List of works - Stefano Zacchini

A general strategy to add diversity to ruthenium arene complexes with bioactive organic compounds via a coordinated (4-hydroxyphenyl)diphenylphosphine ligand

scientific article

A total scattering Debye function analysis study of faulted Pt nanocrystals embedded in a porous matrix

scientific article

Allowing the direct interaction of N-aryl α-diimines with a high valent metal chloride: one-pot WCl6-promoted formation of quinoxalinium salts.

scientific article published on 21 September 2017

Bis-conjugation of Bioactive Molecules to Cisplatin-like Complexes through (2,2'-Bipyridine)-4,4'-Dicarboxylic Acid with Optimal Cytotoxicity Profile Provided by the Combination Ethacrynic Acid/Flurbiprofen

scientific article published on 30 November 2020

Bypassing the Inertness of Aziridine/CO2 Systems to Access 5-Aryl-2-Oxazolidinones: Catalyst-Free Synthesis Under Ambient Conditions

scientific article published on 09 September 2020

Cationic Diiron and Diruthenium μ-Allenyl Complexes: Synthesis, X-Ray Structures and Cyclization Reactions with Ethyldiazoacetate/Amine Affording Unprecedented Butenolide- and Furaniminium-Substituted Bridging Carbene Ligands ⬇️

scientific article published on October 18, 2010

Cluster Core Isomerism Induced by Crystal Packing Effects in the [HCo15Pd9C3(CO)38]2- Molecular Nanocluster

scientific article published on 16 October 2018

Conductive sub-micrometric wires of platinum-carbonyl clusters fabricated by soft-lithography

article published in 2008

Controlled Dissociation of Iron and Cyclopentadienyl from a Diiron Complex with a Bridging C3 Ligand Triggered by One-Electron Reduction

scientific article published on 30 November 2018

Decarbonylation of phenylacetic acids by high valent transition metal halides

scientific article published on 01 April 2019

From Mononuclear Complexes to Molecular Nanoparticles: The Buildup of Atomically Precise Heterometallic Rhodium Carbonyl Nanoclusters

scientific article published on 12 October 2018

Heteroleptic Chini-Type Platinum Clusters: Synthesis and Characterization of Bis-Phospine Derivatives of [Pt3n(CO)6n]2- (n = 2-4).

scientific article

Insertion of germanium atoms in high-nuclearity rhodium carbonyl compounds: synthesis, characterization and preliminary biological activity of the heterometallic [RhGe(CO)], [RhGe(CO)] and [RhGe(CO)] clusters

scientific article published on 01 November 2018

Interstitial Bismuth Atoms in Icosahedral Rhodium Cages: Syntheses, Characterizations, and Molecular Structures of the [Bi@Rh12(CO)27]3-, [(Bi@Rh12(CO)26)2Bi]5-, [Bi@Rh14(CO)27Bi2]3-, and [Bi@Rh17(CO)33Bi2]4- Carbonyl Clusters.

scientific article

Luminescent protein staining with Re(i) tetrazolato complexes

scientific article published on 01 July 2018

Methylation of Ir(iii)-tetrazolato complexes: an effective route to modulate the emission outputs and to switch to antimicrobial properties.

scientific article

Molecular Nickel Phosphide Carbonyl Nanoclusters: Synthesis, Structure, and Electrochemistry of [Ni11P(CO)18]3- and [H6-nNi31P4(CO)39]n- (n = 4 and 5).

scientific article

Mono-, Di- and Tetra-iron Complexes with Selenium or Sulphur Functionalized Vinyliminium Ligands: Synthesis, Structural Characterization and Antiproliferative Activity

scientific article published on 03 April 2020

Polymerization Isomerism in [{MFe(CO)4} n] n- (M = Cu, Ag, Au; n = 3, 4) Molecular Clusters Supported by Metallophilic Interactions

scientific article published on 14 February 2019

Reactions of Platinum Carbonyl Chini Clusters with Ag(NHC)Cl Complexes: Formation of Acid-Base Lewis Adducts and Heteroleptic Clusters.

