List of works - Alexey Y. Timoshkin

"True" inorganic heterocycles: structures and stability of group 13-15 analogues of benzene and their dimers

scientific article

A Convenient Route to Mixed Pnictogenylboranes

scientific article published on 7 August 2017

Access to Phosphorus-Rich Zirconium Complexes

scholarly article by Ulf Vogel et al published 24 August 2011 in Angewandte Chemie International Edition

Al(OCArF3)3 - a thermally stable Lewis superacid

scientific article published on 02 October 2018

Alumazene adducts with pyridines: synthesis, structure, and stability studies

scientific article published on 13 June 2007

Aluminum-nitrogen rings and cages with organic handles: a theoretical study

scientific article published on 01 April 2009

An approach to mixed P(n)A(sm) ligand complexes.

scientific article

An end-on-coordinated As4 tetrahedron.

scientific article

Anionic Chains of Parent Pnictogenylboranes

scientific article published on 25 October 2016

Aurolysis of alpha-C-deprotonated group 6 aminocarbene and thiocarbene complexes with Ph3PAu+

scientific article published on 21 July 2006

Bidentate Phosphanyl- and Arsanylboranes

scientific article published on 11 December 2018

Competitive reaction pathways for the gas-phase reactivity of [Me2 AlNH2 ]3

scientific article published on 27 June 2014

Complex beryllium amidoboranes: Structures, stability, and evaluation of their potential as hydrogen storage materials

scientific article published on 19 December 2016

Complexes of adamantane-based group 13 Lewis acids and superacids: Bonding analysis and thermodynamics of hydrogen splitting

scientific article published in March 2016

Controlled oligomerization of Lewis acid/base-stabilized phosphanylalanes

scientific article published on 01 January 2009

Depolymerization of Poly(phosphinoboranes): From Polymers to Lewis Base Stabilized Monomers

scientific article published on 22 November 2017

Design of Neutral Lewis Superacids of Group 13 Elements

scientific article published on 14 December 2011

Diminished electron density in the Vaska-type rhodium(I) complex trans-[Rh(NCBH3)(CO)(PPh3)2].

scientific article published on 3 June 2016

Do solid-state structures reflect Lewis acidity trends of heavier group 13 trihalides? Experimental and theoretical case study

scientific article published on 09 October 2012

Donor Acceptor Complexes of Noble Gases

scientific article published on 25 March 2009

Donor-acceptor "dressing" of "naked" group 13-15 cubanes

scientific article published in September 2009

Fascinating transformations of donor-acceptor complexes of group 13 metal (Al, Ga, In) derivatives with nitriles and isonitriles: from monomeric cyanides to rings and cages

scientific article published on 01 August 2003

Fast H/D exchange of B,B',B''-tribromoborazine in C6D6 in the presence of aluminum tribromide: first evidence for an electrophilic substitution reaction of borazines in solution

scientific article published on 05 August 2011

Formation of cyclo-E42− Units (E4=P4, As4, AsP3) by a Complex with a CrCr Quintuple Bond

scientific article published on 22 June 2011

From "parasitic" association reactions toward the stoichiometry controlled gas phase synthesis of nanoparticles: a theoretically driven challenge for experimentalists.

scientific article published in January 2002

Gold(I) Complexes Containing Phosphanyl- and Arsanylborane Ligands

scientific article published on 29 May 2018

Hydrogen splitting by pyramidalized 13-15 donor-acceptor cryptands: A computational study

scientific article published on 24 April 2019

Influence of the solvent on the Lewis acidity of antimony pentahalides and group 13 Lewis acids toward acetonitrile and pyridine

scientific article published on 06 July 2021

Initial gas phase reactions between Al(CH3)3/AlH3 and ammonia: theoretical study.

scientific article published on 14 January 2015

Initial steps for the thermal decomposition of alkaline-earth metal amidoboranes: a cluster approximation.

scientific article published on 3 November 2016

Insight into the Reaction of a Dinuclear Phosphinidene Complex with Nitriles.

scientific article published on 9 March 2016

Intact P4Tetrahedra as Terminal and Bridging Ligands in Neutral Complexes of Manganese

scholarly article by Sebastian Heinl et al published 3 September 2013 in Angewandte Chemie International Edition

Iron bispentazole Fe(eta5-N5)2, a theoretically predicted high-energy compound: structure, bonding analysis, metal-ligand bond strength and a comparison with the isoelectronic ferrocene

scientific article published in October 2001

Isolation and Characterization of Lewis Base Stabilized Monomeric Parent Stibanylboranes

scientific article published on 04 September 2015

Lewis Acid/Base Stabilized Phosphanylalane and -gallane This work was supported by the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie. A.Y.T. is grateful to the Alexander von Humboldt Foundation for a research fellowship

