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List of works by Koji Hirano

2,6-Diphenyl- and -distyryl-capped 3,7-dialkoxybenzo[1,2-b:4,5-b']dithiophenes and their dithieno-annulated higher homologs: structural phase transition with enhanced charge carrier mobility

scientific article published in September 2014

A Divergent Approach to Indoles and Oxazoles from Enamides by Directing-Group-Controlled Cu-Catalyzed Intramolecular C-H Amination and Alkoxylation.

scientific article published on 7 August 2017

A concise access to (polyfluoroaryl)allenes by Cu-catalyzed direct coupling with propargyl phosphates

scientific article published on 02 May 2012

A lesson for site-selective C-H functionalization on 2-pyridones: radical, organometallic, directing group and steric controls.

scientific article published on 27 November 2017

A new entry of amination reagents for heteroaromatic C-H bonds: copper-catalyzed direct amination of azoles with chloroamines at room temperature

scientific article published on 01 May 2010

An annulative electrophilic amination approach to 3-aminobenzoheteroles

scientific article published on 15 December 2011

An approach to benzophosphole oxides through silver- or manganese-mediated dehydrogenative annulation involving C-C and C-P bond formation

scientific article published on 11 October 2013

Asymmetric Synthesis of Diarylmethyl Sulfones by Palladium-Catalyzed Enantioselective Benzylic Substitution: A Remarkable Effect of Water

scientific article published on 14 April 2018

Asymmetric Synthesis of α-Aminoboronic Acid Derivatives by Copper-Catalyzed Enantioselective Hydroamination

scientific article published on 14 December 2015

Boron trifluoride-mediated alkylation of diphenylphosphine with tert-alkyl fluoride

scientific article published in December 2004

Brønsted Base Mediated Stereoselective Diphosphination of Terminal Alkynes with Diphosphanes.

scientific article published on 17 May 2017

Construction of Bisbenzofuro[2,3-b:3',2'-e]pyridines by Palladium-Catalyzed Double Intramolecular Oxidative C-H/C-H Coupling.

scientific article published on 23 February 2017

Copper-Catalyzed Direct Sulfoximination of Azoles and Polyfluoroarenes under Ambient Conditions

scholarly article by Mitsuru Miyasaka et al published 4 February 2011 in Organic Letters

Copper-Catalyzed Electrophilic Amination of gem-Diborylalkanes with Hydroxylamines Providing α-Aminoboronic Acid Derivatives

scientific article published on 05 June 2019

Copper-Catalyzed Formal [4 + 1] Cycloaddition of Benzamides and Isonitriles via Directed C-H Cleavage

scientific article published on 3 August 2015

Copper-Catalyzed Intramolecular Benzylic C-H Amination for the Synthesis of Isoindolinones

scientific article published on 9 August 2016

Copper-Catalyzed Regio- and Enantioselective Aminoboration of Unactivated Terminal Alkenes

scientific article published on 23 March 2018

Copper-Catalyzed Regio- and Stereoselective Aminoboration of Alkenylboronates

scientific article published on 20 September 2016

Copper-Catalyzed Regioselective Ring-Opening Hydroamination of Methylenecyclopropanes.

scientific article

Copper-Catalyzed Vicinal Diphosphination of Styrenes: Access to 1,2-Bis(diphenylphosphino)ethane-Type Bidentate Ligands from Olefins

scientific article published on 27 September 2016

Copper-Mediated Decarboxylative Coupling of Benzamides with ortho-Nitrobenzoic Acids by Directed C-H Cleavage

scientific article

Copper-Mediated Oxidative Coupling of Benzamides with Maleimides via Directed C-H Cleavage

scientific article published on 30 July 2015

Copper-Mediated Regioselective C-H Sulfenylation and Selenation of Phenols with Phenanthroline Bidentate Auxiliary

scientific article published on 16 July 2020

Copper-catalyzed amination of arylboronates with N,N-dialkylhydroxylamines

scientific article published on 01 March 2012

Copper-catalyzed amination of ketene silyl acetals with hydroxylamines: electrophilic amination approach to α-amino acids

scientific article published on 15 October 2012

Copper-catalyzed annulative amination of ortho-alkynylphenols with hydroxylamines: synthesis of 3-aminobenzofurans by umpolung amination strategy

scientific article published on 30 March 2011

Copper-catalyzed direct amination of electron-deficient arenes with hydroxylamines

scientific article published on 06 May 2011

Copper-catalyzed electrophilic amination of arylsilanes with hydroxylamines

scientific article published on 20 December 2012

Copper-catalyzed enantioselective formal hydroamination of oxa- and azabicyclic alkenes with hydrosilanes and hydroxylamines

