List of works - Pedro J Pérez

1,2,3-Triazoles from carbonyl azides and alkynes: filling the gap

scientific article published on 01 August 2014

A Quantitative Model for Alkane Nucleophilicity Based on C-H Bond Structural/Topological Descriptors

scientific article published on 21 January 2020

A competing, dual mechanism for catalytic direct benzene hydroxylation from combined experimental-DFT studies.

scientific article published on 5 October 2017

A family of highly active copper(I)-homoscorpionate catalysts for the alkyne cyclopropenation reaction.

scientific article published in September 2001

A fully recyclable heterogenized Cu catalyst for the general carbene transfer reaction in batch and flow.

scientific article published on 28 November 2014

A general mechanism for the copper- and silver-catalyzed olefin aziridination reactions: concomitant involvement of the singlet and triplet pathways.

scientific article published on 22 January 2013

A gold catalyst for carbene-transfer reactions from ethyl diazoacetate.

scientific article published in August 2005

A non-fluorous copper catalyst for the styrene cyclopropanation reaction in a fluorous medium.

scientific article published on 20 January 2006

A valuable, inexpensive Cui/n-heterocyclic carbene catalyst for the selective diboration of styrene

scientific article published on 01 January 2007

Aerobic intramolecular carbon-hydrogen bond oxidation promoted by Cu(I) complexes

scientific article published on 15 October 2020

Alkane Carbon−Hydrogen Bond Functionalization with (NHC)MCl Precatalysts (M = Cu, Au; NHC = N-Heterocyclic Carbene)

article published in 2006

Alkenyl Boronates: Synthesis and Applications

scientific article published on 16 January 2019

An efficient, selective, and reducing agent-free copper catalyst for the atom-transfer radical addition of halo compounds to activated olefins.

scientific article published in January 2010

Bis(ethylene) complexes of molybdenum and tungsten and their reactivity toward carbon dioxide. New examples of acrylate formation by coupling of ethylene and carbon dioxide

article

Catalytic Functionalization of C-H Bonds of Azulene by Carbene/Nitrene Incorporation

scientific article published on 26 July 2018

Catalytic Nitrene Transfer To Alkynes: A Novel and Versatile Route for the Synthesis of Sulfinamides and Isothiazoles

scientific article published on 14 July 2017

Catalytic cross-coupling of diazo compounds with coinage metal-based catalysts: an experimental and theoretical study

scientific article published in March 2013

Catalytic functionalization of low reactive C(sp(3))-H and C(sp(2))-H bonds of alkanes and arenes by carbene transfer from diazo compounds

scientific article published on 16 November 2015

Catalytic functionalization of methane and light alkanes in supercritical carbon dioxide

scientific article published on 25 July 2014

Catalytic insertion of diazo compounds into N-H bonds: the copper alternative

scientific article published on 01 December 2002

Chemo-, regio-, and stereoselective silver-catalyzed aziridination of dienes: scope, mechanistic studies, and ring-opening reactions

scientific article published on 28 March 2014

Coinage metal catalyzed C-H bond functionalization of hydrocarbons.

scientific article published on August 2008

Complete control of the chemoselectivity in catalytic carbene transfer reactions from ethyl diazoacetate: an N-heterocyclic carbene-Cu system that suppresses diazo coupling.

scientific article published in September 2004

Copper(I) complexes as catalysts for the synthesis of N-sulfonyl-1,2,3-triazoles from N-sulfonylazides and alkynes

scientific article published on 27 November 2009

Copper(I) complexes with trispyrazolylmethane ligands: synthesis, characterization, and catalytic activity in cross-coupling reactions

scientific article published on 25 July 2012

Copper(I)-homoscorpionate catalysts for the preferential, kinetically controlled cis cyclopropanation of alpha-olefins with ethyl diazoacetate

scientific article published in February 2002

Copper-Carbene Intermediates in the Copper-Catalyzed Functionalization of O-H Bonds

scientific article published on 26 May 2015

Copper-Catalyzed N-F Bond Activation for Uniform Intramolecular C-H Amination Yielding Pyrrolidines and Piperidines

scientific article published on 20 May 2019

Copper-catalysed azide-alkyne cycloadditions (CuAAC): an update.

