List of works - Xiao-Song Xue

2,6-Azulene-based Homopolymers: Design, Synthesis, and Application in Proton Exchange Membrane Fuel Cells

scientific article published on 29 April 2022

A Highly Efficient Chirality Switchable Synthesis of Dihydropyran-Fused Benzofurans by Fine-Tuning the Phenolic Proton of β-Isocupreidine (β-ICD) Catalyst with Methyl

scientific article published on 8 June 2015

A Systematic Assessment of Trifluoromethyl Radical Donor Abilities of Electrophilic Trifluoromethylating Reagents

scientific article published on 30 December 2016

A Systematic Evaluation of the N-F Bond Strength of Electrophilic N-F Reagents: Hints for Atomic Fluorine Donating Ability.

scientific article published on 27 March 2017

A Systematic Theoretical Study on the Acidities for Cations of Ionic Liquids in Dimethyl Sulfoxide

scientific article published on 22 June 2018

A ring expansion strategy towards diverse azaheterocycles

scientific article published on 19 July 2021

Acidity Scale of N-Heterocyclic Carbene Precursors: Can We Predict the Stability of NHC-CO Adducts?

scientific article published on 14 September 2018

Ambimodal Trispericyclic Transition State and Dynamic Control of Periselectivity

scientific article published on 14 January 2019

An Energetic Guide for Estimating Trifluoromethyl Cation Donor Abilities of Electrophilic Trifluoromethylating Reagents: Computations of X-CF3 Bond Heterolytic Dissociation Enthalpies

scientific article

Asymmetric Michael addition reactions of 3-substituted benzofuran-2(3H)-ones to nitroolefins catalyzed by a bifunctional tertiary-amine thiourea

scientific article published on 16 November 2011

Biomimetic Total Synthesis of (±)-Carbocyclinone-534 Reveals Its Biosynthetic Pathway

scientific article published on 21 October 2020

Catalytic Direct Construction of Cyano-tetrazoles

scientific article published on 23 September 2020

Catalytic Enantioselective Cyclopropenation of Internal Alkynes: Access to Difluoromethylated Three-Membered Carbocycles

scientific article published on 11 November 2019

Chemodivergent and Stereoselective Construction of gem-Difluoroallylic Amines from Masked Difluorodiazo Reagents

scientific article published on 12 September 2019

Chiral Lewis Base Catalyzed Enantioselective Selenocyclization of 1,1-Disubstituted Alkenes: Asymmetric Synthesis of Selenium-Containing 4 H -3,1-Benzoxazines

scientific article published in June 2022

Chiral Spiro Phosphoric Acid-Catalyzed Friedel–Crafts Conjugate Addition/Enantioselective Protonation Reactions

scientific article published on 11 June 2019

Cleaving arene rings for acyclic alkenylnitrile synthesis

scientific article published on 19 July 2021

Comprehensive Basicity Scales for N-Heterocyclic Carbenes in DMSO: Implications on the Stabilities of N-Heterocyclic Carbene and CO2 Adducts

scientific article published on 12 December 2019

Comprehensive Energetic Scale for Quantitatively Estimating the Fluorinating Potential of N-F Reagents in Electrophilic Fluorinations

scientific article published on 27 April 2016

Computational Design of a Tetrapericyclic Cycloaddition and the Nature of Potential Energy Surfaces with Multiple Bifurcations

scientific article published on 9 February 2023

Computational Exploration of the Mechanism of Critical Steps in the Biomimetic Synthesis of Preuisolactone A, and Discovery of New Ambimodal (5 + 2)/(4 + 2) Cycloadditions

scientific article published on 22 April 2021

Computational I(III)-X BDEs for Benziodoxol(on)e-based Hypervalent Iodine Reagents: Implications for Their Functional Group Transfer Abilities

scientific article published on 26 February 2019

Computational insights into the effects of reagent structure and bases on nucleophilic monofluoromethylation of aldehydes

scientific article published in May 2022

Computational study on the acidic constants of chiral Brønsted acids in dimethyl sulfoxide

scientific article published on 24 April 2014

Computational study on the pKa shifts in proline induced by hydrogen-bond-donating cocatalysts

scientific article

Construction of Complex Macromulticyclic Peptides via Stitching with Formaldehyde and Guanidine

