List of works - Felipe García

A multi-step solvent-free mechanochemical route to indium(iii) complexes

scientific article published on 26 April 2016

A one-pot synthesis to [(Me3Si)3SiSb]4; a potential precursor for Sb42-

scientific article published on 03 June 2004

An unexpected pathway in the cage opening and aggregation of P4

scientific article published on 01 January 2007

Ansa-tris(allyl) complexes of alkali metals: tripodal analogues of cyclopentadienyl and ansa-metallocene ligands

scientific article published on 4 October 2007

Aryl-NHC-group 13 trimethyl complexes: structural, stability and bonding insights

scientific article published on 21 December 2016

Bay-Region Functionalisation of Ar-BIAN Ligands and Their Use Within Highly Absorptive Cationic Iridium(III) Dyes.

scientific article published on 14 November 2017

Completely Solvent-free Protocols to Access Phase-Pure, Metastable Metal Halide Perovskites and Functional Photodetectors from the Precursor Salts

scientific article published on 03 June 2019

Confinement of halide ions within homologous inverse coordination hosts; modification of halide-ion selectivity

article

Direct synthesis of the 1,2,3-[C6H4P...P...P]- anion, isoelectronic with the indenyl anion [C6H4CH...CH...CH]-.

scientific article published on 15 January 2008

Effective visible light-activated B-doped and B,N-codoped TiO2 photocatalysts

scientific article published on 23 October 2007

Efficient visible light-active N-doped TiO2 photocatalysts by a reproducible and controllable synthetic route

scientific article published on 31 August 2006

Enabling Mitochondrial Uptake of Lipophilic Dications Using Methylated Triphenylphosphonium Moieties

scientific article published on 11 June 2019

Encapsulation of hydride by molecular main group metal clusters: manipulating the source and coordination sphere of the interstitial ion

scientific article published on 18 October 2006

Exo-metal coordination by a tricyclic [(P(mu-N-2-NC5H4))2(mu-O)]2 dimer in [(P(mu-N-2-NC5H4))2(mu-O)]2(CuCl x (C5H5N)2)4 (2-NC5H4 = 2-pyridyl, C5H5N = pyridine).

scientific article

Formation and structure of the [(1,2-C(6)H(4)P(2)Sb)(2)](4-) ion: implications for an extended family of isoelectronic main-group radicals

scientific article published on 01 January 2007

Highly selective epoxidation of styrene using a transition metal-aluminium(III) complex containing the [MeAl(2-py)3]- anion (2-py = 2-pyridyl).

scientific article

Inverse coordination of an ionic lattice by a metal host

scientific article published on 01 September 2005

Main group mechanochemistry

scientific article published on 5 October 2017

Main group mechanochemistry: from curiosity to established protocols

scientific article published on 01 April 2019

Mechanochemical Synthesis of Phosphazane-Based Frameworks.

scientific article

Mixed alkylamido aluminate as a kinetically controlled base

scientific article

Orthogonality in main group compounds: a direct one-step synthesis of air- and moisture-stable cyclophosphazanes by mechanochemistry

scientific article published on 01 June 2018

Pyridyl 'ring-flipping' in the dimers [Me2E(2-py)]2 (E=B, Al, Ga; 2-py=2-pyridyl)

scientific article published on 13 November 2006

Quadruple deprotonation of 2-aminophenylphosphane with a p-block-metal/alkali-metal base

scientific article published in May 2005

Reactions of Sn(NMe2)2 with MPHCy: The Effects of Alkali Metal Phosphide Coupling (Cy=Cyclohexyl; M=Li, Na, K, Rb)

scientific article published on 01 January 2007

Reactions of Sn(NMe2)2with Alkali-Metaltert-ButylphosphidestBuPHM (M = Li, Na, K): Evidence for Metal-Induced Modification of the Tin(II) Phosphinidene Anions

article

Reactions of Sn(NMe2)2with Primary Aryl Phosphides, ArPH-: Synthesis and Structures of the Heteroleptic Cages [{(PhP−PPh)Sn(μ-PPh)}2(Na·PMDETA)4and [{Sn(μ3-Ppy)}3{Sn(μ3,μ1-pyP−Ppy)}3]