Lewis acid stabilized group 13–15 element analogs of ethylene

scientific article published on 18 April 2022

Low-valent group-13 chemistry. Theoretical investigation of the structures and relative stabilities of donor-acceptor complexes R(3)E[bond]E'R' and their isomers R(2)E[bond]E'RR'.

scientific article

Masking of Lewis acidity trends in the solid-state structures of trichlorido- and tribromido(2,2':6',2''-terpyridine-κ(3)N,N',N'')gallium(III)

scientific article published on 28 February 2014

Mechanisms of Hydrogen Generation from Tetrameric Clusters of Lithium Amidoborane

scientific article published on 31 December 2015

Monomeric β-Diketiminato Group 13 Metal Dipnictogenide Complexes with Two Terminal EH2 Groups (E=P, As)

scientific article published on 04 October 2019

Normal to abnormal ItBu·AlH3 isomerization in solution and in the solid state

scientific article published on 03 March 2020

Novel group 13 Lewis superacids and 13-15 donor-acceptor cryptands for hydrogen activation: a theoretical study

scientific article published on 24 September 2012

Phosphanylalanes and Phosphanylgallanes Stabilized only by a Lewis Base

scientific article published on 23 January 2020

Reaction of Pentelidene Complexes with Diazoalkanes: Stabilization of Parent 2,3-Dipnictabutadienes

scientific article published on 6 October 2016

Reaction of tungsten-phosphinidene and -arsinidene complexes with carbodiimides and alkyl azides: a straightforward way to four-membered heterocycles

scientific article published on 07 January 2015

Reactivity of bridged pentelidene complexes with isonitriles: a new way to pentel-containing heterocycles

scientific article

Redox and Coordination Behavior of the Hexaphosphabenzene Ligand in [(Cp*Mo)2 (μ,η(6) :η(6) -P6 )] Towards the "Naked" Cations Cu(+) , Ag(+) , and Tl(.).

scientific article published on 4 September 2015

Selective Dimerization of Lewis-Acid/Base-Stabilized Phosphanylalanes

Selective formation and unusual reactivity of tetraarsabicyclo[1.1.0]butane complexes

scientific article published on 01 August 2014

Selective halogenation at the pnictogen atom in Lewis-acid/base-stabilised phosphanylboranes and arsanylboranes

scientific article published on 06 August 2008

Spontaneous gas-phase generation of needle-shaped clusters which violate the isolated square rule: a facile road to GaN nanorods?

scientific article published in September 2004

Stepwise Formation of a 1,3-Butadiene Analogue of Mixed Heavier Group 15 Elements

scientific article published on 09 November 2015

Stepwise activation of "non-innocent" Cp* substituents--a Cp* based cascade reaction

scientific article published on 14 June 2012

Stepwise expansion of a Cp* ring at pentelidene complexes and stereoselective formation of triphosphines

scientific article published on 01 January 2010

Structural and thermodynamic properties of group 13 imidometallanes and their heavier analogues

scientific article published on 01 May 2004

Structural and thermodynamic properties of molecular complexes of aluminum and gallium trihalides with bifunctional donor pyrazine: decisive role of Lewis acidity in 1D polymer formation

scientific article published on 03 July 2013

Structure and stability of M6N8 clusters (M = Si, Ge, Sn, Ti)

scientific article published on 01 June 2010

Structures and stability of molecular InBr3Py(x) (x = 1-3) complexes: unexpected solid state stabilization of dimeric In2Br6Py4 as compared to valence-isoelectronic group 15 and 17 halogen bridging dimers.

scientific article published on 7 November 2013

The Cobalt cyclo-P4 Sandwich Complex and Its Role in the Formation of Polyphosphorus Compounds

scientific article published on 12 January 2017

The Lewis Base Stabilized Parent Arsanylborane H2AsBH2⋅NMe3.

scientific article published on 31 July 2013

The Lewis-Base-Stabilized Diphenyl-Substituted Arsanylborane: A Versatile Building Block for Arsanylborane Oligomers

scientific article published on 17 October 2018

The effect of terminal substituents on the electronic properties of rod-shaped [HGaNH]n oligomers.

scientific article

The oligomerization of phosphinoborane by titanium complexes

scientific article published on 10 April 2013

The road to 13-15 nano structures: structures and energetics of (MYH(2))(4) tetramers (M = B, Al, Ga; Y = N, P, As)

scientific article published on 01 January 2010

The stabilization of monomeric parent compounds of phosphanyl- and arsanylboranes

scientific article published on 01 January 2003

Theoretical studies of [MYR2]n isomers (M = B, Al, Ga; Y = N, P, As; R = H, CH3): structures and energetics of monomeric and dimeric compounds (n = 1, 2)

scientific article published on 01 December 2008

Thermodynamics of the decomposition processes of donor-acceptor complexes MX3 x en x MX3 and MX3 x en

scientific article published on 01 February 2007

Transformation of nortricyclane type cage compounds P4S3, P4Se3 and As4S3 by [Cp''2Zr(CO)2].