scientific article published on 31 May 2022

Controllable catalytic difluorocarbene transfer enables access to diversified fluoroalkylated arenes

scientific article published on 23 September 2019

Cooperative Stapling of Native Peptides at Lysine and Tyrosine or Arginine with Formaldehyde

scientific article published on 18 December 2020

Copper(I)-Catalyzed Asymmetric Conjugate Addition of 1,4-Dienes to β-Substituted Alkenyl Azaarenes

scientific article published on 9 January 2023

Correction to "A Systematic Theoretical Study on the Acidities for Cations of Ionic Liquids in Dimethyl Sulfoxide"

scientific article published on 29 October 2019

Correction to "Acidity Scale of N-Heterocyclic Carbene Precursors: Can We Predict the Stability of NHC-CO2 Adducts?"

scientific article published on 25 October 2019

Correction to "Theoretical Study on the Acidities of Chiral Phosphoric Acids in Dimethyl Sulfoxide: Hints for Organocatalysis".

scientific article published on 19 September 2017

Design and Applications of N-tert-Butyl Sulfinyl Squaramide Catalysts

scientific article published on 30 March 2017

Difluoromethylation of Unactivated Alkenes Using Freon-22 through Tertiary Amine-Borane-Triggered Halogen Atom Transfer

scientific article published on 27 July 2022

Enantioselective Organocatalyzed Sulfenylation of 3-Substituted Oxindoles ⬇️

scientific article published on August 17, 2012

Enantioselective Synthesis of Planar‐Chiral Macrocycles through Asymmetric Electrophilic Aromatic Amination

scientific article published on 30 March 2022

Establishing Cation and Radical Donor Ability Scales of Electrophilic F, CF3, and SCF3 Transfer Reagents

scientific article published on 11 December 2019

Establishing the Trifluoromethylthio Radical Donating Abilities of Electrophilic SCF3-Transfer Reagents

scientific article

Expanding the Frontiers of Higher-Order Cycloadditions

scientific article published on 02 December 2019

Exploration of the Synthetic Potential of Electrophilic Trifluoromethylthiolating and Difluoromethylthiolating Reagents

scientific article published on 03 September 2018

Exploration of the Synthetic Potential of Electrophilic Trifluoromethylthiolating and Difluoromethylthiolating Reagents

scientific article published on 3 September 2018

Factors Controlling Reactivity in the Hydrogen Atom Transfer and Radical Addition Steps of a Radical Relay Cascade

scientific article published on 15 July 2019

Harnessing Natural Products by a Pharmacophore-Oriented Semisynthesis Approach for the Discovery of Potential Anti-SARS-CoV-2 Agents

scientific article published on 11 July 2022

High Site Selectivity in Electrophilic Aromatic Substitutions: Mechanism of C-H Thianthrenation

scientific article published on 6 October 2021

Highly selective synthesis of all-carbon tetrasubstituted alkenes by deoxygenative alkenylation of carboxylic acids

scientific article published on 4 February 2022

Hypervalent-Iodine-Mediated Formation of Epoxides from Carbon(sp2)-Carbon(sp3) Single Bonds.

scientific article published on 3 June 2017

Internal Alkyne-Directed Fluorination of Unactivated C(sp3)-H Bonds

scientific article published on 23 November 2020

Ligand-Dependent Regiodivergent Enantioselective Allylic Alkylations of α-Trifluoromethylated Ketones

scientific article published on 11 March 2021

Ligand-Dependent Regiodivergent Enantioselective Allylic Alkylations of α-Trifluoromethylated Ketones

scientific article published on 30 November 2020

Low-temperature mineralization of perfluorocarboxylic acids

scholarly article

Mechanism and Origin of the Unexpected Chemoselectivity in Fluorocyclization of o-Styryl Benzamides with a Hypervalent Fluoroiodane Reagent

scientific article published on 21 September 2016

Mechanism and Origins of Chemo- and Stereoselectivities of Aryl Iodide-Catalyzed Asymmetric Difluorinations of β-Substituted Styrenes

scientific article published on 05 November 2018

Mechanism and Origins of Enantioselectivities in Spirobiindane-Based Hypervalent Iodine(III)-Induced Asymmetric Dearomatizing Spirolactonizations

scientific article published on 25 September 2019

Mechanism and Origins of Stereoinduction in Natural Cinchona Alkaloid Catalyzed Asymmetric Electrophilic Trifluoromethylthiolation of β-Keto Esters with N -Trifluoromethylthiophthalimide as Electrophilic SCF 3 Source

scientific article published on 26 October 2017

Mechanism and Selectivity of Bioinspired Cinchona Alkaloid Derivatives Catalyzed Asymmetric Olefin Isomerization: A Computational Study ⬇️

scientific article published on May 14, 2013

Mechanism of Silver-Mediated Geminal Difluorination of Styrenes with a Fluoroiodane Reagent: Insights into Lewis-Acid-Activation Model.