scientific article

Copper-catalyzed intermolecular regioselective hydroamination of styrenes with polymethylhydrosiloxane and hydroxylamines

scientific article

Copper-catalyzed oxidative direct cyclization of N-methylanilines with electron-deficient alkenes using molecular oxygen

scientific article published on 11 July 2011

Copper-catalyzed stereoselective aminoboration of bicyclic alkenes

scientific article

Copper-catalyzed α-methylenation of benzylpyridines using dimethylacetamide as one-carbon source

scientific article

Copper-mediated C-H/C-H biaryl coupling of benzoic acid derivatives and 1,3-azoles

scientific article published on 19 March 2013

Copper-mediated C6-selective dehydrogenative heteroarylation of 2-pyridones with 1,3-azoles

scientific article published on 19 August 2014

Copper-mediated and copper-catalyzed cross-coupling of indoles and 1,3-azoles: double C-H activation

scientific article published on 31 May 2012

Copper-mediated annulative direct coupling of o-alkynylphenols with oxadiazoles: a dehydrogenative cascade construction of biheteroaryls

scientific article published on 17 May 2011

Copper-mediated dehydrogenative biaryl coupling of naphthylamines and 1,3-azoles.

scientific article published on 21 October 2013

Copper-mediated direct arylation of 1,3,4-oxadiazoles and 1,2,4-triazoles with aryl iodides

scientific article published on 01 July 2009

Copper-mediated direct cross-coupling of 1,3,4-oxadiazoles and oxazoles with terminal alkynes

scientific article published on 01 February 2010

Copper-mediated formally dehydrative biaryl coupling of azine N-oxides and oxazoles

scientific article published on 02 February 2015

Copper-mediated intermolecular direct biaryl coupling

scientific article published on 26 January 2011

Copper-mediated oxidative direct C-C (hetero)aromatic cross-coupling

scientific article published on 01 November 2012

Copper/Bisphosphine Catalysts in the Internally Borylative Aminoboration of Unactivated Terminal Alkenes with Bis(pinacolato)diboron.

scientific article

Diphosphination of 1,3-Dienes with Diphosphines under Visible-Light-Promoted Photoredox Catalysis

scientific article published on 06 December 2018

Diphosphination of Arynes with Diphosphines

scientific article published on 06 June 2018

Direct Synthesis of Dibenzophospholes from Biaryls by Double C-P Bond Formation via Phosphenium Dication Equivalents

scientific article published on 07 April 2020

Direct synthesis of N-H carbazoles via iridium(III)-catalyzed intramolecular C-H amination

scientific article published on 11 March 2015

Effect of the substitution pattern of alkyl side chain in a benzodithiophene core π-system on intra and inter-molecular charge carrier mobility

scientific article

Evaluation of the intrinsic charge carrier transporting properties of linear- and bent-shaped π-extended benzo-fused thieno[3,2-b]thiophenes

scientific article published in April 2015

Fluorescent diarylindoles by palladium-catalyzed direct and decarboxylative arylations of carboxyindoles

scientific article published in January 2009

Fused ring construction around pyrrole, indole, and related compounds via palladium-catalyzed oxidative coupling with alkynes.

scientific article published in October 2009

Gallium-mediated allyl transfer from bulky homoallylic alcohol to aldehydes via retro-allylation: stereoselective synthesis of both erythro- and threo-homoallylic alcohols

scientific article published in August 2005

Highly Stereoselective Synthesis of 1,2-Disubstituted Indanes by Pd-Catalyzed Heck/Suzuki Sequence of Diarylmethyl Carbonates

scientific article published on 03 April 2020

Highly stereoselective synthesis of (borylmethyl)cyclopropylamines by copper-catalyzed aminoboration of methylenecyclopropanes

scientific article

Iridium-catalyzed annulative coupling of 2-arylbenzoyl chlorides with alkynes: selective formation of phenanthrene derivatives

scientific article published on 18 September 2014

Ligand-controlled regiodivergent cu-catalyzed aminoboration of unactivated terminal alkenes

scientific article published on 15 May 2015

Manganese-mediated C3-selective direct alkylation and arylation of 2-pyridones with diethyl malonates and arylboronic acids

scientific article

Metal-Free Electrophilic Phosphination/Cyclization of Alkynes.

