List of works - Constantinos J. Milios

1,1,1-Tris(hydroxymethyl)propane in manganese carboxylate chemistry: synthesis, structure and magnetic properties of a mixed-valence [MnIII4MnII4] cluster featuring the novel [MnIII4MnII4(mu3-OR)6(mu2-OR)8]6+ core

scientific article

1,2,3-Triazolate-Bridged Tetradecametallic Transition Metal Clusters [M14(L)6O6(OMe)18X6] (M = FeIII, CrIIIand VIII/IV) and Related Compounds: Ground-State Spins Ranging fromS= 0 toS= 25 and Spin-Enhanced Magnetocaloric Effect

scientific article published on 16 May 2007

2-Aminoisobutyric acid in Co(II) and Co(II)/Ln(III) chemistry: homometallic and heterometallic clusters

scientific article published on 22 December 2011

2-Pyridinealdoxime [(py)CHNOH] in manganese(II) carboxylate chemistry: mononuclear, dinuclear, tetranuclear and polymeric complexes, and partial transformation of (py)CHNOH to picolinate(−1)

article published in 2004

A Cube in a Tetrahedron: Microwave-Assisted Synthesis of an Octametallic FeIIICluster

scientific article published on 01 July 2006

A Family of [Mn6] Complexes Featuring Tripodal Ligands

scientific article published on 01 August 2006

A Ferromagnetically Coupled, Bell-Shaped [Ni4Gd5] Cage

scientific article published on 15 August 2019

A MnII4 cubane and a novel MnII10MnIII4 cluster from the use of di-2-pyridyl ketone in manganese acetate chemistry

scientific article

A [Ce21] keplerate

scientific article published on 7 June 2017

A [Cr2Ni] coordination polymer: slow relaxation of magnetization in quasi-one-dimensional ferromagnetic chains

scientific article published in 2018

A comparative EPR study of high- and low-spin Mn6 single-molecule magnets

A decanuclear [DyIII6ZnII4] cluster: a {ZnII4} rectangle surrounding an octahedral {DyIII6} single molecule magnet

scientific article published in 2019

A family of [Mn(III)₆Ln(III)₂] rod-like clusters

scientific article published on 01 April 2015

A family of dinuclear lanthanide(iii) complexes from the use of a tridentate Schiff base

scientific article published on 01 June 2015

A general synthetic route for the preparation of high-spin molecules: Replacement of bridging hydroxo ligands in molecular clusters by end-on azido ligands

A ligand-field study of the ground spin-state magnetic anisotropy in a family of hexanuclear Mn(iii) single-molecule magnets

scientific article published on 03 March 2008

A mononuclear and a mixed-valence chain polymer arising from copper(II) halide chemistry and the use of 2,2'-pyridil

scientific article published in January 2007

A new oxime ligand in manganese chemistry: a [Mn8] and a [Mn6] cage from the use of 2-dihydroxy-2-phenylacetamidine

scientific article published on 29 September 2011

A rare all-Mn2+ decametallic cage from distorted face-sharing cubes

A rare ferromagnetic manganese(iii) ‘cube’

scientific article published on 26 October 2006

A record anisotropy barrier for a single-molecule magnet

scientific article

A single-molecule magnet with a "twist".

scientific article

A strongly blue-emitting heptametallic [Dy(III)7] centered-octahedral single-molecule magnet

scientific article published on 29 June 2012

A triacontanuclear [Zn12Dy18] cluster: a ring of [Dy4] cubes

scientific article published on 30 October 2015

Addressing the magnetic properties of sub-monolayers of single-molecule magnets by X-ray magnetic circular dichroism

scientific article

Adsorption dynamics and interfacial properties of thiol-based cobalt terpyridine monolayers

article

Artificial amino acids in nickel(II) and nickel(II)/lanthanide(III) chemistry

scientific article published on 27 April 2011

Assembling molecular triangles into discrete and infinite architectures

Attempting to understand (and control) the relationship between structure and magnetism in an extended family of Mn6 single-molecule magnets

scientific article published on 17 March 2009

Bipolar mass spectrometry of labile coordination complexes, redox active inorganic compounds, and proteins using a glass nebulizer for sonic-spray ionization.

