List of works - Yann Sarazin

A versatile nitrogen ligand for alkaline-earth chemistry

scientific article published on 18 August 2020

Alkali aminoether-phenolate complexes: synthesis, structural characterization and evidence for an activated monomer ROP mechanism.

scientific article published on 18 January 2013

Alkaline Earth-Olefin Complexes with Secondary Interactions

scientific article published on 9 March 2016

Alkaline-Earth-Catalysed Cross-Dehydrocoupling of Amines and Hydrosilanes: Reactivity Trends, Scope and Mechanism

scientific article published on 11 February 2016

Alkaline-earth complexes with macrocyclic-functionalised bis(phenolate)s and bis(fluoroalkoxide)s

scientific article published on 11 September 2020

Allyl strontium compounds: synthesis, molecular structure and properties

scientific article published on 12 June 2012

Aminofluoroalkoxide amido and boryloxo lead(ii) complexes

scientific article published on 24 June 2019

Barium Siloxides and Catalysed Formation of Si-O-Si' Motifs

scientific article published on 24 September 2019

Barium complexes with crown-ether-functionalised amidinate and iminoanilide ligands for the hydrophosphination of vinylarenes

scientific article published on 01 June 2019

Barium-Catalysed Dehydrocoupling of Hydrosilanes and Borinic Acids: A Mechanistic Insight

scientific article published on 25 February 2020

Barium-Catalysed Dehydrocoupling of Hydrosilanes and Borinic Acids: A Mechanistic Insight

scientific article published on 21 February 2020

Barium-mediated cross-dehydrocoupling of hydrosilanes with amines: a theoretical and experimental approach

scientific article published on 27 May 2015

Beyond stereoselectivity, switchable catalysis: some of the last frontier challenges in ring-opening polymerization of cyclic esters.

scientific article published on April 2015

Binary cerium(IV) tert-butoxides-dialkylmagnesium systems: Radical versus coordinative polymerization of styrene

Bis(imino)carbazolate: A Master Key for Barium Chemistry

scientific article published on 24 February 2020

C(sp₃)-H bond activation with triel metals: indium and gallium zwitterions through internal hydride abstraction in rigid salan ligands.

scientific article published on 19 May 2014

Cadmium complexes bearing Me2N^E^O- (E = S, Se) organochalcogenoalkoxides and their zinc and mercury analogues.

scientific article published on 21 February 2017

Cationic Brønsted Acids for the Preparation of SnIV Salts: Synthesis and Characterisation of [Ph3Sn(OEt2)][H2N{B(C6F5)3}2],[Sn(NMe2)3(HNMe2)2][B(C6F5)4] and [Me3Sn(HNMe2)2][B(C6F5)4]

Chiral (1,2)-diphenylethylene-salen complexes of triel metals: coordination patterns and mechanistic considerations in the isoselective ROP of lactide

scientific article published on 7 April 2014

Chromium allyl and alkyl catalysts for the vinyl polymerization of norbornene and ethylene–norbornene copolymerizations

Copolymerization of Propene and 5-Vinyl-2-Norbornene: A Simple Route to Polar Poly(propylene)s

scientific article

Cyclohydroamination of aminoalkenes catalyzed by disilazide alkaline-earth metal complexes: reactivity patterns and deactivation pathways.

scientific article

Discrete Cationic Complexes for Ring-Opening Polymerization Catalysis of Cyclic Esters and Epoxides

scientific article published on 21 April 2015

Discrete divalent rare-earth cationic ROP catalysts: ligand-dependent redox behavior and discrepancies with alkaline-earth analogues in a ligand-assisted activated monomer mechanism

scientific article published on 5 February 2013

Discrete, solvent-free alkaline-earth metal cations: metal···fluorine interactions and ROP catalytic activity

scientific article published on 18 May 2011

Divalent heteroleptic ytterbium complexes--effective catalysts for intermolecular styrene hydrophosphination and hydroamination.

scientific article published on 14 January 2014

Heterobimetallic Ba/Li and Ca/Li amides and diphenylmethanide

scientific article published on 01 April 2019

Heterogenized “Ligand-Free” Lanthanide Catalysts for the Homo- and Copolymerization of Ethylene and 1,3-Butadiene

