List of works - Hirohisa Ohmiya

(Invited, Digital Presentation) Carbocation Generation By Organophotoredox Catalyzed Radical-Polar Crossover

scientific article published in 2022

Allylic cross-coupling using aromatic aldehydes as α-alkoxyalkyl anions

scientific article published on 07 February 2020

Anti-selective vicinal silaboration and diboration of alkynoates through phosphine organocatalysis

scientific article published on 12 February 2015

Asymmetric Catalysis Using Aromatic Aldehydes as Chiral α-Alkoxyalkyl Anions

scientific article published on 20 December 2018

Asymmetric Synthesis of α-Alkylidene-β-Lactams through Copper Catalysis with a Prolinol-Phosphine Chiral Ligand

scientific article published on 01 March 2019

Asymmetric Synthesis of β-Lactams through Copper-Catalyzed Alkyne-Nitrone Coupling with a Prolinol-Phosphine Chiral Ligand.

scientific article

Boracene-based alkylborate enabled Ni/Ir hybrid catalysis

scientific article published on 19 August 2020

Cobalt(diamine)-catalyzed cross-coupling reaction of alkyl halides with arylmagnesium reagents: stereoselective constructions of arylated asymmetric carbons and application to total synthesis of AH13205.

scientific article published in February 2006

Cobalt-catalyzed cross-coupling reactions of alkyl halides with allylic and benzylic Grignard reagents and their application to tandem radical cyclization/cross-coupling reactions.

scientific article published in November 2004

Cobalt-catalyzed regioselective dehydrohalogenation of alkyl halides with dimethylphenylsilylmethylmagnesium chloride

scientific article published on 31 July 2008

Cobalt-catalyzed syn hydrophosphination of alkynes

scientific article published in April 2005

Cobalt-catalyzed trimethylsilylmethylmagnesium-promoted radical alkenylation of alkyl halides: a complement to the Heck reaction

scientific article published in June 2006

Cobalt-mediated cross-coupling reactions of primary and secondary alkyl halides with 1-(trimethylsilyl)ethenyl- and 2-trimethylsilylethynylmagnesium reagents

scientific article published in July 2006

Construction of Methylenecycloheptane Frameworks through 7-Exo-Dig Cyclization of Acetylenic Silyl Enol Ethers Catalyzed by Triethynylphosphine−Gold Complex ⬇️

scientific article published on October 1, 2010

Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Alkylation of Azoles

scientific article published on 09 March 2016

Construction of quaternary stereogenic carbon centers through copper-catalyzed enantioselective allylic cross-coupling with alkylboranes

scientific article published on 25 March 2014

Copper(I)-catalyzed intramolecular hydroalkoxylation of unactivated alkenes

scientific article published on 07 April 2015

Copper-Catalyzed Enantioselective Allyl-Allyl Coupling between Allylic Boronates and Phosphates with a Phenol/N-Heterocyclic Carbene Chiral Ligand

scientific article published on 28 July 2016

Copper-Catalyzed Enantioselective Reductive Cross-Coupling of Aldehydes and Imines

scientific article published on 09 January 2020

Copper-Catalyzed γ-Selective and Stereospecific Allylic Cross-Coupling with Secondary Alkylboranes

scientific article published on 26 May 2015

Copper-catalyzed carboxylation of alkylboranes with carbon dioxide: formal reductive carboxylation of terminal alkenes

scientific article published on 28 January 2011

Copper-catalyzed conjugate additions of alkylboranes to imidazolyl α,β-unsaturated ketones: formal reductive conjugate addition of terminal alkenes

scientific article published on 20 December 2010

Copper-catalyzed enantioselective allylic alkylation of terminal alkyne pronucleophiles.