scientific article published on 13 June 2013

Breakdown of the Giant Spin Model in the Magnetic Relaxation of theMn6Nanomagnets

scientific article published in Physical Review Letters

Building 1D lanthanide chains and non-symmetrical [Ln2] "triple-decker" clusters using salen-type ligands: magnetic cooling and relaxation phenomena

scientific article published on 9 November 2016

Constructing CrIII-centered heterometallic complexes: [NiCrIII] and [CoCrIII] wheels.

scientific article published on 29 November 2017

Constructing clusters with enhanced magnetic properties by assembling and distorting Mn3 building blocks

scientific article

Crystal engineering with 2,1,3-benzoselenadiazole and mercury(II) chloride

Di-2-pyridyl ketone oxime [(py)2CNOH] in manganese carboxylate chemistry: mononuclear, dinuclear and tetranuclear complexes, and partial transformation of (py)2CNOH to the gem-diolate(2-) derivative of di-2-pyridyl ketone leading to the formation of

scientific article published on 5 January 2005

Di-2-pyridyl ketone oxime in 3d-metal carboxylate cluster chemistry: a new family of mixed-valence Mn2IIMn2III complexes

Dinuclear and Mononuclear Rhenium Coordination Compounds upon Employment of a Schiff-Base Triol Ligand: Structural, Magnetic, and Computational Studies

scientific article published on 10 June 2019

Dinuclear, tetrakis(acetato)-bridged lanthanide(III) complexes from the use of 2-acetylpyridine hydrazone

Dodecanuclear [Mn6(III)Ln6(III)] species: synthesis, structures and characterization of magnetic relaxation phenomena.

scientific article published on 15 June 2015

Electronic structure of aMn6(S=4)single molecule magnet grafted on Au(111)

scholarly article in Physical Review B, vol. 77 no. 8, February 2008

Employment of a naphthalene-based tetraol ligand in Mn chemistry: Mononuclear and linear trinuclear clusters

Employment of a new tripodal ligand for the synthesis of cobalt(II/III), nickel(II), and copper(II) clusters: magnetic, optical, and thermal properties.

scientific article published on 18 September 2012

Enhancing SMM properties in a family of [Mn6] clusters

scientific article published on 25 June 2007

Enneanuclear [Ni6Ln3] Cages: [Ln(III)3] Triangles Capping [Ni(II)6] Trigonal Prisms Including a [Ni6Dy3] Single-Molecule Magnet

scientific article published on 02 July 2015

Ferromagnetic manganese "cubes": from PSII to single-molecule magnets.

scientific article published on May 2010

Grafting derivatives of Mn6 single-molecule magnets with high anisotropy energy barrier on Au111 surface.

scientific article published on 23 July 2008

Ground state spin-switching via targeted structural distortion: twisted single-molecule magnets from derivatised salicylaldoximes

scientific article

Heptanuclear heterometallic [Cu6Ln] clusters: trapping lanthanides into copper cages with artificial amino acids

scientific article published on 01 May 2012

Heptanuclear lanthanide [Ln7] clusters: from blue-emitting solution-stable complexes to hybrid clusters.

scientific article published in September 2014

Heterometallic lanthanide-centred [NiII6LnIII] rings

scientific article published on 01 September 2018

Hexametallic manganese clusters with bulky derivatised salicylaldoximes

scientific article published on 20 January 2011

Hexanuclear Manganese(III) Single-Molecule Magnets

scientific article published on 01 January 2004

High pressure induced spin changes and magneto-structural correlations in hexametallic SMMs

scientific article published on 7 May 2009

High-Spin M2+Carboxylate Triangles from the Microwave

scientific article published on 01 September 2006

Inelastic neutron scattering and frequency-domain magnetic resonance studies ofS=4andS=12Mn6single-molecule magnets

article

Influence of antisymmetric exchange interaction on quantum tunneling of magnetization in a dimeric molecular magnetMn6

scholarly article in Physical Review B, vol. 78 no. 13, October 2008

Linear and cubane carboxylate clusters derived from di-2-pyridyl ketone: Synthesis, characterization and magnetic properties