scientific article

Metal-Free Electrochemical Carboxylation of Organic Halides in the Presence of Catalytic Amounts of an Organomediator

German version of a scholarly article

Metal-Free Electrochemical Carboxylation of Organic Halides in the Presence of Catalytic Amounts of an Organomediator

scholarly article

Metal‐Free C−H Functionalization via Diaryliodonium Salts with a Chemically Robust Dummy Ligand

scientific article published on 17 May 2022

Metal‐Free C−H Functionalization via Diaryliodonium Salts with a Chemically Robust Dummy Ligand

scientific article published on 18 May 2022

Mild Ring-Opening 1,3-Hydroborations of Non-Activated Cyclopropanes

scientific article published on 21 November 2018

N-Trifluoromethylthiodibenzenesulfonimide: A Shelf-Stable, Broadly Applicable Electrophilic Trifluoromethylthiolating Reagent

scientific article published on 21 July 2016

N-tert-Butyl Sulfinyl Squaramide Receptors for Anion Recognition through Assisted tert-Butyl C-H Hydrogen Bonding.

scientific article published on 2 August 2017

Near-Infrared Afterglow Luminescent Aggregation-Induced Emission Dots with Ultrahigh Tumor-to-Liver Signal Ratio for Promoted Image-Guided Cancer Surgery

scientific article published on 17 December 2018

Nickel-catalyzed intermolecular oxidative Heck arylation driven by transfer hydrogenation

scientific article published on 05 November 2019

Open-Shell Fluorination of Alkyl Bromides: Unexpected Selectivity in a Silyl Radical-Mediated Chain Process

scientific article published on 12 December 2019

Origin of Stereocontrol in Photoredox Organocatalysis of Asymmetric α-Functionalizations of Aldehydes.

scientific article published on 26 February 2018

Origin of Stereoselectivity of the Photoinduced Asymmetric Phase-Transfer-Catalyzed Perfluoroalkylation of β-Ketoesters

scientific article

Origins of Selectivities in the Stork Diels-Alder Cycloaddition for the Synthesis of (±)-4-Methylenegermine

scientific article published on 24 September 2018

Oxidative addition of an alkyl halide to form a stable Cu(III) product

scientific article published on 07 September 2023

Polarity Umpolung Strategy for the Radical Alkylation of Alkenes

scientific article published on 11 February 2020

Potassium Acetate-Catalyzed Double Decarboxylative Transannulation To Access Highly Functionalized Pyrroles

scientific article published on 01 December 2020

Preparation, characterization and reactivity of trifluoromethoxy palladium( ii ) complexes

scientific article published in 2022

Quantification of the Activation Capabilities of Lewis/Brønsted Acid for Electrophilic Trifluoromethylthiolating Reagents †

scientific article published on 24 December 2019

Quantitative Scale for the Trifluoromethylthio Cation-Donating Ability of Electrophilic Trifluoromethylthiolating Reagents

scientific article published on 07 January 2016

Radical C-H Arylation of Oxazoles with Aryl Iodides: dppf as an Electron-Transfer Mediator for Cs2CO3.