scientific article published on 18 August 2015

Copper-catalysed radical reactions of alkenes, alkynes and cyclopropanes with N-F reagents

scientific article published on 22 October 2020

Copper-catalyzed addition of ethyl diazoacetate to furans: an alternative to dirhodium(II) tetraacetate

scientific article published in July 2005

Copper-homoscorpionate complexes as active catalysts for atom transfer radical addition to olefins

scientific article published on 16 May 2007

Copper-induced ammonia N-H functionalization.

scientific article published on 17 February 2016

Cu(I)-catalyzed atom transfer radical cyclization of trichloroacetamides tethered to electron-deficient, -neutral, and -rich alkenes: synthesis of polyfunctionalized 2-azabicyclo[3.3.1]nonanes

scientific article published on 26 July 2012

Cyclohexane and benzene amination by catalytic nitrene insertion into C-H bonds with the copper-homoscorpionate catalyst TpBr3CuNCMe.

scientific article published in October 2003

CC Bond-Forming Reactions of IrIII-Alkenyls and Nitriles or Aldehydes: Generation of Reactive Hydride- and Alkyl-Alkylidene Compounds and Observation of a Reversible 1,2-H Shift in Stable Hydride–IrIII Alkylidene Complexes

scientific article published on 01 November 2002

Dimensioning the Term Carbenoid.

scientific article published on 22 June 2017

Dinitrogen, butadiene and related complexes of molybdenum. Crystal structures of [Mo(N2)(PMe3)5] and [Mo(η3-CH3CHCHCH2)(η4-C4H6)(PEt3)2][BF4]

Direct Benzene Hydroxylation with Dioxygen Induced by Copper Complexes: Uncovering the Active Species by DFT Calculations

scientific article published in 2022

Direct, copper-catalyzed oxidation of aromatic C-H bonds with hydrogen peroxide under acid-free conditions

scientific article published on 16 June 2011

Discrete Cu(i) complexes for azide-alkyne annulations of small molecules inside mammalian cells.

scientific article published on 15 January 2018

Does the Facile Inter- and Intramolecular CH Bond Activation by Tp*–Rh Complexes Proceed via RhI or RhIII Intermediates?

Double carbon-hydrogen activation at the .alpha.-carbon of cyclic ethers by Tp*Ir(C2H4)2

scientific article published in 1992

Effects of the substituents in the TpxCu activation of dioxygen: an experimental study

scientific article published on 03 August 2007

Efficient silver-catalyzed regio- and stereospecific aziridination of dienes

scientific article published on 01 September 2010

Enantio- and Diastereoselective Cyclopropanation of 1-Alkenylboronates: Synthesis of 1-Boryl-2,3-Disubstituted Cyclopropanes.

scientific article

Ethylene dimerization: an alternative route involving vinyl hydride intermediates

Evidencing an inner-sphere mechanism for NHC-Au(I)-catalyzed carbene-transfer reactions from ethyl diazoacetate.

scientific article published on 20 November 2015

Facile amine formation by intermolecular catalytic amidation of carbon-hydrogen bonds

scientific article published on 01 September 2006

Formation of Hydrido–η3-Allyl Complexes of IrIII by Sequential Olefinic CH Bond Activation and CC Coupling of Alkenyl and Olefin Ligands

Formation of carbonyl-carbonate complexes of molybdenum by reductive disproportionation of carbon dioxide. X-ray structure of Mo4(.mu.4-CO3)(CO)2(O)2(.mu.2-O)2(.mu.2-OH)4(PMe3)6

scholarly article by Rafael. Alvarez et al published April 1991 in Inorganic Chemistry