scientific article published on 5 January 2017

Trimeric cluster of lithium amidoborane-the smallest unit for the modeling of hydrogen release mechanism

scientific article published on 08 February 2016

Triple-decker sandwich complexes with a bent cyclo-P5 middle-deck

scientific article published on 28 September 2016

Unexpected differences in the reactivity between the phosphorus and arsenic derivatives [(CpBIGFe)2(μ,η4:4-E4)] (E = P and As).

scientific article published on 12 February 2018

Versatile structures of group 13 metal halide complexes with 4,4′-bipy: from 1D coordination polymers to 2D and 3D metal–organic frameworks

scientific article published in 2015

Violation of the isolated square rule for group 13-15 oligomers: theoretical prediction of a new class of inorganic polymers

scientific article published on 01 February 2005

Why Do B-P and Al-P Polymers Differ? Structures, Stability, and Electronic Properties of Chain and Ring [H2 PEH2 ]n Oligomers (E=B, Al; n=1-15)

scientific article published on 24 October 2018

List of works by Alexey Y. Timoshkin

"True" inorganic heterocycles: structures and stability of group 13-15 analogues of benzene and their dimers

A Convenient Route to Mixed Pnictogenylboranes

Access to Phosphorus-Rich Zirconium Complexes

Al(OCArF3)3 - a thermally stable Lewis superacid

Alumazene adducts with pyridines: synthesis, structure, and stability studies

Aluminum-nitrogen rings and cages with organic handles: a theoretical study

An approach to mixed P(n)A(sm) ligand complexes.

An end-on-coordinated As4 tetrahedron.

Anionic Chains of Parent Pnictogenylboranes

Aurolysis of alpha-C-deprotonated group 6 aminocarbene and thiocarbene complexes with Ph3PAu+

Bidentate Phosphanyl- and Arsanylboranes

Competitive reaction pathways for the gas-phase reactivity of [Me2 AlNH2 ]3

Complex beryllium amidoboranes: Structures, stability, and evaluation of their potential as hydrogen storage materials

Complexes of adamantane-based group 13 Lewis acids and superacids: Bonding analysis and thermodynamics of hydrogen splitting

Controlled oligomerization of Lewis acid/base-stabilized phosphanylalanes

Depolymerization of Poly(phosphinoboranes): From Polymers to Lewis Base Stabilized Monomers

Design of Neutral Lewis Superacids of Group 13 Elements

Diminished electron density in the Vaska-type rhodium(I) complex trans-[Rh(NCBH3)(CO)(PPh3)2].

Do solid-state structures reflect Lewis acidity trends of heavier group 13 trihalides? Experimental and theoretical case study

Donor Acceptor Complexes of Noble Gases

Donor-acceptor "dressing" of "naked" group 13-15 cubanes

Fascinating transformations of donor-acceptor complexes of group 13 metal (Al, Ga, In) derivatives with nitriles and isonitriles: from monomeric cyanides to rings and cages

Fast H/D exchange of B,B',B''-tribromoborazine in C6D6 in the presence of aluminum tribromide: first evidence for an electrophilic substitution reaction of borazines in solution

Formation of cyclo-E42− Units (E4=P4, As4, AsP3) by a Complex with a CrCr Quintuple Bond

From "parasitic" association reactions toward the stoichiometry controlled gas phase synthesis of nanoparticles: a theoretically driven challenge for experimentalists.

Gold(I) Complexes Containing Phosphanyl- and Arsanylborane Ligands

Hydrogen splitting by pyramidalized 13-15 donor-acceptor cryptands: A computational study

Influence of the solvent on the Lewis acidity of antimony pentahalides and group 13 Lewis acids toward acetonitrile and pyridine

Initial gas phase reactions between Al(CH3)3/AlH3 and ammonia: theoretical study.

Initial steps for the thermal decomposition of alkaline-earth metal amidoboranes: a cluster approximation.

Insight into the Reaction of a Dinuclear Phosphinidene Complex with Nitriles.

Intact P4Tetrahedra as Terminal and Bridging Ligands in Neutral Complexes of Manganese

Iron bispentazole Fe(eta5-N5)2, a theoretically predicted high-energy compound: structure, bonding analysis, metal-ligand bond strength and a comparison with the isoelectronic ferrocene

Isolation and Characterization of Lewis Base Stabilized Monomeric Parent Stibanylboranes

Lewis Acid/Base Stabilized Phosphanylalane and -gallane This work was supported by the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie. A.Y.T. is grateful to the Alexander von Humboldt Foundation for a research fellowship

Lewis acid stabilized group 13–15 element analogs of ethylene

Low-valent group-13 chemistry. Theoretical investigation of the structures and relative stabilities of donor-acceptor complexes R(3)E[bond]E'R' and their isomers R(2)E[bond]E'RR'.