scientific article published in March 2018

Radical-mediated C-C cleavage of unstrained cycloketones and DFT study for unusual regioselectivity

scientific article published on 03 February 2020

Recent Advances and Advisable Applications of Bond Energetics in Organic Chemistry

article

Recent Computational Studies on Mechanisms of Hypervalent Iodine(III)-Promoted Dearomatization of Phenols

scientific article published on 18 November 2020

Remote Enantioselective Desymmetrization of 9,9-Disubstituted 9,10-Dihydroacridines through Asymmetric Aromatic Aminations

scientific article published on 15 November 2022

Rhodium-Catalyzed 2-Arylphenol-Derived Six-Membered Silacyclization: Straightforward Access toward Dibenzooxasilines and Silicon-Containing Planar Chiral Metallocenes

scientific article published on 19 July 2018

Silver-catalysed [3 + 2] annulation reaction of aryldiazonium salts with allenes enabled by boronate direction

scientific article published in 2023

Solvent-controlled photocatalytic divergent cyclization of alkynyl aldehydes: access to cyclopentenones and dihydropyranols

scientific article published on 18 March 2021

Synthesis of Optically Enriched Spirocyclic Benzofuran‐2‐ones by Bifunctional Thiourea‐Base Catalyzed Double‐Michael Addition of Benzofuran‐2‐ones to Dienones ⬇️

scientific article published on February 19, 2013

The Acidities of Nucleophilic Monofluoromethylation Reagents: An Anomalous α‐Fluorine Effect

scientific article published on 17 March 2021

The Acidities of Nucleophilic Monofluoromethylation Reagents: An Anomalous α‐Fluorine Effect

scientific article published on 18 March 2021

The Brönsted Basicities of N-Heterocyclic Olefins in DMSO: An Effective Way to Evaluate the Stability of NHO-CO2 Adducts

scientific article published on 09 September 2020

The Essential Role of Bond Energetics in C-H Activation/Functionalization

scientific article published on 10 March 2017

Theoretical Study on the Acidities of Chiral Phosphoric Acids in Dimethyl Sulfoxide: Hints for Organocatalysis ⬇️

scientific article published on July 19, 2013

Theoretical Study on the Origin of Abnormal Regioselectivity in Ring-Opening Reaction of Hexafluoropropylene Oxide

scientific article published on 9 February 2023

Toward Prediction of the Chemistry in Ionic Liquids: An Accurate Computation of Absolute pK(a) Values of Benzoic Acids and Benzenethiols.

scientific article published on 24 August 2015

Transition State Stabilization by SCF 2 −H⋅⋅⋅O Bifurcated Hydrogen Bond

scholarly article

Transition-Metal-Free ipso-Trifluoromethylthiolation of Lithium Aryl Boronates

scientific article published on 02 August 2019

Violations. How Nature Circumvents the Woodward-Hoffmann Rules and Promotes the Forbidden Conrotatory 4<i>n</i> + 2 Electron Electrocyclization of Prinzbach's Vinylogous Sesquifulvalene

scientific article published on 16 December 2021

Visible-Light-Driven Neutral Nitrogen Radical Mediated Intermolecular Styrene Difunctionalization

scientific article published on 08 May 2019

[8+2] vs [4+2] Cycloadditions of Cyclohexadienamines to Tropone and Heptafulvenes-Mechanisms and Selectivities

scientific article published on 08 January 2021

List of works by Xiao-Song Xue

2,6-Azulene-based Homopolymers: Design, Synthesis, and Application in Proton Exchange Membrane Fuel Cells

A Highly Efficient Chirality Switchable Synthesis of Dihydropyran-Fused Benzofurans by Fine-Tuning the Phenolic Proton of β-Isocupreidine (β-ICD) Catalyst with Methyl

A Systematic Assessment of Trifluoromethyl Radical Donor Abilities of Electrophilic Trifluoromethylating Reagents

A Systematic Evaluation of the N-F Bond Strength of Electrophilic N-F Reagents: Hints for Atomic Fluorine Donating Ability.

A Systematic Theoretical Study on the Acidities for Cations of Ionic Liquids in Dimethyl Sulfoxide

A ring expansion strategy towards diverse azaheterocycles

Acidity Scale of N-Heterocyclic Carbene Precursors: Can We Predict the Stability of NHC-CO Adducts?

