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List of works by Sankar Prasad Rath

A Highly Oxidized Cobalt Porphyrin Dimer: Spin Coupling and Stabilization of the Four-Electron Oxidation Product.

scientific article

A Nonempirical Approach for Direct Determination of the Absolute Configuration of 1,2-Diols and Amino Alcohols Using Mg(II)bisporphyrin.

scientific article published on 13 June 2016

A Tunable Cyclic Container: Guest-Induced Conformational Switching, Efficient Guest Exchange, and Selective Isolation of C70 from a Fullerene Mixture

scientific article

A counter ion triggers stabilization of two geometrical isomers of a Ni(ii) dication diradical porphyrin dimer: the role of anion-π interactions

scientific article published on 01 July 2019

A dimanganese(iii) porphyrin dication diradical and its transformation to a μ-hydroxo porphyrin-oxophlorin heterodimer

scientific article published on 01 January 2019

A remarkably bent diiron(III)-μ-hydroxo bisporphyrin: unusual stabilization of two spin states of iron in a single molecular framework

scientific article published on 03 December 2010

An ethane-bridged porphyrin dimer as a model of di-heme proteins: inorganic and bioinorganic perspectives and consequences of heme-heme interactions

scientific article published on 01 October 2015

Axial ligand coordination in sterically strained vanadyl porphyrins: synthesis, structure, and properties.

scientific article published on 30 September 2008

Axial ligand orientations in a distorted porphyrin macrocycle: synthesis, structure, and properties of low-spin bis(imidazole)iron(III) and iron(II) porphyrinates.

scientific article published in March 2010

Axial thiophenolate coordination on diiron(III)bisporphyrin: influence of heme-heme interactions on structure, function and electrochemical properties of the individual heme center

scientific article published on 06 November 2014

Building-up remarkably stable magnesium porphyrin polymers self-assembled via bidentate axial ligands: synthesis, structure, surface morphology, and effect of bridging ligands

scientific article published on 31 August 2012

Complexation of Chiral Zinc(II) Porphyrin Tweezer with Achiral Aliphatic Diamines Revisited: Molecular Dynamics, Electronic CD, and 1H NMR Analysis

scientific article published on 14 August 2019

Complexation of Chiral Zinc(II)Porphyrin Tweezer with Chiral Guests: Control, Discrimination and Rationalization of Supramolecular Chirality

scientific article published on 08 May 2020

Complexation of Chiral Zinc-Porphyrin Tweezer with Achiral Diamines: Induction and Two-Step Inversion of Interporphyrin Helicity Monitored by ECD.

scientific article published on 10 March 2017

Control of spins by ring deformation in a diiron(III)bisporphyrin: reversal of ClO4⁻ and CF3SO3⁻ ligand field strength in the magnetochemical series

scientific article published on 14 March 2011

Controlled generation of highly saddled (porphyrinato)iron(III) iodide, tri-iodide and one-electron oxidized complexes

scientific article published on 01 December 2015

Cyclic Bis-porphyrin-Based Flexible Molecular Containers: Controlling Guest Arrangements and Supramolecular Catalysis by Tuning Cavity Size

scientific article published on 20 March 2017

Cyclic Zinc(II) Bisporphyrin-Based Molecular Switches: Supramolecular Control of Complexation-Mediated Conformational Switching and Photoinduced Electron Transfer

scientific article published on 08 March 2016

Diheme Cytochrome c: Structure-Function Correlation and Effect of Heme-Heme Interactions

scientific article published on 27 August 2018

Diiron(III)-μ-Fluoro Bisporphyrins: Effect of Bridging Ligand on the Metal Spin State

scientific article published on 15 June 2016

Effect of Inter-Porphyrin Distance on Spin-State in Diiron(III) μ-Hydroxo Bisporphyrins.