Functional-Group-Tolerant, Silver-Catalyzed N-N Bond Formation by Nitrene Transfer to Amines

scientific article published on 18 January 2017

Functionalization of non-activated C-H bonds of alkanes: an effective and recyclable catalytic system based on fluorinated silver catalysts and solvents

scientific article published on 29 November 2012

Gold and diazo reagents: a fruitful tool for developing molecular complexity

scientific article published on 03 May 2016

Gold-catalyzed ethylene cyclopropanation

Gold-catalyzed naphthalene functionalization.

scientific article published on 23 May 2011

Gold-promoted styrene polymerization

scientific article published on 01 February 2008

Group 11 tris(pyrazolyl)methane complexes: structural features and catalytic applications

scientific article published on 03 June 2019

Highly regioselective functionalization of aliphatic carbon-hydrogen bonds with a perbromohomoscorpionate copper(I) catalyst.

scientific article

Hydrotris(3-mesitylpyrazolyl)borato-copper(i) alkyne complexes: synthesis, structural characterization and rationalization of their activities as alkyne cyclopropenation catalysts

scientific article published on 02 March 2012

Improving Catalyst Activity in Hydrocarbon Functionalization by Remote Pyrene-Graphene Stacking

scientific article published on 24 May 2019

Intermolecular copper-catalyzed carbon [bond] hydrogen bond activation via carbene insertion

scientific article published on 01 February 2002

Intramolecular cycloaddition of azomethine ylides, from imines of O-acylsalicylic aldehyde and ethyl diazoacetate, to ester carbonyl--experimental and DFT computational study

scientific article published on 21 June 2012

Intramolecular dealkylation of chelating diamines with Ru(ii) complexes

scientific article published on 01 September 2002

Introducing copper as catalyst for oxidative alkane dehydrogenation.

scientific article published on 4 March 2013

Iridapyrrole Complexes via Formal 3 + 2 Cycloaddition of Iridium Alkenyls to Acetonitrile

scholarly article by Ysaias Alvarado et al published January 1996 in Organometallics

Iron and Manganese Catalysts for the Selective Functionalization of Arene C(sp(2) )-H Bonds by Carbene Insertion

scientific article published on 18 April 2016

Mechanism of the Selective Fe-Catalyzed Arene Carbon–Hydrogen Bond Functionalization

article published in 2018

Mechanistic and computational studies of the atom transfer radical addition of CCl4 to styrene catalyzed by copper homoscorpionate complexes.

scientific article published on 14 February 2011

Methane as raw material in synthetic chemistry: the final frontier.

scientific article

Molybdenum and tungsten complexes with carbon dioxide and ethylene ligands

scientific article published on 27 August 2019

Nitrene transfer reactions catalysed by copper(I) complexes in ionic liquid using chloramine-T.

scientific article published in January 2009

Novel carbon dioxide and carbonyl carbonate complexes of molybdenum. The X-ray structures of trans-[Mo(CO2)2{HN(CH2CH2PMe2)2}(PMe3)] and [Mo3(μ2-CO3)(μ2-O)2(O)2(CO)2(H2O)(PMe3)6]·H2O

Reaction of alkynes and azides: not triazoles through copper-acetylides but oxazoles through copper-nitrene intermediates.

scientific article published on 24 February 2014

Rediscovering copper-based catalysts for intramolecular carbon-hydrogen bond functionalization by carbene insertion

scientific article published on 21 September 2009

Regioselective Formation of 2,5-Disubstituted Oxazoles Via Copper(I)-Catalyzed Cycloaddition of Acyl Azides and 1-Alkynes ⬇️

scientific article published on December 20, 2010

Rotational isomerism and fluxional behavior of bis(carbon dioxide) adducts of molybdenum

scientific article published in 1991

Rotational isomerism in bis(carbon dioxide) complexes of molybdenum generated by conrotatory motion of the CO2 ligands

Ruthenium-Catalyzed Heck-Type Alkenylation of Alkyl Bromides

scientific article published on 10 June 2019

Silver-catalyzed C-C bond formation between methane and ethyl diazoacetate in supercritical CO₂.

scientific article

Silver-catalyzed silicon-hydrogen bond functionalization by carbene insertion.

