List of works - Nicolas Blanchard

2,2-Dimethyl-5-nitroso-1,3-dioxan-5-yl benzoate, 2,2-dimethyl-5-nitroso-1,3-dioxan-5-yl 4-chlorobenzoate and 5-nitroso-1,3-dioxan-5-yl 4-chlorobenzoate

2-Deoxy-2-iodo-β-glucopyranosyl Fluorides: Mild and Highly Stereoselective Glycosyl Donors for the Synthesis of 2-Deoxy-β-glycosides from β-Hydroxy Ketones

article

A Diverted Total Synthesis of Mycolactone Analogues: An Insight into Buruli Ulcer Toxins

article by Anne-Caroline Chany et al published 30 November 2011 in Chemistry—A European Journal

A Journey in the Chemistry of Ynamides: From Synthesis to Applications

article published in 2016

A Novel Photopolymerization Initiating System Based on an Iridium Complex Photocatalyst

scholarly article by Jacques Lalevée et al published 21 April 2011 in Macromolecular Rapid Communications

A Straightforward Entry to γ-Trifluoromethylated Allenamides and Their Synthetic Applications

A Walk Across Africa with Captain Grant

article

Acid Fluorides in Transition-Metal Catalysis: A Good Balance between Stability and Reactivity

scientific article published on 09 April 2019

Acid-catalyzed ring-opening reactions of a cyclopropanated 3-aza-2-oxabicyclo[2.2.1]hept-5-ene with alcohols

scientific article published on 27 December 2017

Activating Pyrimidines by Pre-distortion for the General Synthesis of 7-Aza-indazoles from 2-Hydrazonylpyrimidines via Intramolecular Diels-Alder Reactions

scientific article published on 09 September 2019

An Approach Toward Homocalystegines and Silyl-homocalystegines. Acid-Mediated Migrations of Acetates in Seven-Membered Ring Systems

article published in 2011

Aryl transition metal chemical warheads for protein bioconjugation

article published in 2018

BODIPY derivatives and boranil as new photoinitiating systems of cationic polymerization exhibiting a tunable absorption in the 400–600 nm spectral range

Bis(germyl)ketones: Toward a New Class of Type I Photoinitiating Systems Sensitive Above 500 nm?

scientific article

Boron chemistry in a new light

scientific article

Chapter 10 Total synthesis of zincophorin and its methyl ester

Chopping unfunctionalized carbon–carbon bonds: a new paradigm for the synthesis of organonitriles

Controlled synthesis of branched poly(vinyl acetate)s by xanthate-mediated RAFT self-condensing vinyl (co)polymerization

article

Copper-mediated coupling reactions and their applications in natural products and designed biomolecules synthesis

scientific article published on August 2008

Copper-mediated synthesis of N-vinyl ynamides from N-vinyl carbamates

Daucus carota L. mediated bioreduction of prochiral ketones

Decatungstate (W10O32(4-))/silane: a new and promising radical source under soft light irradiation

scientific article

Diastereoselective Hydroboration of Isopropenylcyclopropanes

scientific article published on 01 April 1999

Diastereoselectivity in the dihydroxylation of isopropenyl substituted three-membered rings

Diels-Alder and Formal Diels-Alder Cycloaddition Reactions of Ynamines and Ynamides

Domino metathesis of 3,6-dihydro-1,2-oxazine: access to isoxazolo[2,3-a]pyridin-7-ones

scientific article published on 13 March 2007

Effect of Lewis base coordination on boryl radical reactivity: investigation using laser flash photolysis and kinetic ESR

article

Efficient cleavage of the N-O bond of 3,6-dihydro-1,2-oxazines mediated by some alpha-hetero substituted carbonyl compounds in mild conditions

scientific article published on 12 February 2008

Efficient dual radical/cationic photoinitiator under visible light: a new concept

scholarly article by Jacques Lalevée et al published 2011 in Polymer Chemistry

Fluorescent Brighteners as Visible LED-Light Sensitive Photoinitiators for Free Radical Photopolymerizations

Formation of N-heterocyclic carbene-boryl radicals through electrochemical and photochemical cleavage of the B-S bond in N-heterocyclic carbene-boryl sulfides.

