List of works - Paul J. Chirik

A Boron Activating Effect Enables Cobalt-Catalyzed Asymmetric Hydrogenation of Sterically Hindered Alkenes

scientific article published on 13 February 2020

Actions at J. Org. Chem., Org. Lett., and Organometallics to Combat Discrimination and Bias

scientific article published on 10 August 2020

Ammonia Activation, H2 Evolution and Nitride Formation from a Molybdenum Complex with a Chemically and Redox Noninnocent Ligand.

scientific article published on 17 April 2017

Benzyltriboronates: Building Blocks for Diastereoselective Carbon-Carbon Bond Formation

scientific article published on 3 February 2017

Beyond Ammonia: Nitrogen-Element Bond Forming Reactions with Coordinated Dinitrogen

scientific article published on 27 May 2020

C(sp2)-H Borylation of Fluorinated Arenes Using an Air-Stable Cobalt Precatalyst: Electronically Enhanced Site Selectivity Enables Synthetic Opportunities.

scientific article

C(sp2)-H Borylation of Heterocycles by Well-Defined Bis(silylene)pyridine Cobalt(III) Precatalysts: Pincer Modification, C(sp2)-H Activation and Catalytically Relevant Intermediates

scientific article published on 08 July 2020

Carbon-Carbon Bond Formation in a Weak Ligand Field: Leveraging Open-Shell First-Row Transition-Metal Catalysts.

scientific article published on 12 January 2017

Cobalt Pincer Complexes in Catalytic C–H Borylation: The Pincer Ligand Flips Rather Than Dearomatizes

scientific article published on 17 October 2018

Cobalt-Catalyzed 1,1-Diboration of Terminal Alkynes: Scope, Mechanism, and Synthetic Applications

scientific article published on 15 February 2017

Cobalt-Catalyzed Asymmetric Hydrogenation of α,β-Unsaturated Carboxylic Acids by Homolytic H2 Cleavage

scientific article published on 03 March 2020

Cobalt-Catalyzed Borylation of Fluorinated Arenes: Thermodynamic Control of C(sp2)-H Oxidative Addition Results in ortho-to-Fluorine Selectivity

scientific article published on 16 September 2019

Cobalt-Catalyzed C(sp2)-C(sp3) Suzuki-Miyaura Cross Coupling

scientific article published on 30 September 2020

Cobalt-Catalyzed Stereoretentive Hydrogen Isotope Exchange of C(sp3)-H Bonds

scientific article published on 28 July 2017

Cobalt-catalysed alkene hydrogenation: a metallacycle can explain the hydroxyl activating effect and the diastereoselectivity† †Electronic supplementary information (ESI) available: Computational and experimental details, calculated reaction profile

scientific article published on 4 May 2018

Cobalt-catalyzed asymmetric hydrogenation of enamides enabled by single-electron reduction

scientific article published in Science

Confronting Racism in Chemistry Journals

scientific article published on 19 June 2020

Determination of the N-H Bond Dissociation Free Energy in a Pyridine(diimine)molybdenum Complex Prepared by Proton-Coupled Electron Transfer

scientific article published on 04 October 2020

Direct Observation of Transmetalation from a Neutral Boronate Ester to a Pyridine(diimine) Iron Alkoxide

scientific article published on 23 December 2019

Electronic structure of bis(imino)pyridine iron dichloride, monochloride, and neutral ligand complexes: a combined structural, spectroscopic, and computational study

scientific article

Enabling Two-Electron Pathways with Iron and Cobalt: From Ligand Design to Catalytic Applications

scientific article published on 28 May 2019

Evaluation of excited state bond weakening for ammonia synthesis from a manganese nitride: stepwise proton coupled electron transfer is preferred over hydrogen atom transfer

scientific article published on 01 May 2019

From Russia, With Chemistry †

scientific article published on 31 January 2020

From Russia, With Chemistry †

scientific article published in 2020

Hydrogenation of N-Heteroarenes Using Rhodium Precatalysts: Reductive Elimination Leads to Formation of Multimetallic Clusters

scientific article published on 22 October 2019

Insight into Transmetalation Enables Cobalt-Catalyzed Suzuki-Miyaura Cross Coupling

scientific article published on December 2016

Insights into Activation of Cobalt Pre-Catalysts for C(sp2)-H Functionalization

scientific article

Interconversion of Molybdenum Imido and Amido Complexes by Proton-Coupled Electron Transfer.

