List of works - Margarita Peneque Sosa

.eta.1- And .eta.2-Alkaneimidoyl complexes of nickel: synthesis and properties

scholarly article by Ernesto Carmona Guzmán et al published March 1990 in Organometallics

A Diels–Alder Reaction Triggered by a [4 + 3] Metallacycloaddition

scientific article published on 23 March 2015

A Measureable Equilibrium between Iridium Hydride Alkylidene and Iridium Hydride Alkene Isomers

scholarly article by Margarita Paneque et al published 12 July 2004 in Angewandte Chemie International Edition

Activation of Aldehydes by the Ir−2,3-Dimethylbutadiene Complex TpMe2Ir(CH2C(Me)C(Me)CH2)

scientific article published in 1999

Activation of Aliphatic Ethers by TpMe2Ir Compounds: Multiple C−H Bond Activation and C−C Bond Formation

Aldehyde-Assisted Hydrogen Transfer during the Formation of Hydride-Iridafurans from Alkynes and Aldehydes

scientific article published on 18 December 2012

Alkylidenes by .alpha.-hydrogen abstraction from metallacycles. Synthesis and characterization of alkylidene-bridged complexes of nickel

scholarly article by Tomas R. Belderrain et al published November 1993 in Organometallics

Alkyne insertion reactions in nickel acyl complexes. Occurrence of a 1,2-trimethylphosphine shift and the x-ray structures of [cyclic] Ni[C(Ph):C(H)(COCH2SiMe3)]Cl(PMe3)2 and [cyclic] Ni[C(Ph)(PMe3)C(H)(COCH2CMe2Ph)]Cl(PMe3)6

scholarly article by Ernesto Carmona Guzmán et al published September 1984 in Organometallics

Barium and titanium aryl oxides as precursors for the preparation of thin-film oxides. The effect of bombardment by O2+

scholarly article by Tomás R Belderraín et al published 1995 in Dalton transactions RSC

Building a Parent Iridabenzene Structure from Acetylene and Dichloromethane on an Iridium Center

scientific article published on 09 August 2013

C-H Bond activation and C-C bond formation in the reaction of 2,5-dimethylthiophene with TpMe2Ir compounds

scientific article published on 9 March 2005

C-H bond activation reactions of ethers that generate iridium carbenes.

scientific article

Catalytic amine-borane dehydrogenation by a PCP-pincer palladium complex: a combined experimental and DFT analysis of the reaction mechanism

article

Coupling of internal alkynes in tp(me2)ir derivatives: selective oxidation of a noncoordinated double bond of the resulting iridacycloheptatrienes

scientific article

C–H bond activation reactions by TpMe2Ir(iii) centres. Generation of Fischer-type carbenes and development of a catalytic system for H/D exchange

article

C−H Bond Activation of Thiophenes by Ir Complexes of the Hydrotris(3,5-dimethylpyrazolyl)borate Ligand, TpMe2

C−H and C−S Activation of Thiophene by Rhodium Complexes: Influence of the Ancillary Ligands on the Thermodynamic Stability of the Products

CC Bond-Forming Reactions of IrIII-Alkenyls and Nitriles or Aldehydes: Generation of Reactive Hydride- and Alkyl-Alkylidene Compounds and Observation of a Reversible 1,2-H Shift in Stable Hydride–IrIII Alkylidene Complexes

scientific article published on 01 November 2002

CN Bond Formation by O2-Mediated Dehydrogenative Coupling of Phenyl and NH-pyridylidene Ligands on Tp Me 2IrIII Complexes

Denticity Changes of Hydrotris(pyrazolyl)borate Ligands in RhI and RhIII Compounds: Fromκ3- to Ionic “κ0”-Tp′

scientific article published on 01 January 2000

Dialkyl complexes of nickel(II) containing chelating diphosphines. The crystal structure of [Ni(CH2SiMe2Ph)2(i Pr2PCH2CH2PiPr2)]

scholarly article by Olivier Boutry et al published February 1993 in Journal of Organometallic Chemistry