scientific article

Copper-catalyzed enantioselective allylic substitution with alkylboranes

scientific article published on 31 October 2012

Copper-catalyzed gamma-selective allyl-alkyl coupling between allylic phosphates and alkylboranes

scientific article published on 01 March 2010

Copper-catalyzed gamma-selective and stereospecific allyl-aryl coupling between (Z)-acyclic and cyclic allylic phosphates and arylboronates

scientific article published on 01 May 2010

Copper-catalyzed stereoselective conjugate addition of alkylboranes to alkynoates.

scientific article

Copper-catalyzed γ-selective and stereospecific allylic alkylation of ketene silyl acetals

scientific article published on 28 March 2011

Copper-catalyzed γ-selective and stereospecific direct allylic alkylation of terminal alkynes: synthesis of skipped enynes

scientific article published on 09 April 2013

Cu(I)-catalyzed intramolecular hydroamination of unactivated alkenes bearing a primary or secondary amino group in alcoholic solvents

scientific article published on 01 May 2009

Cyclization of nonterminal alkynic beta-keto esters catalyzed by gold(I) complex with a semihollow, end-capped triethynylphosphine ligand

scientific article published on 16 October 2008

Dehydrative Allylation between Aldehydes and Allylic Alcohols through Synergistic N-Heterocyclic Carbene/Palladium Catalysis

scientific article published on 20 December 2018

Directed ortho borylation of functionalized arenes catalyzed by a silica-supported compact phosphine-iridium system

scientific article

Directed ortho borylation of phenol derivatives catalyzed by a silica-supported iridium complex.

scientific article published on September 2010

Enantiocontrol by assembled attractive interactions in copper-catalyzed asymmetric direct alkynylation of α-ketoesters with terminal alkynes: OH···O/sp3-CH···O two-point hydrogen bonding combined with dispersive attractions.

scientific article published on 28 February 2018

Enantioselective conjugate addition of alkylboranes catalyzed by a copper-N-heterocyclic carbene complex

scientific article published on 13 July 2012

General and functional group-tolerable approach to allenylsilanes by rhodium-catalyzed coupling between propargylic carbonates and a silylboronate

scientific article published on 01 December 2009

General approach to allenes through copper-catalyzed γ-selective and stereospecific coupling between propargylic phosphates and alkylboranes

scientific article published on 04 November 2011

Hydrogenation of hindered ketones catalyzed by a silica-supported compact phosphine-Rh system

scientific article published on 24 September 2008

N-Heterocyclic Carbene (NHC)/Metal Cooperative Catalysis

scientific article published on 13 November 2019

N-Heterocyclic Carbene-Catalyzed Decarboxylative Alkylation of Aldehydes

scientific article published on 22 February 2019

N-Heterocyclic Carbene-Catalyzed Radical Relay Enabling Synthesis of δ-Ketocarbonyls

scientific article published on 27 April 2020

N-Heterocyclic Carbene-Catalyzed Radical Relay Enabling Vicinal Alkylacylation of Alkenes

scientific article published on 28 August 2019

N-heterocyclic carbene ligands in cobalt-catalyzed sequential cyclization/cross-coupling reactions of 6-halo-1-hexene derivatives with Grignard reagents

scientific article published on 16 March 2007

Organophotoredox-Catalyzed Decarboxylative C(sp3)-O Bond Formation

scientific article published on 08 January 2020

Organophotoredox-catalyzed semipinacol rearrangement via radical-polar crossover

scientific article published in 2022

Palladium-catalyzed borylation of sterically demanding aryl halides with a silica-supported compact phosphane ligand

scientific article published on 12 July 2011

Palladium-catalyzed gamma-selective and stereospecific allyl-aryl coupling between allylic acetates and arylboronic acids.

scientific article

Phosphine-Catalyzed Anti-Hydroboration of Internal Alkynes.

scientific article published on 8 March 2018

Phosphine-Catalyzed Vicinal Acylcyanation of Alkynoates

scientific article published on 24 March 2016

Phosphine-Catalyzed anti-Carboboration of Alkynoates with 9-BBN-Based 1,1-Diborylalkanes: Synthesis and Use of Multisubstituted γ-Borylallylboranes.

