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List of works by Joaquín García-Álvarez

A new class of tethered-arene ruthenium(II) complexes with pendant P and C donor atoms: synthesis of eta6:eta1:eta1 phosphonio-azabutadienyl ruthenabicycles via allenylidene intermediates.

scientific article

Access to the first (iminophosphoranyl)(selenophosphoranyl)methane ligands Ph2P(=Se)CH2P(=NR)Ph2: coordination of their methanide and methandiide anions to ruthenium

scientific article published on 19 November 2009

Alkali-Metal-Mediated Manganation: A Method for Directly Attaching Manganese(II) Centers to Aromatic Frameworks

article

Bis(iminophosphorano)methane Derivatives as Precursors of Unusual Ruthenium Carbene Complexes: A Synthetic and DFT Study

article published in 2004

Chemoenzymatic one-pot synthesis in an aqueous medium: combination of metal-catalysed allylic alcohol isomerisation-asymmetric bioamination.

scientific article

Combination of organocatalytic oxidation of alcohols and organolithium chemistry (RLi) in aqueous media, at room temperature and under aerobic conditions

scientific article published on 08 July 2020

Contacted Ion-Pair Lithium Alkylamidoaluminates: Intramolecular Alumination (Al−H Exchange) Traps for TMEDA and PMDETA

article

Deep eutectic solvent-catalyzed Meyer-Schuster rearrangement of propargylic alcohols under mild and bench reaction conditions

scientific article published on 20 November 2020

From a Sequential to a Concurrent Reaction in Aqueous Medium: Ruthenium-Catalyzed Allylic Alcohol Isomerization and Asymmetric Bioreduction.

scientific article

Introducing deep eutectic solvents as biorenewable media for Au(I)-catalysed cycloisomerisation of γ-alkynoic acids: an unprecedented catalytic system

scientific article published in November 2014

Introducing deep eutectic solvents to polar organometallic chemistry: chemoselective addition of organolithium and Grignard reagents to ketones in air.

scientific article published on 25 April 2014

Isolation and structural elucidation of a key aluminoaromatic intermediate and evidence for dismutation phenomena in TMP-alumination chemistry.

scientific article published on 12 October 2007

Lewis base stabilized lithium TMP-aluminates: an unexpected fragmentation and capture reaction involving cyclic ether 1,4-dioxane

article

New Ag(I)-iminophosphorane coordination polymers as efficient catalysts precursors for the MW-assisted Meyer-Schuster rearrangement of propargylic alcohols in water.

scientific article

New reactivity and structural insights of alkali-metal-mediated alumination in directed ortho-alumination of a tertiary aromatic amide

article

Novel rhenium(I) catalysts for the isomerization of propargylic alcohols into α,β-unsaturated carbonyl compounds: an unprecedented recyclable catalytic system in ionic liquids

scientific article published on 09 May 2011

Organolithium-Initiated Polymerization of Olefins in Deep Eutectic Solvents under Aerobic Conditions

scientific article published on 02 May 2019

Recent Progress of Cu-Catalyzed Azide-Alkyne Cycloaddition Reactions (CuAAC) in Sustainable Solvents: Glycerol, Deep Eutectic Solvents, and Aqueous Media

scientific article published on 26 April 2020

Ruthenium(II) and ruthenium(IV) complexes containing kappa1-P-, kappa2-P,O-, and kappa3-P,N,O-iminophosphorane-phosphine ligands Ph2PCH2P[=NP(=O)(OR)2]Ph2 (R = Et, Ph): synthesis, reactivity, theoretical studies, and catalytic activity in transfer h

scientific article published in May 2003

Silver(I) complexes of N-thiophosphorylated bis(iminophosphorane) ligands: from monomers to polymers

scientific article published on 22 May 2007

Special Issue: "Organic Reactions in Green Solvents".

scientific article

Structural basis for regioisomerization in the alkali-metal-mediated zincation (AMMZn) of trifluoromethyl benzene by isolation of kinetic and thermodynamic intermediates.

scientific article published on July 2010

Synthesis and characterisation of new bimetallic alkali metal-magnesium mixed diisopropylamide-acetylides: structural variations in bimetallic lithium- and sodium-heteroleptic magnesiates.

scientific article published on 14 February 2008

Synthesis and reactivity of new rhenium(I) complexes containing iminophosphorane-phosphine ligands: application to the catalytic isomerization of propargylic alcohols in ionic liquids.

scientific article published on 17 April 2013

Synthesis and reactivity studies of palladium(II) complexes containing the N-phosphorylated iminophosphorane-phosphine ligands Ph2PCH2P{=NP(=O)(OR)2}Ph2 (R=Et, Ph): application to the catalytic synthesis of 2,3-dimethylfuran.

scientific article published on 10 October 2006

Synthesis, Structural Authentication, and Structurally Defined Metalation Reactions of Lithium and Sodium DA-Zincate Bases (DA = diisopropylamide) with Phenylacetylene†

article

Synthesis, reactivity and catalytic activity in transfer hydrogenation of ketones of ruthenium(ii) and ruthenium(iv) complexes containing the novel N-thiophosphorylated iminophosphorane-phosphine ligands Ph2PCH2P{NP(S)(OR)2}Ph2(R = Et, Ph)

scholarly article by Victorio Cadierno et al published 2003 in Dalton Transactions

The Future of Polar Organometallic Chemistry Written in Bio-Based Solvents and Water

scientific article published on 20 September 2018

Transamination chemistry of sodium TMP-zincate: synthesis and crystal structure of a chiral amidozincate.

scientific article

Ultrafast amidation of esters using lithium amides under aerobic ambient temperature conditions in sustainable solvents

scientific article published on 30 April 2020

s-Block cooperative catalysis: alkali metal magnesiate-catalysed cyclisation of alkynols

scientific article published on 14 May 2019

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