Masking of Lewis acidity trends in the solid-state structures of trichlorido- and tribromido(2,2':6',2''-terpyridine-κ(3)N,N',N'')gallium(III)

Mechanisms of Hydrogen Generation from Tetrameric Clusters of Lithium Amidoborane

Monomeric β-Diketiminato Group 13 Metal Dipnictogenide Complexes with Two Terminal EH2 Groups (E=P, As)

Normal to abnormal ItBu·AlH3 isomerization in solution and in the solid state

Novel group 13 Lewis superacids and 13-15 donor-acceptor cryptands for hydrogen activation: a theoretical study

Phosphanylalanes and Phosphanylgallanes Stabilized only by a Lewis Base

Reaction of Pentelidene Complexes with Diazoalkanes: Stabilization of Parent 2,3-Dipnictabutadienes

Reaction of tungsten-phosphinidene and -arsinidene complexes with carbodiimides and alkyl azides: a straightforward way to four-membered heterocycles

Reactivity of bridged pentelidene complexes with isonitriles: a new way to pentel-containing heterocycles

Redox and Coordination Behavior of the Hexaphosphabenzene Ligand in [(Cp*Mo)2 (μ,η(6) :η(6) -P6 )] Towards the "Naked" Cations Cu(+) , Ag(+) , and Tl(.).

Selective Dimerization of Lewis-Acid/Base-Stabilized Phosphanylalanes

Selective formation and unusual reactivity of tetraarsabicyclo[1.1.0]butane complexes

Selective halogenation at the pnictogen atom in Lewis-acid/base-stabilised phosphanylboranes and arsanylboranes

Spontaneous gas-phase generation of needle-shaped clusters which violate the isolated square rule: a facile road to GaN nanorods?

Stepwise Formation of a 1,3-Butadiene Analogue of Mixed Heavier Group 15 Elements

Stepwise activation of "non-innocent" Cp* substituents--a Cp* based cascade reaction

Stepwise expansion of a Cp* ring at pentelidene complexes and stereoselective formation of triphosphines

Structural and thermodynamic properties of group 13 imidometallanes and their heavier analogues

Structural and thermodynamic properties of molecular complexes of aluminum and gallium trihalides with bifunctional donor pyrazine: decisive role of Lewis acidity in 1D polymer formation

Structure and stability of M6N8 clusters (M = Si, Ge, Sn, Ti)

Structures and stability of molecular InBr3Py(x) (x = 1-3) complexes: unexpected solid state stabilization of dimeric In2Br6Py4 as compared to valence-isoelectronic group 15 and 17 halogen bridging dimers.

The Cobalt cyclo-P4 Sandwich Complex and Its Role in the Formation of Polyphosphorus Compounds

The Lewis Base Stabilized Parent Arsanylborane H2AsBH2⋅NMe3.

The Lewis-Base-Stabilized Diphenyl-Substituted Arsanylborane: A Versatile Building Block for Arsanylborane Oligomers

The effect of terminal substituents on the electronic properties of rod-shaped [HGaNH]n oligomers.

The oligomerization of phosphinoborane by titanium complexes

The road to 13-15 nano structures: structures and energetics of (MYH(2))(4) tetramers (M = B, Al, Ga; Y = N, P, As)

The stabilization of monomeric parent compounds of phosphanyl- and arsanylboranes

Theoretical studies of [MYR2]n isomers (M = B, Al, Ga; Y = N, P, As; R = H, CH3): structures and energetics of monomeric and dimeric compounds (n = 1, 2)

Thermodynamics of the decomposition processes of donor-acceptor complexes MX3 x en x MX3 and MX3 x en

Transformation of nortricyclane type cage compounds P4S3, P4Se3 and As4S3 by [Cp''2Zr(CO)2].

Trimeric cluster of lithium amidoborane-the smallest unit for the modeling of hydrogen release mechanism

Triple-decker sandwich complexes with a bent cyclo-P5 middle-deck

Unexpected differences in the reactivity between the phosphorus and arsenic derivatives [(CpBIGFe)2(μ,η4:4-E4)] (E = P and As).

Versatile structures of group 13 metal halide complexes with 4,4′-bipy: from 1D coordination polymers to 2D and 3D metal–organic frameworks

Violation of the isolated square rule for group 13-15 oligomers: theoretical prediction of a new class of inorganic polymers

Why Do B-P and Al-P Polymers Differ? Structures, Stability, and Electronic Properties of Chain and Ring [H2 PEH2 ]n Oligomers (E=B, Al; n=1-15)