scientific article published on 24 August 2016

Effect of Two Interacting Rings in Metalloporphyrin Dimers upon Stepwise Oxidations

scientific article published on 17 March 2016

Effect of heme-heme interactions and modulation of metal spins by counter anions in a series of diiron(III)-μ-hydroxo bisporphyrins: unusual stabilization of two different spins in a single molecular framework.

scientific article

Effects of axial pyridine coordination on a saddle-distorted porphyrin macrocycle: stabilization of hexa-coordinated high-spin Fe(III) and air-stable low-spin iron(II) porphyrinates.

scientific article published on 20 May 2010

Efficient complexation of pyrrole-bridged dizinc(II) bisporphyrin with fluorescent probe pyrene: synthesis, structure, and photoinduced singlet-singlet energy transfer

scientific article published on 26 August 2011

Electronic structure of the glyoxalbis(2-hydroxyanil) (gha) ligand in [Co(III)(gha)(PPh3)2]+: radical vs. non-radical states

scientific article published on 9 June 2008

Encapsulation of TCNQ and the acridinium ion within a bisporphyrin cavity: synthesis, structure, and photophysical and HOMO-LUMO-gap-mediated electron-transfer properties

scientific article published on 08 May 2012

Equatorial ligand plane perturbations lead to a spin-state change in an iron(iii) porphyrin dimer

scientific article published on 01 May 2019

Experimental and Theoretical Investigation of a Series of Novel Dimanganese(III) μ-Hydroxo Bisporphyrins: Magneto-Structural Correlation and Effect of Metal Spin on Porphyrin Core Deformation

scientific article

Facile ring opening of iron(III) and iron(II) complexes of meso-amino-octaethylporphyrin by dioxygen.

scientific article

First ruthenium complex of glyoxalbis(N-phenyl)osazone (L(NHPh)H(2)): synthesis, x-ray structure, spectra, and density functional theory calculations of (L(NHPh)H(2))Ru(PPh(3))(2)Cl(2)

scientific article published on 27 June 2007

Formation and Isolation of an Iron-Tripyrrole Complex from Heme Degradation ⬇️

scientific article published on October 22, 2003

Formation of a highly oxidized iron biliverdin complex upon treatment of a five-coordinate verdoheme with dioxygen

scientific article

Heme Cleavage with Remarkable Ease: Paramagnetic Intermediates Formed by Aerobic Oxidation of a Meso-Amino-Substituted Iron Porphyrin ⬇️

scientific article published on April 23, 2003

Hg···Hg···Hg Interaction Stabilizes Unusual Trinuclear Double Sandwich Structure of Mercury(II) Porphyrins

scientific article published on 03 September 2020

Highly enhanced bisignate circular dichroism of ferrocene-bridged Zn(II) bisporphyrin tweezer with extended chiral substrates due to well-matched host-guest system

scientific article published on 12 February 2014

Hydrogen-bonding interactions trigger a spin-flip in iron(III) porphyrin complexes.

scientific article published on 3 February 2015

Hydroxo-bridged diiron(iii) and dimanganese(iii) bisporphyrins: modulation of metal spins by counter anions.

scientific article published on 5 January 2017

Induction and Rationalization of Supramolecular Chirality in the Tweezer-Diamine Complexes: Insights from Experimental and DFT Studies

scientific article

Induction of supramolecular chirality in di-zinc(II) bisporphyrin via tweezer formation: synthesis, structure and rationalization of chirality

scientific article published on 19 March 2012

Induction, control, and rationalization of supramolecular chirogenesis using metalloporphyrin tweezers: a structure-function correlation

scientific article published on 16 July 2020

Intermacrocyclic Interaction Triggers Facile One-Pot Synthesis of a Chlorin-Porphyrin Heterodimer

scientific article

Metal-Center-Driven Supramolecular Chirogenesis in Tweezer Amino Alcohol Complexes: Structural, Spectroscopic, and Theoretical Investigations

scientific article

Metal-coordination-driven mixed ligand binding in supramolecular bisporphyrin tweezers