scientific article published on 23 January 2018

Phosphine-catalyzed anti-carboboration of alkynoates with alkyl-, alkenyl-, and arylboranes

scientific article published on 21 July 2014

Reductive Coupling between Aromatic Aldehydes and Ketones or Imines by Copper Catalysis

scientific article published on 31 January 2019

Reductive umpolung for asymmetric synthesis of chiral α-allenic alcohols

scientific article published on 04 June 2020

Regio- and stereocontrolled introduction of secondary alkyl groups to electron-deficient arenes through copper-catalyzed allylic alkylation

scientific article published on 13 March 2012

Regio- and stereoselective approach to 1,2-di- and 1,1,2-trisilylethenes by cobalt-mediated reaction of silyl-substituted dibromomethanes with silylmethylmagnesium reagents

scientific article published in May 2005

Reversible 1,3-anti/syn-stereochemical courses in copper-catalyzed γ-selective allyl-alkyl coupling between chiral allylic phosphates and alkylboranes

scientific article published on 16 May 2012

Rh-catalyzed borylation of N-adjacent C(sp3)-H bonds with a silica-supported triarylphosphine ligand

scientific article published on 26 July 2012

Rh-catalyzed ortho-selective C-H borylation of N-functionalized arenes with silica-supported bridgehead monophosphine ligands

scientific article published on 11 November 2011

Silver-catalyzed benzylation and allylation reactions of tertiary and secondary alkyl halides with grignard reagents

scientific article published on 02 February 2008

Sulfonamidoquinoline/palladium(II)-dimer complex as a catalyst precursor for palladium-catalyzed γ-selective and stereospecific allyl-aryl coupling reaction between allylic acetates and arylboronic acids

scientific article published on 24 November 2010

Synergistic N-Heterocyclic Carbene/Palladium-Catalyzed Reactions of Aldehyde Acyl Anions with either Diarylmethyl or Allylic Carbonates

scientific article published on 23 January 2018

Synergistic palladium/copper-catalyzed Csp3-Csp2 cross-couplings using aldehydes as latent α-alkoxyalkyl anion equivalents

scientific article published on 16 February 2018

Synthesis of 1,1-Diborylalkenes through a Brønsted Base Catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron

scientific article published on 13 November 2015

Synthesis of alpha-arylated allylsilanes through palladium-catalyzed gamma-selective allyl-aryl coupling.

scientific article

Synthesis of conjugated allenes through copper-catalyzed γ-selective and stereospecific coupling between propargylic phosphates and aryl- or alkenylboronates

scientific article published on 18 January 2012

Synthesis of trisubstituted alkenylstannanes through copper-catalyzed three-component coupling of alkylboranes, alkynoates, and tributyltin methoxide.

scientific article published on 5 September 2013

Synthesis of α-Quaternary Formimides and Aldehydes through Umpolung Asymmetric Copper Catalysis with Isocyanides.

scientific article

List of works by Hirohisa Ohmiya

(Invited, Digital Presentation) Carbocation Generation By Organophotoredox Catalyzed Radical-Polar Crossover

Allylic cross-coupling using aromatic aldehydes as α-alkoxyalkyl anions

Anti-selective vicinal silaboration and diboration of alkynoates through phosphine organocatalysis

Asymmetric Catalysis Using Aromatic Aldehydes as Chiral α-Alkoxyalkyl Anions

Asymmetric Synthesis of α-Alkylidene-β-Lactams through Copper Catalysis with a Prolinol-Phosphine Chiral Ligand

Asymmetric Synthesis of β-Lactams through Copper-Catalyzed Alkyne-Nitrone Coupling with a Prolinol-Phosphine Chiral Ligand.

