List of works - David P Mills

A delocalized arene-bridged diuranium single-molecule magnet

scientific article

A double-dysprosocenium single-molecule magnet bound together with neutral ligands

scientific article published on 22 April 2020

A lanthanide-gallium complex stabilized by the N-heterocyclic carbene group.

scientific article published on 6 April 2007

Actinide covalency measured by pulsed electron paramagnetic resonance spectroscopy.

scientific article

An EPR and ENDOR investigation of a series of diazabutadiene-group 13 complexes.

scientific article

Analysis of Lanthanide-Radical Magnetic Interactions in Ce(III) 2,2'-Bipyridyl Complexes

scientific article published on 16 February 2017

Bis-Monophospholyl Dysprosium Cation Showing Magnetic Hysteresis at 48 K

scientific article published on 05 December 2019

Chromium chains as polydentate fluoride ligands for actinides and group IV metals.

scientific article

Complexes of an anionic gallium(I) N-heterocyclic carbene analogue with group 14 element(II) fragments: synthetic, structural and theoretical studies

scientific article published in September 2006

Concomitant Carboxylate and Oxalate Formation From the Activation of CO2 by a Thorium(III) Complex

scientific article published on 7 October 2016

Double Reduction of 4,4'-Bipyridine and Reductive Coupling of Pyridine by Two Thorium(III) Single-Electron Transfers

scientific article published on 23 December 2016

Early metal bis(phosphorus-stabilised)carbene chemistry.

scientific article published on 14 February 2011

Electronic structures of bent lanthanide(III) complexes with two N-donor ligands

scientific article published on 18 September 2019

Flexible coordination of bulky amidinates and guanidinates towards rhodium(I): conversion of kinetic to thermodymanic isomers

scientific article published on 21 July 2008

Heteroleptic Samarium(III) Chalcogenide Complexes: Opportunities for Giant Exchange Coupling in Bridging σ- and π-Radical Lanthanide Dichalcogenides

scientific article published on 18 May 2020

Heteroleptic samarium(iii) halide complexes probed by fluorescence-detected L-edge X-ray absorption spectroscopy

scientific article published on 23 May 2018

Investigation into the Effects of a Trigonal-Planar Ligand Field on the Electronic Properties of Lanthanide(II) Tris(silylamide) Complexes (Ln = Sm, Eu, Tm, Yb).

scientific article published in May 2017

Isolation and electronic structures of derivatized manganocene, ferrocene and cobaltocene anions

scientific article published on 14 December 2020

Lanthanide tri-benzyl complexes: structural variations and useful precursors to phosphorus-stabilised lanthanide carbenes.

scientific article published on 27 August 2009

Light Lanthanide Metallocenium Cations Exhibiting Weak Equatorial Anion Interactions

scientific article published on 13 May 2019

Low coordinate lanthanide(II) complexes supported by bulky guanidinato and amidinato ligands.

scientific article published on 7 January 2010

Molecular magnetic hysteresis at 60 kelvin in dysprosocenium.

scientific article

New vistas in the molecular chemistry of thorium: low oxidation state complexes.

scientific article published on 20 April 2016

Physicochemical Properties of Near-Linear Lanthanide(II) Bis(silylamide) Complexes (Ln = Sm, Eu, Tm, Yb).

scientific article published on 23 May 2016

Polarised covalent thorium(IV)- and uranium(IV)-silicon bonds

scientific article published on 21 September 2020

Reactivity of the uranium(IV) carbene complex [U(BIPM(TMS))(Cl)(μ-Cl)₂Li(THF)₂] (BIPM(TMS) = {C(PPh₂NSiMe₃)₂}) towards carbonyl and heteroallene substrates: metallo-Wittig, adduct formation, C-F bond activation, and [2 + 2]-cycloaddition reactions

scientific article published on 01 October 2014

Salt metathesis routes to homoleptic near-linear Mg(ii) and Ca(ii) bulky bis(silyl)amide complexes.

