List of works - Thomas Poisson

1,4-Addition of the CF3 group, perfluoroalkyl groups and functionalized difluoromethylated moieties: An overview

article

18F-Fluoroform: a 18F-trifluoromethylating agent for the synthesis of SCF218F-aromatic derivatives.

scientific article

2-Nitroglycals: Versatile Building Blocks for the Synthesis of 2-Aminoglycosides

article published in 2014

A practical and straightforward access to fluorinated homoallylic alcohols in aqueous media

Access to Difluoromethylated Alkynes through the Castro-Stephens Reaction

Addition of Electrophilic Radicals to 2-Benzyloxyglycals: Synthesis and Functionalization of Fluorinated α-C-Glycosides and Derivatives

article

An electrophilic reagent for the synthesis of OCHFMe-containing molecules.

scientific article published on 19 February 2018

Asymmetric Mannich Reaction of Malonates with Imines Catalyzed by a Chiral Calcium Complex

scientific article published on 01 February 2010

BiCl3-Mediated direct functionalization of unsaturated C–C bonds with an electrophilic SCF2PO(OEt)2 reagent

scientific article published on 01 July 2019

Catalytic Asymmetric Protonation of Chiral Calcium Enolates via 1,4-Addition of Malonates

article

Catalytic Asymmetric Synthesis of α,α-Difluoromethylated and α-Fluoromethylated Tertiary Alcohols

scientific article published on 09 September 2019

Catalytic Enantioselective Cyclopropanation of α-Fluoroacrylates: An Experimental and Theoretical Study

Copper Catalyzed β-Difluoroacetylation of Dihydropyrans and Glycals by Means of Direct C–H Functionalization

scientific article published on 21 June 2013

Copper Salt-Controlled Divergent Reactivity of [Cu]CF2 PO(OEt)2 with α-Diazocarbonyl Derivatives

scientific article published on 10 October 2016

Copper Salt-Controlled Divergent Reactivity of [Cu]CF2PO(OEt)2with α-Diazocarbonyl Derivatives

article published in 2016

Copper-Catalyzed Direct Arylation of Cyclic Enamides Using Diaryliodonium Salts

scientific article published on 28 December 2012

Copper-Catalyzed Direct C-2 Difluoromethylation of Furans and Benzofurans: Access to C-2 CF2H Derivatives

scientific article published on 09 July 2014

Copper-Catalyzed Enantioselective Formation of C-CF3 Centers from β-CF3 -Substituted Acrylates and Acrylonitriles

scientific article published on 31 October 2019

Copper-Catalyzed Innate Ethoxycarbonyldifluoromethylation of Electron-Rich Arenes

article published in 2015

Copper-Mediated Direct Functionalization of Unsaturated C–C Bonds with Ethyl Bromo(difluoro)acetate: A Straightforward Access to Highly Valuable Difluoromethylated Alkenes

scholarly article by Tatiana Besset et al published 28 May 2014 in Synthesis

Copper-Mediated Formation of Aryl, Heteroaryl, Vinyl and Alkynyl Difluoromethylphosphonates: A General Approach to Fluorinated Phosphate Mimics

scientific article published on 11 September 2015

Copper-Mediated Introduction of the CF2 PO(OEt)2 Motif: Scope and Limitations

scientific article

Copper-Mediated Synthesis of Aryldifluoromethylphosphonates: A Sandmeyer Approach

article

Copper-Mediated [(Diethylphosphono)difluoromethyl]thiolation of α-Bromo Ketones

Copper-Photocatalyzed Contra-Thermodynamic Isomerization of Polarized Alkenes

scientific article published on 18 September 2020

Copper-catalyzed olefinic C-H difluoroacetylation of enamides

scientific article published in June 2014

Copper‐Photocatalyzed Borylation of Organic Halides under Batch and Continuous‐Flow Conditions

scientific article published on 06 February 2019

DMAP-Organocatalyzed O-Silyl-O-(or C-)-Benzoyl Interconversions by Means of Benzoyl Fluoride

Diethylzinc-Mediated Addition of 2,2-Dibromo-2-fluoroacetamides to Carbonyl Compounds: Synthesis of α-Bromo-α-fluoro-β-hydroxy Amides and/or (Z)-Fluorovinyl Amides

article

Direct Vicinal Difunctionalization of Alkynes: An Efficient Approach Towards the Synthesis of Highly Functionalized Fluorinated Alkenes

Efficient C-3 functionalization of 4-dimethylaminopyridine (DMAP). A straightforward access to new chiral nucleophilic catalysts