Dinitrogen, butadiene and related complexes of molybdenum. Crystal structures of [Mo(N2)(PMe3)5] and [Mo(η3-CH3CHCHCH2)(η4-C4H6)(PEt3)2][BF4]

Electron-rich metal complexes for CO2 and CS2 incorporation

Ethoxycarbonyl-, cyano- and methoxy-methyl complexes of nickel(II) and their carbonylation reactions

scholarly article by Tomás R Belderraín et al published 1992 in Dalton transactions RSC

Ethylene Coordination and Acetylene Dimerization at Tp′IrIIICenters

article published in 2009

Experimental and computational studies on the iridium activation of aliphatic and aromatic C-H bonds of alkyl aryl ethers and related molecules

scientific article published in September 2009

Experimental evidences in favour of the hydroxylamine→nitrene-water tautomerization on the coordination sphere of Ir(III) centres

scientific article

Formation and Cleavage of C−H, C−C, and C−O Bonds ofortho-Methyl-Substituted Anisoles by Late Transition Metals

scientific article published in 2006

Formation of 2-thienyl derivatives during the thermal activation of thiophene by Tp∗Ir(C2H4)2

Formation of Iridabenzenes by Coupling of Iridacyclopentadienes and Alkenes

scientific article published on 01 January 2006

Formation of Palladium- and Platinum-Substituted Fulvenes by Activation of a Cyclopentadienyl or Indenyl Ligand

article

Formation of Palladium- and Platinum-Substituted Fulvenes by Cyclopentadienyl Activation in a Formal Insertion Reaction

Formation of Unusual Iridabenzene and Metallanaphthalene Containing Electron-Withdrawing Substituents

scientific article published on 01 August 2003

Functionalization of 3-Iridacyclopentenes

scientific article published on 12 September 2017

Further studies on organonickel compounds: the synthesis of some new alkyl-, acyl- and cyclopentadienyl-derivatives and the crystal structure of trans-[Ni(CH2SiMe3)2(PMe3)2]

Generation and reactivity of sterically hindered iridium carbenes. Competitive α- vs. β-hydrogen elimination in iridium(iii) alkyls

scholarly article by Ernesto Carmona Guzmán et al published 2003 in Dalton Transactions

Generation of Metallacyclic Structures from the Reactions of Vinyl Ethers with a TpMe2IrIIICompound

Hydroboration of carbon dioxide with catechol- and pinacolborane using an Ir-CNP* pincer complex. Water influence on the catalytic activity

scientific article published on 01 November 2018

Hydrogenation of an iridium-coordinated imidazol-2-ylidene ligand fragment

scientific article published on 29 March 2018

Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands

scientific article published on 10 July 2020

Iridium solutes effect C-H bond activation and C-C bond forming reactions of C6H6-MeOCH2CH2OMe solvent mixtures

scientific article

Iridium(III)-Induced Isomerization of 2-Substituted Pyridines to N-Heterocyclic Carbenes

scholarly article by Eleuterio Álvarez et al published October 2006 in Journal of the American Chemical Society

Iridium(iii) complexes with polypyridine ligands coordinated as N-heterocyclic carbenes. Synthesis, structure and photophysical properties

scientific article published on 02 October 2012

Metallacyclic Pyridylidene Structures from Reactions of Terminal Pyridylidenes with Alkenes and Acetylene

scientific article published on 01 May 2010

Monodentate, N-heterocyclic carbene-type coordination of 2,2'-bipyridine and 1,10-phenanthroline to iridium

scientific article published in January 2008

Monohapto co-ordination of poly(tert-butylpyrazolyl)borate ligands in nickel and palladium complexes

scholarly article by Enrique Gutiérrez et al published 1992 in Dalton transactions RSC