scientific article published on 24 April 2018

Salt metathesis versus protonolysis routes for the synthesis of silylamide Hauser base (R2NMgX; X = halogen) and amido-Grignard (R2NMgR) complexes

scientific article published on 14 August 2015

Sigma and pi donation in an unsupported uranium-gallium bond

scientific article published on 01 January 2009

Structural Characterization of Lithium and Sodium Bulky Bis(silyl)amide Complexes

scientific article published on 10 May 2018

Studies of hysteresis and quantum tunnelling of the magnetisation in dysprosium(iii) single molecule magnets

scientific article published on 21 May 2019

Synthesis and Electronic Structures of Heavy Lanthanide Metallocenium Cations.

scientific article published on 28 November 2017

Synthesis and characterisation of light lanthanide bis-phospholyl borohydride complexes

scientific article published on 05 May 2020

Synthesis and structural characterisation of group 10 metal(II) gallyl complexes: analogies with platinum diboration catalysts?

scientific article published on 3 July 2008

Synthesis of a Uranium(VI)-Carbene: Reductive Formation of Uranyl(V)-Methanides, Oxidative Preparation of a [R2C═U═O]2+ Analogue of the [O═U═O]2+ Uranyl Ion (R = Ph2PNSiMe3), and Comparison of the Nature of UIV═C, UV═C, and UVI═C Double

scientific article published on 07 June 2012

Synthesis, Structural Characterization, and Theoretical Studies of Complexes of Magnesium and Calcium with Gallium Heterocycles

scientific article published on 01 April 2006

Terbocenium: completing a heavy lanthanide metallocenium cation family with an alternative anion abstraction strategy

scientific article published on 01 August 2018

The first near-linear bis(amide) f-block complex: a blueprint for a high temperature single molecule magnet

scientific article published on 01 January 2015

The inherent single-molecule magnet character of trivalent uranium

scientific article published on 10 February 2013

The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes

scientific article published on 03 February 2017

The nature of the U=C double bond: pushing the stability of high-oxidation-state uranium carbenes to the limit.

scientific article published on 4 April 2013

The reactivity of gallium-(I), -(II) and -(III) heterocycles towards Group 15 substrates: attempts to prepare gallium-terminal pnictinidene complexes

scientific article published on 26 October 2005

Uranium(III)-carbon multiple bonding supported by arene δ-bonding in mixed-valence hexauranium nanometre-scale rings.

scientific article

Uranium-carbon multiple bonding: facile access to the pentavalent uranium carbene [U{C(PPh2NSiMe3)2}(Cl)2(I)] and comparison of U(V)=C and U(IV)=C bonds.

scientific article published on 14 February 2011

White phosphorus activation by a Th(III) complex

scientific article published on 13 January 2016

[U(III) {N(SiMe2 tBu)2 }3 ]: a structurally authenticated trigonal planar actinide complex

scientific article

List of works by David P Mills

A delocalized arene-bridged diuranium single-molecule magnet

A double-dysprosocenium single-molecule magnet bound together with neutral ligands

A lanthanide-gallium complex stabilized by the N-heterocyclic carbene group.

Actinide covalency measured by pulsed electron paramagnetic resonance spectroscopy.

An EPR and ENDOR investigation of a series of diazabutadiene-group 13 complexes.

Analysis of Lanthanide-Radical Magnetic Interactions in Ce(III) 2,2'-Bipyridyl Complexes

Bis-Monophospholyl Dysprosium Cation Showing Magnetic Hysteresis at 48 K

Chromium chains as polydentate fluoride ligands for actinides and group IV metals.

Complexes of an anionic gallium(I) N-heterocyclic carbene analogue with group 14 element(II) fragments: synthetic, structural and theoretical studies

Concomitant Carboxylate and Oxalate Formation From the Activation of CO2 by a Thorium(III) Complex

Double Reduction of 4,4'-Bipyridine and Reductive Coupling of Pyridine by Two Thorium(III) Single-Electron Transfers

Early metal bis(phosphorus-stabilised)carbene chemistry.

