List of works - Sergio Castillón

A new and efficient catalytic method for synthesizing isocyanates from carbamates

A phosphine-free Pd catalyst for the selective double carbonylation of aryl iodides

scientific article published on 21 December 2011

Advances in the enantioselective synthesis of carbocyclic nucleosides.

scientific article

An Efficient and General Enantioselective Synthesis of Sphingosine, Phythosphingosine, and 4-Substituted Derivatives†

scientific article published on 01 January 2009

An efficient method for the synthesis of enantiopure phosphine–imidazoline ligands: application to the Ir-catalyzed hydrogenation of imines

An expeditious and efficient procedure for the synthesis of unsaturated acyclonucleosides of Z configuration related to D4T.

scientific article

An outstanding palladium system containing a C2-symmetrical phosphite ligand for enantioselective allylic substitution processes

scientific article published on 24 October 2008

Asymmetric Hydroformylation

Asymmetric hydroformylation of styrene by rhodium(I) catalysts with chiral ligands containing sulfur donors

scholarly article by Carmen Claver et al published 1993 in Journal of the Chemical Society. Chemical communications

Asymmetric hydroformylation of styrene using a rhodium catalyst with BDPP as the chiral ligand

scholarly article by Anna M. Masdeu-Bultó et al published June 1996 in Tetrahedron: Asymmetry

Asymmetric hydroformylation of styrene using dithiolato bridged dirhodium catalyst with BDPP as chiral ligand

Asymmetric sulfur ylide based enantioselective synthesis of D-erythro-sphingosine.

scientific article published on 17 October 2008

C1 and C2-symmetric carbohydrate phosphorus ligands in asymmetric catalysis

scientific article

C1-Symmetric Diphosphite Ligands Derived from Carbohydrates: Influence of Structural Modifications on the Rhodium-Catalyzed Asymmetric Hydroformylation of Styrene

C1-Symmetric carbohydrate diphosphite ligands for asymmetric Pd-allylic alkylation reactions. Study of the key Pd-allyl intermediates ⬇️

scientific article published on 09 February 2011

C2-symmetric diphosphinite ligands derived from carbohydrates. The strong influence of remote stereocenters on asymmetric rhodium-catalyzed hydrogenation

scientific article published in October 2004

Carbohydrate derivative ligands in asymmetric catalysis

Carbohydrate-derived 1,3-diphosphite ligands as chiral nanoparticle stabilizers: promising catalytic systems for asymmetric hydrogenation.

scientific article published in January 2009

Changing the Palladium Coordination to Phosphinoimidazolines with a Remote Triazole Substituent

Chemo-, regio-, and stereoselective silver-catalyzed aziridination of dienes: scope, mechanistic studies, and ring-opening reactions

scientific article published on 28 March 2014

Chiral Diphosphite‐Modified Rhodium(0) Nanoparticles: Catalyst Reservoir for Styrene Hydroformylation

scholarly article by M. Rosa Axet et al published August 2008 in European Journal of Inorganic Chemistry

Colloidal Ru, Co and Fe-nanoparticles. Synthesis and application as nanocatalysts in the Fischer–Tropsch process

Computational insight into the reaction intermediates in the glycosylation reaction assisted by donor heteroatoms.

scientific article

Conformationally-Locked N-Glycosides with Selective β-Glucosidase Inhibitory Activity: Identification of a New Non-Iminosugar-Type Pharmacological Chaperone for Gaucher Disease

scientific article published on 18 July 2012

Conformationally-locked N-glycosides: Exploiting long-range non-glycone interactions in the design of pharmacological chaperones for Gaucher disease

scientific article published on 04 November 2014

Correlation between Hydrocarbon Product Distribution and Solvent Composition in the Fischer–Tropsch Synthesis Catalyzed by Colloidal Cobalt Nanoparticles

article

Designing an effective approach for obtaining methylenecarboxylate analogues of adenophostin A. Preliminary results

scientific article published in October 2009

Diphosphite ligands derived from carbohydrates as stabilizers for ruthenium nanoparticles: promising catalytic systems in arene hydrogenation

scientific article published on 9 April 2008

Effect of pH on catalyst activity and selectivity in the aqueous Fischer–Tropsch synthesis catalyzed by cobalt nanoparticles

scholarly article by Jorge A. Delgado et al published November 2015 in Catalysis Communications