Heteroleptic alkyl and amide iminoanilide alkaline earth and divalent rare earth complexes for the catalysis of hydrophosphination and (cyclo)hydroamination reactions

scientific article published on 19 August 2013

Heteroleptic silylamido phenolate complexes of calcium and the larger alkaline earth metals: β-agostic Ae⋅⋅⋅Si-H stabilization and activity in the ring-opening polymerization of L-lactide

scientific article published on 11 April 2012

Heteroleptic tin(II) initiators for the ring-opening (co)polymerization of lactide and trimethylene carbonate: mechanistic insights from experiments and computations

scientific article published on 19 August 2013

Highly Effective Alkaline Earth Catalysts for the Sterically Governed Hydrophosphonylation of Aldehydes and Nonactivated Ketones ⬇️

scientific article published on September 13, 2012

Highly active, chemo- and regioselective Yb(II) and Sm(II) catalysts for the hydrophosphination of styrene with phenylphosphine

scientific article published on 11 March 2015

Highly fluorinated tris(indazolyl)borate silylamido complexes of the heavier alkaline earth metals: synthesis, characterization, and efficient catalytic intramolecular hydroamination

scientific article published on 23 January 2015

Isoselective Styrene Polymerization Catalyzed byansa-Bis(indenyl) Allyl Rare Earth Complexes. Stereochemical and Mechanistic Aspects

Kinetic Analysis of the Immortal Ring-Opening Polymerization of Cyclic Esters: A Case Study with Tin(II) Catalysts

Kinetic Analysis of the Living Ring-Opening Polymerisation ofL-Lactide with Tin(II) Initiators

Lead(II) Siloxides

scientific article published on 16 October 2019

Low-Coordinate Barium Boryloxides: Synthesis and Dehydrocoupling Catalysis for the Production of Borasiloxanes

scientific article published on 08 August 2018

Metal-catalyzed immortal ring-opening polymerization of lactones, lactides and cyclic carbonates.

scientific article published on 27 April 2010

Metal⋅⋅⋅F-C Bonding in Low-Coordinate Alkaline Earth Fluoroarylamides

scientific article published on 30 May 2019

Mixed-ligand iminopyrrolato-salicylaldiminato group 4 metal complexes: Optimising catalyst structure for ethylene/propylene copolymerisations

article

Mono(arene) Complexes of Thallium(I) Supported by a Weakly Coordinating Anion

Novel Zinc and Magnesium Alkyl and Amido Cations for Ring-Opening Polymerization Reactions

scholarly article by Yann Sarazin et al published June 2004 in Organometallics

On the coordination chemistry of organochalcogenolates R(NMe2)^E(-) and R(NMe2)^E^O(-) (E = S, Se) onto lead(II) and lighter divalent tetrel elements.

scientific article published in November 2014

On the initiation mechanism of syndiospecific styrene polymerization catalyzed by single-component ansa-lanthanidocenes.

scientific article published in January 2009

One-pot synthesis of lactide-styrene diblock copolymers via catalytic immortal ring-opening polymerization of lactide and nitroxide-mediated polymerization of styrene

scientific article published in May 2010

Sequential Barium-Catalysed N-H/H-Si Dehydrogenative Cross-Couplings: Cyclodisilazanes versus Linear Oligosilazanes

scientific article published on 26 September 2016

Stable divalent germanium, tin and lead amino(ether)-phenolate monomeric complexes: structural features, inclusion heterobimetallic complexes, and ROP catalysis

scientific article published on 01 March 2014

Stable lead(ii) boroxides.

scientific article

Synthesis and crystal structure of [C6H5Hg(H2NSiMe3)][H2N{B(C6F5)3}2], a phenyl–mercury(II) cation stabilised by a non-coordinating counter-anion

Synthesis and structure of [Cp2Zr(OPri)(HOPri)]+ and its activity in the polymerisation of propene oxide

article published in 2004

Synthesis and structures of new binuclear zinc alkyl, aryl and aryloxo complexes

Synthesis of Bridged Tetrahydrobenzo[b]azepines and Derivatives through an Aza-Piancatelli Cyclization/Michael Addition Sequence

scientific article published on 27 November 2019

Synthetic and Mechanistic Aspects of the Immortal Ring-Opening Polymerization of Lactide and Trimethylene Carbonate with New Homo- and Heteroleptic Tin(II)-Phenolate Catalysts

scientific article published on 20 January 2012

Tailored Cyclic and Linear Polycarbosilazanes by Barium-Catalyzed N-H/H-Si Dehydrocoupling Reactions.

scientific article published on 16 February 2016

Tethered cationic alkaline earth - olefin complexes.