scientific article published on 10 January 2018

Investigations into the Mechanism of Inter- and Intramolecular Iron-Catalyzed [2 + 2] Cycloaddition of Alkenes

scientific article published on 04 March 2020

Iron-Mediated Coupling of Carbon Dioxide and Ethylene: Macrocyclic Metallalactones Enable Access to Various Carboxylates

scientific article published on 10 September 2018

Ketone Synthesis from Benzyldiboronates and Esters: Leveraging α-Boryl Carbanions for Carbon-Carbon Bond Formation

scientific article published on 24 January 2020

Kinetic and thermodynamic control of C(sp <sup>2</sup> )–H activation enables site-selective borylation

scientific article published on 07 December 2023

Mechanistic Studies of Cobalt-Catalyzed C(sp2)-H Borylation of Five-Membered Heteroarenes with Pinacolborane

scientific article published on 17 May 2017

N-H Bond Formation in a Manganese(V) Nitride Yields Ammonia by Light-Driven Proton-Coupled Electron Transfer

scientific article published on 05 March 2019

Neutral-Ligand Complexes of Bis(imino)pyridine Iron: Synthesis, Structure, and Spectroscopy

Ni(I)-X Complexes Bearing a Bulky α-Diimine Ligand: Synthesis, Structure, and Superior Catalytic Performance in the Hydrogen Isotope Exchange in Pharmaceuticals

scientific article published on 13 March 2019

Oxidative Addition of Dihydrogen, Boron Compounds, and Aryl Halides to a Cobalt(I) Cation Supported by a Strong-Field Pincer Ligand

scientific article published on 20 February 2019

Oxidative addition of carbon-carbon bonds with a redox-active bis(imino)pyridine iron complex

scientific article published on 08 October 2012

Reduced N-alkyl substituted bis(imino)pyridine cobalt complexes: molecular and electronic structures for compounds varying by three oxidation states

scientific article published in July 2010

Reduction chemistry of aryl- and alkyl-substituted bis(imino)pyridine iron dihalide compounds: molecular and electronic structures of [(PDI)2Fe] derivatives

scientific article published in May 2009

Regio- and Diastereoselective Iron-Catalyzed [4+4]-Cycloaddition of 1,3-Dienes

scientific article published on 16 May 2019

Selective [1,4]-Hydrovinylation of 1,3-Dienes with Unactivated Olefins Enabled by Iron Diimine Catalysts.

scientific article published on 7 February 2018

Straddling the Rooftop: Finding a Balance between Traditional and Modern Views of Chemistry

scientific article published on 28 August 2018

Syntheses and Catalytic Hydrogenation Performance of Cationic Bis(phosphine) Cobalt(I) Diene and Arene Compounds

scientific article published on 27 May 2019

Synthesis and Electronic Structure Diversity of Pyridine(diimine)iron Tetrazene Complexes

scientific article published on 5 April 2018

Synthesis and Reactivity of Organometallic Intermediates Relevant to Cobalt-Catalyzed Hydroformylation

scientific article published on 17 March 2020

Synthesis, Structure, and Hydrogenolysis of Pyridine Dicarbene Iron Dialkyl Complexes

scientific article published on 09 August 2019

Ultrafast Photophysics of a Dinitrogen-Bridged Molybdenum Complex

scientific article published on 15 May 2018

Update to Our Reader, Reviewer, and Author Communities-April 2020

scientific article published on 22 April 2020

Update to Our Reader, Reviewer, and Author Communities-April 2020

scientific article published on 23 April 2020

Using nature's blueprint to expand catalysis with Earth-abundant metals

scientific article

List of works by Paul J. Chirik

A Boron Activating Effect Enables Cobalt-Catalyzed Asymmetric Hydrogenation of Sterically Hindered Alkenes

Actions at J. Org. Chem., Org. Lett., and Organometallics to Combat Discrimination and Bias

Ammonia Activation, H2 Evolution and Nitride Formation from a Molybdenum Complex with a Chemically and Redox Noninnocent Ligand.

Benzyltriboronates: Building Blocks for Diastereoselective Carbon-Carbon Bond Formation

Beyond Ammonia: Nitrogen-Element Bond Forming Reactions with Coordinated Dinitrogen

C(sp2)-H Borylation of Fluorinated Arenes Using an Air-Stable Cobalt Precatalyst: Electronically Enhanced Site Selectivity Enables Synthetic Opportunities.

C(sp2)-H Borylation of Heterocycles by Well-Defined Bis(silylene)pyridine Cobalt(III) Precatalysts: Pincer Modification, C(sp2)-H Activation and Catalytically Relevant Intermediates

Carbon-Carbon Bond Formation in a Weak Ligand Field: Leveraging Open-Shell First-Row Transition-Metal Catalysts.

