List of works - Marcin Kałek

31P NMR and Computational Studies on Stereochemistry of Conversion of Phosphoramidate Diesters into the Corresponding Phosphotriesters

scientific article published on 01 July 2011

A New Reagent System for Efficient Silylation of Alcohols: Silyl Chloride-N-Methylimidazole-Iodine

A direct method for the synthesis of nucleoside 5′-methylenebis(phosphonate)s from nucleosides

Atom-efficient gold(I)-chloride-catalyzed synthesis of α-sulfenylated carbonyl compounds from propargylic alcohols and aryl thiols: substrate scope and experimental and theoretical mechanistic investigation

scientific article

Caution in the Use of Nonlinear Effects as a Mechanistic Tool for Catalytic Enantioconvergent Reactions: Intrinsic Negative Nonlinear Effects in the Absence of Higher-Order Species

scientific article

Combining Meyer–Schuster Rearrangement with Aldol and Mannich Reactions: Theoretical Study of the Intermediate Interception Strategy

scientific article published on 08 November 2012

Computational Study of the Mechanism and Selectivity of Palladium-Catalyzed Propargylic Substitution with Phosphorus Nucleophiles

scientific article published on 13 August 2012

Differential inhibition of mRNA degradation pathways by novel cap analogs

scientific article

Effective Modulation of DNA Duplex Stability by Reversible Transition Metal Complex Formation in the Minor Groove

scientific article published on 07 July 2007

Efficient synthesis of mono- and diarylphosphinic acids: a microwave-assisted palladium-catalyzed cross-coupling of aryl halides with phosphinate

Elucidation of Mechanisms and Selectivities of Metal-Catalyzed Reactions using Quantum Chemical Methodology.

scientific article published on 15 April 2016

Enzymatically stable 5′ mRNA cap analogs: Synthesis and binding studies with human DcpS decapping enzyme

scientific article published on 23 January 2006

Identification of efficient and sequence specific bimolecular artificial ribonucleases by a combinatorial approach

scientific article

Interaction of human decapping scavenger with 5′ mRNA cap analogues: structural requirements for catalytic activity

Iodine-promoted silylation of alcohols with silyl chlorides. Synthetic and mechanistic studies

Kinetics of C. elegans DcpS cap hydrolysis studied by fluorescence spectroscopy

scientific article published in January 2007

Mechanism and Selectivity of Cooperatively Catalyzed Meyer-Schuster Rearrangement/Tsuji-Trost Allylic Substitution. Evaluation of Synergistic Catalysis by Means of Combined DFT and Kinetics Simulations.

scientific article

Mechanism and Selectivity of Rhodium-Catalyzed 1:2 Coupling of Aldehydes and Allenes

scientific article published on 09 May 2013

Mechanism, reactivity, and selectivity of the iridium-catalyzed C(sp3)-H borylation of chlorosilanes

scientific article published on 4 December 2014

Mechanistic Insight into Enantioselective Palladium-Catalyzed Oxidative Carbocyclization-Borylation of Enallenes.

scientific article published on 21 December 2017

Microwave-Assisted Palladium-Catalyzed Cross-Coupling of Aryl and Vinyl Halides with H-Phosphonate Diesters

scientific article published on 23 September 2008

N-Heterocyclic Carbene-Catalyzed Olefination of Aldehydes with Vinyliodonium Salts To Generate α,β-Unsaturated Ketones.

scientific article published on 14 March 2018

Novel dinucleoside 5',5'-triphosphate cap analogues. Synthesis and affinity for murine translation factor eIF4E.

scientific article

Novel, Stereoselective and Stereospecific Synthesis of Allenylphosphonates and Related Compounds via Palladium-Catalyzed Propargylic Substitution

On the Sulfurization ofH-Phosphonate Diesters and Phosphite Triesters Using Elemental Sulfur

Organocatalytic Group Transfer Reactions with Hypervalent Iodine Reagents

Palladium-Catalyzed C−P Bond Formation: Mechanistic Studies on the Ligand Substitution and the Reductive Elimination. An Intramolecular Catalysis by the Acetate Group in PdIIComplexes

Palladium-catalyzed propargylic substitution with phosphorus nucleophiles: efficient, stereoselective synthesis of allenylphosphonates and related compounds

scientific article published on 01 October 2010

Pd(0)-Catalyzed Phosphorus−Carbon Bond Formation. Mechanistic and Synthetic Studies on the Role of the Palladium Sources and Anionic Additives

Phosphine-Catalyzed Doubly Stereoconvergent γ-Additions of Racemic Heterocycles to Racemic Allenoates: The Catalytic Enantioselective Synthesis of Protected α,α-Disubstituted α-Amino Acid Derivatives

scientific article

Phosphine-catalyzed enantioselective intramolecular [3+2] annulations to generate fused ring systems

scientific article published on 27 March 2015

Preparation of Arylphosphonates by Palladium(0)-Catalyzed Cross-Coupling in the Presence of Acetate Additives: Synthetic and Mechanistic Studies

Preparation of benzylphosphonates via a palladium(0)-catalyzed cross-coupling of H-phosphonate diesters with benzyl halides. Synthetic and mechanistic studies

SYNTHESIS AND BIOCHEMICAL PROPERTIES OF NOVEL mRNA 5′ CAP ANALOGS RESISTANT TO ENZYMATIC HYDROLYSIS

scientific article published on 01 January 2005

Synthesis of nucleoside phosphorothio-, phosphorodithio- and phosphoroselenoate diesters via oxidative esterification of the corresponding H-phosphonate analogues

scientific article published on 01 January 2008

The Case for the Intermediacy of Monomeric Metaphosphate Analogues during Oxidation ofH-Phosphonothioate,H-Phosphonodithioate, andH-Phosphonoselenoate Monoesters: Mechanistic and Synthetic Studies

scientific article published on 29 May 2008

Transition-Metal-Free Aryl-Aryl Cross-Coupling: C-H Arylation of 2-Naphthols with Diaryliodonium Salts

scientific article published on 26 June 2019

mRNA decapping is promoted by an RNA-binding channel in Dcp2

scientific article

List of works by Marcin Kałek

31P NMR and Computational Studies on Stereochemistry of Conversion of Phosphoramidate Diesters into the Corresponding Phosphotriesters