Reductive-elimination of phosphide units; the basis of a general approach to a range of alloys and materials

article

Selection of a Pentameric Host in the Host-Guest Complexes {[{[P(μ-NtBu)]2(μ-NH)}5]⋅I}−[Li(thf)4]+and [{[P(μ-NtBu)]2(μ-NH)}5]⋅HBr⋅THF

scientific article published on 01 November 2004

Selection of the cis and trans phosph(iii)azane macrocycles [{P(µ-NtBu)}2(1-Y-2-NH-C6H4)]2(Y = O, S)

scientific article published on 13 April 2005

Selective formation of the [PhP(H)-PPh]- anion in the reaction of PhPHLi with MeAlCl(2); synthesis and structure of the unusual tetramer [(PhP(H)-PPh)Li.thf]4

scientific article published on 08 March 2004

Single- and double-bridged PNP ligands in chromium-catalysed ethylene oligomerisation

scientific article published in 2022

Stepwise nucleophilic substitution of manganocene, syntheses and structures of the dimer [CpMn(hpp)]2 and the unusual manganate cage [LiMn(hpp)3]2 (hppH = 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2,a]pyrimidine)

scientific article published on 15 March 2007

Steric C-N bond activation on the dimeric macrocycle [{P(μ-NR)}2(μ-NR)]2.

scientific article published on 14 September 2015

Steric control in the oligomerisation of phosphazane dimers; towards new phosphorus-nitrogen macrocycles

scientific article published on 09 February 2004

Structural, Solid-State NMR and Theoretical Studies of the Inverse-Coordination of Lithium Chloride Using Group 13 Phosphide Hosts

scientific article published on 01 January 2007

Synthesis and Hydrolytic Studies on the Air-Stable [(4-CN-PhO)(E)P(μ-N(t)Bu)]2 (E = O, S, and Se) Cyclodiphosphazanes

scientific article published on 12 June 2015

Synthesis and Structure of [{Sn2(μ-PMes)3}K2·3THF]∞, Exhibiting Multifunctional Coordination of [Sn2(μ-PMes)3]2-Anions to K+

Synthesis and structure of [[MeAl(mu-PMes)(PMes)]2Li4]2 x 7thf, containing a [MeAl(mu-PMes)(PMes)]2(4-) tetraanion (Mes = 2,4,6-Me3C6H2)

scientific article published on 01 August 2003

Synthesis and structure of the Li13 cage [{[OP(μ-NtBu)]2Li2}3(LiCl)6Li(Cl/OnBu)0.5(thf)7], containing a [OP(μ-NtBu)]22− dianion

article

Synthesis and structure of the calixarene-like phosph(III)azane macrocycle [{P(mu-N(t)Bu)}2{1,5-(NH)2C10H6}]3.

scientific article published on 17 June 2005

Synthesis and the Optical and Electrochemical Properties of Indium(III) Bis(arylimino)acenaphthene Complexes.

scientific article published on 28 June 2017

Synthesis of Unique Phosphazane Macrocycles via Steric Activation of C-N Bonds

scientific article published on 20 August 2018

Synthesis of a deca-lithium cage containing an [(RN)2As(mu-NR)As(NR)2]4- tetraanion; a homologue of group 15 trianions of the type [E(NR)3]3-.

scientific article

Synthesis, structural studies and ligand influence on the stability of aryl-NHC stabilised trimethylaluminium complexes

scientific article published on 27 February 2015

Targeting large phosp(III)azane macrocyles [{P(mu-NR)}(2)(LL)](n) (n> or = 2)

scientific article published on 21 July 2006

Templating and selection in the formation of macrocycles containing [[P(micro-NtBu)(2)](micro-NH)](n) frameworks: observation of halide ion coordination

scientific article published on 01 August 2002

The First Synthesis of the Sterically Encumbered Adamantoid Phosphazane P4 (N(t) Bu)6 : Enabled by Mechanochemistry

scientific article

The cationic cluster Grignard [{MgCl(thf)2}3(μ3-C3H5)2]+

scientific article published on 11 April 2006

The first example of a Si-bridged tris(pyridyl) ligand; synthesis and structure of [MeSi(2-C5H4N)3LiX](X = 0.2Br, 0.8Cl)

scientific article published on 08 January 2004

The folded, tetrameric phosph(III)azane macrocycle [(P(mu-NtBu))2(1,4-(NH)2C6H4)]4.