MCD spectroscopy of hexanuclear Mn(iii) salicylaldoxime single-molecule magnets

scientific article published on 19 August 2010

Magnetic quantum tunneling: insights from simple molecule-based magnets

scientific article published on 19 April 2010

Making ‘wheels’ and ‘cubes’ from triangles

scientific article published on 12 June 2006

Microwave-Assisted Synthesis of a Hexanuclear MnIIISingle-Molecule Magnet

scientific article published on 01 July 2006

Neutron spectroscopy and magnetic relaxation of the Mn6 nanomagnets

article

New octa- and dodecametallic mixed-valent Mn rods

Octanuclearity and tetradecanuclearity in manganese chemistry: an octanuclear manganese(II)/(III) complex featuring the novel [Mn8(mu4-O)2(mu3-OH)2]14+ core and [Mn10(II)Mn4(III)O4(O2CMe)20[(2-py)2C(OH)O]4] (2-py = 2-pyridyl).

scientific article published in April 2003

On the origin of ferromagnetism in oximato-based [Mn3O]7+triangles

scientific article published on 19 October 2007

Phenyl 2-Pyridyl Ketone and Its Oxime in Manganese Carboxylate Chemistry: Synthesis, Characterisation, X-ray Studies and Magnetic Properties of Mononuclear, Trinuclear and Octanuclear Complexes

Polymetallic clusters of iron(III) with derivatised salicylaldoximes

scientific article published on 19 February 2008

Polynuclear manganese amino acid complexes.

scientific article published on 3 August 2010

Pseudopeptidic ligands: exploring the self-assembly of isophthaloylbisglycine (H2IBG) and divalent metal ions

scientific article published on 01 October 2012

Quantum tunnelling of magnetization in the single-molecule magnet Mn6

Rare oxidation-state combinations and unusual structural motifs in hexanuclear Mn complexes using 2-pyridyloximate ligands

scientific article published in May 2010

Solvothermal synthesis of enneanuclear [Cu₇(II)Ln₂(III)] clusters

scientific article published on 01 December 2015

Spin Switching via Targeted Structural Distortion

scientific article published on 26 April 2007

Supramolecular Entanglement from Interlocked Molecular Nanomagnets

Switching pairwise exchange interactions to enhance SMM properties

Synthesis and characterisation of a mixed-valence Mn13complex with S6symmetry by using 2-phenoxybenzoate

scientific article published on 18 December 2006

Synthesis and magnetic properties of heptadecametallic Fe(III) clusters

Synthesis, Characterization, Magnetic and Catalytic Properties of a Ladder-Shaped MnIICoordination Polymer

Tetradecanuclearity in 3d-4f chemistry: relaxation and magnetocaloric effects in [NiLn] species

scientific article published on 21 February 2017

The first amino acid bound manganese-calcium clusters: a {[MnCa]2} methylalanine complex, and a [MnCa] trigonal prism

scientific article published on 22 July 2020

The first amino acid manganese cluster: a [Mn(IV)2Mn(III)3] DL-valine cage.

scientific article published on 9 September 2009

The use of di-2-pyridyl ketone in manganese(II) benzoate chemistry: Two novel linkage isomers containing the ketone form of the ligand and a neutral cubane containing the ligand in its gem-diolate(-1) form

The use of methylsalicyloxime in manganese chemistry: A triangle and its oxidation to a rod

Theoretical methods enlighten magnetic properties of a family of Mn(6) single-molecule magnets.

scientific article published in August 2009

Toward a magnetostructural correlation for a family of Mn6 SMMs

scientific article published on 22 September 2007

Transverse anisotropy in the mixed-valent Mn2IIMn4IIIMn3IV single-molecule magnet

Turning up the spin, turning on single-molecule magnetism: from S = 1 to S = 7 in a [Mn8] cluster via ligand induced structural distortion

scientific article published on 03 May 2007

Twisted molecular magnets

scientific article

Two Frustrated, Bitetrahedral Single-Molecule Magnets

scientific article published on 03 July 2007

Unique trigonal prism encapsulated Ln complexes: a [Co(II)6Eu] and a [Co(II)6Dy] cage

scientific article published on 11 March 2011

[Mn6] under Pressure: A Combined Crystallographic and Magnetic Study

scientific article published on 01 January 2008

List of works by Constantinos J. Milios

1,1,1-Tris(hydroxymethyl)propane in manganese carboxylate chemistry: synthesis, structure and magnetic properties of a mixed-valence [MnIII4MnII4] cluster featuring the novel [MnIII4MnII4(mu3-OR)6(mu2-OR)8]6+ core

