List of works - Rita Delgado

1-Oxa-4,8,12-triazacyclotetradecane-4,12-diacetic acid (H2L2): studies on protonation and metal complexation; crystal structure of [CuL2]·5H2O

13- and 14-membered macrocyclic ligands containing methylcarboxylate or methylphosphonate pendant arms: chemical and biological evaluation of their (153)Sm and (166)Ho complexes as potential agents for therapy or bone pain palliation

scientific article published on 4 January 2006

153Sm and 166Ho complexes with tetraaza macrocycles containing pyridine and methylcarboxylate or methylphosphonate pendant arms

scientific article published on 28 August 2004

A polyoxapolyaza macrobicyclic receptor for the recognition of zwitterions.

scientific article published on 26 June 2012

Anion recognition by a macrobicycle based on a tetraoxadiaza macrocycle and an isophthalamide head unit

scientific article

Bis- and tris-(3-aminopropyl) derivatives of 14-membered tetraazamacrocycles containing pyridine: synthesis, protonation and complexation studies

scientific article published on 26 June 2006

Bis[1,1′-N,N′-(2-picolyl)aminomethyl]ferrocene as a redox sensor for transition metal ions

scientific article published on 07 May 2004

Carboxylate anions binding and sensing by a novel tetraazamacrocycle containing ferrocene as receptor.

scientific article

Copper(II) Complexes of Phenanthroline and Histidine Containing Ligands: Synthesis, Characterization and Evaluation of their DNA Cleavage and Cytotoxic Activity

scientific article published on 7 November 2016

Copper(II) and gallium(III) complexes of trans-bis(2-hydroxybenzyl) cyclen derivatives: absence of a cross-bridge proves surprisingly more favorable.

scientific article published on 22 April 2014

Cyclam derivatives containing three acetate pendant arms: synthesis, acid-base, metal complexation and structural studies

scientific article

Cyclams with Ambidentate Methylthiazolyl Pendants for Stable, Inert, and Selective Cu(II) Coordination.

scientific article published on 23 December 2015

Cyclen derivatives with two trans-methylnitrophenolic pendant arms: a structural study of their copper(II) and zinc(II) complexes.

scientific article published on 18 January 2013

Design of protonated polyazamacrocycles based on phenanthroline motifs for selective uptake of aromatic carboxylate anions and herbicides.

scientific article published in January 2009

Di- versus Trinuclear Copper(II) Cryptate for the Uptake of Dicarboxylate Anions

scientific article published on 29 June 2016

Dicarboxylate Recognition by Two Macrobicyclic Receptors: Selectivity for Fumarate over Maleate ⬇️

scientific article published on May 2, 2012

Dicarboxylate recognition properties of a dinuclear copper(II) cryptate.

scientific article published on 8 December 2014

Dicopper(ii) complexes of a new di-para-xylyldioxatetraazamacrocycle and cascade species with dicarboxylate anions: thermodynamics and structural properties

scientific article published on 01 June 2007

Dimetallic complexes of macrocycles with two rigid dibenzofuran units as receptors for detection of anionic substrates.

scientific article published on 3 September 2010

Dinuclear Zinc(II) Macrocyclic Complex as Receptor for Selective Fluorescence Sensing of Pyrophosphate.

scientific article published on 12 February 2016

Dioxadiaza- and trioxadiaza-macrocycles containing one dibenzofuran unit selective for cadmium

scientific article published on 23 August 2006

Dioxatriazamacrocycle-N,N′,N″-triacetic Acids: Synthesis, Protonation Constants, and Metal-Complex Studies. Crystal Structure of Hydrogen [1,4-Dioxa-7,10,13-triazacyclopentadecane-7,10,13-triacetato(4)-κN7,κN11,κN13,κO7]copper(1 -) Hydrate (2

Effect of the Peptidic Scaffold in Copper(II) Coordination and the Redox Properties of Short Histidine-Containing Peptides

scientific article published on 28 July 2015

Electron spin resonance studies and crystal structures of copper(II) complexes of some 12-, 13- and 14-membered oxatriaza macrocycles

Exploring Mycobacterium avium inhibition by macrocyclic compounds.

scientific article

H2Me-do2pa: an attractive chelator with fast, stable and inert natBi3+ and 213Bi3+ complexation for potential α-radioimmunotherapy applications

scientific article published on 01 October 2014

Harnessing the flexibility of peptidic scaffolds to control their copper(II)-coordination properties: a potentiometric and spectroscopic study

scholarly article by Ana Fragoso et al published 4 February 2013 in Chemistry—A European Journal