scientific article

Redox active Ni-Pd carbonyl alloy nanoclusters: syntheses, molecular structures and electrochemistry of [Ni22-xPd20+x(CO)48]6- (x = 0.62), [Ni29-xPd6+x(CO)42]6- (x = 0.09) and [Ni29+xPd6-x(CO)42]6- (x = 0.27)

scientific article published on 08 April 2020

Rh-Sb Nanoclusters: Synthesis, Structure, and Electrochemical Studies of the Atomically Precise [Rh20Sb3(CO)36]3- and [Rh21Sb2(CO)38]5- Carbonyl Compounds

scientific article published on 24 March 2020

Ruthenium arene complexes with triphenylphosphane ligands: cytotoxicity towards pancreatic cancer cells, interaction with model proteins, and effect of ethacrynic acid substitution

article

Stable coordination complexes of α-diimines with Nb(v) and Ta(v) halides

scientific article published on 9 February 2018

Straightforward formation of carbocations from tertiary carboxylic acids via CO release at room temperature

scientific article published on 07 December 2018

Structural Diversity in Molecular Nickel Phosphide Carbonyl Nanoclusters

scientific article published on 21 October 2020

Synthesis of [Pt(CO)(dppm)] and [Pt(CO)(dppm)] Heteroleptic Chini-type Platinum Clusters by the Oxidative Oligomerization of [Pt(CO)(dppm)]

scientific article published on 11 June 2018

Synthesis, Structural Characterization, and DFT Investigations of [MxM'5-xFe4(CO)16]3- (M, M' = Cu, Ag, Au; M ≠ M') 2-D Molecular Alloy Clusters

scientific article published on 20 October 2020

Tetrasubstituted Selenophenes from the Stepwise Assembly of Molecular Fragments on a Diiron Frame and Final Cleavage of a Bridging Alkylidene

scientific article published on 18 November 2020

Thermal Growth of Au-Fe Heterometallic Carbonyl Clusters Containing N-Heterocyclic Carbene and Phosphine Ligands

scientific article published on 31 January 2020

Towards All-Organic Field-Effect Transistors by Additive Soft Lithography

article

Tuning the cytotoxicity of ruthenium(ii) para-cymene complexes by mono-substitution at a triphenylphosphine/phenoxydiphenylphosphine ligand

scientific article

Ubiquity of cis-Halide → Isocyanide Direct Interligand Interaction in Organometallic Complexes

scientific article published on 15 November 2018

Versatile coordination of acetazolamide to ruthenium(ii) p-cymene complexes and preliminary cytotoxicity studies

scientific article published on 01 July 2018

Water soluble derivatives of platinum carbonyl Chini clusters: synthesis, molecular structures and cytotoxicity of [Pt12(CO)20(PTA)4]2- and [Pt15(CO)25(PTA)5]2- .

scientific article published on 5 March 2018

α-Diimine homologues of cisplatin: synthesis, speciation in DMSO/water and cytotoxicity

α-Diimines as Versatile, Derivatizable Ligands in Ruthenium(II) p-Cymene Anticancer Complexes

article published in 2018

List of works by Stefano Zacchini

A general strategy to add diversity to ruthenium arene complexes with bioactive organic compounds via a coordinated (4-hydroxyphenyl)diphenylphosphine ligand

A total scattering Debye function analysis study of faulted Pt nanocrystals embedded in a porous matrix

Allowing the direct interaction of N-aryl α-diimines with a high valent metal chloride: one-pot WCl6-promoted formation of quinoxalinium salts.

Bis-conjugation of Bioactive Molecules to Cisplatin-like Complexes through (2,2'-Bipyridine)-4,4'-Dicarboxylic Acid with Optimal Cytotoxicity Profile Provided by the Combination Ethacrynic Acid/Flurbiprofen

Bypassing the Inertness of Aziridine/CO2 Systems to Access 5-Aryl-2-Oxazolidinones: Catalyst-Free Synthesis Under Ambient Conditions

Cationic Diiron and Diruthenium μ-Allenyl Complexes: Synthesis, X-Ray Structures and Cyclization Reactions with Ethyldiazoacetate/Amine Affording Unprecedented Butenolide- and Furaniminium-Substituted Bridging Carbene Ligands ⬇️

Cluster Core Isomerism Induced by Crystal Packing Effects in the [HCo15Pd9C3(CO)38]2- Molecular Nanocluster

Conductive sub-micrometric wires of platinum-carbonyl clusters fabricated by soft-lithography

Controlled Dissociation of Iron and Cyclopentadienyl from a Diiron Complex with a Bridging C3 Ligand Triggered by One-Electron Reduction

Decarbonylation of phenylacetic acids by high valent transition metal halides

From Mononuclear Complexes to Molecular Nanoparticles: The Buildup of Atomically Precise Heterometallic Rhodium Carbonyl Nanoclusters

Heteroleptic Chini-Type Platinum Clusters: Synthesis and Characterization of Bis-Phospine Derivatives of [Pt3n(CO)6n]2- (n = 2-4).