scientific article published on 18 October 2017

Thallium(I) sandwich, multidecker, and ether complexes stabilized by weakly-coordinating anions: a spectroscopic, structural, and theoretical investigation

scientific article published in January 2007

Titanium, zinc and alkaline-earth metal complexes supported by bulky O,N,N,O-multidentate ligands: syntheses, characterisation and activity in cyclic ester polymerisation

scientific article published on 26 October 2005

Versatile catalytic systems based on complexes of zinc, magnesium and calcium supported by a bulky bis(morpholinomethyl)phenoxy ligand for the large-scale immortal ring-opening polymerisation of cyclic esters

scientific article published on 28 September 2009

Well-defined syndiotactic polystyrene-b-atactic polystyrene stereoblock polymers

scientific article published on 30 March 2011

When bigger is better: intermolecular hydrofunctionalizations of activated alkenes catalyzed by heteroleptic alkaline Earth complexes

scientific article published on 11 April 2012

Zinc and magnesium complexes supported by bulky multidentate amino-ether phenolate ligands: potent pre-catalysts for the immortal ring-opening polymerisation of cyclic esters

scientific article

List of works by Yann Sarazin

A versatile nitrogen ligand for alkaline-earth chemistry

Alkali aminoether-phenolate complexes: synthesis, structural characterization and evidence for an activated monomer ROP mechanism.

Alkaline Earth-Olefin Complexes with Secondary Interactions

Alkaline-Earth-Catalysed Cross-Dehydrocoupling of Amines and Hydrosilanes: Reactivity Trends, Scope and Mechanism

Alkaline-earth complexes with macrocyclic-functionalised bis(phenolate)s and bis(fluoroalkoxide)s

Allyl strontium compounds: synthesis, molecular structure and properties

Aminofluoroalkoxide amido and boryloxo lead(ii) complexes

Barium Siloxides and Catalysed Formation of Si-O-Si' Motifs

Barium complexes with crown-ether-functionalised amidinate and iminoanilide ligands for the hydrophosphination of vinylarenes

Barium-Catalysed Dehydrocoupling of Hydrosilanes and Borinic Acids: A Mechanistic Insight

Barium-Catalysed Dehydrocoupling of Hydrosilanes and Borinic Acids: A Mechanistic Insight

Barium-mediated cross-dehydrocoupling of hydrosilanes with amines: a theoretical and experimental approach

Beyond stereoselectivity, switchable catalysis: some of the last frontier challenges in ring-opening polymerization of cyclic esters.

Binary cerium(IV) tert-butoxides-dialkylmagnesium systems: Radical versus coordinative polymerization of styrene

Bis(imino)carbazolate: A Master Key for Barium Chemistry

C(sp₃)-H bond activation with triel metals: indium and gallium zwitterions through internal hydride abstraction in rigid salan ligands.

Cadmium complexes bearing Me2N^E^O- (E = S, Se) organochalcogenoalkoxides and their zinc and mercury analogues.

Cationic Brønsted Acids for the Preparation of SnIV Salts: Synthesis and Characterisation of [Ph3Sn(OEt2)][H2N{B(C6F5)3}2],[Sn(NMe2)3(HNMe2)2][B(C6F5)4] and [Me3Sn(HNMe2)2][B(C6F5)4]

Chiral (1,2)-diphenylethylene-salen complexes of triel metals: coordination patterns and mechanistic considerations in the isoselective ROP of lactide

Chromium allyl and alkyl catalysts for the vinyl polymerization of norbornene and ethylene–norbornene copolymerizations

Copolymerization of Propene and 5-Vinyl-2-Norbornene: A Simple Route to Polar Poly(propylene)s

Cyclohydroamination of aminoalkenes catalyzed by disilazide alkaline-earth metal complexes: reactivity patterns and deactivation pathways.

Discrete Cationic Complexes for Ring-Opening Polymerization Catalysis of Cyclic Esters and Epoxides

Discrete divalent rare-earth cationic ROP catalysts: ligand-dependent redox behavior and discrepancies with alkaline-earth analogues in a ligand-assisted activated monomer mechanism

Discrete, solvent-free alkaline-earth metal cations: metal···fluorine interactions and ROP catalytic activity

Divalent heteroleptic ytterbium complexes--effective catalysts for intermolecular styrene hydrophosphination and hydroamination.