Homo-and heterodinuclear complexes of the tris(catecholamide) derivative of a tetraazamacrocycle with Fe3+, Cu2+ and Zn2+ metal ions.

scientific article

Improving the stability and inertness of Cu(ii) and Cu(i) complexes with methylthiazolyl ligands by tuning the macrocyclic structure.

scientific article

In vitro effect of free and complexed indium(III) against Mycobacterium tuberculosis.

scientific article published on October 2005

Inhibition of the STAT3 Protein by a Dinuclear Macrocyclic Complex.

scientific article published on 21 March 2016

Investigating the Complexation of the Pb2+/Bi3+ Pair with Dipicolinate Cyclen Ligands

scientific article published on 06 July 2015

Metal Complexes of an Oxatriaza Macrocycle Containing Pyridine: Thermodynamic Stability and Structural Studies

Metal complexes of cyclen and cyclam derivatives useful for medical applications: a discussion based on thermodynamic stability constants and structural data

scientific article

Methylthiazolyl Tacn Ligands for Copper Complexation and Their Bifunctional Chelating Agent Derivatives for Bioconjugation and Copper-64 Radiolabeling: An Example with Bombesin

scientific article published on 28 January 2019

Mn2+, Co2+, Cu2+ and Zn2+complexes with two macrocyclic ligands bearing l-lactate-like functions: potentiometric studies and evaluation of superoxide-scavenging properties of the Mn2+ complex

scientific article published on 01 July 2000

Monitoring inorganic pyrophosphatase activity with the fluorescent dizinc(ii) complex of a macrocycle bearing one dansylamidoethyl antenna

scientific article published on 01 July 2020

Monopicolinate cross-bridged cyclam combining very fast complexation with very high stability and inertness of its copper(II) complex

scientific article published on 23 April 2014

Monopicolinate-dipicolyl Derivative of Triazacyclononane for Stable Complexation of Cu2+ and 64Cu2+

scientific article published on 12 April 2013

New dioxadiaza- and trioxadiaza-macrocycles containing one dibenzofuran unit with two amino pendant arms: synthesis, protonation and complexation studies

scientific article published on 15 February 2007

Phosphate and polyphosphate anion recognition by a dinuclear copper(ii) complex of an unsymmetrical squaramide

scientific article published on 10 June 2019

Polyamide-Polyamine Cryptand as Dicarboxylate Receptor: Dianion Binding Studies in the Solid State, in Solution, and in the Gas Phase.

scientific article

Polyaza cryptand receptor selective for dihydrogen phosphate

scientific article

Properties of a new 4-imidazolyl derivative of a 14-membered tetraazamacrocyclic chelating agent.

scientific article published on 7 September 2007

Radiopharmaceuticals for targeted radiotherapy

scientific article published on 01 January 2005

Reasons behind the Relative Abundances of Heptacoordinate Complexes along the Late First-Row Transition Metal Series

scientific article published on 21 November 2014

Recognition of Oxalate by a Copper(II) Polyaza Macrobicyclic Complex

scientific article published on 06 May 2011

Recognition of phosphopeptides by a dinuclear copper(ii) macrocyclic complex in a water : methanol 50 : 50 v/v solution.

scientific article published on 12 July 2017

Redox method for the determination of stability constants of some trivalent metal complexes

scientific article published on 01 December 1997

Remarkable Inertness of Copper(II) Chelates of Cyclen-Based Macrobicycles with Two trans-N-Acetate Arms

scientific article published on 11 April 2013

Selective recognition of tetrahedral dianions by a hexaaza cryptand receptor.

scientific article

Steric Effects on the Binding of Phosphate and Polyphosphate Anions by Zinc(II) and Copper(II) Dinuclear Complexes of m-Xylyl-bis-cyclen

scientific article published on 11 May 2018

Structure, Characterization, and Metal-Complexation Properties of a New Tetraazamacrocycle Containing Two Phenolic Pendant Arms

Sulfate recognition by a hexaaza cryptand receptor

scientific article published on 01 January 2015

Supramolecular aggregates between carboxylate anions and an octaaza macrocyclic receptor.

scientific article published on 14 September 2004

TETA analogue containing one methylenephosphonate pendant arm: Lanthanide complexes and biological evaluation of its 153Sm and 166Ho complexes.