Boracene-based alkylborate enabled Ni/Ir hybrid catalysis

Cobalt(diamine)-catalyzed cross-coupling reaction of alkyl halides with arylmagnesium reagents: stereoselective constructions of arylated asymmetric carbons and application to total synthesis of AH13205.

Cobalt-catalyzed cross-coupling reactions of alkyl halides with allylic and benzylic Grignard reagents and their application to tandem radical cyclization/cross-coupling reactions.

Cobalt-catalyzed regioselective dehydrohalogenation of alkyl halides with dimethylphenylsilylmethylmagnesium chloride

Cobalt-catalyzed syn hydrophosphination of alkynes

Cobalt-catalyzed trimethylsilylmethylmagnesium-promoted radical alkenylation of alkyl halides: a complement to the Heck reaction

Cobalt-mediated cross-coupling reactions of primary and secondary alkyl halides with 1-(trimethylsilyl)ethenyl- and 2-trimethylsilylethynylmagnesium reagents

Construction of Methylenecycloheptane Frameworks through 7-Exo-Dig Cyclization of Acetylenic Silyl Enol Ethers Catalyzed by Triethynylphosphine−Gold Complex ⬇️

Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Alkylation of Azoles

Construction of quaternary stereogenic carbon centers through copper-catalyzed enantioselective allylic cross-coupling with alkylboranes

Copper(I)-catalyzed intramolecular hydroalkoxylation of unactivated alkenes

Copper-Catalyzed Enantioselective Allyl-Allyl Coupling between Allylic Boronates and Phosphates with a Phenol/N-Heterocyclic Carbene Chiral Ligand

Copper-Catalyzed Enantioselective Reductive Cross-Coupling of Aldehydes and Imines

Copper-Catalyzed γ-Selective and Stereospecific Allylic Cross-Coupling with Secondary Alkylboranes

Copper-catalyzed carboxylation of alkylboranes with carbon dioxide: formal reductive carboxylation of terminal alkenes

Copper-catalyzed conjugate additions of alkylboranes to imidazolyl α,β-unsaturated ketones: formal reductive conjugate addition of terminal alkenes

Copper-catalyzed enantioselective allylic alkylation of terminal alkyne pronucleophiles.

Copper-catalyzed enantioselective allylic substitution with alkylboranes

Copper-catalyzed gamma-selective allyl-alkyl coupling between allylic phosphates and alkylboranes

Copper-catalyzed gamma-selective and stereospecific allyl-aryl coupling between (Z)-acyclic and cyclic allylic phosphates and arylboronates

Copper-catalyzed stereoselective conjugate addition of alkylboranes to alkynoates.

Copper-catalyzed γ-selective and stereospecific allylic alkylation of ketene silyl acetals

Copper-catalyzed γ-selective and stereospecific direct allylic alkylation of terminal alkynes: synthesis of skipped enynes

Cu(I)-catalyzed intramolecular hydroamination of unactivated alkenes bearing a primary or secondary amino group in alcoholic solvents

Cyclization of nonterminal alkynic beta-keto esters catalyzed by gold(I) complex with a semihollow, end-capped triethynylphosphine ligand

Dehydrative Allylation between Aldehydes and Allylic Alcohols through Synergistic N-Heterocyclic Carbene/Palladium Catalysis

Directed ortho borylation of functionalized arenes catalyzed by a silica-supported compact phosphine-iridium system

Directed ortho borylation of phenol derivatives catalyzed by a silica-supported iridium complex.

Enantiocontrol by assembled attractive interactions in copper-catalyzed asymmetric direct alkynylation of α-ketoesters with terminal alkynes: OH···O/sp3-CH···O two-point hydrogen bonding combined with dispersive attractions.