Novel carbon dioxide and carbonyl carbonate complexes of molybdenum. The X-ray structures of trans-[Mo(CO2)2{HN(CH2CH2PMe2)2}(PMe3)] and [Mo3(μ2-CO3)(μ2-O)2(O)2(CO)2(H2O)(PMe3)6]·H2O

Pyrrolyl, hydroxo, and carbonate organometallic derivatives of nickel(II). Crystal and molecular structure of [Ni(CH2C6H4-o-Me)(PMe3)(.mu.-OH)]2.cntdot.2,5-HNC4H2Me2

scholarly article by Ernesto Carmona Guzmán et al published May 1989 in Inorganic Chemistry

Reaction of [TpRh(C2 H4 )2 ] with Dimethyl Acetylenedicarboxylate: Identification of Intermediates of the [2+2+2] Alkyne and Alkyne-Ethylene Cyclo(co)trimerizations.

scientific article published on 18 August 2016

Reactivity Studies of Iridium Pyridylidenes [TpMe2Ir(C6H5)2(C(CH)3C(R)NH] (R=H, Me, Ph)

scientific article published on 11 February 2013

Rearrangement of pyridine to its 2-carbene tautomer mediated by iridium

scientific article published on 31 October 2007

Step-by-step uncoordination of the pyrazolyl rings of hydrotris(pyrazolyl)borate ligands in comlexes of Rh and RhIII.

scientific article

Study of the Coordination Modes of Hybrid NNCp Cyclopentadienyl/Scorpionate Ligands in Ir Compounds

scientific article published on 12 December 2018

Substitution and Hydrogenation Reactions on Rhodium(I)−Ethylene Complexes of the Hydrotris(pyrazolyl)borate Ligands Tp‘ (Tp‘ = Tp, TpMe2)†

scientific article published on 01 January 2000

Substitution reactions in cyclometallated complexes. Crystal and molecular structure of (C5H5N)(Me3P)6H4)]

article published in 1989

Synthesis and Properties of TpMe2IrH4and TpMe2IrH3(SiEt3): Ir(V) Polyhydride Species withC3vGeometry

scientific article published in 1999

Synthesis and characterization of some new organometallic complexes of nickel(II) containing trimethylphosphine

scholarly article by Ernesto Carmona Guzmán et al published January 1989 in Polyhedron

Synthesis and reactivity studies of Pd(II) complexes of the bulky CH(SiMe3)2 group. X ray structure of the indenyl derivative (η-Ind)Pd[CH(SiMe3)2](PMe3)

Synthesis and structural characterization of a binuclear iridium complex with bridging, bidentate N-heterocyclic carbene coordination of 2,2':6',2''-terpyridine

scientific article published on 18 August 2009

Synthesis and structural characterization of volatile poly(3,5-dimethyl-1-pyrazolyl)-borate-complexes of Ca, Sr, and Ba

Synthesis and x-ray structure of the nickelabenzocyclopentene complex [cyclic](Me3P)2Ni(CH2CMe2-o-C6H4). Reactivity toward simple, unsaturated molecules and the crystal and molecular structure of the cyclic carboxylate (Me3P)2Ni(CH2CMe2-o-C6H4C(O)O)

scientific article published in 1989

Synthesis of new heteroscorpionate iridium(i) and iridium(iii) complexes

scientific article published on 01 April 2015

Synthetic, mechanistic, and theoretical studies on the generation of iridium hydride alkylidene and iridium hydride alkene isomers

scientific article published in September 2009

Tautomerisation of 2-Substituted Pyridines to N-Heterocyclic Carbene Ligands Induced by the 16 e− Unsaturated [TpMe2IrIII(C6H5)2] Moiety

The Synthesis of Iridabenzenes by the Coupling of Iridacyclopentadienes and Olefins

Three-center, two-electron M...H-B bonds in complexes of Ni, Co, and Fe and the dihydrobis(3-tert-butylpyrazolyl)borate ligand

scientific article published in January 2002

Transition metal migration upon attempting the Wolff rearrangement of an Ir(III) five-membered metallacycle.