scientific article published on 17 September 2010

The role of methylation in the copper(ii) coordination properties of a His-containing decapeptide

scientific article published on 16 January 2019

The stability of the metal complexes of cyclic tetra-aza tetra-acetic acids

scientific article published on 01 March 1992

Two macrocyclic pentaaza compounds containing pyridine evaluated as novel chelating agents in copper(II) and nickel(II) overload.

scientific article published on 13 December 2010

Water encapsulation in a polyoxapolyaza macrobicyclic compound.

scientific article

Zinc(II) and copper(II) complexes as tools to monitor/inhibit protein phosphorylation events

scientific article published on 12 November 2020

endo- versus exo-Cyclic coordination in copper complexes with methylthiazolylcarboxylate tacn derivatives

scientific article published on 30 May 2019

trans-Methylpyridine cyclen versus cross-bridged trans-methylpyridine cyclen. Synthesis, acid-base and metal complexation studies (metal = Co2+, Cu2+, and Zn2+).

scientific article

List of works by Rita Delgado

1-Oxa-4,8,12-triazacyclotetradecane-4,12-diacetic acid (H2L2): studies on protonation and metal complexation; crystal structure of [CuL2]·5H2O

13- and 14-membered macrocyclic ligands containing methylcarboxylate or methylphosphonate pendant arms: chemical and biological evaluation of their (153)Sm and (166)Ho complexes as potential agents for therapy or bone pain palliation

153Sm and 166Ho complexes with tetraaza macrocycles containing pyridine and methylcarboxylate or methylphosphonate pendant arms

A polyoxapolyaza macrobicyclic receptor for the recognition of zwitterions.

Anion recognition by a macrobicycle based on a tetraoxadiaza macrocycle and an isophthalamide head unit

Bis- and tris-(3-aminopropyl) derivatives of 14-membered tetraazamacrocycles containing pyridine: synthesis, protonation and complexation studies

Bis[1,1′-N,N′-(2-picolyl)aminomethyl]ferrocene as a redox sensor for transition metal ions

Carboxylate anions binding and sensing by a novel tetraazamacrocycle containing ferrocene as receptor.

Copper(II) Complexes of Phenanthroline and Histidine Containing Ligands: Synthesis, Characterization and Evaluation of their DNA Cleavage and Cytotoxic Activity

Copper(II) and gallium(III) complexes of trans-bis(2-hydroxybenzyl) cyclen derivatives: absence of a cross-bridge proves surprisingly more favorable.

Cyclam derivatives containing three acetate pendant arms: synthesis, acid-base, metal complexation and structural studies

Cyclams with Ambidentate Methylthiazolyl Pendants for Stable, Inert, and Selective Cu(II) Coordination.

Cyclen derivatives with two trans-methylnitrophenolic pendant arms: a structural study of their copper(II) and zinc(II) complexes.

Design of protonated polyazamacrocycles based on phenanthroline motifs for selective uptake of aromatic carboxylate anions and herbicides.

Di- versus Trinuclear Copper(II) Cryptate for the Uptake of Dicarboxylate Anions

Dicarboxylate Recognition by Two Macrobicyclic Receptors: Selectivity for Fumarate over Maleate ⬇️

Dicarboxylate recognition properties of a dinuclear copper(II) cryptate.

Dicopper(ii) complexes of a new di-para-xylyldioxatetraazamacrocycle and cascade species with dicarboxylate anions: thermodynamics and structural properties

Dimetallic complexes of macrocycles with two rigid dibenzofuran units as receptors for detection of anionic substrates.

Dinuclear Zinc(II) Macrocyclic Complex as Receptor for Selective Fluorescence Sensing of Pyrophosphate.

Dioxadiaza- and trioxadiaza-macrocycles containing one dibenzofuran unit selective for cadmium

Dioxatriazamacrocycle-N,N′,N″-triacetic Acids: Synthesis, Protonation Constants, and Metal-Complex Studies. Crystal Structure of Hydrogen [1,4-Dioxa-7,10,13-triazacyclopentadecane-7,10,13-triacetato(4)-κN7,κN11,κN13,κO7]copper(1 -) Hydrate (2

Effect of the Peptidic Scaffold in Copper(II) Coordination and the Redox Properties of Short Histidine-Containing Peptides

Electron spin resonance studies and crystal structures of copper(II) complexes of some 12-, 13- and 14-membered oxatriaza macrocycles

Exploring Mycobacterium avium inhibition by macrocyclic compounds.