scientific article

Green Bulb Light Source Induced Epoxy Cationic Polymerization under Air Using Tris(2,2′-bipyridine)ruthenium(II) and Silyl Radicals

article

History, biology and chemistry of Mycobacterium ulcerans infections (Buruli ulcer disease).

scientific article published on December 2013

Household LED irradiation under air: cationic polymerization using iridium or ruthenium complex photocatalysts

scholarly article by Jacques Lalevée et al published 12 June 2011 in Polymer Bulletin

Intermolecular nitroso Diels–Alder cycloaddition of α-acetoxynitroso derivatives in aqueous medium

Intramolecular Inverse Electron-Demand [4 + 2] Cycloadditions of Ynamides with Pyrimidines: Scope and Density Functional Theory Insights

scientific article published on 6 January 2017

Intramolecular inverse electron-demand [4+2] cycloadditions of ynamidyl-tethered pyrimidines: Comparative studies in trifluorotoluene and sulfolane

Inverse Electron-Demand [4 + 2]-Cycloadditions of Ynamides: Access to Novel Pyridine Scaffolds

article

Ipomoeassin F Binds Sec61α to Inhibit Protein Translocation

scientific article published on 15 May 2019

Iridium Photocatalysts in Free Radical Photopolymerization under Visible Lights

scholarly article by Jacques Lalevée et al published 18 January 2012 in ACS Macro Letters

Lewis acid-promoted hetero Diels-Alder cycloaddition of alpha-acetoxynitroso dienophiles

scientific article

Mechanistic and preparative studies of radical chain homolytic substitution reactions of N-heterocyclic carbene boranes and disulfides

scientific article

Metathesis of heteroatom-substituted olefins and alkynes: Current scope and limitations

article

Modular total syntheses of mycolactone A/B and its [2H]-isotopologue

article

Mycolactone subverts immunity by selectively blocking the Sec61 translocon.

scientific article

Near UV–visible light induced cationic photopolymerization reactions: A three component photoinitiating system based on acridinedione/silane/iodonium salt

scholarly article by Mohamad-Ali Tehfe et al published November 2010 in European Polymer Journal

New Photoiniferters: Respective Role of the Initiating and Persistent Radicals

New Photoinitiators Based on the Silyl Radical Chemistry: Polymerization Ability, ESR Spin Trapping, and Laser Flash Photolysis Investigation

New boryl radicals derived from N-heteroaryl boranes: generation and reactivity

scientific article

New thioxanthone and xanthone photoinitiators based on silyl radical chemistry

Novel applications of fluorescent brighteners in aqueous visible-light photopolymerization: high performance water-based coating and LED-assisted hydrogel synthesis

scholarly article by Xiaoling Zuo et al published 2018 in Polymer Chemistry

On the Synthesis, Characterization and Reactivity of N-Heteroaryl-Boryl Radicals, a New Radical Class Based on Five-Membered Ring Ligands

Organic Photocatalyst for Polymerization Reactions: 9,10-Bis[(triisopropylsilyl)ethynyl]anthracene

article

Photopolymerization of Cationic Monomers and Acrylate/Divinylether Blends under Visible Light Using Pyrromethene Dyes

scholarly article by Sofia Telitel et al published 24 August 2012 in Macromolecules

Photoredox catalysis for polymerization reactions.

scientific article published in January 2012

Practical Methods for the Synthesis of Trifluoromethylated Alkynes: Oxidative Trifluoromethylation of Copper Acetylides and Alkynes

scholarly article by Cédric Tresse et al published 13 May 2014 in Advanced Synthesis & Catalysis

Reaction between aminoalkyl radicals and akyl halides: Dehalogenation by electron transfer?