scientific article

Unexpected reactivity of 2,5-dimethylthiophene towards TpMe2Ir(C2H4)2

Unusual alkylidene-bridged complexes of nickel by α-H abstraction from a nickelacycle. Crystal and molecular structure of [{Ni2(CHCMe2-o-C6H4)Cl(PMe3)2}2]

scholarly article by Ernesto Carmona Guzmán et al published 1991 in Journal of the Chemical Society. Chemical communications

Unusual fragmentation of CH2Cl2 by an Ir(III) centre bonded to a doubly metalated Tp(Ms) Ligand (Tp(Ms) = hydrotris(3-mesitylpyrazol-1-yl)borate).

scientific article published on 4 August 2006

Vinylidene Compounds from the Reactions of Me3SiC⋮CSiMe3with TpMe2Ir Precursors. Protonation to Alkylidene and Iridabenzene Structures

X-ray crystal structure of [Ni{η2−C(NBut)CH(SiMe3)2}Cl(PMe3)], the first structurally characterized η2-alkaneimidoyl complex of nickel

scholarly article by Tomas R. Belderraín et al published January 1995 in Polyhedron

List of works by Margarita Peneque Sosa

.eta.1- And .eta.2-Alkaneimidoyl complexes of nickel: synthesis and properties

A Diels–Alder Reaction Triggered by a [4 + 3] Metallacycloaddition

A Measureable Equilibrium between Iridium Hydride Alkylidene and Iridium Hydride Alkene Isomers

Activation of Aldehydes by the Ir−2,3-Dimethylbutadiene Complex TpMe2Ir(CH2C(Me)C(Me)CH2)

Activation of Aliphatic Ethers by TpMe2Ir Compounds: Multiple C−H Bond Activation and C−C Bond Formation

Aldehyde-Assisted Hydrogen Transfer during the Formation of Hydride-Iridafurans from Alkynes and Aldehydes

Alkylidenes by .alpha.-hydrogen abstraction from metallacycles. Synthesis and characterization of alkylidene-bridged complexes of nickel

Alkyne insertion reactions in nickel acyl complexes. Occurrence of a 1,2-trimethylphosphine shift and the x-ray structures of [cyclic] Ni[C(Ph):C(H)(COCH2SiMe3)]Cl(PMe3)2 and [cyclic] Ni[C(Ph)(PMe3)C(H)(COCH2CMe2Ph)]Cl(PMe3)6

Barium and titanium aryl oxides as precursors for the preparation of thin-film oxides. The effect of bombardment by O2+

Building a Parent Iridabenzene Structure from Acetylene and Dichloromethane on an Iridium Center

C-H Bond activation and C-C bond formation in the reaction of 2,5-dimethylthiophene with TpMe2Ir compounds

C-H bond activation reactions of ethers that generate iridium carbenes.

Catalytic amine-borane dehydrogenation by a PCP-pincer palladium complex: a combined experimental and DFT analysis of the reaction mechanism

Coupling of internal alkynes in tp(me2)ir derivatives: selective oxidation of a noncoordinated double bond of the resulting iridacycloheptatrienes

C–H bond activation reactions by TpMe2Ir(iii) centres. Generation of Fischer-type carbenes and development of a catalytic system for H/D exchange

C−H Bond Activation of Thiophenes by Ir Complexes of the Hydrotris(3,5-dimethylpyrazolyl)borate Ligand, TpMe2

C−H and C−S Activation of Thiophene by Rhodium Complexes: Influence of the Ancillary Ligands on the Thermodynamic Stability of the Products

CC Bond-Forming Reactions of IrIII-Alkenyls and Nitriles or Aldehydes: Generation of Reactive Hydride- and Alkyl-Alkylidene Compounds and Observation of a Reversible 1,2-H Shift in Stable Hydride–IrIII Alkylidene Complexes