H2Me-do2pa: an attractive chelator with fast, stable and inert natBi3+ and 213Bi3+ complexation for potential α-radioimmunotherapy applications

Harnessing the flexibility of peptidic scaffolds to control their copper(II)-coordination properties: a potentiometric and spectroscopic study

Homo-and heterodinuclear complexes of the tris(catecholamide) derivative of a tetraazamacrocycle with Fe3+, Cu2+ and Zn2+ metal ions.

Improving the stability and inertness of Cu(ii) and Cu(i) complexes with methylthiazolyl ligands by tuning the macrocyclic structure.

In vitro effect of free and complexed indium(III) against Mycobacterium tuberculosis.

Inhibition of the STAT3 Protein by a Dinuclear Macrocyclic Complex.

Investigating the Complexation of the Pb2+/Bi3+ Pair with Dipicolinate Cyclen Ligands

Metal Complexes of an Oxatriaza Macrocycle Containing Pyridine: Thermodynamic Stability and Structural Studies

Metal complexes of cyclen and cyclam derivatives useful for medical applications: a discussion based on thermodynamic stability constants and structural data

Methylthiazolyl Tacn Ligands for Copper Complexation and Their Bifunctional Chelating Agent Derivatives for Bioconjugation and Copper-64 Radiolabeling: An Example with Bombesin

Mn2+, Co2+, Cu2+ and Zn2+complexes with two macrocyclic ligands bearing l-lactate-like functions: potentiometric studies and evaluation of superoxide-scavenging properties of the Mn2+ complex

Monitoring inorganic pyrophosphatase activity with the fluorescent dizinc(ii) complex of a macrocycle bearing one dansylamidoethyl antenna

Monopicolinate cross-bridged cyclam combining very fast complexation with very high stability and inertness of its copper(II) complex

Monopicolinate-dipicolyl Derivative of Triazacyclononane for Stable Complexation of Cu2+ and 64Cu2+

New dioxadiaza- and trioxadiaza-macrocycles containing one dibenzofuran unit with two amino pendant arms: synthesis, protonation and complexation studies

Phosphate and polyphosphate anion recognition by a dinuclear copper(ii) complex of an unsymmetrical squaramide

Polyamide-Polyamine Cryptand as Dicarboxylate Receptor: Dianion Binding Studies in the Solid State, in Solution, and in the Gas Phase.

Polyaza cryptand receptor selective for dihydrogen phosphate

Properties of a new 4-imidazolyl derivative of a 14-membered tetraazamacrocyclic chelating agent.

Radiopharmaceuticals for targeted radiotherapy

Reasons behind the Relative Abundances of Heptacoordinate Complexes along the Late First-Row Transition Metal Series

Recognition of Oxalate by a Copper(II) Polyaza Macrobicyclic Complex

Recognition of phosphopeptides by a dinuclear copper(ii) macrocyclic complex in a water : methanol 50 : 50 v/v solution.

Redox method for the determination of stability constants of some trivalent metal complexes

Remarkable Inertness of Copper(II) Chelates of Cyclen-Based Macrobicycles with Two trans-N-Acetate Arms

Selective recognition of tetrahedral dianions by a hexaaza cryptand receptor.

Steric Effects on the Binding of Phosphate and Polyphosphate Anions by Zinc(II) and Copper(II) Dinuclear Complexes of m-Xylyl-bis-cyclen

Structure, Characterization, and Metal-Complexation Properties of a New Tetraazamacrocycle Containing Two Phenolic Pendant Arms

Sulfate recognition by a hexaaza cryptand receptor

Supramolecular aggregates between carboxylate anions and an octaaza macrocyclic receptor.

TETA analogue containing one methylenephosphonate pendant arm: Lanthanide complexes and biological evaluation of its 153Sm and 166Ho complexes.

The role of methylation in the copper(ii) coordination properties of a His-containing decapeptide

The stability of the metal complexes of cyclic tetra-aza tetra-acetic acids

Two macrocyclic pentaaza compounds containing pyridine evaluated as novel chelating agents in copper(II) and nickel(II) overload.

Water encapsulation in a polyoxapolyaza macrobicyclic compound.

Zinc(II) and copper(II) complexes as tools to monitor/inhibit protein phosphorylation events

endo- versus exo-Cyclic coordination in copper complexes with methylthiazolylcarboxylate tacn derivatives

trans-Methylpyridine cyclen versus cross-bridged trans-methylpyridine cyclen. Synthesis, acid-base and metal complexation studies (metal = Co2+, Cu2+, and Zn2+).