scientific article

Nickel- and cobalt-catalyzed direct alkylation of azoles with N-tosylhydrazones bearing unactivated alkyl groups

scientific article published on 07 December 2011

Nickel- and copper-catalyzed direct alkynylation of azoles and polyfluoroarenes with terminal alkynes under O(2) or atmospheric conditions

scientific article published on 01 May 2010

Nickel- and rhodium-catalyzed addition of terminal silylacetylenes to propargyl amines: catalyst-dependent complementary regioselectivity

scientific article

Nickel-Catalyzed Directed C6-Selective C-H Alkylation of 2-Pyridones with Dienes and Activated Alkenes.

scientific article published on 27 April 2017

Nickel-Catalyzed Stereospecific C-H Coupling of Benzamides with Epoxides

scientific article published on 06 August 2018

Nickel-catalysed reactions with trialkylboranes and silacyclobutanes

scientific article published on 12 May 2008

Nickel-catalyzed 1,4-addition of trialkylboranes to alpha,beta-unsaturated esters: dramatic enhancement by addition of methanol

scientific article published on 16 March 2007

Nickel-catalyzed C-H alkenylation and alkylation of 1,3,4-oxadiazoles with alkynes and styrenes.

scientific article published in August 2009

Nickel-catalyzed alkylation of aldehydes with trialkylboranes

scientific article published in October 2005

Nickel-catalyzed allylation of allyl carbonates with homoallyl alcohols via retro-allylation providing 1,5-hexadienes

scientific article published on 21 March 2008

Nickel-catalyzed beta-boration of alpha,beta-unsaturated esters and amides with bis(pinacolato)diboron

scientific article

Nickel-catalyzed carboxylation of organozinc reagents with CO2

scientific article published on 04 June 2008

Nickel-catalyzed direct C-H arylation and alkenylation of heteroarenes with organosilicon reagents

scientific article published on 01 March 2010

Nickel-catalyzed direct alkylation of heterocycles with α-bromo carbonyl compounds: C3-selective functionalization of 2-pyridones

scientific article published on 02 May 2013

Nickel-catalyzed direct alkynylation of azoles with alkynyl bromides

scientific article published on 01 September 2009

Nickel-catalyzed direct arylation of azoles with aryl bromides

scientific article published on 01 April 2009

Nickel-catalyzed reactions of silacyclobutanes with aldehydes: ring opening and ring expansion reaction

scientific article published in February 2006

Nickel-catalyzed regio- and stereoselective silylation of terminal alkenes with silacyclobutanes: facile access to vinylsilanes from alkenes

scientific article published on 19 April 2007

Palladium- and nickel-catalyzed direct alkylation of azoles with unactivated alkyl bromides and chlorides

scientific article published on 01 November 2010

Palladium-Catalyzed Asymmetric Benzylic Alkylation of Active Methylene Compounds with α-Naphthylbenzyl Carbonates and Pivalates

scientific article published on 27 April 2016

Palladium-Catalyzed Asymmetric Benzylic Substitution of Secondary Benzyl Carbonates with Nitrogen and Oxygen Nucleophiles

scientific article published on 27 April 2017

Palladium-Catalyzed Benzylic Phosphorylation of Diarylmethyl Carbonates

scientific article published on 25 May 2018

Palladium-catalyzed decarboxylative arylation of benzoylacrylic acids toward the synthesis of chalcones

scientific article published on 06 May 2013

Palladium-catalyzed direct oxidative alkenylation of azoles

scientific article published on 01 August 2010

Palladium-catalyzed formal cycloaddition of silacyclobutanes with enones: synthesis of eight-membered cyclic silyl enolates

scientific article published on 06 May 2008

Palladium-catalyzed stereo- and regiospecific allylation of aryl halides with homoallyl alcohols via retro-allylation: selective generation and use of sigma-allylpalladium

scientific article published in February 2006

Pd(OAc)2/P(cC6H11)3-catalyzed allylation of aryl halides with homoallyl alcohols via retro-allylation

scientific article published on 21 March 2007

Pd-Catalyzed Regioselective C-H Alkenylation and Alkynylation of Allylic Alcohols with the Assistance of a Bidentate Phenanthroline Auxiliary

scientific article published on 04 November 2020

Phosphenium-Cation-Mediated Formal Cycloaddition Approach to Benzophospholes

scientific article published on 16 August 2018

Regioselective C-H bond cleavage/alkyne insertion under ruthenium catalysis

scientific article published on 27 December 2012

Regioselective Synthesis of Benzo[b]phosphole Derivatives via Direct ortho-Alkenylation and Cyclization of Arylthiophosphinamides

scientific article published on 11 October 2016

Regioselective and stereospecific copper-catalyzed aminoboration of styrenes with bis(pinacolato)diboron and O-benzoyl-N,N-dialkylhydroxylamines.