Recombinant Antibodies against Mycolactone

scientific article published on 17 June 2019

Rhodium-catalyzed ring-opening reactions of a 3-aza-2-oxabicyclo[2.2.1]hept-5-ene with arylboronic acids

scientific article published in October 2009

Ruthenium-Catalyzed Nucleophilic Ring-Opening Reactions of a 3-Aza-2-oxabicyclo[2.2.1]hept-5-ene with Alcohols

article

Ruthenium-catalyzed [2+2] cycloaddition reactions of a 2-oxa-3-azabicyclo[2.2.1]hept-5-ene with unsymmetrical alkynes

article

Shaping mycolactone for therapeutic use against inflammatory disorders

scientific article published on May 2015

Silyl Radical Chemistry and Conventional Photoinitiators: A Route for the Design of Efficient Systems

Silyloxyamines as sources of silyl radicals: ESR spin-trapping, laser flash photolysis investigation, and photopolymerization ability

Soft Photopolymerizations Initiated by Dye-Sensitized Formation of NHC-Boryl Radicals under Visible Light

article

Spatiotemporal analysis of mycolactone distribution in vivo reveals partial diffusion in the central nervous system

scientific article published on 02 December 2020

Stereodivergent Hydrogermylations of α-Trifluoromethylated Alkynes and Their Applications in Cross-Coupling Reactions

scientific article published in 2015

Stereodivergent Hydrosilylation, Hydrostannylation, and Hydrogermylation of α-Trifluoromethylated Alkynes and Their Synthetic Applications

Stereoselective oxymercuration of cyclopropylcarbinols with anchimeric assistance by aromatic groups

Stereoselective synthesis of polypropionate units and heterocyclic compounds by cyclopropylcarbinol ring-opening with mercury(II) salts

scientific article published in October 2003

Subtle ligand effects in oxidative photocatalysis with iridium complexes: application to photopolymerization

scientific article published on 28 November 2011

Synthesis of Natural Products Containing Medium-Size Carbocycles by Ring-Closing Alkene Metathesis

Synthesis of Polysubstituted Pyrroles from Nitroso-Diels-Alder Cycloadducts

Synthesis of Stereotriads by Oxymercuration of Substituted Cyclopropylcarbinols

scientific article published on 01 August 2001

Synthesis of cyclopropanated [2.2.1] heterobicycloalkenes: An improved procedure

article

Synthesis of polypropionate subunits from cyclopropanes

article published in 2005

Synthesis of spiroketals under neutral conditions via a type III ring-rearrangement metathesis strategy

article published in 2011

Synthetic Variants of Mycolactone Bind and Activate Wiskott–Aldrich Syndrome Proteins

Synthetic strategies towards mycolactone A/B, an exotoxin secreted by Mycobacterium ulcerans

Taming sulfur dioxide: a breakthrough for its wide utilization in chemistry and biology

scientific article published on September 2013

Tandem cationic and sol-gel photopolymerizations of a vinyl ether alkoxysilane

scholarly article in Polymer Engineering and Science, vol. 51 no. 8, March 2011

Total Syntheses of Mycolactone A/B and its Analogues for the Exploration of the Biology of Buruli Ulcer

scientific article published in December 2017

Total Synthesis of Zincophorin Methyl Ester

article by Magali Defosseux et al published October 2003 in Organic Letters

Total Synthesis of the Formamicin Aglycon, Formamicinone

article

Total synthesis of formamicin

scientific article

Total synthesis of zincophorin

Total synthesis of zincophorin and its methyl ester

scientific article

Tris(trimethylsilyl)silyl versus tris(trimethylsilyl)germyl: Radical reactivity and oxidation ability

article

Tunable Organophotocatalysts for Polymerization Reactions Under Visible Lights

Turning unreactive copper acetylides into remarkably powerful and mild alkyne transfer reagents by oxidative umpolung

scientific article

List of works by Nicolas Blanchard

2,2-Dimethyl-5-nitroso-1,3-dioxan-5-yl benzoate, 2,2-dimethyl-5-nitroso-1,3-dioxan-5-yl 4-chlorobenzoate and 5-nitroso-1,3-dioxan-5-yl 4-chlorobenzoate

2-Deoxy-2-iodo-β-glucopyranosyl Fluorides: Mild and Highly Stereoselective Glycosyl Donors for the Synthesis of 2-Deoxy-β-glycosides from β-Hydroxy Ketones

A Diverted Total Synthesis of Mycolactone Analogues: An Insight into Buruli Ulcer Toxins

