List of works - Tsuneomi Kawasaki

A reversal phenomenon of enantioface selectivity by the cooperative operation of two chiral catalysts

scientific article published on 22 March 2011

Absolute asymmetric Strecker synthesis in a mixed aqueous medium: reliable access to enantioenriched α-aminonitrile

scientific article published on 01 January 2019

Absolute chirality of the γ-polymorph of glycine: correlation of the absolute structure with the optical rotation

scientific article published on 11 May 2012

Achiral Inorganic Gypsum Acts as an Origin of Chirality through Its Enantiotopic Surface in Conjunction with Asymmetric Autocatalysis

scientific article published in December 2016

Achiral amino acid glycine acts as an origin of homochirality in asymmetric autocatalysis

scientific article published on 01 April 2019

Achiral nucleobase cytosine acts as an origin of homochirality of biomolecules in conjunction with asymmetric autocatalysis

scientific article published in January 2008

Asymmetric Induction by a Nitrogen (14) N/(15) N Isotopomer in Conjunction with Asymmetric Autocatalysis

scientific article (publication date: 5 December 2016)

Asymmetric Strecker Reaction Arising from the Molecular Orientation of an Achiral Imine at the Single-Crystal Face: Enantioenriched l- and d-Amino Acids

scientific article

Asymmetric autocatalysis induced by chiral crystals of achiral tetraphenylethylenes.

scientific article published on 13 November 2009

Asymmetric autocatalysis induced by cinnabar: observation of the enantioselective adsorption of a 5-pyrimidyl alkanol on the crystal surface.

scientific article published on 23 July 2013

Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality.

scientific article published on 24 June 2009

Asymmetric autocatalysis initiated by achiral nucleic acid base adenine: implications on the origin of homochirality of biomolecules

scientific article published on 01 November 2012

Asymmetric autocatalysis of pyrimidyl alkanol and its application to the study on the origin of homochirality

scientific article published on 19 November 2014

Asymmetric autocatalysis triggered by carbon isotope (13C/12C) chirality.

scientific article

Asymmetric autocatalysis triggered by oxygen isotopically chiral glycerin.

scientific article published in May 2013

Asymmetric autocatalysis: triggered by chiral isotopomer arising from oxygen isotope substitution

scientific article published on 14 July 2011

Crystal Structure of the Isopropylzinc Alkoxide of Pyrimidyl Alkanol: Mechanistic Insights for Asymmetric Autocatalysis with Amplification of Enantiomeric Excess

scientific article

Discovery of asymmetric autocatalysis with amplification of chirality and its implication in chiral homogeneity of biomolecules

scientific article published on 01 August 2006

Enantioselective C-C bond formation as a result of the oriented prochirality of an achiral aldehyde at the single-crystal face upon treatment with a dialkyl zinc vapor.

scientific article

Enantioselective synthesis induced by chiral crystal composed of DL-serine in conjunction with asymmetric autocatalysis

scientific article published on 24 March 2011

Enantioselective synthesis mediated by chiral crystal of achiral hippuric acid in conjunction with asymmetric autocatalysis

scientific article published on 21 March 2006

Enantioselective synthesis of near enantiopure compound by asymmetric autocatalysis triggered by asymmetric photolysis with circularly polarized light

scientific article published on 01 March 2005

Enantioselective synthesis utilizing enantiomorphous organic crystal of achiral benzils as a source of chirality in asymmetric autocatalysis

scientific article published on 23 August 2008

Five-State Molecular Shuttling of a Pair of [2]Rotaxanes: Distinct Outputs in Response to Acid and Base Stimuli

scientific article published on 29 June 2016

Five-state molecular switching of a [3]rotaxane in response to weak and strong acid and base stimuli

scientific article published in December 2013

Formation of [2]- and [3]Rotaxanes through Bridging under Kinetic and Thermodynamic Control

scientific article published on 28 December 2017

Formation of enantioenriched alkanol with stochastic distribution of enantiomers in the absolute asymmetric synthesis under heterogeneous solid-vapor phase conditions

scientific article published on 10 April 2019

Four-State Molecular Shuttling of [2]Rotaxanes in Response to Acid/Base and Alkali-Metal Cation Stimuli

scientific article published on 13 April 2017

Generation of absolute controlled crystal chirality by the removal of crystal water from achiral crystal of nucleobase cytosine.

scientific article

Helical mesoporous silica as an inorganic heterogeneous chiral trigger for asymmetric autocatalysis with amplification of enantiomeric excess

scientific article published on 01 May 2015

Highly Stereoselective Strecker Synthesis Induced by a Slight Modification of Benzhydrylamine from Achiral to Chiral

scientific article

Point-to-Point Ultra-Remote Asymmetric Control with Flexible Linker

scientific article published in November 2016

Replication of α-amino acids via Strecker synthesis with amplification and multiplication of chiral intermediate aminonitriles

scientific article

Self-replication and amplification of enantiomeric excess of chiral multifunctionalized large molecules by asymmetric autocatalysis

scientific article published on 4 September 2014

Small amounts of achiral beta-amino alcohols reverse the enantioselectivity of chiral catalysts in cooperative asymmetric autocatalysis

scientific article

Spontaneous absolute asymmetric synthesis in the presence of achiral silica gel in conjunction with asymmetric autocatalysis

scientific article published on 01 August 2006

Spontaneous formation and amplification of an enantioenriched α-amino nitrile: a chiral precursor for Strecker amino acid synthesis

scientific article published on 13 August 2015

Synthesis of a Chiral [2]Rotaxane: Induction of a Helical Structure through Double Threading

scientific article published on 30 July 2018

The origins of homochirality examined by using asymmetric autocatalysis

scientific article published on 22 January 2014

List of works by Tsuneomi Kawasaki

A reversal phenomenon of enantioface selectivity by the cooperative operation of two chiral catalysts