scientific article

Rhodium(III)-catalyzed ortho-alkenylation through C-H bond cleavage directed by sulfoxide groups

scientific article published on 12 February 2014

Rhodium(III)-catalyzed oxidative alkenylation of 1,3-dithiane-protected arenecarbaldehydes via regioselective C-H bond cleavage

scientific article published on 16 January 2015

Rhodium(III)-catalyzed oxidative coupling through C-H bond cleavage directed by phosphinoxy groups

scientific article published on 17 June 2013

Rhodium(III)-catalyzed regioselective C-H alkenylation of phenylphosphine sulfides

scientific article published on 4 August 2014

Rhodium- and iridium-catalyzed dehydrogenative cyclization through double C-H bond cleavages to produce fluorene derivatives

scientific article published on 05 February 2013

Rhodium-Catalyzed C6-Selective C-H Borylation of 2-Pyridones

scientific article published on 15 July 2016

Rhodium-catalyzed C3-selective alkenylation of substituted thiophene-2-carboxylic acids and related compounds.

scientific article published on 8 July 2013

Rhodium-catalyzed Direct Coupling of Benzothioamides with Alkenes and Alkynes through Directed C–H Bond Cleavage

scholarly article by Yuki Yokoyama et al published 5 August 2015 in Chemistry Letters

Rhodium-catalyzed Intramolecular Dehydrogenative Aryl–Aryl Coupling Using Air as Terminal Oxidant

Rhodium-catalyzed allyl transfer from homoallyl alcohols to aldehydes via retro-allylation followed by isomerization into ketones

scientific article published in June 2006

Rhodium-catalyzed allylation of aldehydes with homoallylic alcohols by retroallylation and isomerization to saturated ketones with conventional or microwave heating

scientific article published in January 2008

Rhodium-catalyzed annulative coupling of 3-phenylthiophenes with alkynes involving double C-H bond cleavages

scientific article published on 29 November 2013

Rhodium-catalyzed decarboxylative and dehydrogenative coupling of maleic acids with alkynes and alkenes.

scientific article

Rhodium-catalyzed dehydrogenative coupling of phenylheteroarenes with alkynes or alkenes

scientific article published on 23 February 2015

Rhodium-catalyzed mono- and divinylation of 1-phenylpyrazoles and related compounds via regioselective C-H bond cleavage

scientific article published in September 2009

Rhodium-catalyzed oxidative 1:1, 1:2, and 1:4 coupling reactions of phenylazoles with internal alkynes through the regioselective cleavages of multiple C-H bonds

scientific article published on 08 December 2010

Rhodium-catalyzed oxidative coupling of aromatic imines with internal alkynes via regioselective C-H bond cleavage.

scientific article published on 28 July 2009

Rhodium-catalyzed oxidative coupling/cyclization of 2-phenylindoles with alkynes via C-H and N-H bond cleavages with air as the oxidant.

scientific article published in May 2010

Rhodium-catalyzed regioselective olefination directed by a carboxylic group

scientific article published on 01 April 2011

Rhodium/phosphine/amine.HBr catalyst system for highly selective cross-cyclodimerization of aryl- and alkylalkynes: efficient access to multisubstituted naphthalene derivatives

scientific article published in January 2010

Room temperature direct alkynylation of 1,3,4-oxadiazoles with alkynyl bromides under copper catalysis.

scientific article published in March 2010

Ru/Ag-Catalyzed Oxidative Alkenylation of Benzamides and Phenylazoles through Regioselective C–H Bond Cleavage

article published in 2012

Ruthenium(II)-catalyzed regio- and stereoselective hydroarylation of alkynes via directed C-H functionalization

scientific article published on 05 April 2012

Ruthenium-catalyzed ortho-alkenylation of phenylphosphine oxides through regio- and stereoselective alkyne insertion into C-H bonds.

scientific article

Ruthenium-catalyzed oxidative vinylation of heteroarene carboxylic acids with alkenes via regioselective C-H bond cleavage

scientific article published on 18 January 2011

Ruthenium-catalyzed regioselective C-H alkenylation directed by a free amino group

scientific article published on 24 July 2013

Silver-catalyzed transmetalation between chlorosilanes and aryl and alkenyl Grignard reagents for the synthesis of tetraorganosilanes

scientific article published in January 2008

Stereospecific Pd-Catalyzed Intermolecular C(sp(3))-C(sp) Cross-Coupling of Diarylmethyl Carbonates and Terminal Alkynes Under Base-Free Conditions

scientific article published on 6 October 2015

Stereospecific copper-catalyzed C-H allylation of electron-deficient arenes with allyl phosphates