A Journey in the Chemistry of Ynamides: From Synthesis to Applications

A Novel Photopolymerization Initiating System Based on an Iridium Complex Photocatalyst

A Straightforward Entry to γ-Trifluoromethylated Allenamides and Their Synthetic Applications

A Walk Across Africa with Captain Grant

Acid Fluorides in Transition-Metal Catalysis: A Good Balance between Stability and Reactivity

Acid-catalyzed ring-opening reactions of a cyclopropanated 3-aza-2-oxabicyclo[2.2.1]hept-5-ene with alcohols

Activating Pyrimidines by Pre-distortion for the General Synthesis of 7-Aza-indazoles from 2-Hydrazonylpyrimidines via Intramolecular Diels-Alder Reactions

An Approach Toward Homocalystegines and Silyl-homocalystegines. Acid-Mediated Migrations of Acetates in Seven-Membered Ring Systems

Aryl transition metal chemical warheads for protein bioconjugation

BODIPY derivatives and boranil as new photoinitiating systems of cationic polymerization exhibiting a tunable absorption in the 400–600 nm spectral range

Bis(germyl)ketones: Toward a New Class of Type I Photoinitiating Systems Sensitive Above 500 nm?

Boron chemistry in a new light

Chapter 10 Total synthesis of zincophorin and its methyl ester

Chopping unfunctionalized carbon–carbon bonds: a new paradigm for the synthesis of organonitriles

Controlled synthesis of branched poly(vinyl acetate)s by xanthate-mediated RAFT self-condensing vinyl (co)polymerization

Copper-mediated coupling reactions and their applications in natural products and designed biomolecules synthesis

Copper-mediated synthesis of N-vinyl ynamides from N-vinyl carbamates

Daucus carota L. mediated bioreduction of prochiral ketones

Decatungstate (W10O32(4-))/silane: a new and promising radical source under soft light irradiation

Diastereoselective Hydroboration of Isopropenylcyclopropanes

Diastereoselectivity in the dihydroxylation of isopropenyl substituted three-membered rings

Diels-Alder and Formal Diels-Alder Cycloaddition Reactions of Ynamines and Ynamides

Domino metathesis of 3,6-dihydro-1,2-oxazine: access to isoxazolo[2,3-a]pyridin-7-ones

Effect of Lewis base coordination on boryl radical reactivity: investigation using laser flash photolysis and kinetic ESR

Efficient cleavage of the N-O bond of 3,6-dihydro-1,2-oxazines mediated by some alpha-hetero substituted carbonyl compounds in mild conditions

Efficient dual radical/cationic photoinitiator under visible light: a new concept

Fluorescent Brighteners as Visible LED-Light Sensitive Photoinitiators for Free Radical Photopolymerizations

Formation of N-heterocyclic carbene-boryl radicals through electrochemical and photochemical cleavage of the B-S bond in N-heterocyclic carbene-boryl sulfides.

Green Bulb Light Source Induced Epoxy Cationic Polymerization under Air Using Tris(2,2′-bipyridine)ruthenium(II) and Silyl Radicals

History, biology and chemistry of Mycobacterium ulcerans infections (Buruli ulcer disease).

Household LED irradiation under air: cationic polymerization using iridium or ruthenium complex photocatalysts

Intermolecular nitroso Diels–Alder cycloaddition of α-acetoxynitroso derivatives in aqueous medium

Intramolecular Inverse Electron-Demand [4 + 2] Cycloadditions of Ynamides with Pyrimidines: Scope and Density Functional Theory Insights

Intramolecular inverse electron-demand [4+2] cycloadditions of ynamidyl-tethered pyrimidines: Comparative studies in trifluorotoluene and sulfolane

Inverse Electron-Demand [4 + 2]-Cycloadditions of Ynamides: Access to Novel Pyridine Scaffolds

Ipomoeassin F Binds Sec61α to Inhibit Protein Translocation

Iridium Photocatalysts in Free Radical Photopolymerization under Visible Lights

Lewis acid-promoted hetero Diels-Alder cycloaddition of alpha-acetoxynitroso dienophiles

Mechanistic and preparative studies of radical chain homolytic substitution reactions of N-heterocyclic carbene boranes and disulfides

Metathesis of heteroatom-substituted olefins and alkynes: Current scope and limitations

Modular total syntheses of mycolactone A/B and its [2H]-isotopologue

Mycolactone subverts immunity by selectively blocking the Sec61 translocon.