Efficient access to fluorinated homoallylic alcohols through an indium promoted fluoroallylation reaction

scholarly article by Gérald Lemonnier et al published May 2014 in Tetrahedron

Enantioselective N-Heterocyclic Carbene-Catalyzed Cascade Reaction for the Synthesis of Pyrroloquinolines via N-H Functionalization of Indoles

scientific article published in 2018

Evaluation of the PAH and water-extractable phenols content in used cross ties from the French rail network

scientific article published on 19 April 2014

First synthesis of diethyl N-acetyl-glycosamine-1-difluoromethylphosphonate from 2-nitroglycals as phosphate analog

General Catalytic Enantioselective Access to Monohalomethyl and Trifluoromethyl Cyclopropanes

scientific article published on 25 June 2018

Indium-Promoted Diastereoselective Addition of Fluorinated Haloallylic Derivatives to Imines

article

Indium-Promoted Reformatsky Reaction: A Straightforward Access to β-Amino and β-Hydroxy α,α-Difluoro Carbonyl Compounds

scientific article published on 08 October 2012

MacMillan’s Imidazolidinones: Powerful Chiral Organocatalysts

N-Heterocyclic Carbene-Catalyzed Synthesis of α-Trifluoromethyl Esters

scientific article published on 13 June 2018

New Prospects toward the Synthesis of Difluoromethylated Phosphate Mimics.

scientific article

Organocatalytic Enantioselective Protonation of Silyl Enolates Mediated by Cinchona Alkaloids and a Latent Source of HF

scientific article published on 01 January 2007

Organocatalyzed Enantioselective Protonation of Silyl Enol Ethers: Scope, Limitations, and Application to the Preparation of Enantioenriched Homoisoflavones

scientific article published on 19 October 2010

Palladium-Catalysed Synthesis of α-(Trifluoromethyl)styrenes by Means of Directed C-H Bond Functionalization

Palladium-Catalyzed Synthesis of 3-Trifluoromethyl-Substituted 1,3-Butadienes by Means of Directed C–H Bond Functionalization

scientific article published on 05 April 2017

Palladium-Catalyzed Synthesis of Aryl and Heteroaryl Difluoromethylated Phosphonates

Pd-Catalyzed Diastereoselective Trifluoromethylthiolation of Functionalized Acrylamides.

scientific article

Pd-Catalyzed Trifluoromethylthiolation of Unsaturated Compounds: A General Approach

Potassium tert-butoxide mediated Heck-type cyclization/isomerization–benzofurans from organocatalytic radical cross-coupling reactions

scientific article published on 05 September 2011

Preparation of β-Lactams by Mannich-Type Addition of Ethyl(trimethylsilyl)acetate (ETSA) to N-(2-Hydroxyphenyl)aldimine Sodium Salts

article

Product-catalyzed addition of alkyl nitriles to unactivated imines promoted by sodium aryloxide/ethyl(trimethylsilyl)acetate (ETSA) combination

scientific article

Recent Progress toward the Introduction of Functionalized Difluoromethylated Building Blocks onto C(sp(2) ) and C(sp) Centers.

scientific article

Recent advances in photocatalyzed reactions using well-defined copper(I) complexes

scientific article published on 23 March 2020

Recent progress in direct introduction of fluorinated groups on alkenes and alkynes by means of C-H bond functionalization.

scientific article

Rhodium catalysed enantioselective synthesis of mono-(halo)-methyl-cyclopropanes

scientific article published on 01 January 2019

Rhodium-catalyzed cyclopropanation of fluorinated olefins: a straightforward route to highly functionalized fluorocyclopropanes

scientific article published on 13 March 2015

Single-Step Preparation of a 4-(Dimethylamino)pyridine Analogue Bearing a Sulfoxide as New Chiral Inducer. Preliminary Evaluation as Nucleophilic Catalyst

Stereoselective Access to β-C-Glycosamines by Nitro-Michael Addition of Organolithium Reagents

article

Stereoselective Synthesis of Terminal Monofluoroalkenes from Trifluoromethylated Alkenes

scientific article published on 02 June 2020

Stereoselectivity of the Honda–Reformatsky Reaction in Reactions with Ethyl Bromodifluoroacetate with α-Oxygenated Sulfinylimines

scientific article published on 18 April 2014

Straightforward Organocatalytic Enantioselective Protonation of Silyl Enolates by Means of Cinchona Alkaloids and Carboxylic Acids