Absolute asymmetric Strecker synthesis in a mixed aqueous medium: reliable access to enantioenriched α-aminonitrile

Absolute chirality of the γ-polymorph of glycine: correlation of the absolute structure with the optical rotation

Achiral Inorganic Gypsum Acts as an Origin of Chirality through Its Enantiotopic Surface in Conjunction with Asymmetric Autocatalysis

Achiral amino acid glycine acts as an origin of homochirality in asymmetric autocatalysis

Achiral nucleobase cytosine acts as an origin of homochirality of biomolecules in conjunction with asymmetric autocatalysis

Asymmetric Induction by a Nitrogen (14) N/(15) N Isotopomer in Conjunction with Asymmetric Autocatalysis

Asymmetric Strecker Reaction Arising from the Molecular Orientation of an Achiral Imine at the Single-Crystal Face: Enantioenriched l- and d-Amino Acids

Asymmetric autocatalysis induced by chiral crystals of achiral tetraphenylethylenes.

Asymmetric autocatalysis induced by cinnabar: observation of the enantioselective adsorption of a 5-pyrimidyl alkanol on the crystal surface.

Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality.

Asymmetric autocatalysis initiated by achiral nucleic acid base adenine: implications on the origin of homochirality of biomolecules

Asymmetric autocatalysis of pyrimidyl alkanol and its application to the study on the origin of homochirality

Asymmetric autocatalysis triggered by carbon isotope (13C/12C) chirality.

Asymmetric autocatalysis triggered by oxygen isotopically chiral glycerin.

Asymmetric autocatalysis: triggered by chiral isotopomer arising from oxygen isotope substitution

Crystal Structure of the Isopropylzinc Alkoxide of Pyrimidyl Alkanol: Mechanistic Insights for Asymmetric Autocatalysis with Amplification of Enantiomeric Excess

Discovery of asymmetric autocatalysis with amplification of chirality and its implication in chiral homogeneity of biomolecules

Enantioselective C-C bond formation as a result of the oriented prochirality of an achiral aldehyde at the single-crystal face upon treatment with a dialkyl zinc vapor.

Enantioselective synthesis induced by chiral crystal composed of DL-serine in conjunction with asymmetric autocatalysis

Enantioselective synthesis mediated by chiral crystal of achiral hippuric acid in conjunction with asymmetric autocatalysis

Enantioselective synthesis of near enantiopure compound by asymmetric autocatalysis triggered by asymmetric photolysis with circularly polarized light

Enantioselective synthesis utilizing enantiomorphous organic crystal of achiral benzils as a source of chirality in asymmetric autocatalysis

Five-State Molecular Shuttling of a Pair of [2]Rotaxanes: Distinct Outputs in Response to Acid and Base Stimuli

Five-state molecular switching of a [3]rotaxane in response to weak and strong acid and base stimuli

Formation of [2]- and [3]Rotaxanes through Bridging under Kinetic and Thermodynamic Control

Formation of enantioenriched alkanol with stochastic distribution of enantiomers in the absolute asymmetric synthesis under heterogeneous solid-vapor phase conditions

Four-State Molecular Shuttling of [2]Rotaxanes in Response to Acid/Base and Alkali-Metal Cation Stimuli

Generation of absolute controlled crystal chirality by the removal of crystal water from achiral crystal of nucleobase cytosine.

Helical mesoporous silica as an inorganic heterogeneous chiral trigger for asymmetric autocatalysis with amplification of enantiomeric excess

Highly Stereoselective Strecker Synthesis Induced by a Slight Modification of Benzhydrylamine from Achiral to Chiral

Point-to-Point Ultra-Remote Asymmetric Control with Flexible Linker

Replication of α-amino acids via Strecker synthesis with amplification and multiplication of chiral intermediate aminonitriles

Self-replication and amplification of enantiomeric excess of chiral multifunctionalized large molecules by asymmetric autocatalysis

Small amounts of achiral beta-amino alcohols reverse the enantioselectivity of chiral catalysts in cooperative asymmetric autocatalysis

Spontaneous absolute asymmetric synthesis in the presence of achiral silica gel in conjunction with asymmetric autocatalysis

Spontaneous formation and amplification of an enantioenriched α-amino nitrile: a chiral precursor for Strecker amino acid synthesis

Synthesis of a Chiral [2]Rotaxane: Induction of a Helical Structure through Double Threading

The origins of homochirality examined by using asymmetric autocatalysis