Insertion of germanium atoms in high-nuclearity rhodium carbonyl compounds: synthesis, characterization and preliminary biological activity of the heterometallic [RhGe(CO)], [RhGe(CO)] and [RhGe(CO)] clusters

Interstitial Bismuth Atoms in Icosahedral Rhodium Cages: Syntheses, Characterizations, and Molecular Structures of the [Bi@Rh12(CO)27]3-, [(Bi@Rh12(CO)26)2Bi]5-, [Bi@Rh14(CO)27Bi2]3-, and [Bi@Rh17(CO)33Bi2]4- Carbonyl Clusters.

Luminescent protein staining with Re(i) tetrazolato complexes

Methylation of Ir(iii)-tetrazolato complexes: an effective route to modulate the emission outputs and to switch to antimicrobial properties.

Molecular Nickel Phosphide Carbonyl Nanoclusters: Synthesis, Structure, and Electrochemistry of [Ni11P(CO)18]3- and [H6-nNi31P4(CO)39]n- (n = 4 and 5).

Mono-, Di- and Tetra-iron Complexes with Selenium or Sulphur Functionalized Vinyliminium Ligands: Synthesis, Structural Characterization and Antiproliferative Activity

Polymerization Isomerism in [{MFe(CO)4} n] n- (M = Cu, Ag, Au; n = 3, 4) Molecular Clusters Supported by Metallophilic Interactions

Reactions of Platinum Carbonyl Chini Clusters with Ag(NHC)Cl Complexes: Formation of Acid-Base Lewis Adducts and Heteroleptic Clusters.

Redox active Ni-Pd carbonyl alloy nanoclusters: syntheses, molecular structures and electrochemistry of [Ni22-xPd20+x(CO)48]6- (x = 0.62), [Ni29-xPd6+x(CO)42]6- (x = 0.09) and [Ni29+xPd6-x(CO)42]6- (x = 0.27)

Rh-Sb Nanoclusters: Synthesis, Structure, and Electrochemical Studies of the Atomically Precise [Rh20Sb3(CO)36]3- and [Rh21Sb2(CO)38]5- Carbonyl Compounds

Ruthenium arene complexes with triphenylphosphane ligands: cytotoxicity towards pancreatic cancer cells, interaction with model proteins, and effect of ethacrynic acid substitution

Stable coordination complexes of α-diimines with Nb(v) and Ta(v) halides

Straightforward formation of carbocations from tertiary carboxylic acids via CO release at room temperature

Structural Diversity in Molecular Nickel Phosphide Carbonyl Nanoclusters

Synthesis of [Pt(CO)(dppm)] and [Pt(CO)(dppm)] Heteroleptic Chini-type Platinum Clusters by the Oxidative Oligomerization of [Pt(CO)(dppm)]

Synthesis, Structural Characterization, and DFT Investigations of [MxM'5-xFe4(CO)16]3- (M, M' = Cu, Ag, Au; M ≠ M') 2-D Molecular Alloy Clusters

Tetrasubstituted Selenophenes from the Stepwise Assembly of Molecular Fragments on a Diiron Frame and Final Cleavage of a Bridging Alkylidene

Thermal Growth of Au-Fe Heterometallic Carbonyl Clusters Containing N-Heterocyclic Carbene and Phosphine Ligands

Towards All-Organic Field-Effect Transistors by Additive Soft Lithography

Tuning the cytotoxicity of ruthenium(ii) para-cymene complexes by mono-substitution at a triphenylphosphine/phenoxydiphenylphosphine ligand

Ubiquity of cis-Halide → Isocyanide Direct Interligand Interaction in Organometallic Complexes

Versatile coordination of acetazolamide to ruthenium(ii) p-cymene complexes and preliminary cytotoxicity studies

Water soluble derivatives of platinum carbonyl Chini clusters: synthesis, molecular structures and cytotoxicity of [Pt12(CO)20(PTA)4]2- and [Pt15(CO)25(PTA)5]2- .

α-Diimine homologues of cisplatin: synthesis, speciation in DMSO/water and cytotoxicity

α-Diimines as Versatile, Derivatizable Ligands in Ruthenium(II) p-Cymene Anticancer Complexes