scientific article published in January 2013

Substitution and Hydrogenation Reactions on Rhodium(I)−Ethylene Complexes of the Hydrotris(pyrazolyl)borate Ligands Tp‘ (Tp‘ = Tp, TpMe2)†

scientific article published on 01 January 2000

Supercritical carbon dioxide: a promoter of carbon-halogen bond heterolysis

scientific article published on 15 October 2013

Syntheses of a Novel Fluorinated Trisphosphinoborate Ligand and Its Copper and Silver Complexes. Catalytic Activity toward Nitrene Transfer Reactions

scientific article published on 04 April 2014

Synthesis and properties of nitrosyl complexes of molybdenum and tungsten containing halide and trimethylphosphine ligands. Crystal and molecular structures of MoCl3(NO)(PMe3)3 and MoCl(NO)(S2CPMe3-S,S',C)(PMe3)2

scholarly article by Ernesto Carmona Guzmán et al published May 1989 in Inorganic Chemistry

Synthesis, characterization, and reactivity of ruthenium diene/diamine complexes including catalytic hydrogenation of ketones.

scientific article published on 27 September 2007

Synthesis, isolation and characterization of cationic gold(i) N-heterocyclic carbene (NHC) complexes

scientific article published on 10 April 2006

Synthesis, structural characterization, reactivity, and catalytic properties of copper(I) complexes with a series of tetradentate tripodal tris(pyrazolylmethyl)amine ligands.

scientific article published on 3 April 2014

The Elusive Palladium-Diazo Adduct Captured: Synthesis, Isolation and Structural Characterization of [(ArNHC-PPh2 )Pd(η2 -N2 C(Ph)CO2 Et)].

scientific article published on 13 April 2017

The carbene insertion methodology for the catalytic functionalization of unreactive hydrocarbons: no classical C-H activation, but efficient C-H functionalization

scientific article published on 30 October 2006

Trispyrazolylborate Ligands Supported on Vinyl Addition Polynorbornenes and Their Copper Derivatives as Recyclable Catalysts

scientific article published on 28 November 2018

Unusual polybrominated polypyrazolylborates and their copper(I) complexes: synthesis, characterization, and catalytic activity

scientific article published on 01 February 2007

Very efficient, reusable copper catalyst for carbene transfer reactions under biphasic conditions using ionic liquids

scientific article published on 01 February 2006

Vinylic C−H Bond Activation and Hydrogenation Reactions of Tp‘Ir(C2H4)(L) Complexes

scientific article published on 01 September 1998

List of works by Pedro J Pérez

1,2,3-Triazoles from carbonyl azides and alkynes: filling the gap

A Quantitative Model for Alkane Nucleophilicity Based on C-H Bond Structural/Topological Descriptors

A competing, dual mechanism for catalytic direct benzene hydroxylation from combined experimental-DFT studies.

A family of highly active copper(I)-homoscorpionate catalysts for the alkyne cyclopropenation reaction.

A fully recyclable heterogenized Cu catalyst for the general carbene transfer reaction in batch and flow.

A general mechanism for the copper- and silver-catalyzed olefin aziridination reactions: concomitant involvement of the singlet and triplet pathways.

A gold catalyst for carbene-transfer reactions from ethyl diazoacetate.

A non-fluorous copper catalyst for the styrene cyclopropanation reaction in a fluorous medium.

A valuable, inexpensive Cui/n-heterocyclic carbene catalyst for the selective diboration of styrene

Aerobic intramolecular carbon-hydrogen bond oxidation promoted by Cu(I) complexes

Alkane Carbon−Hydrogen Bond Functionalization with (NHC)MCl Precatalysts (M = Cu, Au; NHC = N-Heterocyclic Carbene)

Alkenyl Boronates: Synthesis and Applications

An efficient, selective, and reducing agent-free copper catalyst for the atom-transfer radical addition of halo compounds to activated olefins.

