1,2-Carboboration of Alkenes: Strategies, Mechanisms, and Stereocontrol

Tridentate Directing Groups Stabilize 6-Membered Palladacycles in Catalytic Alkene Hydrofunctionalization

Trifluoromethylation of Allylsilanes under Copper Catalysis

Trifluoromethylation of Allylsilanes under Photoredox Catalysis

Weak coordination as a powerful means for developing broadly useful C-H functionalization reactions

Z-Selective Cross-Metathesis and Homodimerization of 3E-1,3-Dienes: Reaction Optimization, Computational Analysis, and Synthetic Applications

β,γ-Vicinal Dicarbofunctionalization of Alkenyl Carbonyl Compounds via Directed Nucleopalladation