A New Reagent System for Efficient Silylation of Alcohols: Silyl Chloride-N-Methylimidazole-Iodine

A direct method for the synthesis of nucleoside 5′-methylenebis(phosphonate)s from nucleosides

Atom-efficient gold(I)-chloride-catalyzed synthesis of α-sulfenylated carbonyl compounds from propargylic alcohols and aryl thiols: substrate scope and experimental and theoretical mechanistic investigation

Caution in the Use of Nonlinear Effects as a Mechanistic Tool for Catalytic Enantioconvergent Reactions: Intrinsic Negative Nonlinear Effects in the Absence of Higher-Order Species

Combining Meyer–Schuster Rearrangement with Aldol and Mannich Reactions: Theoretical Study of the Intermediate Interception Strategy

Computational Study of the Mechanism and Selectivity of Palladium-Catalyzed Propargylic Substitution with Phosphorus Nucleophiles

Differential inhibition of mRNA degradation pathways by novel cap analogs

Effective Modulation of DNA Duplex Stability by Reversible Transition Metal Complex Formation in the Minor Groove

Efficient synthesis of mono- and diarylphosphinic acids: a microwave-assisted palladium-catalyzed cross-coupling of aryl halides with phosphinate

Elucidation of Mechanisms and Selectivities of Metal-Catalyzed Reactions using Quantum Chemical Methodology.

Enzymatically stable 5′ mRNA cap analogs: Synthesis and binding studies with human DcpS decapping enzyme

Identification of efficient and sequence specific bimolecular artificial ribonucleases by a combinatorial approach

Interaction of human decapping scavenger with 5′ mRNA cap analogues: structural requirements for catalytic activity

Iodine-promoted silylation of alcohols with silyl chlorides. Synthetic and mechanistic studies

Kinetics of C. elegans DcpS cap hydrolysis studied by fluorescence spectroscopy

Mechanism and Selectivity of Cooperatively Catalyzed Meyer-Schuster Rearrangement/Tsuji-Trost Allylic Substitution. Evaluation of Synergistic Catalysis by Means of Combined DFT and Kinetics Simulations.

Mechanism and Selectivity of Rhodium-Catalyzed 1:2 Coupling of Aldehydes and Allenes

Mechanism, reactivity, and selectivity of the iridium-catalyzed C(sp3)-H borylation of chlorosilanes

Mechanistic Insight into Enantioselective Palladium-Catalyzed Oxidative Carbocyclization-Borylation of Enallenes.

Microwave-Assisted Palladium-Catalyzed Cross-Coupling of Aryl and Vinyl Halides with H-Phosphonate Diesters

N-Heterocyclic Carbene-Catalyzed Olefination of Aldehydes with Vinyliodonium Salts To Generate α,β-Unsaturated Ketones.

Novel dinucleoside 5',5'-triphosphate cap analogues. Synthesis and affinity for murine translation factor eIF4E.

Novel, Stereoselective and Stereospecific Synthesis of Allenylphosphonates and Related Compounds via Palladium-Catalyzed Propargylic Substitution

On the Sulfurization ofH-Phosphonate Diesters and Phosphite Triesters Using Elemental Sulfur

Organocatalytic Group Transfer Reactions with Hypervalent Iodine Reagents

Palladium-Catalyzed C−P Bond Formation: Mechanistic Studies on the Ligand Substitution and the Reductive Elimination. An Intramolecular Catalysis by the Acetate Group in PdIIComplexes

Palladium-catalyzed propargylic substitution with phosphorus nucleophiles: efficient, stereoselective synthesis of allenylphosphonates and related compounds

Pd(0)-Catalyzed Phosphorus−Carbon Bond Formation. Mechanistic and Synthetic Studies on the Role of the Palladium Sources and Anionic Additives

Phosphine-Catalyzed Doubly Stereoconvergent γ-Additions of Racemic Heterocycles to Racemic Allenoates: The Catalytic Enantioselective Synthesis of Protected α,α-Disubstituted α-Amino Acid Derivatives

Phosphine-catalyzed enantioselective intramolecular [3+2] annulations to generate fused ring systems

Preparation of Arylphosphonates by Palladium(0)-Catalyzed Cross-Coupling in the Presence of Acetate Additives: Synthetic and Mechanistic Studies

Preparation of benzylphosphonates via a palladium(0)-catalyzed cross-coupling of H-phosphonate diesters with benzyl halides. Synthetic and mechanistic studies

SYNTHESIS AND BIOCHEMICAL PROPERTIES OF NOVEL mRNA 5′ CAP ANALOGS RESISTANT TO ENZYMATIC HYDROLYSIS

Synthesis of nucleoside phosphorothio-, phosphorodithio- and phosphoroselenoate diesters via oxidative esterification of the corresponding H-phosphonate analogues

The Case for the Intermediacy of Monomeric Metaphosphate Analogues during Oxidation ofH-Phosphonothioate,H-Phosphonodithioate, andH-Phosphonoselenoate Monoesters: Mechanistic and Synthetic Studies

Transition-Metal-Free Aryl-Aryl Cross-Coupling: C-H Arylation of 2-Naphthols with Diaryliodonium Salts

mRNA decapping is promoted by an RNA-binding channel in Dcp2