Bis(ethylene) complexes of molybdenum and tungsten and their reactivity toward carbon dioxide. New examples of acrylate formation by coupling of ethylene and carbon dioxide

Catalytic Functionalization of C-H Bonds of Azulene by Carbene/Nitrene Incorporation

Catalytic Nitrene Transfer To Alkynes: A Novel and Versatile Route for the Synthesis of Sulfinamides and Isothiazoles

Catalytic cross-coupling of diazo compounds with coinage metal-based catalysts: an experimental and theoretical study

Catalytic functionalization of low reactive C(sp(3))-H and C(sp(2))-H bonds of alkanes and arenes by carbene transfer from diazo compounds

Catalytic functionalization of methane and light alkanes in supercritical carbon dioxide

Catalytic insertion of diazo compounds into N-H bonds: the copper alternative

Chemo-, regio-, and stereoselective silver-catalyzed aziridination of dienes: scope, mechanistic studies, and ring-opening reactions

Coinage metal catalyzed C-H bond functionalization of hydrocarbons.

Complete control of the chemoselectivity in catalytic carbene transfer reactions from ethyl diazoacetate: an N-heterocyclic carbene-Cu system that suppresses diazo coupling.

Copper(I) complexes as catalysts for the synthesis of N-sulfonyl-1,2,3-triazoles from N-sulfonylazides and alkynes

Copper(I) complexes with trispyrazolylmethane ligands: synthesis, characterization, and catalytic activity in cross-coupling reactions

Copper(I)-homoscorpionate catalysts for the preferential, kinetically controlled cis cyclopropanation of alpha-olefins with ethyl diazoacetate

Copper-Carbene Intermediates in the Copper-Catalyzed Functionalization of O-H Bonds

Copper-Catalyzed N-F Bond Activation for Uniform Intramolecular C-H Amination Yielding Pyrrolidines and Piperidines

Copper-catalysed azide-alkyne cycloadditions (CuAAC): an update.

Copper-catalysed radical reactions of alkenes, alkynes and cyclopropanes with N-F reagents

Copper-catalyzed addition of ethyl diazoacetate to furans: an alternative to dirhodium(II) tetraacetate

Copper-homoscorpionate complexes as active catalysts for atom transfer radical addition to olefins

Copper-induced ammonia N-H functionalization.

Cu(I)-catalyzed atom transfer radical cyclization of trichloroacetamides tethered to electron-deficient, -neutral, and -rich alkenes: synthesis of polyfunctionalized 2-azabicyclo[3.3.1]nonanes

Cyclohexane and benzene amination by catalytic nitrene insertion into C-H bonds with the copper-homoscorpionate catalyst TpBr3CuNCMe.

CC Bond-Forming Reactions of IrIII-Alkenyls and Nitriles or Aldehydes: Generation of Reactive Hydride- and Alkyl-Alkylidene Compounds and Observation of a Reversible 1,2-H Shift in Stable Hydride–IrIII Alkylidene Complexes

Dimensioning the Term Carbenoid.

Dinitrogen, butadiene and related complexes of molybdenum. Crystal structures of [Mo(N2)(PMe3)5] and [Mo(η3-CH3CHCHCH2)(η4-C4H6)(PEt3)2][BF4]

Direct Benzene Hydroxylation with Dioxygen Induced by Copper Complexes: Uncovering the Active Species by DFT Calculations

Direct, copper-catalyzed oxidation of aromatic C-H bonds with hydrogen peroxide under acid-free conditions

Discrete Cu(i) complexes for azide-alkyne annulations of small molecules inside mammalian cells.

Does the Facile Inter- and Intramolecular CH Bond Activation by Tp*–Rh Complexes Proceed via RhI or RhIII Intermediates?

Double carbon-hydrogen activation at the .alpha.-carbon of cyclic ethers by Tp*Ir(C2H4)2

Effects of the substituents in the TpxCu activation of dioxygen: an experimental study

Efficient silver-catalyzed regio- and stereospecific aziridination of dienes

Enantio- and Diastereoselective Cyclopropanation of 1-Alkenylboronates: Synthesis of 1-Boryl-2,3-Disubstituted Cyclopropanes.