Near UV–visible light induced cationic photopolymerization reactions: A three component photoinitiating system based on acridinedione/silane/iodonium salt

New Photoiniferters: Respective Role of the Initiating and Persistent Radicals

New Photoinitiators Based on the Silyl Radical Chemistry: Polymerization Ability, ESR Spin Trapping, and Laser Flash Photolysis Investigation

New boryl radicals derived from N-heteroaryl boranes: generation and reactivity

New thioxanthone and xanthone photoinitiators based on silyl radical chemistry

Novel applications of fluorescent brighteners in aqueous visible-light photopolymerization: high performance water-based coating and LED-assisted hydrogel synthesis

On the Synthesis, Characterization and Reactivity of N-Heteroaryl-Boryl Radicals, a New Radical Class Based on Five-Membered Ring Ligands

Organic Photocatalyst for Polymerization Reactions: 9,10-Bis[(triisopropylsilyl)ethynyl]anthracene

Photopolymerization of Cationic Monomers and Acrylate/Divinylether Blends under Visible Light Using Pyrromethene Dyes

Photoredox catalysis for polymerization reactions.

Practical Methods for the Synthesis of Trifluoromethylated Alkynes: Oxidative Trifluoromethylation of Copper Acetylides and Alkynes

Reaction between aminoalkyl radicals and akyl halides: Dehalogenation by electron transfer?

Recombinant Antibodies against Mycolactone

Rhodium-catalyzed ring-opening reactions of a 3-aza-2-oxabicyclo[2.2.1]hept-5-ene with arylboronic acids

Ruthenium-Catalyzed Nucleophilic Ring-Opening Reactions of a 3-Aza-2-oxabicyclo[2.2.1]hept-5-ene with Alcohols

Ruthenium-catalyzed [2+2] cycloaddition reactions of a 2-oxa-3-azabicyclo[2.2.1]hept-5-ene with unsymmetrical alkynes

Shaping mycolactone for therapeutic use against inflammatory disorders

Silyl Radical Chemistry and Conventional Photoinitiators: A Route for the Design of Efficient Systems

Silyloxyamines as sources of silyl radicals: ESR spin-trapping, laser flash photolysis investigation, and photopolymerization ability

Soft Photopolymerizations Initiated by Dye-Sensitized Formation of NHC-Boryl Radicals under Visible Light

Spatiotemporal analysis of mycolactone distribution in vivo reveals partial diffusion in the central nervous system

Stereodivergent Hydrogermylations of α-Trifluoromethylated Alkynes and Their Applications in Cross-Coupling Reactions

Stereodivergent Hydrosilylation, Hydrostannylation, and Hydrogermylation of α-Trifluoromethylated Alkynes and Their Synthetic Applications

Stereoselective oxymercuration of cyclopropylcarbinols with anchimeric assistance by aromatic groups

Stereoselective synthesis of polypropionate units and heterocyclic compounds by cyclopropylcarbinol ring-opening with mercury(II) salts

Subtle ligand effects in oxidative photocatalysis with iridium complexes: application to photopolymerization

Synthesis of Natural Products Containing Medium-Size Carbocycles by Ring-Closing Alkene Metathesis

Synthesis of Polysubstituted Pyrroles from Nitroso-Diels-Alder Cycloadducts

Synthesis of Stereotriads by Oxymercuration of Substituted Cyclopropylcarbinols

Synthesis of cyclopropanated [2.2.1] heterobicycloalkenes: An improved procedure

Synthesis of polypropionate subunits from cyclopropanes

Synthesis of spiroketals under neutral conditions via a type III ring-rearrangement metathesis strategy

Synthetic Variants of Mycolactone Bind and Activate Wiskott–Aldrich Syndrome Proteins

Synthetic strategies towards mycolactone A/B, an exotoxin secreted by Mycobacterium ulcerans