List of works - Luigi Vaccaro

A Catalytic Peterson-like Synthesis of Alkenyl Nitriles

scientific article published on 17 May 2016

A biomass-derived safe medium to replace toxic dipolar solvents and access cleaner Heck coupling reactions

scientific article from 2015

A catalytic approach to the metal-free reaction of epoxides with ketene silyl acetals for accessing γ-lactones.

scientific article published on 16 October 2014

A continuous flow approach for the C–H functionalization of 1,2,3-triazoles in γ-valerolactone as a biomass-derived medium

A protocol for accessing the β-azidation of α,β-unsaturated carboxylic acids

scientific article published on 14 August 2012

Accessing stable zirconium carboxy-aminophosphonate nanosheets as support for highly active Pd nanoparticles

scientific article published on 18 September 2015

Amberlite IRA900N3 as a new catalyst for the azidation of alpha,beta-unsaturated ketones under solvent-free conditions

scientific article published in December 2006

Azeotropes as Powerful Tool for Waste Minimization in Industry and Chemical Processes

scientific article published on 12 November 2020

Azidolysis of alpha,beta-epoxycarboxylic acids. A water-promoted process efficiently catalyzed by indium trichloride at pH 4.0.

scientific article published on 01 May 2001

Biomass Waste-Derived Pd–PiNe Catalyst for the Continuous-Flow Copper-Free Sonogashira Reaction in a CPME–Water Azeotropic Mixture

scientific article published in 2021

Boosting biomass valorisation. Synergistic design of continuous flow reactors and water-tolerant polystyrene acid catalysts for a non-stop production of esters

Bromolysis and iodolysis of alpha,beta-epoxycarboxylic acids in water catalyzed by indium halides

scientific article published on 01 June 2001

C-H arylations of 1,2,3-triazoles by reusable heterogeneous palladium catalysts in biomass-derived γ-valerolactone.

scientific article published on 15 July 2016

C-H functionalization reactions under flow conditions

scientific article published on 01 May 2019

C2-H Arylation of Indoles Catalyzed by Palladium-Containing Metal-Organic-Framework in γ-Valerolactone

scientific article published on 15 February 2020

Click-chemistry approaches to π-conjugated polymers for organic electronics applications.

scientific article published on 27 June 2016

Copper(II) Triflate-Sodium Dodecyl Sulfate Catalyzed Preparation of 1,2-Diphenyl-2,3-dihydro-4-pyridones in Aqueous Acidic Medium

Corrigendum to “New zirconium hydrogen phosphate alkyl and/or aryl phosphonates with high surface area as heterogeneous Brønsted acid catalysts for aza-Diels–Alder reaction in aqueous medium” [J. Catal. 277 (2011) 80–87]

scholarly article by Daniela Lanari et al published July 2011 in Journal of Catalysis

Diels-Alder reactions of 3-substituted coumarins in water and under high-pressure condition. An uncatalyzed route to tetrahydro-6H-benzo[c]chromen-6-ones.

scientific article published in January 2006

Domino Hydrogenation-Reductive Amination of Phenols, a Simple Process To Access Substituted Cyclohexylamines

scientific article published on 31 July 2015

E-Factor minimized hydrophosphonylation of aldehydes catalyzed by polystyryl-BEMP under solvent-free conditions

scientific article published on 27 June 2013

Efficient O-trimethylsilylation of alcohols and phenols with trimethylsilyl azide catalyzed by tetrabutylammonium bromide under neat conditions.

scientific article

Excited-State Proton Transfer in Indigo

scientific article published on 21 February 2017

First one-pot copper-catalyzed synthesis of alpha-hydroxy-beta-amino acids in water. A new protocol for preparation of optically active norstatines

scientific article published on 01 September 2003

Heterogeneous C–H alkenylations in continuous-flow: oxidative palladium-catalysis in a biomass-derived reaction medium

scholarly article by Francesco Ferlin et al published 2017 in Green Chemistry

Immobilized palladium nanoparticles on potassium zirconium phosphate as an efficient recoverable heterogeneous catalyst for a clean Heck reaction in flow

scholarly article by Chiara Petrucci et al published May 2015 in Journal of Molecular Catalysis A

InCl3-catalyzed regio- and stereoselective thiolysis of alpha,beta-epoxycarboxylic acids in water

scientific article published on 01 September 2005

Lewis-acid catalyzed organic reactions in water. The case of AlCl(3), TiCl(4), and SnCl(4) believed to be unusable in aqueous medium

scientific article published on 01 June 2001

NaOH-catalyzed thiolysis of alpha,beta-epoxyketones in water. A key step in the synthesis of target molecules starting from alpha,beta-unsaturated ketones.