Efficient recycling of a chiral palladium catalytic system for asymmetric allylic substitutions in ionic liquid

scientific article published on 03 June 2011

Efficient silver-catalyzed regio- and stereospecific aziridination of dienes

scientific article published on 01 September 2010

Enantioselective Formal Synthesis of Nectrisine Using a Palladium-Catalyzed Asymmetric Allylic Amination and Cross-Metathesis as Key Steps

scientific article published on 02 June 2016

Enantioselective Synthesis of 3-Heterosubstituted-2-amino-1-ols by Sequential Metal-Free Diene Aziridination/Kinetic Resolution

scientific article published on 03 September 2019

Enantioselective Synthesis of Aminodiols by Sequential Rh-Catalysed Oxyamination/Kinetic Resolution. Expanding the Substrate Scope of Amidine-Based Catalysis

scientific article published on 17 January 2018

Enhanced regioselectivity in palladium-catalysed asymmetric methoxycarbonylation of styrene using phosphetanes as chiral ligands

Fe-Catalyzed Olefin Epoxidation with Tridentate Non-Heme Ligands and Hydrogen Peroxide as the Oxidant

Fluorinated triazole-containing sphingosine analogues. Syntheses and in vitro evaluation as SPHK inhibitors

scientific article published on 01 October 2018

General Method for Synthesizing Pyranoid Glycals.A New Route to Allal and Gulal Derivatives

scientific article published on 01 February 2006

Heterogenization of Pd–NHC complexes onto a silica support and their application in Suzuki–Miyaura coupling under batch and continuous flow conditions

Highlights of Transition Metal-Catalyzed Asymmetric Hydrogenation of Imines

Highlights of the Rh-catalysed asymmetric hydroformylation of alkenes using phosphorus donor ligands

Highly Efficient Rhodium Catalysts for the Asymmetric Hydroformylation of Vinyl and Allyl Ethers usingC1-Symmetrical Diphosphite Ligands

Highly Selective Palladium-Catalysed Aminocarbonylation of Aryl Iodides using a Bulky Diphosphine Ligand

Highly efficient and stereoselective synthesis of beta-glycolipids

scientific article published on 11 December 2007

Hydroformylation of allyl ethers. A study of the regioselectivity using rhodium catalysts

Hydroformylation of glucal derivatives with rhodium catalysts. Crucial influence of the auxiliary ligand tris(ortho-tert-butylphenyl) phosphite

scholarly article by A. Polo et al published 1992 in Journal of the Chemical Society. Chemical communications

Insights into CO/styrene copolymerization by using Pd(II) catalysts containing modular pyridine-imidazoline ligands

scientific article

Ir(I) complexes with oxazoline-thioether ligands: nucleophilic attack of pyridine on coordinated 1,5-cyclooctadiene and application as catalysts in imine hydrogenation

Modular Synthesis of Functionalisable Alkoxy-Tethered N-Heterocyclic Carbene Ligands and an Active Catalyst for Buchwald-Hartwig Aminations

Montmorillonite K10 as a suitable co-catalyst for atom economy in chelation-assisted intermolecular hydroacylation

New Chiral P-N Ligands for the Regio- and Stereoselective Pd-Catalyzed Dimerization of Styrene

scientific article published on 22 February 2011

New alkyl derivatives phosphine sulfonate (P–O) ligands. Catalytic activity in Pd-catalysed Suzuki–Miyaura reactions in water

scientific article published on 08 June 2007

New camphor-derived sulfur chiral controllers: Synthesis of (2R-exo)-10-methylthio-2-bornanethiol and (2R-exo)-2,10-bis(methylthio)bornane

New chiral diphosphites derived from substituted 9,10-dihydroanthracene. Applications in asymmetric catalytic processes

New dithiolate-bridged rhodium complexes

NewC2-Symmetric Diphosphite Ligands Derived from Carbohydrates: Effect of the Remote Stereocenters on Asymmetric Catalysis

Norbornene Bidentate Ligands: Coordination Chemistry and Enantioselective Catalytic Applications

Novel Polymer Stabilized Water Soluble Ru-Nanoparticles as Aqueous Colloidal Fischer–Tropsch Catalysts

article published in 2013

Oxidative carbonylation of aniline with new cobalt catalytic systems

scholarly article by Aránzazu Orejón et al published June 2005 in Canadian Journal of Chemistry