Heterobimetallic Ba/Li and Ca/Li amides and diphenylmethanide

Heterogenized “Ligand-Free” Lanthanide Catalysts for the Homo- and Copolymerization of Ethylene and 1,3-Butadiene

Heteroleptic alkyl and amide iminoanilide alkaline earth and divalent rare earth complexes for the catalysis of hydrophosphination and (cyclo)hydroamination reactions

Heteroleptic silylamido phenolate complexes of calcium and the larger alkaline earth metals: β-agostic Ae⋅⋅⋅Si-H stabilization and activity in the ring-opening polymerization of L-lactide

Heteroleptic tin(II) initiators for the ring-opening (co)polymerization of lactide and trimethylene carbonate: mechanistic insights from experiments and computations

Highly Effective Alkaline Earth Catalysts for the Sterically Governed Hydrophosphonylation of Aldehydes and Nonactivated Ketones ⬇️

Highly active, chemo- and regioselective Yb(II) and Sm(II) catalysts for the hydrophosphination of styrene with phenylphosphine

Highly fluorinated tris(indazolyl)borate silylamido complexes of the heavier alkaline earth metals: synthesis, characterization, and efficient catalytic intramolecular hydroamination

Isoselective Styrene Polymerization Catalyzed byansa-Bis(indenyl) Allyl Rare Earth Complexes. Stereochemical and Mechanistic Aspects

Kinetic Analysis of the Immortal Ring-Opening Polymerization of Cyclic Esters: A Case Study with Tin(II) Catalysts

Kinetic Analysis of the Living Ring-Opening Polymerisation ofL-Lactide with Tin(II) Initiators

Lead(II) Siloxides

Low-Coordinate Barium Boryloxides: Synthesis and Dehydrocoupling Catalysis for the Production of Borasiloxanes

Metal-catalyzed immortal ring-opening polymerization of lactones, lactides and cyclic carbonates.

Metal⋅⋅⋅F-C Bonding in Low-Coordinate Alkaline Earth Fluoroarylamides

Mixed-ligand iminopyrrolato-salicylaldiminato group 4 metal complexes: Optimising catalyst structure for ethylene/propylene copolymerisations

Mono(arene) Complexes of Thallium(I) Supported by a Weakly Coordinating Anion

Novel Zinc and Magnesium Alkyl and Amido Cations for Ring-Opening Polymerization Reactions

On the coordination chemistry of organochalcogenolates R(NMe2)^E(-) and R(NMe2)^E^O(-) (E = S, Se) onto lead(II) and lighter divalent tetrel elements.

On the initiation mechanism of syndiospecific styrene polymerization catalyzed by single-component ansa-lanthanidocenes.

One-pot synthesis of lactide-styrene diblock copolymers via catalytic immortal ring-opening polymerization of lactide and nitroxide-mediated polymerization of styrene

Sequential Barium-Catalysed N-H/H-Si Dehydrogenative Cross-Couplings: Cyclodisilazanes versus Linear Oligosilazanes

Stable divalent germanium, tin and lead amino(ether)-phenolate monomeric complexes: structural features, inclusion heterobimetallic complexes, and ROP catalysis

Stable lead(ii) boroxides.

Synthesis and crystal structure of [C6H5Hg(H2NSiMe3)][H2N{B(C6F5)3}2], a phenyl–mercury(II) cation stabilised by a non-coordinating counter-anion

Synthesis and structure of [Cp2Zr(OPri)(HOPri)]+ and its activity in the polymerisation of propene oxide

Synthesis and structures of new binuclear zinc alkyl, aryl and aryloxo complexes

Synthesis of Bridged Tetrahydrobenzo[b]azepines and Derivatives through an Aza-Piancatelli Cyclization/Michael Addition Sequence

Synthetic and Mechanistic Aspects of the Immortal Ring-Opening Polymerization of Lactide and Trimethylene Carbonate with New Homo- and Heteroleptic Tin(II)-Phenolate Catalysts

Tailored Cyclic and Linear Polycarbosilazanes by Barium-Catalyzed N-H/H-Si Dehydrocoupling Reactions.

Tethered cationic alkaline earth - olefin complexes.

Thallium(I) sandwich, multidecker, and ether complexes stabilized by weakly-coordinating anions: a spectroscopic, structural, and theoretical investigation

Titanium, zinc and alkaline-earth metal complexes supported by bulky O,N,N,O-multidentate ligands: syntheses, characterisation and activity in cyclic ester polymerisation

Versatile catalytic systems based on complexes of zinc, magnesium and calcium supported by a bulky bis(morpholinomethyl)phenoxy ligand for the large-scale immortal ring-opening polymerisation of cyclic esters

Well-defined syndiotactic polystyrene-b-atactic polystyrene stereoblock polymers

When bigger is better: intermolecular hydrofunctionalizations of activated alkenes catalyzed by heteroleptic alkaline Earth complexes

Zinc and magnesium complexes supported by bulky multidentate amino-ether phenolate ligands: potent pre-catalysts for the immortal ring-opening polymerisation of cyclic esters