Synthesis and Reactivity ofN-tert-Butanesulfinyl Glycosylamines

Synthesis and immunological evaluation of fluorinated α-C-galactosylceramide analogs

Synthesis of 4-Difluoromethylquinolines by NHC-Catalyzed Umpolung of Imines

scientific article published on 24 January 2018

Trifluoromethylthiolation of α-Chloroaldehydes: Access to Quaternary SCF3 -Containing Centers

Tunable Approach for the Stereoselective Synthesis of 1-C-Diethylphosphono(difluoromethyl) Iminosugars as Glycosyl Phosphate Mimics

scientific article

Visible light mediated azomethine ylide formation—photoredox catalyzed [3+2] cycloadditions ⬇️

scientific article published on July 27, 2011

List of works by Thomas Poisson

1,4-Addition of the CF3 group, perfluoroalkyl groups and functionalized difluoromethylated moieties: An overview

18F-Fluoroform: a 18F-trifluoromethylating agent for the synthesis of SCF218F-aromatic derivatives.

2-Nitroglycals: Versatile Building Blocks for the Synthesis of 2-Aminoglycosides

A practical and straightforward access to fluorinated homoallylic alcohols in aqueous media

Access to Difluoromethylated Alkynes through the Castro-Stephens Reaction

Addition of Electrophilic Radicals to 2-Benzyloxyglycals: Synthesis and Functionalization of Fluorinated α-C-Glycosides and Derivatives

An electrophilic reagent for the synthesis of OCHFMe-containing molecules.

Asymmetric Mannich Reaction of Malonates with Imines Catalyzed by a Chiral Calcium Complex

BiCl3-Mediated direct functionalization of unsaturated C–C bonds with an electrophilic SCF2PO(OEt)2 reagent

Catalytic Asymmetric Protonation of Chiral Calcium Enolates via 1,4-Addition of Malonates

Catalytic Asymmetric Synthesis of α,α-Difluoromethylated and α-Fluoromethylated Tertiary Alcohols

Catalytic Enantioselective Cyclopropanation of α-Fluoroacrylates: An Experimental and Theoretical Study

Copper Catalyzed β-Difluoroacetylation of Dihydropyrans and Glycals by Means of Direct C–H Functionalization

Copper Salt-Controlled Divergent Reactivity of [Cu]CF2 PO(OEt)2 with α-Diazocarbonyl Derivatives

Copper Salt-Controlled Divergent Reactivity of [Cu]CF2PO(OEt)2with α-Diazocarbonyl Derivatives

Copper-Catalyzed Direct Arylation of Cyclic Enamides Using Diaryliodonium Salts

Copper-Catalyzed Direct C-2 Difluoromethylation of Furans and Benzofurans: Access to C-2 CF2H Derivatives

Copper-Catalyzed Enantioselective Formation of C-CF3 Centers from β-CF3 -Substituted Acrylates and Acrylonitriles

Copper-Catalyzed Innate Ethoxycarbonyldifluoromethylation of Electron-Rich Arenes

Copper-Mediated Direct Functionalization of Unsaturated C–C Bonds with Ethyl Bromo(difluoro)acetate: A Straightforward Access to Highly Valuable Difluoromethylated Alkenes

Copper-Mediated Formation of Aryl, Heteroaryl, Vinyl and Alkynyl Difluoromethylphosphonates: A General Approach to Fluorinated Phosphate Mimics

Copper-Mediated Introduction of the CF2 PO(OEt)2 Motif: Scope and Limitations

Copper-Mediated Synthesis of Aryldifluoromethylphosphonates: A Sandmeyer Approach

Copper-Mediated [(Diethylphosphono)difluoromethyl]thiolation of α-Bromo Ketones

Copper-Photocatalyzed Contra-Thermodynamic Isomerization of Polarized Alkenes

Copper-catalyzed olefinic C-H difluoroacetylation of enamides

Copper‐Photocatalyzed Borylation of Organic Halides under Batch and Continuous‐Flow Conditions

DMAP-Organocatalyzed O-Silyl-O-(or C-)-Benzoyl Interconversions by Means of Benzoyl Fluoride

Diethylzinc-Mediated Addition of 2,2-Dibromo-2-fluoroacetamides to Carbonyl Compounds: Synthesis of α-Bromo-α-fluoro-β-hydroxy Amides and/or (Z)-Fluorovinyl Amides

Direct Vicinal Difunctionalization of Alkynes: An Efficient Approach Towards the Synthesis of Highly Functionalized Fluorinated Alkenes