Enantioselective conjugate addition of alkylboranes catalyzed by a copper-N-heterocyclic carbene complex

General and functional group-tolerable approach to allenylsilanes by rhodium-catalyzed coupling between propargylic carbonates and a silylboronate

General approach to allenes through copper-catalyzed γ-selective and stereospecific coupling between propargylic phosphates and alkylboranes

Hydrogenation of hindered ketones catalyzed by a silica-supported compact phosphine-Rh system

N-Heterocyclic Carbene (NHC)/Metal Cooperative Catalysis

N-Heterocyclic Carbene-Catalyzed Decarboxylative Alkylation of Aldehydes

N-Heterocyclic Carbene-Catalyzed Radical Relay Enabling Synthesis of δ-Ketocarbonyls

N-Heterocyclic Carbene-Catalyzed Radical Relay Enabling Vicinal Alkylacylation of Alkenes

N-heterocyclic carbene ligands in cobalt-catalyzed sequential cyclization/cross-coupling reactions of 6-halo-1-hexene derivatives with Grignard reagents

Organophotoredox-Catalyzed Decarboxylative C(sp3)-O Bond Formation

Organophotoredox-catalyzed semipinacol rearrangement via radical-polar crossover

Palladium-catalyzed borylation of sterically demanding aryl halides with a silica-supported compact phosphane ligand

Palladium-catalyzed gamma-selective and stereospecific allyl-aryl coupling between allylic acetates and arylboronic acids.

Phosphine-Catalyzed Anti-Hydroboration of Internal Alkynes.

Phosphine-Catalyzed Vicinal Acylcyanation of Alkynoates

Phosphine-Catalyzed anti-Carboboration of Alkynoates with 9-BBN-Based 1,1-Diborylalkanes: Synthesis and Use of Multisubstituted γ-Borylallylboranes.

Phosphine-catalyzed anti-carboboration of alkynoates with alkyl-, alkenyl-, and arylboranes

Reductive Coupling between Aromatic Aldehydes and Ketones or Imines by Copper Catalysis

Reductive umpolung for asymmetric synthesis of chiral α-allenic alcohols

Regio- and stereocontrolled introduction of secondary alkyl groups to electron-deficient arenes through copper-catalyzed allylic alkylation

Regio- and stereoselective approach to 1,2-di- and 1,1,2-trisilylethenes by cobalt-mediated reaction of silyl-substituted dibromomethanes with silylmethylmagnesium reagents

Reversible 1,3-anti/syn-stereochemical courses in copper-catalyzed γ-selective allyl-alkyl coupling between chiral allylic phosphates and alkylboranes

Rh-catalyzed borylation of N-adjacent C(sp3)-H bonds with a silica-supported triarylphosphine ligand

Rh-catalyzed ortho-selective C-H borylation of N-functionalized arenes with silica-supported bridgehead monophosphine ligands

Silver-catalyzed benzylation and allylation reactions of tertiary and secondary alkyl halides with grignard reagents

Sulfonamidoquinoline/palladium(II)-dimer complex as a catalyst precursor for palladium-catalyzed γ-selective and stereospecific allyl-aryl coupling reaction between allylic acetates and arylboronic acids

Synergistic N-Heterocyclic Carbene/Palladium-Catalyzed Reactions of Aldehyde Acyl Anions with either Diarylmethyl or Allylic Carbonates

Synergistic palladium/copper-catalyzed Csp3-Csp2 cross-couplings using aldehydes as latent α-alkoxyalkyl anion equivalents

Synthesis of 1,1-Diborylalkenes through a Brønsted Base Catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron

Synthesis of alpha-arylated allylsilanes through palladium-catalyzed gamma-selective allyl-aryl coupling.

Synthesis of conjugated allenes through copper-catalyzed γ-selective and stereospecific coupling between propargylic phosphates and aryl- or alkenylboronates

Synthesis of trisubstituted alkenylstannanes through copper-catalyzed three-component coupling of alkylboranes, alkynoates, and tributyltin methoxide.

Synthesis of α-Quaternary Formimides and Aldehydes through Umpolung Asymmetric Copper Catalysis with Isocyanides.