scientific article published in April 2004

New zirconium hydrogen phosphate alkyl and/or aryl phosphonates with high surface area as heterogeneous Brønsted acid catalysts for aza-Diels–Alder reaction in aqueous medium

scholarly article by Daniela Lanari et al published 3 January 2011 in Journal of Catalysis

Non-Covalent Supported of l-Proline on Graphene Oxide/Fe₃O₄ Nanocomposite: A Novel, Highly Efficient and Superparamagnetically Separable Catalyst for the Synthesis of Bis-Pyrazole Derivatives

scientific article

One-pot synthesis of benzo[e]1,4-oxathiepin-5-ones under solvent-free condition via self-promoted thiolysis of 1,2-epoxides.

scientific article published in December 2004

PS-BEMP as a basic catalyst for the phospha-Michael addition to electron-poor alkenes

scientific article published on 14 March 2016

Polymer-Anchored Bifunctional Pincer Catalysts for Chemoselective Transfer Hydrogenation and Related Reactions

scientific article published on 20 September 2019

Polystyryl-supported TBD as an efficient and reusable catalyst under solvent-free conditions

scientific article published on 19 October 2004

Ring Opening of Epoxides with Sodium Azide in Water. A Regioselective pH-Controlled Reaction

Ruthenium(ii) oxidase catalysis for C–H alkenylations in biomass-derived γ-valerolactone

article published in 2018

Sc(III)-catalyzed enantioselective addition of thiols to α,β-unsaturated ketones in neutral water

scientific article published in April 2011

Semiconducting Polymers Prepared by Direct Arylation Polycondensation

scientific article from 2012

Supported l-proline on zirconium phosphates methyl and/or phenyl phosphonates as heterogeneous organocatalysts for direct asymmetric aldol addition

article

Sustainable Protocol for the Reduction of Nitroarenes by Heterogeneous Au@SBA-15 with NaBH4 under Flow Conditions

scientific article published on 11 February 2019

Synthesis of 4-Aryl-1H-1,2,3-triazoles through TBAF-Catalyzed [3 + 2] Cycloaddition of 2-Aryl-1-nitroethenes with TMSN3under Solvent-Free Conditions

Synthesis of liquid biofuels from biomass by hydrothermal gasification: A critical review

scientific article published in 2022

TBAF-catalyzed synthesis of 5-substituted 1H-tetrazoles under solventless conditions.

scientific article published in April 2004

Uncatalyzed and solvent-free multicomponent process for the synthesis of biphenyl-2-carbonitrile derivatives.

scientific article

Waste Minimized Multistep Preparation in Flow of β-Amino Acids Starting from α,β-Unsaturated Carboxylic Acids

Water, a clean, inexpensive, and re-usable reaction medium. One-pot synthesis of (E)-2-aryl-1-cyano-1-nitroethenes

Zn(II)-Catalyzed Thiolysis of Oxiranes in Water under Neutral Conditions ⬇️

scientific article published on October 17, 2003

[AlCl3 + 2THF]: a new and efficient catalytic system for Diels-Alder cycloaddition of alpha,beta-unsaturated carbonyl compounds under solvent-free conditions

scientific article published on 01 June 2006

List of works by Luigi Vaccaro

A Catalytic Peterson-like Synthesis of Alkenyl Nitriles

A biomass-derived safe medium to replace toxic dipolar solvents and access cleaner Heck coupling reactions

A catalytic approach to the metal-free reaction of epoxides with ketene silyl acetals for accessing γ-lactones.

A continuous flow approach for the C–H functionalization of 1,2,3-triazoles in γ-valerolactone as a biomass-derived medium

A protocol for accessing the β-azidation of α,β-unsaturated carboxylic acids

Accessing stable zirconium carboxy-aminophosphonate nanosheets as support for highly active Pd nanoparticles

Amberlite IRA900N3 as a new catalyst for the azidation of alpha,beta-unsaturated ketones under solvent-free conditions

Azeotropes as Powerful Tool for Waste Minimization in Industry and Chemical Processes

Azidolysis of alpha,beta-epoxycarboxylic acids. A water-promoted process efficiently catalyzed by indium trichloride at pH 4.0.

Biomass Waste-Derived Pd–PiNe Catalyst for the Continuous-Flow Copper-Free Sonogashira Reaction in a CPME–Water Azeotropic Mixture

Boosting biomass valorisation. Synergistic design of continuous flow reactors and water-tolerant polystyrene acid catalysts for a non-stop production of esters

Bromolysis and iodolysis of alpha,beta-epoxycarboxylic acids in water catalyzed by indium halides

C-H arylations of 1,2,3-triazoles by reusable heterogeneous palladium catalysts in biomass-derived γ-valerolactone.