scientific article published on 25 February 2011

Synthesis of (arylalkenyl)silanes by palladium-catalyzed regiospecific and stereoselective allyl transfer from silyl-substituted homoallyl alcohols to aryl halides

scientific article published on 29 September 2007

Synthesis of Benzo[c]thiophenes by Rhodium(III)-Catalyzed Dehydrogenative Annulation

scientific article published on 03 March 2016

Synthesis of DPPP- and DPPPEN-Type Bidentate Ligands by Ring-Opening Diphosphination of Methylene- and Vinylcyclopropanes under Visible-Light-Promoted Photoredox Catalysis

scientific article published on 07 April 2020

Synthesis of Dibenzophospholes by Tf2O-Mediated Intramolecular Phospha-Friedel-Crafts-Type Reaction

scientific article published on 14 February 2019

Synthesis of Indolo[1,2-a][1,8]naphthyridines by Rhodium(III)-Catalyzed Dehydrogenative Coupling via Rollover Cyclometalation

scientific article published on 11 June 2015

Synthesis of N-azolylindoles by copper-catalyzed C-H/N-H coupling-annulation sequence of o-alkynylanilines

scientific article published on 11 January 2012

Synthesis of N-vinylcarbazoles via dehydrogenative coupling of N-H carbazoles with alkenes under palladium catalysis

scientific article published on 25 February 2013

Synthesis of Seven-Membered Benzolactones by Nickel-Catalyzed C-H Coupling of Benzamides with Oxetanes

scientific article published on 19 March 2019

Synthesis of arylallenes by palladium-catalyzed retro-propargylation of homopropargyl alcohols

scientific article

Synthesis of carbazoles by copper-catalyzed intramolecular C-H/N-H coupling

scientific article

Synthesis of condensed heteroaromatic compounds by palladium-catalyzed oxidative coupling of heteroarene carboxylic acids with alkynes

scientific article published on 01 June 2009

Synthesis of enantiomerically pure P-stereogenic diphosphacrowns and their palladium complexes

scientific article published on 03 February 2011

Synthesis of fluorene derivatives through rhodium-catalyzed dehydrogenative cyclization

scientific article published on 19 April 2012

Synthesis of functionalized alpha-pyrone and butenolide derivatives by rhodium-catalyzed oxidative coupling of substituted acrylic acids with alkynes and alkenes.

scientific article published in August 2009

Synthesis of highly substituted acenes through rhodium-catalyzed oxidative coupling of arylboron reagents with alkynes

scientific article published on 21 March 2011

Synthesis of highly substituted naphthalene and anthracene derivatives by rhodium-catalyzed oxidative coupling of arylboronic acids with alkynes

scientific article published on 01 November 2009

Synthesis of indolines by copper-mediated intramolecular aromatic C-h amination

scientific article published on 05 March 2015

Synthesis of isochromene and related derivatives by rhodium-catalyzed oxidative coupling of benzyl and allyl alcohols with alkynes

scientific article published on 17 October 2011

Synthesis of naphtho[1,8-bc]pyran derivatives and related compounds through hydroxy group directed C-H bond cleavage under rhodium catalysis.

scientific article published in April 2010

Synthesis of stilbene and distyrylbenzene derivatives through rhodium-catalyzed ortho-olefination and decarboxylation of benzoic acids.

scientific article published on 18 November 2010

Synthesis of triarylmethanes by palladium-catalyzed C-H/C-O coupling of oxazoles and diarylmethanol derivatives

scientific article published on 11 June 2014

Synthesis of α-Aminophosphines by Copper-Catalyzed Regioselective Hydroamination of Vinylphosphines

scientific article published on 05 July 2018

Synthesis of α-Trifluoromethylamines by Cu-Catalyzed Regio- and Enantioselective Hydroamination of 1-Trifluoromethylalkenes

scientific article published on 13 May 2019

Synthesis of β-Boryl-α-Aminosilanes by Copper-Catalyzed Aminoboration of Vinylsilanes

scientific article published on 18 October 2016

Triethylborane-induced radical allylation reaction with zirconocene-olefin complex.

scientific article published in February 2004

Unexpected cyclization of tritylamines promoted by copper salt through C-H and C-N bond cleavages to produce acridine derivatives

scientific article published on 04 September 2014

Waste-free synthesis of condensed heterocyclic compounds by rhodium-catalyzed oxidative coupling of substituted arene or heteroarene carboxylic acids with alkynes

scientific article published on 01 May 2009

vic-Diphosphination of Alkenes with Silylphosphine under Visible-Light-Promoted Photoredox Catalysis.

scientific article published on 24 August 2017

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