Ethylene dimerization: an alternative route involving vinyl hydride intermediates

Evidencing an inner-sphere mechanism for NHC-Au(I)-catalyzed carbene-transfer reactions from ethyl diazoacetate.

Facile amine formation by intermolecular catalytic amidation of carbon-hydrogen bonds

Formation of Hydrido–η3-Allyl Complexes of IrIII by Sequential Olefinic CH Bond Activation and CC Coupling of Alkenyl and Olefin Ligands

Formation of carbonyl-carbonate complexes of molybdenum by reductive disproportionation of carbon dioxide. X-ray structure of Mo4(.mu.4-CO3)(CO)2(O)2(.mu.2-O)2(.mu.2-OH)4(PMe3)6

Functional-Group-Tolerant, Silver-Catalyzed N-N Bond Formation by Nitrene Transfer to Amines

Functionalization of non-activated C-H bonds of alkanes: an effective and recyclable catalytic system based on fluorinated silver catalysts and solvents

Gold and diazo reagents: a fruitful tool for developing molecular complexity

Gold-catalyzed ethylene cyclopropanation

Gold-catalyzed naphthalene functionalization.

Gold-promoted styrene polymerization

Group 11 tris(pyrazolyl)methane complexes: structural features and catalytic applications

Highly regioselective functionalization of aliphatic carbon-hydrogen bonds with a perbromohomoscorpionate copper(I) catalyst.

Hydrotris(3-mesitylpyrazolyl)borato-copper(i) alkyne complexes: synthesis, structural characterization and rationalization of their activities as alkyne cyclopropenation catalysts

Improving Catalyst Activity in Hydrocarbon Functionalization by Remote Pyrene-Graphene Stacking

Intermolecular copper-catalyzed carbon [bond] hydrogen bond activation via carbene insertion

Intramolecular cycloaddition of azomethine ylides, from imines of O-acylsalicylic aldehyde and ethyl diazoacetate, to ester carbonyl--experimental and DFT computational study

Intramolecular dealkylation of chelating diamines with Ru(ii) complexes

Introducing copper as catalyst for oxidative alkane dehydrogenation.

Iridapyrrole Complexes via Formal 3 + 2 Cycloaddition of Iridium Alkenyls to Acetonitrile

Iron and Manganese Catalysts for the Selective Functionalization of Arene C(sp(2) )-H Bonds by Carbene Insertion

Mechanism of the Selective Fe-Catalyzed Arene Carbon–Hydrogen Bond Functionalization

Mechanistic and computational studies of the atom transfer radical addition of CCl4 to styrene catalyzed by copper homoscorpionate complexes.

Methane as raw material in synthetic chemistry: the final frontier.

Molybdenum and tungsten complexes with carbon dioxide and ethylene ligands

Nitrene transfer reactions catalysed by copper(I) complexes in ionic liquid using chloramine-T.

Novel carbon dioxide and carbonyl carbonate complexes of molybdenum. The X-ray structures of trans-[Mo(CO2)2{HN(CH2CH2PMe2)2}(PMe3)] and [Mo3(μ2-CO3)(μ2-O)2(O)2(CO)2(H2O)(PMe3)6]·H2O

Reaction of alkynes and azides: not triazoles through copper-acetylides but oxazoles through copper-nitrene intermediates.

Rediscovering copper-based catalysts for intramolecular carbon-hydrogen bond functionalization by carbene insertion

Regioselective Formation of 2,5-Disubstituted Oxazoles Via Copper(I)-Catalyzed Cycloaddition of Acyl Azides and 1-Alkynes ⬇️

Rotational isomerism and fluxional behavior of bis(carbon dioxide) adducts of molybdenum

Rotational isomerism in bis(carbon dioxide) complexes of molybdenum generated by conrotatory motion of the CO2 ligands

Ruthenium-Catalyzed Heck-Type Alkenylation of Alkyl Bromides