Ambimodal Trispericyclic Transition State and Dynamic Control of Periselectivity

An Energetic Guide for Estimating Trifluoromethyl Cation Donor Abilities of Electrophilic Trifluoromethylating Reagents: Computations of X-CF3 Bond Heterolytic Dissociation Enthalpies

Asymmetric Michael addition reactions of 3-substituted benzofuran-2(3H)-ones to nitroolefins catalyzed by a bifunctional tertiary-amine thiourea

Biomimetic Total Synthesis of (±)-Carbocyclinone-534 Reveals Its Biosynthetic Pathway

Catalytic Direct Construction of Cyano-tetrazoles

Catalytic Enantioselective Cyclopropenation of Internal Alkynes: Access to Difluoromethylated Three-Membered Carbocycles

Chemodivergent and Stereoselective Construction of gem-Difluoroallylic Amines from Masked Difluorodiazo Reagents

Chiral Lewis Base Catalyzed Enantioselective Selenocyclization of 1,1-Disubstituted Alkenes: Asymmetric Synthesis of Selenium-Containing 4 H -3,1-Benzoxazines

Chiral Spiro Phosphoric Acid-Catalyzed Friedel–Crafts Conjugate Addition/Enantioselective Protonation Reactions

Cleaving arene rings for acyclic alkenylnitrile synthesis

Comprehensive Basicity Scales for N-Heterocyclic Carbenes in DMSO: Implications on the Stabilities of N-Heterocyclic Carbene and CO2 Adducts

Comprehensive Energetic Scale for Quantitatively Estimating the Fluorinating Potential of N-F Reagents in Electrophilic Fluorinations

Computational Design of a Tetrapericyclic Cycloaddition and the Nature of Potential Energy Surfaces with Multiple Bifurcations

Computational Exploration of the Mechanism of Critical Steps in the Biomimetic Synthesis of Preuisolactone A, and Discovery of New Ambimodal (5 + 2)/(4 + 2) Cycloadditions

Computational I(III)-X BDEs for Benziodoxol(on)e-based Hypervalent Iodine Reagents: Implications for Their Functional Group Transfer Abilities

Computational insights into the effects of reagent structure and bases on nucleophilic monofluoromethylation of aldehydes

Computational study on the acidic constants of chiral Brønsted acids in dimethyl sulfoxide

Computational study on the pKa shifts in proline induced by hydrogen-bond-donating cocatalysts

Construction of Complex Macromulticyclic Peptides via Stitching with Formaldehyde and Guanidine

Controllable catalytic difluorocarbene transfer enables access to diversified fluoroalkylated arenes

Cooperative Stapling of Native Peptides at Lysine and Tyrosine or Arginine with Formaldehyde

Copper(I)-Catalyzed Asymmetric Conjugate Addition of 1,4-Dienes to β-Substituted Alkenyl Azaarenes

Correction to "A Systematic Theoretical Study on the Acidities for Cations of Ionic Liquids in Dimethyl Sulfoxide"

Correction to "Acidity Scale of N-Heterocyclic Carbene Precursors: Can We Predict the Stability of NHC-CO2 Adducts?"

Correction to "Theoretical Study on the Acidities of Chiral Phosphoric Acids in Dimethyl Sulfoxide: Hints for Organocatalysis".

Design and Applications of N-tert-Butyl Sulfinyl Squaramide Catalysts

Difluoromethylation of Unactivated Alkenes Using Freon-22 through Tertiary Amine-Borane-Triggered Halogen Atom Transfer

Enantioselective Organocatalyzed Sulfenylation of 3-Substituted Oxindoles ⬇️

Enantioselective Synthesis of Planar‐Chiral Macrocycles through Asymmetric Electrophilic Aromatic Amination

Establishing Cation and Radical Donor Ability Scales of Electrophilic F, CF3, and SCF3 Transfer Reagents

Establishing the Trifluoromethylthio Radical Donating Abilities of Electrophilic SCF3-Transfer Reagents

Expanding the Frontiers of Higher-Order Cycloadditions

Exploration of the Synthetic Potential of Electrophilic Trifluoromethylthiolating and Difluoromethylthiolating Reagents

Exploration of the Synthetic Potential of Electrophilic Trifluoromethylthiolating and Difluoromethylthiolating Reagents

Factors Controlling Reactivity in the Hydrogen Atom Transfer and Radical Addition Steps of a Radical Relay Cascade

Harnessing Natural Products by a Pharmacophore-Oriented Semisynthesis Approach for the Discovery of Potential Anti-SARS-CoV-2 Agents

High Site Selectivity in Electrophilic Aromatic Substitutions: Mechanism of C-H Thianthrenation

Highly selective synthesis of all-carbon tetrasubstituted alkenes by deoxygenative alkenylation of carboxylic acids

Hypervalent-Iodine-Mediated Formation of Epoxides from Carbon(sp2)-Carbon(sp3) Single Bonds.