scientific article

The formation of dimeric phosph(III)azane macrocycles [[P(mu-NtBu)]2.LL]2 [LL = organic spacer]

scientific article published on 13 August 2004

Trapping of oligomeric cyclopentadienyllithium cationic and anionic fragments by a V[triple bond]V-bonded ligand

scientific article published on 01 January 2007

Triphosph(III)azanes to diphosph(III)azanes; a cracking transformation

scientific article published on 04 July 2005

Unique Triphenylphosphonium Derivatives for Enhanced Mitochondrial Uptake and Photodynamic Therapy.

scientific article published on 3 January 2017

pi-Bonding versus oligomerisation in the aromatic anions [C(6)H(4)N(2)E](-): formation of the cyclic tetrameric tetraanion [C(6)H(4)N(2)Sb](4)(4-)

scientific article published on 11 December 2007

thermodynamic/kinetic control in the isomerization of the [[tBuNP(mu-NtBu)]2]2- ion

scientific article published on 01 May 2004

List of works by Felipe García

A multi-step solvent-free mechanochemical route to indium(iii) complexes

A one-pot synthesis to [(Me3Si)3SiSb]4; a potential precursor for Sb42-

An unexpected pathway in the cage opening and aggregation of P4

Ansa-tris(allyl) complexes of alkali metals: tripodal analogues of cyclopentadienyl and ansa-metallocene ligands

Aryl-NHC-group 13 trimethyl complexes: structural, stability and bonding insights

Bay-Region Functionalisation of Ar-BIAN Ligands and Their Use Within Highly Absorptive Cationic Iridium(III) Dyes.

Completely Solvent-free Protocols to Access Phase-Pure, Metastable Metal Halide Perovskites and Functional Photodetectors from the Precursor Salts

Confinement of halide ions within homologous inverse coordination hosts; modification of halide-ion selectivity

Direct synthesis of the 1,2,3-[C6H4P...P...P]- anion, isoelectronic with the indenyl anion [C6H4CH...CH...CH]-.

Effective visible light-activated B-doped and B,N-codoped TiO2 photocatalysts

Efficient visible light-active N-doped TiO2 photocatalysts by a reproducible and controllable synthetic route

Enabling Mitochondrial Uptake of Lipophilic Dications Using Methylated Triphenylphosphonium Moieties

Encapsulation of hydride by molecular main group metal clusters: manipulating the source and coordination sphere of the interstitial ion

Exo-metal coordination by a tricyclic [(P(mu-N-2-NC5H4))2(mu-O)]2 dimer in [(P(mu-N-2-NC5H4))2(mu-O)]2(CuCl x (C5H5N)2)4 (2-NC5H4 = 2-pyridyl, C5H5N = pyridine).

Formation and structure of the [(1,2-C(6)H(4)P(2)Sb)(2)](4-) ion: implications for an extended family of isoelectronic main-group radicals

Highly selective epoxidation of styrene using a transition metal-aluminium(III) complex containing the [MeAl(2-py)3]- anion (2-py = 2-pyridyl).

Inverse coordination of an ionic lattice by a metal host

Main group mechanochemistry

Main group mechanochemistry: from curiosity to established protocols

Mechanochemical Synthesis of Phosphazane-Based Frameworks.

Mixed alkylamido aluminate as a kinetically controlled base

Orthogonality in main group compounds: a direct one-step synthesis of air- and moisture-stable cyclophosphazanes by mechanochemistry

Pyridyl 'ring-flipping' in the dimers [Me2E(2-py)]2 (E=B, Al, Ga; 2-py=2-pyridyl)

Quadruple deprotonation of 2-aminophenylphosphane with a p-block-metal/alkali-metal base

Reactions of Sn(NMe2)2 with MPHCy: The Effects of Alkali Metal Phosphide Coupling (Cy=Cyclohexyl; M=Li, Na, K, Rb)

Reactions of Sn(NMe2)2with Alkali-Metaltert-ButylphosphidestBuPHM (M = Li, Na, K): Evidence for Metal-Induced Modification of the Tin(II) Phosphinidene Anions

Reactions of Sn(NMe2)2with Primary Aryl Phosphides, ArPH-: Synthesis and Structures of the Heteroleptic Cages [{(PhP−PPh)Sn(μ-PPh)}2(Na·PMDETA)4and [{Sn(μ3-Ppy)}3{Sn(μ3,μ1-pyP−Ppy)}3]

Reductive-elimination of phosphide units; the basis of a general approach to a range of alloys and materials