CN Bond Formation by O2-Mediated Dehydrogenative Coupling of Phenyl and NH-pyridylidene Ligands on Tp Me 2IrIII Complexes

Denticity Changes of Hydrotris(pyrazolyl)borate Ligands in RhI and RhIII Compounds: Fromκ3- to Ionic “κ0”-Tp′

Dialkyl complexes of nickel(II) containing chelating diphosphines. The crystal structure of [Ni(CH2SiMe2Ph)2(i Pr2PCH2CH2PiPr2)]

Dinitrogen, butadiene and related complexes of molybdenum. Crystal structures of [Mo(N2)(PMe3)5] and [Mo(η3-CH3CHCHCH2)(η4-C4H6)(PEt3)2][BF4]

Electron-rich metal complexes for CO2 and CS2 incorporation

Ethoxycarbonyl-, cyano- and methoxy-methyl complexes of nickel(II) and their carbonylation reactions

Ethylene Coordination and Acetylene Dimerization at Tp′IrIIICenters

Experimental and computational studies on the iridium activation of aliphatic and aromatic C-H bonds of alkyl aryl ethers and related molecules

Experimental evidences in favour of the hydroxylamine→nitrene-water tautomerization on the coordination sphere of Ir(III) centres

Formation and Cleavage of C−H, C−C, and C−O Bonds ofortho-Methyl-Substituted Anisoles by Late Transition Metals

Formation of 2-thienyl derivatives during the thermal activation of thiophene by Tp∗Ir(C2H4)2

Formation of Iridabenzenes by Coupling of Iridacyclopentadienes and Alkenes

Formation of Palladium- and Platinum-Substituted Fulvenes by Activation of a Cyclopentadienyl or Indenyl Ligand

Formation of Palladium- and Platinum-Substituted Fulvenes by Cyclopentadienyl Activation in a Formal Insertion Reaction

Formation of Unusual Iridabenzene and Metallanaphthalene Containing Electron-Withdrawing Substituents

Functionalization of 3-Iridacyclopentenes

Further studies on organonickel compounds: the synthesis of some new alkyl-, acyl- and cyclopentadienyl-derivatives and the crystal structure of trans-[Ni(CH2SiMe3)2(PMe3)2]

Generation and reactivity of sterically hindered iridium carbenes. Competitive α- vs. β-hydrogen elimination in iridium(iii) alkyls

Generation of Metallacyclic Structures from the Reactions of Vinyl Ethers with a TpMe2IrIIICompound

Hydroboration of carbon dioxide with catechol- and pinacolborane using an Ir-CNP* pincer complex. Water influence on the catalytic activity

Hydrogenation of an iridium-coordinated imidazol-2-ylidene ligand fragment

Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands

Iridium solutes effect C-H bond activation and C-C bond forming reactions of C6H6-MeOCH2CH2OMe solvent mixtures

Iridium(III)-Induced Isomerization of 2-Substituted Pyridines to N-Heterocyclic Carbenes

Iridium(iii) complexes with polypyridine ligands coordinated as N-heterocyclic carbenes. Synthesis, structure and photophysical properties

Metallacyclic Pyridylidene Structures from Reactions of Terminal Pyridylidenes with Alkenes and Acetylene

Monodentate, N-heterocyclic carbene-type coordination of 2,2'-bipyridine and 1,10-phenanthroline to iridium

Monohapto co-ordination of poly(tert-butylpyrazolyl)borate ligands in nickel and palladium complexes

Novel carbon dioxide and carbonyl carbonate complexes of molybdenum. The X-ray structures of trans-[Mo(CO2)2{HN(CH2CH2PMe2)2}(PMe3)] and [Mo3(μ2-CO3)(μ2-O)2(O)2(CO)2(H2O)(PMe3)6]·H2O

Pyrrolyl, hydroxo, and carbonate organometallic derivatives of nickel(II). Crystal and molecular structure of [Ni(CH2C6H4-o-Me)(PMe3)(.mu.-OH)]2.cntdot.2,5-HNC4H2Me2

Reaction of [TpRh(C2 H4 )2 ] with Dimethyl Acetylenedicarboxylate: Identification of Intermediates of the [2+2+2] Alkyne and Alkyne-Ethylene Cyclo(co)trimerizations.