C-H functionalization reactions under flow conditions

C2-H Arylation of Indoles Catalyzed by Palladium-Containing Metal-Organic-Framework in γ-Valerolactone

Click-chemistry approaches to π-conjugated polymers for organic electronics applications.

Copper(II) Triflate-Sodium Dodecyl Sulfate Catalyzed Preparation of 1,2-Diphenyl-2,3-dihydro-4-pyridones in Aqueous Acidic Medium

Corrigendum to “New zirconium hydrogen phosphate alkyl and/or aryl phosphonates with high surface area as heterogeneous Brønsted acid catalysts for aza-Diels–Alder reaction in aqueous medium” [J. Catal. 277 (2011) 80–87]

Diels-Alder reactions of 3-substituted coumarins in water and under high-pressure condition. An uncatalyzed route to tetrahydro-6H-benzo[c]chromen-6-ones.

Domino Hydrogenation-Reductive Amination of Phenols, a Simple Process To Access Substituted Cyclohexylamines

E-Factor minimized hydrophosphonylation of aldehydes catalyzed by polystyryl-BEMP under solvent-free conditions

Efficient O-trimethylsilylation of alcohols and phenols with trimethylsilyl azide catalyzed by tetrabutylammonium bromide under neat conditions.

Excited-State Proton Transfer in Indigo

First one-pot copper-catalyzed synthesis of alpha-hydroxy-beta-amino acids in water. A new protocol for preparation of optically active norstatines

Heterogeneous C–H alkenylations in continuous-flow: oxidative palladium-catalysis in a biomass-derived reaction medium

Immobilized palladium nanoparticles on potassium zirconium phosphate as an efficient recoverable heterogeneous catalyst for a clean Heck reaction in flow

InCl3-catalyzed regio- and stereoselective thiolysis of alpha,beta-epoxycarboxylic acids in water

Lewis-acid catalyzed organic reactions in water. The case of AlCl(3), TiCl(4), and SnCl(4) believed to be unusable in aqueous medium

NaOH-catalyzed thiolysis of alpha,beta-epoxyketones in water. A key step in the synthesis of target molecules starting from alpha,beta-unsaturated ketones.

New zirconium hydrogen phosphate alkyl and/or aryl phosphonates with high surface area as heterogeneous Brønsted acid catalysts for aza-Diels–Alder reaction in aqueous medium

Non-Covalent Supported of l-Proline on Graphene Oxide/Fe₃O₄ Nanocomposite: A Novel, Highly Efficient and Superparamagnetically Separable Catalyst for the Synthesis of Bis-Pyrazole Derivatives

One-pot synthesis of benzo[e]1,4-oxathiepin-5-ones under solvent-free condition via self-promoted thiolysis of 1,2-epoxides.

PS-BEMP as a basic catalyst for the phospha-Michael addition to electron-poor alkenes

Polymer-Anchored Bifunctional Pincer Catalysts for Chemoselective Transfer Hydrogenation and Related Reactions

Polystyryl-supported TBD as an efficient and reusable catalyst under solvent-free conditions

Ring Opening of Epoxides with Sodium Azide in Water. A Regioselective pH-Controlled Reaction

Ruthenium(ii) oxidase catalysis for C–H alkenylations in biomass-derived γ-valerolactone

Sc(III)-catalyzed enantioselective addition of thiols to α,β-unsaturated ketones in neutral water

Semiconducting Polymers Prepared by Direct Arylation Polycondensation

Supported l-proline on zirconium phosphates methyl and/or phenyl phosphonates as heterogeneous organocatalysts for direct asymmetric aldol addition

Sustainable Protocol for the Reduction of Nitroarenes by Heterogeneous Au@SBA-15 with NaBH4 under Flow Conditions

Synthesis of 4-Aryl-1H-1,2,3-triazoles through TBAF-Catalyzed [3 + 2] Cycloaddition of 2-Aryl-1-nitroethenes with TMSN3under Solvent-Free Conditions

Synthesis of liquid biofuels from biomass by hydrothermal gasification: A critical review

TBAF-catalyzed synthesis of 5-substituted 1H-tetrazoles under solventless conditions.

Uncatalyzed and solvent-free multicomponent process for the synthesis of biphenyl-2-carbonitrile derivatives.

Waste Minimized Multistep Preparation in Flow of β-Amino Acids Starting from α,β-Unsaturated Carboxylic Acids

Water, a clean, inexpensive, and re-usable reaction medium. One-pot synthesis of (E)-2-aryl-1-cyano-1-nitroethenes

Zn(II)-Catalyzed Thiolysis of Oxiranes in Water under Neutral Conditions ⬇️

[AlCl3 + 2THF]: a new and efficient catalytic system for Diels-Alder cycloaddition of alpha,beta-unsaturated carbonyl compounds under solvent-free conditions