Selection of a Pentameric Host in the Host-Guest Complexes {[{[P(μ-NtBu)]2(μ-NH)}5]⋅I}−[Li(thf)4]+and [{[P(μ-NtBu)]2(μ-NH)}5]⋅HBr⋅THF

Selection of the cis and trans phosph(iii)azane macrocycles [{P(µ-NtBu)}2(1-Y-2-NH-C6H4)]2(Y = O, S)

Selective formation of the [PhP(H)-PPh]- anion in the reaction of PhPHLi with MeAlCl(2); synthesis and structure of the unusual tetramer [(PhP(H)-PPh)Li.thf]4

Single- and double-bridged PNP ligands in chromium-catalysed ethylene oligomerisation

Stepwise nucleophilic substitution of manganocene, syntheses and structures of the dimer [CpMn(hpp)]2 and the unusual manganate cage [LiMn(hpp)3]2 (hppH = 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2,a]pyrimidine)

Steric C-N bond activation on the dimeric macrocycle [{P(μ-NR)}2(μ-NR)]2.

Steric control in the oligomerisation of phosphazane dimers; towards new phosphorus-nitrogen macrocycles

Structural, Solid-State NMR and Theoretical Studies of the Inverse-Coordination of Lithium Chloride Using Group 13 Phosphide Hosts

Synthesis and Hydrolytic Studies on the Air-Stable [(4-CN-PhO)(E)P(μ-N(t)Bu)]2 (E = O, S, and Se) Cyclodiphosphazanes

Synthesis and Structure of [{Sn2(μ-PMes)3}K2·3THF]∞, Exhibiting Multifunctional Coordination of [Sn2(μ-PMes)3]2-Anions to K+

Synthesis and structure of [[MeAl(mu-PMes)(PMes)]2Li4]2 x 7thf, containing a [MeAl(mu-PMes)(PMes)]2(4-) tetraanion (Mes = 2,4,6-Me3C6H2)

Synthesis and structure of the Li13 cage [{[OP(μ-NtBu)]2Li2}3(LiCl)6Li(Cl/OnBu)0.5(thf)7], containing a [OP(μ-NtBu)]22− dianion

Synthesis and structure of the calixarene-like phosph(III)azane macrocycle [{P(mu-N(t)Bu)}2{1,5-(NH)2C10H6}]3.

Synthesis and the Optical and Electrochemical Properties of Indium(III) Bis(arylimino)acenaphthene Complexes.

Synthesis of Unique Phosphazane Macrocycles via Steric Activation of C-N Bonds

Synthesis of a deca-lithium cage containing an [(RN)2As(mu-NR)As(NR)2]4- tetraanion; a homologue of group 15 trianions of the type [E(NR)3]3-.

Synthesis, structural studies and ligand influence on the stability of aryl-NHC stabilised trimethylaluminium complexes

Targeting large phosp(III)azane macrocyles [{P(mu-NR)}(2)(LL)](n) (n> or = 2)

Templating and selection in the formation of macrocycles containing [[P(micro-NtBu)(2)](micro-NH)](n) frameworks: observation of halide ion coordination

The First Synthesis of the Sterically Encumbered Adamantoid Phosphazane P4 (N(t) Bu)6 : Enabled by Mechanochemistry

The cationic cluster Grignard [{MgCl(thf)2}3(μ3-C3H5)2]+

The first example of a Si-bridged tris(pyridyl) ligand; synthesis and structure of [MeSi(2-C5H4N)3LiX](X = 0.2Br, 0.8Cl)

The folded, tetrameric phosph(III)azane macrocycle [(P(mu-NtBu))2(1,4-(NH)2C6H4)]4.

The formation of dimeric phosph(III)azane macrocycles [[P(mu-NtBu)]2.LL]2 [LL = organic spacer]

Trapping of oligomeric cyclopentadienyllithium cationic and anionic fragments by a V[triple bond]V-bonded ligand

Triphosph(III)azanes to diphosph(III)azanes; a cracking transformation

Unique Triphenylphosphonium Derivatives for Enhanced Mitochondrial Uptake and Photodynamic Therapy.

pi-Bonding versus oligomerisation in the aromatic anions [C(6)H(4)N(2)E](-): formation of the cyclic tetrameric tetraanion [C(6)H(4)N(2)Sb](4)(4-)

thermodynamic/kinetic control in the isomerization of the [[tBuNP(mu-NtBu)]2]2- ion