Cobalt Pincer Complexes in Catalytic C–H Borylation: The Pincer Ligand Flips Rather Than Dearomatizes

Cobalt-Catalyzed 1,1-Diboration of Terminal Alkynes: Scope, Mechanism, and Synthetic Applications

Cobalt-Catalyzed Asymmetric Hydrogenation of α,β-Unsaturated Carboxylic Acids by Homolytic H2 Cleavage

Cobalt-Catalyzed Borylation of Fluorinated Arenes: Thermodynamic Control of C(sp2)-H Oxidative Addition Results in ortho-to-Fluorine Selectivity

Cobalt-Catalyzed C(sp2)-C(sp3) Suzuki-Miyaura Cross Coupling

Cobalt-Catalyzed Stereoretentive Hydrogen Isotope Exchange of C(sp3)-H Bonds

Cobalt-catalysed alkene hydrogenation: a metallacycle can explain the hydroxyl activating effect and the diastereoselectivity† †Electronic supplementary information (ESI) available: Computational and experimental details, calculated reaction profile

Cobalt-catalyzed asymmetric hydrogenation of enamides enabled by single-electron reduction

Confronting Racism in Chemistry Journals

Determination of the N-H Bond Dissociation Free Energy in a Pyridine(diimine)molybdenum Complex Prepared by Proton-Coupled Electron Transfer

Direct Observation of Transmetalation from a Neutral Boronate Ester to a Pyridine(diimine) Iron Alkoxide

Electronic structure of bis(imino)pyridine iron dichloride, monochloride, and neutral ligand complexes: a combined structural, spectroscopic, and computational study

Enabling Two-Electron Pathways with Iron and Cobalt: From Ligand Design to Catalytic Applications

Evaluation of excited state bond weakening for ammonia synthesis from a manganese nitride: stepwise proton coupled electron transfer is preferred over hydrogen atom transfer

From Russia, With Chemistry †

From Russia, With Chemistry †

Hydrogenation of N-Heteroarenes Using Rhodium Precatalysts: Reductive Elimination Leads to Formation of Multimetallic Clusters

Insight into Transmetalation Enables Cobalt-Catalyzed Suzuki-Miyaura Cross Coupling

Insights into Activation of Cobalt Pre-Catalysts for C(sp2)-H Functionalization

Interconversion of Molybdenum Imido and Amido Complexes by Proton-Coupled Electron Transfer.

Investigations into the Mechanism of Inter- and Intramolecular Iron-Catalyzed [2 + 2] Cycloaddition of Alkenes

Iron-Mediated Coupling of Carbon Dioxide and Ethylene: Macrocyclic Metallalactones Enable Access to Various Carboxylates

Ketone Synthesis from Benzyldiboronates and Esters: Leveraging α-Boryl Carbanions for Carbon-Carbon Bond Formation

Kinetic and thermodynamic control of C(sp <sup>2</sup> )–H activation enables site-selective borylation

Mechanistic Studies of Cobalt-Catalyzed C(sp2)-H Borylation of Five-Membered Heteroarenes with Pinacolborane

N-H Bond Formation in a Manganese(V) Nitride Yields Ammonia by Light-Driven Proton-Coupled Electron Transfer

Neutral-Ligand Complexes of Bis(imino)pyridine Iron: Synthesis, Structure, and Spectroscopy

Ni(I)-X Complexes Bearing a Bulky α-Diimine Ligand: Synthesis, Structure, and Superior Catalytic Performance in the Hydrogen Isotope Exchange in Pharmaceuticals

Oxidative Addition of Dihydrogen, Boron Compounds, and Aryl Halides to a Cobalt(I) Cation Supported by a Strong-Field Pincer Ligand

Oxidative addition of carbon-carbon bonds with a redox-active bis(imino)pyridine iron complex

Reduced N-alkyl substituted bis(imino)pyridine cobalt complexes: molecular and electronic structures for compounds varying by three oxidation states

Reduction chemistry of aryl- and alkyl-substituted bis(imino)pyridine iron dihalide compounds: molecular and electronic structures of [(PDI)2Fe] derivatives

Regio- and Diastereoselective Iron-Catalyzed [4+4]-Cycloaddition of 1,3-Dienes

Selective [1,4]-Hydrovinylation of 1,3-Dienes with Unactivated Olefins Enabled by Iron Diimine Catalysts.

Straddling the Rooftop: Finding a Balance between Traditional and Modern Views of Chemistry

Syntheses and Catalytic Hydrogenation Performance of Cationic Bis(phosphine) Cobalt(I) Diene and Arene Compounds

Synthesis and Electronic Structure Diversity of Pyridine(diimine)iron Tetrazene Complexes

Synthesis and Reactivity of Organometallic Intermediates Relevant to Cobalt-Catalyzed Hydroformylation

Synthesis, Structure, and Hydrogenolysis of Pyridine Dicarbene Iron Dialkyl Complexes

Ultrafast Photophysics of a Dinitrogen-Bridged Molybdenum Complex

Update to Our Reader, Reviewer, and Author Communities-April 2020

Update to Our Reader, Reviewer, and Author Communities-April 2020

Using nature's blueprint to expand catalysis with Earth-abundant metals