1,2,3-Triazolate-Bridged Tetradecametallic Transition Metal Clusters [M14(L)6O6(OMe)18X6] (M = FeIII, CrIIIand VIII/IV) and Related Compounds: Ground-State Spins Ranging fromS= 0 toS= 25 and Spin-Enhanced Magnetocaloric Effect

2-Aminoisobutyric acid in Co(II) and Co(II)/Ln(III) chemistry: homometallic and heterometallic clusters

2-Pyridinealdoxime [(py)CHNOH] in manganese(II) carboxylate chemistry: mononuclear, dinuclear, tetranuclear and polymeric complexes, and partial transformation of (py)CHNOH to picolinate(−1)

A Cube in a Tetrahedron: Microwave-Assisted Synthesis of an Octametallic FeIIICluster

A Family of [Mn6] Complexes Featuring Tripodal Ligands

A Ferromagnetically Coupled, Bell-Shaped [Ni4Gd5] Cage

A MnII4 cubane and a novel MnII10MnIII4 cluster from the use of di-2-pyridyl ketone in manganese acetate chemistry

A [Ce21] keplerate

A [Cr2Ni] coordination polymer: slow relaxation of magnetization in quasi-one-dimensional ferromagnetic chains

A comparative EPR study of high- and low-spin Mn6 single-molecule magnets

A decanuclear [DyIII6ZnII4] cluster: a {ZnII4} rectangle surrounding an octahedral {DyIII6} single molecule magnet

A family of [Mn(III)₆Ln(III)₂] rod-like clusters

A family of dinuclear lanthanide(iii) complexes from the use of a tridentate Schiff base

A general synthetic route for the preparation of high-spin molecules: Replacement of bridging hydroxo ligands in molecular clusters by end-on azido ligands

A ligand-field study of the ground spin-state magnetic anisotropy in a family of hexanuclear Mn(iii) single-molecule magnets

A mononuclear and a mixed-valence chain polymer arising from copper(II) halide chemistry and the use of 2,2'-pyridil

A new oxime ligand in manganese chemistry: a [Mn8] and a [Mn6] cage from the use of 2-dihydroxy-2-phenylacetamidine

A rare all-Mn2+ decametallic cage from distorted face-sharing cubes

A rare ferromagnetic manganese(iii) ‘cube’

A record anisotropy barrier for a single-molecule magnet

A single-molecule magnet with a "twist".

A strongly blue-emitting heptametallic [Dy(III)7] centered-octahedral single-molecule magnet

A triacontanuclear [Zn12Dy18] cluster: a ring of [Dy4] cubes

Addressing the magnetic properties of sub-monolayers of single-molecule magnets by X-ray magnetic circular dichroism

Adsorption dynamics and interfacial properties of thiol-based cobalt terpyridine monolayers

Artificial amino acids in nickel(II) and nickel(II)/lanthanide(III) chemistry

Assembling molecular triangles into discrete and infinite architectures

Attempting to understand (and control) the relationship between structure and magnetism in an extended family of Mn6 single-molecule magnets

Bipolar mass spectrometry of labile coordination complexes, redox active inorganic compounds, and proteins using a glass nebulizer for sonic-spray ionization.

Breakdown of the Giant Spin Model in the Magnetic Relaxation of theMn6Nanomagnets

Building 1D lanthanide chains and non-symmetrical [Ln2] "triple-decker" clusters using salen-type ligands: magnetic cooling and relaxation phenomena

Constructing CrIII-centered heterometallic complexes: [NiCrIII] and [CoCrIII] wheels.

Constructing clusters with enhanced magnetic properties by assembling and distorting Mn3 building blocks

Crystal engineering with 2,1,3-benzoselenadiazole and mercury(II) chloride

Di-2-pyridyl ketone oxime [(py)2CNOH] in manganese carboxylate chemistry: mononuclear, dinuclear and tetranuclear complexes, and partial transformation of (py)2CNOH to the gem-diolate(2-) derivative of di-2-pyridyl ketone leading to the formation of

Di-2-pyridyl ketone oxime in 3d-metal carboxylate cluster chemistry: a new family of mixed-valence Mn2IIMn2III complexes

Dinuclear and Mononuclear Rhenium Coordination Compounds upon Employment of a Schiff-Base Triol Ligand: Structural, Magnetic, and Computational Studies

Dinuclear, tetrakis(acetato)-bridged lanthanide(III) complexes from the use of 2-acetylpyridine hydrazone

Dodecanuclear [Mn6(III)Ln6(III)] species: synthesis, structures and characterization of magnetic relaxation phenomena.