Reactivity Studies of Iridium Pyridylidenes [TpMe2Ir(C6H5)2(C(CH)3C(R)NH] (R=H, Me, Ph)

Rearrangement of pyridine to its 2-carbene tautomer mediated by iridium

Step-by-step uncoordination of the pyrazolyl rings of hydrotris(pyrazolyl)borate ligands in comlexes of Rh and RhIII.

Study of the Coordination Modes of Hybrid NNCp Cyclopentadienyl/Scorpionate Ligands in Ir Compounds

Substitution and Hydrogenation Reactions on Rhodium(I)−Ethylene Complexes of the Hydrotris(pyrazolyl)borate Ligands Tp‘ (Tp‘ = Tp, TpMe2)†

Substitution reactions in cyclometallated complexes. Crystal and molecular structure of (C5H5N)(Me3P)6H4)]

Synthesis and Properties of TpMe2IrH4and TpMe2IrH3(SiEt3): Ir(V) Polyhydride Species withC3vGeometry

Synthesis and characterization of some new organometallic complexes of nickel(II) containing trimethylphosphine

Synthesis and reactivity studies of Pd(II) complexes of the bulky CH(SiMe3)2 group. X ray structure of the indenyl derivative (η-Ind)Pd[CH(SiMe3)2](PMe3)

Synthesis and structural characterization of a binuclear iridium complex with bridging, bidentate N-heterocyclic carbene coordination of 2,2':6',2''-terpyridine

Synthesis and structural characterization of volatile poly(3,5-dimethyl-1-pyrazolyl)-borate-complexes of Ca, Sr, and Ba

Synthesis and x-ray structure of the nickelabenzocyclopentene complex [cyclic](Me3P)2Ni(CH2CMe2-o-C6H4). Reactivity toward simple, unsaturated molecules and the crystal and molecular structure of the cyclic carboxylate (Me3P)2Ni(CH2CMe2-o-C6H4C(O)O)

Synthesis of new heteroscorpionate iridium(i) and iridium(iii) complexes

Synthetic, mechanistic, and theoretical studies on the generation of iridium hydride alkylidene and iridium hydride alkene isomers

Tautomerisation of 2-Substituted Pyridines to N-Heterocyclic Carbene Ligands Induced by the 16 e− Unsaturated [TpMe2IrIII(C6H5)2] Moiety

The Synthesis of Iridabenzenes by the Coupling of Iridacyclopentadienes and Olefins

Three-center, two-electron M...H-B bonds in complexes of Ni, Co, and Fe and the dihydrobis(3-tert-butylpyrazolyl)borate ligand

Transition metal migration upon attempting the Wolff rearrangement of an Ir(III) five-membered metallacycle.

Unexpected reactivity of 2,5-dimethylthiophene towards TpMe2Ir(C2H4)2

Unusual alkylidene-bridged complexes of nickel by α-H abstraction from a nickelacycle. Crystal and molecular structure of [{Ni2(CHCMe2-o-C6H4)Cl(PMe3)2}2]

Unusual fragmentation of CH2Cl2 by an Ir(III) centre bonded to a doubly metalated Tp(Ms) Ligand (Tp(Ms) = hydrotris(3-mesitylpyrazol-1-yl)borate).

Vinylidene Compounds from the Reactions of Me3SiC⋮CSiMe3with TpMe2Ir Precursors. Protonation to Alkylidene and Iridabenzene Structures

X-ray crystal structure of [Ni{η2−C(NBut)CH(SiMe3)2}Cl(PMe3)], the first structurally characterized η2-alkaneimidoyl complex of nickel