Electronic structures of bent lanthanide(III) complexes with two N-donor ligands

Flexible coordination of bulky amidinates and guanidinates towards rhodium(I): conversion of kinetic to thermodymanic isomers

Heteroleptic Samarium(III) Chalcogenide Complexes: Opportunities for Giant Exchange Coupling in Bridging σ- and π-Radical Lanthanide Dichalcogenides

Heteroleptic samarium(iii) halide complexes probed by fluorescence-detected L-edge X-ray absorption spectroscopy

Investigation into the Effects of a Trigonal-Planar Ligand Field on the Electronic Properties of Lanthanide(II) Tris(silylamide) Complexes (Ln = Sm, Eu, Tm, Yb).

Isolation and electronic structures of derivatized manganocene, ferrocene and cobaltocene anions

Lanthanide tri-benzyl complexes: structural variations and useful precursors to phosphorus-stabilised lanthanide carbenes.

Light Lanthanide Metallocenium Cations Exhibiting Weak Equatorial Anion Interactions

Low coordinate lanthanide(II) complexes supported by bulky guanidinato and amidinato ligands.

Molecular magnetic hysteresis at 60 kelvin in dysprosocenium.

New vistas in the molecular chemistry of thorium: low oxidation state complexes.

Physicochemical Properties of Near-Linear Lanthanide(II) Bis(silylamide) Complexes (Ln = Sm, Eu, Tm, Yb).

Polarised covalent thorium(IV)- and uranium(IV)-silicon bonds

Reactivity of the uranium(IV) carbene complex [U(BIPM(TMS))(Cl)(μ-Cl)₂Li(THF)₂] (BIPM(TMS) = {C(PPh₂NSiMe₃)₂}) towards carbonyl and heteroallene substrates: metallo-Wittig, adduct formation, C-F bond activation, and [2 + 2]-cycloaddition reactions

Salt metathesis routes to homoleptic near-linear Mg(ii) and Ca(ii) bulky bis(silyl)amide complexes.

Salt metathesis versus protonolysis routes for the synthesis of silylamide Hauser base (R2NMgX; X = halogen) and amido-Grignard (R2NMgR) complexes

Sigma and pi donation in an unsupported uranium-gallium bond

Structural Characterization of Lithium and Sodium Bulky Bis(silyl)amide Complexes

Studies of hysteresis and quantum tunnelling of the magnetisation in dysprosium(iii) single molecule magnets

Synthesis and Electronic Structures of Heavy Lanthanide Metallocenium Cations.

Synthesis and characterisation of light lanthanide bis-phospholyl borohydride complexes

Synthesis and structural characterisation of group 10 metal(II) gallyl complexes: analogies with platinum diboration catalysts?

Synthesis of a Uranium(VI)-Carbene: Reductive Formation of Uranyl(V)-Methanides, Oxidative Preparation of a [R2C═U═O]2+ Analogue of the [O═U═O]2+ Uranyl Ion (R = Ph2PNSiMe3), and Comparison of the Nature of UIV═C, UV═C, and UVI═C Double

Synthesis, Structural Characterization, and Theoretical Studies of Complexes of Magnesium and Calcium with Gallium Heterocycles

Terbocenium: completing a heavy lanthanide metallocenium cation family with an alternative anion abstraction strategy

The first near-linear bis(amide) f-block complex: a blueprint for a high temperature single molecule magnet

The inherent single-molecule magnet character of trivalent uranium

The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes

The nature of the U=C double bond: pushing the stability of high-oxidation-state uranium carbenes to the limit.

The reactivity of gallium-(I), -(II) and -(III) heterocycles towards Group 15 substrates: attempts to prepare gallium-terminal pnictinidene complexes

Uranium(III)-carbon multiple bonding supported by arene δ-bonding in mixed-valence hexauranium nanometre-scale rings.

Uranium-carbon multiple bonding: facile access to the pentavalent uranium carbene [U{C(PPh2NSiMe3)2}(Cl)2(I)] and comparison of U(V)=C and U(IV)=C bonds.

White phosphorus activation by a Th(III) complex

[U(III) {N(SiMe2 tBu)2 }3 ]: a structurally authenticated trigonal planar actinide complex