Efficient C-3 functionalization of 4-dimethylaminopyridine (DMAP). A straightforward access to new chiral nucleophilic catalysts

Efficient access to fluorinated homoallylic alcohols through an indium promoted fluoroallylation reaction

Enantioselective N-Heterocyclic Carbene-Catalyzed Cascade Reaction for the Synthesis of Pyrroloquinolines via N-H Functionalization of Indoles

Evaluation of the PAH and water-extractable phenols content in used cross ties from the French rail network

First synthesis of diethyl N-acetyl-glycosamine-1-difluoromethylphosphonate from 2-nitroglycals as phosphate analog

General Catalytic Enantioselective Access to Monohalomethyl and Trifluoromethyl Cyclopropanes

Indium-Promoted Diastereoselective Addition of Fluorinated Haloallylic Derivatives to Imines

Indium-Promoted Reformatsky Reaction: A Straightforward Access to β-Amino and β-Hydroxy α,α-Difluoro Carbonyl Compounds

MacMillan’s Imidazolidinones: Powerful Chiral Organocatalysts

N-Heterocyclic Carbene-Catalyzed Synthesis of α-Trifluoromethyl Esters

New Prospects toward the Synthesis of Difluoromethylated Phosphate Mimics.

Organocatalytic Enantioselective Protonation of Silyl Enolates Mediated by Cinchona Alkaloids and a Latent Source of HF

Organocatalyzed Enantioselective Protonation of Silyl Enol Ethers: Scope, Limitations, and Application to the Preparation of Enantioenriched Homoisoflavones

Palladium-Catalysed Synthesis of α-(Trifluoromethyl)styrenes by Means of Directed C-H Bond Functionalization

Palladium-Catalyzed Synthesis of 3-Trifluoromethyl-Substituted 1,3-Butadienes by Means of Directed C–H Bond Functionalization

Palladium-Catalyzed Synthesis of Aryl and Heteroaryl Difluoromethylated Phosphonates

Pd-Catalyzed Diastereoselective Trifluoromethylthiolation of Functionalized Acrylamides.

Pd-Catalyzed Trifluoromethylthiolation of Unsaturated Compounds: A General Approach

Potassium tert-butoxide mediated Heck-type cyclization/isomerization–benzofurans from organocatalytic radical cross-coupling reactions

Preparation of β-Lactams by Mannich-Type Addition of Ethyl(trimethylsilyl)acetate (ETSA) to N-(2-Hydroxyphenyl)aldimine Sodium Salts

Product-catalyzed addition of alkyl nitriles to unactivated imines promoted by sodium aryloxide/ethyl(trimethylsilyl)acetate (ETSA) combination

Recent Progress toward the Introduction of Functionalized Difluoromethylated Building Blocks onto C(sp(2) ) and C(sp) Centers.

Recent advances in photocatalyzed reactions using well-defined copper(I) complexes

Recent progress in direct introduction of fluorinated groups on alkenes and alkynes by means of C-H bond functionalization.

Rhodium catalysed enantioselective synthesis of mono-(halo)-methyl-cyclopropanes

Rhodium-catalyzed cyclopropanation of fluorinated olefins: a straightforward route to highly functionalized fluorocyclopropanes

Single-Step Preparation of a 4-(Dimethylamino)pyridine Analogue Bearing a Sulfoxide as New Chiral Inducer. Preliminary Evaluation as Nucleophilic Catalyst

Stereoselective Access to β-C-Glycosamines by Nitro-Michael Addition of Organolithium Reagents

Stereoselective Synthesis of Terminal Monofluoroalkenes from Trifluoromethylated Alkenes

Stereoselectivity of the Honda–Reformatsky Reaction in Reactions with Ethyl Bromodifluoroacetate with α-Oxygenated Sulfinylimines

Straightforward Organocatalytic Enantioselective Protonation of Silyl Enolates by Means of Cinchona Alkaloids and Carboxylic Acids

Synthesis and Reactivity ofN-tert-Butanesulfinyl Glycosylamines

Synthesis and immunological evaluation of fluorinated α-C-galactosylceramide analogs

Synthesis of 4-Difluoromethylquinolines by NHC-Catalyzed Umpolung of Imines

Trifluoromethylthiolation of α-Chloroaldehydes: Access to Quaternary SCF3 -Containing Centers

Tunable Approach for the Stereoselective Synthesis of 1-C-Diethylphosphono(difluoromethyl) Iminosugars as Glycosyl Phosphate Mimics

Visible light mediated azomethine ylide formation—photoredox catalyzed [3+2] cycloadditions ⬇️