scientific article published on 01 September 2015

Modulation of metal displacements in a saddle distorted macrocycle: synthesis, structure, and properties of high-spin Fe(III) porphyrins and implications for the hemoproteins

scientific article published on 14 August 2008

Molecule to Supramolecule: Chirality Induction, Inversion, and Amplification in a Mg(II)porphyrin Dimer Templated by Chiral Diols

scientific article published on 26 December 2019

Multiheme proteins: effect of heme-heme interactions

scientific article published on 01 October 2018

Oxidation triggers extensive conjugation and unusual stabilization of two di-heme dication diradical intermediates: role of bridging group for electronic communication.

scientific article

Probing Bis-FeIV MauG: Isolation of Highly Reactive Radical Intermediates.

scientific article published on 7 July 2017

Protonation of an oxo-bridged diiron unit gives two different iron centers: synthesis and structure of a new class of diiron(III)-μ-hydroxo bisporphyrins and the control of spin states by using counterions.

scientific article published on 7 September 2012

Pyramidalization of Gd3N inside a C80 cage. The synthesis and structure of Gd3N@C80.

scientific article published on 16 November 2004

Remarkable Anion-Dependent Spin-State Switching in Diiron(III) μ-Hydroxo Bisporphyrins: What Role do Counterions Play?

scientific article published on 29 September 2016

Remarkably bent, ethane-linked, diiron(III) mu-oxobisporphyrin: synthesis, structure, conformational switching, and photocatalytic oxidation

scientific article published on 16 October 2008

Reversible Binding of Nitric Oxide and Carbon−Carbon Bond Formation in a Meso-hydroxylated Heme ⬇️

scientific article published on October 1, 2003

Silver(III)⋅⋅⋅Silver(III) Interactions that Stabilize the syn Form in a Porphyrin Dimer Upon Oxidation

scientific article published on 31 May 2017

Spin-state ordering in hydroxo-bridged diiron(III)bisporphyrin complexes.

scientific article published on 22 January 2015

Step-wise induction, amplification and inversion of molecular chirality through the coordination of chiral diamines with Zn(II) bisporphyrin

scientific article published on 28 November 2014

Stepwise oxidations of a nickel(ii)-iron(iii) heterobimetallic porphyrin dimer: structure, spectroscopic and theoretical investigation

scientific article published on 10 June 2019

Sugar binding to VO3+. Synthesis and structure of a new mannopyranoside vanadate

scientific article published on 01 April 2000

Supramolecular BODIPY-Zn(II)-bisporphyrin dyad and trinitrofluorenone encapsulated triad as models of antenna-reaction center: synthesis, structure and photophysical properties

scientific article published on 16 July 2013

Switching orientation of two axial imidazole ligands between parallel and perpendicular in low-spin Fe(III) and Fe(II) nonplanar porphyrinates

scientific article published on 22 October 2012

Syn-anti conformational switching in an ethane-bridged Co(II)bisporphyrin induced by external stimuli: effects of inter-macrocyclic interactions, axial ligation and chemical and electrochemical oxidations

scientific article published on 01 February 2014

Synthesis, structure, and properties of a series of chiral tweezer-diamine complexes consisting of an achiral zinc(II) bisporphyrin host and chiral diamine guest: induction and rationalization of supramolecular chirality.

scientific article

Through-Space Spin Coupling in a Silver(II) Porphyrin Dimer upon Stepwise Oxidations: AgII ⋅⋅⋅AgII , AgII ⋅⋅⋅AgIII , and AgIII ⋅⋅⋅AgIII Metallophilic Interactions

scientific article published on 18 July 2019

Transfer and control of molecular chirality in the 1 : 2 host-guest supramolecular complex consisting of Mg(II)bisporphyrin and chiral diols: the effect of H-bonding on the rationalization of chirality

scientific article published on 01 November 2014

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