Internal Alkyne-Directed Fluorination of Unactivated C(sp3)-H Bonds

Ligand-Dependent Regiodivergent Enantioselective Allylic Alkylations of α-Trifluoromethylated Ketones

Ligand-Dependent Regiodivergent Enantioselective Allylic Alkylations of α-Trifluoromethylated Ketones

Low-temperature mineralization of perfluorocarboxylic acids

Mechanism and Origin of the Unexpected Chemoselectivity in Fluorocyclization of o-Styryl Benzamides with a Hypervalent Fluoroiodane Reagent

Mechanism and Origins of Chemo- and Stereoselectivities of Aryl Iodide-Catalyzed Asymmetric Difluorinations of β-Substituted Styrenes

Mechanism and Origins of Enantioselectivities in Spirobiindane-Based Hypervalent Iodine(III)-Induced Asymmetric Dearomatizing Spirolactonizations

Mechanism and Origins of Stereoinduction in Natural Cinchona Alkaloid Catalyzed Asymmetric Electrophilic Trifluoromethylthiolation of β-Keto Esters with N -Trifluoromethylthiophthalimide as Electrophilic SCF 3 Source

Mechanism and Selectivity of Bioinspired Cinchona Alkaloid Derivatives Catalyzed Asymmetric Olefin Isomerization: A Computational Study ⬇️

Mechanism of Silver-Mediated Geminal Difluorination of Styrenes with a Fluoroiodane Reagent: Insights into Lewis-Acid-Activation Model.

Metal-Free Electrochemical Carboxylation of Organic Halides in the Presence of Catalytic Amounts of an Organomediator

Metal-Free Electrochemical Carboxylation of Organic Halides in the Presence of Catalytic Amounts of an Organomediator

Metal‐Free C−H Functionalization via Diaryliodonium Salts with a Chemically Robust Dummy Ligand

Metal‐Free C−H Functionalization via Diaryliodonium Salts with a Chemically Robust Dummy Ligand

Mild Ring-Opening 1,3-Hydroborations of Non-Activated Cyclopropanes

N-Trifluoromethylthiodibenzenesulfonimide: A Shelf-Stable, Broadly Applicable Electrophilic Trifluoromethylthiolating Reagent

N-tert-Butyl Sulfinyl Squaramide Receptors for Anion Recognition through Assisted tert-Butyl C-H Hydrogen Bonding.

Near-Infrared Afterglow Luminescent Aggregation-Induced Emission Dots with Ultrahigh Tumor-to-Liver Signal Ratio for Promoted Image-Guided Cancer Surgery

Nickel-catalyzed intermolecular oxidative Heck arylation driven by transfer hydrogenation

Open-Shell Fluorination of Alkyl Bromides: Unexpected Selectivity in a Silyl Radical-Mediated Chain Process

Origin of Stereocontrol in Photoredox Organocatalysis of Asymmetric α-Functionalizations of Aldehydes.

Origin of Stereoselectivity of the Photoinduced Asymmetric Phase-Transfer-Catalyzed Perfluoroalkylation of β-Ketoesters

Origins of Selectivities in the Stork Diels-Alder Cycloaddition for the Synthesis of (±)-4-Methylenegermine

Oxidative addition of an alkyl halide to form a stable Cu(III) product

Polarity Umpolung Strategy for the Radical Alkylation of Alkenes

Potassium Acetate-Catalyzed Double Decarboxylative Transannulation To Access Highly Functionalized Pyrroles

Preparation, characterization and reactivity of trifluoromethoxy palladium( ii ) complexes

Quantification of the Activation Capabilities of Lewis/Brønsted Acid for Electrophilic Trifluoromethylthiolating Reagents †

Quantitative Scale for the Trifluoromethylthio Cation-Donating Ability of Electrophilic Trifluoromethylthiolating Reagents

Radical C-H Arylation of Oxazoles with Aryl Iodides: dppf as an Electron-Transfer Mediator for Cs2CO3.

Radical-mediated C-C cleavage of unstrained cycloketones and DFT study for unusual regioselectivity

Recent Advances and Advisable Applications of Bond Energetics in Organic Chemistry

Recent Computational Studies on Mechanisms of Hypervalent Iodine(III)-Promoted Dearomatization of Phenols