Electronic structure of aMn6(S=4)single molecule magnet grafted on Au(111)

Employment of a naphthalene-based tetraol ligand in Mn chemistry: Mononuclear and linear trinuclear clusters

Employment of a new tripodal ligand for the synthesis of cobalt(II/III), nickel(II), and copper(II) clusters: magnetic, optical, and thermal properties.

Enhancing SMM properties in a family of [Mn6] clusters

Enneanuclear [Ni6Ln3] Cages: [Ln(III)3] Triangles Capping [Ni(II)6] Trigonal Prisms Including a [Ni6Dy3] Single-Molecule Magnet

Ferromagnetic manganese "cubes": from PSII to single-molecule magnets.

Grafting derivatives of Mn6 single-molecule magnets with high anisotropy energy barrier on Au111 surface.

Ground state spin-switching via targeted structural distortion: twisted single-molecule magnets from derivatised salicylaldoximes

Heptanuclear heterometallic [Cu6Ln] clusters: trapping lanthanides into copper cages with artificial amino acids

Heptanuclear lanthanide [Ln7] clusters: from blue-emitting solution-stable complexes to hybrid clusters.

Heterometallic lanthanide-centred [NiII6LnIII] rings

Hexametallic manganese clusters with bulky derivatised salicylaldoximes

Hexanuclear Manganese(III) Single-Molecule Magnets

High pressure induced spin changes and magneto-structural correlations in hexametallic SMMs

High-Spin M2+Carboxylate Triangles from the Microwave

Inelastic neutron scattering and frequency-domain magnetic resonance studies ofS=4andS=12Mn6single-molecule magnets

Influence of antisymmetric exchange interaction on quantum tunneling of magnetization in a dimeric molecular magnetMn6

Linear and cubane carboxylate clusters derived from di-2-pyridyl ketone: Synthesis, characterization and magnetic properties

MCD spectroscopy of hexanuclear Mn(iii) salicylaldoxime single-molecule magnets

Magnetic quantum tunneling: insights from simple molecule-based magnets

Making ‘wheels’ and ‘cubes’ from triangles

Microwave-Assisted Synthesis of a Hexanuclear MnIIISingle-Molecule Magnet

Neutron spectroscopy and magnetic relaxation of the Mn6 nanomagnets

New octa- and dodecametallic mixed-valent Mn rods

Octanuclearity and tetradecanuclearity in manganese chemistry: an octanuclear manganese(II)/(III) complex featuring the novel [Mn8(mu4-O)2(mu3-OH)2]14+ core and [Mn10(II)Mn4(III)O4(O2CMe)20[(2-py)2C(OH)O]4] (2-py = 2-pyridyl).

On the origin of ferromagnetism in oximato-based [Mn3O]7+triangles

Phenyl 2-Pyridyl Ketone and Its Oxime in Manganese Carboxylate Chemistry: Synthesis, Characterisation, X-ray Studies and Magnetic Properties of Mononuclear, Trinuclear and Octanuclear Complexes

Polymetallic clusters of iron(III) with derivatised salicylaldoximes

Polynuclear manganese amino acid complexes.

Pseudopeptidic ligands: exploring the self-assembly of isophthaloylbisglycine (H2IBG) and divalent metal ions

Quantum tunnelling of magnetization in the single-molecule magnet Mn6

Rare oxidation-state combinations and unusual structural motifs in hexanuclear Mn complexes using 2-pyridyloximate ligands

Solvothermal synthesis of enneanuclear [Cu₇(II)Ln₂(III)] clusters

Spin Switching via Targeted Structural Distortion

Supramolecular Entanglement from Interlocked Molecular Nanomagnets

Switching pairwise exchange interactions to enhance SMM properties

Synthesis and characterisation of a mixed-valence Mn13complex with S6symmetry by using 2-phenoxybenzoate

Synthesis and magnetic properties of heptadecametallic Fe(III) clusters

Synthesis, Characterization, Magnetic and Catalytic Properties of a Ladder-Shaped MnIICoordination Polymer