Palladium Catalytic Species Containing Chiral Phosphites: Towards a Discrimination between Molecular and Colloidal Catalysts

article

Palladium-catalyzed allylic amination: a powerful tool for the enantioselective synthesis of acyclic nucleoside phosphonates

scientific article published on 01 August 2017

Pd-catalysed mono- and dicarbonylation of aryl iodides: insights into the mechanism and the selectivity

scientific article published on 22 July 2014

Phosphine ligands in the palladium-catalysed methoxycarbonylation of ethene: insights into the catalytic cycle through an HP NMR spectroscopic study

scientific article published in June 2010

Phosphine-free Suzuki-Miyaura cross-coupling in aqueous media enables access to 2-C-aryl-glycosides

scientific article published on 13 March 2012

Preparation, structure and reactivity of dinuclear aminothiolate-bridged iridium complexes

scholarly article by Elena Fernández et al published 1995 in Dalton transactions RSC

Recent advances in the glycosylation of sphingosines and ceramides.

scientific article published on 11 April 2007

Recycling of allylic alkylation Pd catalysts containing phosphine-imidazoline ligands in ionic liquids

article published in 2012

Rhodium-catalyzed regio- and stereoselective oxyamination of dienes via tandem aziridination/ring-opening of dienyl carbamates

scientific article published on 01 July 2014

Rhodium-diphosphite catalysed hydroformylation of allylbenzene and propenylbenzene derivatives

scholarly article by M. Rosa Axet et al published June 2006 in Inorganica Chimica Acta

Ruthenium-catalyzed cross-metathesis with electron-rich phenyl vinyl sulfide enables access to 2,3-dideoxy-d-ribopyranose ring system donors

scholarly article in RSC Advances, vol. 4 no. 38, 2014

Selective catalytic deuteration of phosphorus ligands using ruthenium nanoparticles: a new approach to gain information on ligand coordination

scientific article published on 01 November 2015

Selective hydrogenation of α,β-unsaturated oxosteroids with homogeneous rhodium catalysts

Sequential Directed Epoxydation-Acidolysis from Glycals with MCPBA. A Flexible Approach to Protected Glycosyl Donors

Soluble transition-metal nanoparticles-catalysed hydrogenation of arenes ⬇️

scientific article published on October 29, 2010

Stannyl ceramides as efficient acceptors for synthesising β-galactosyl ceramides

scientific article published on 13 August 2008

Stereoselective Synthesis of 2‘,3‘-Dideoxy-3‘-fluoro-2‘-phenylselenenyl- β-nucleosides from Phenyl 1-Seleno-α-arabino-furanosides through Consecutive 1,2-Migration and Glycosylation under Mitsunobu Conditions. A New Entry to 2‘,3‘-Dideo

article published in 1999

Stereoselective synthesis of 2-deoxy-2-iodo-glycosides from furanoses. A new route to 2-deoxy-glycosides and 2-deoxy-oligosaccharides of ribo and xylo configuration.

scientific article published in December 2005

Strategies for the Immobilization of Homogeneous Catalysts and Their Use in the Synthesis of Carbamates

Studies on the Zn(II)-mediated electrophilic selenocyclization and elimination of 3,4-O-isopropylidene-protected hydroxyalkenyl sulfides: synthesis of a 2-phenylselenenyl glycal

scientific article published on 04 March 2010

Syntheses of a Novel Fluorinated Trisphosphinoborate Ligand and Its Copper and Silver Complexes. Catalytic Activity toward Nitrene Transfer Reactions

scientific article published on 04 April 2014

Synthesis of 2-Iodoglycals, Glycals, and 1,1‘-Disaccharides from 2-Deoxy-2-iodopyranoses under Dehydrative Glycosylation Conditions

scientific article published on 11 October 2007

Synthesis of 2-substituted-benzothiazoles by palladium-catalyzed intramolecular cyclization of o-bromophenylthioureas and o-bromophenylthioamides

Synthesis of Fluorosugar Reagents for the Construction of Well-Defined Fluoroglycoproteins

scientific article published on 22 May 2015

Synthesis of carbohydrate-based vinyl selenides via Wittig-type reactions

scientific article published on 14 January 2007

Synthesis of erythro and threo furanoid glycals from 1- and 2-phenylselenenyl-carbohydrate derivatives.

scientific article published in November 2001

Synthesis of novel diphosphines from d-(+)-glucose. Use in asymmetric hydrogenation

Synthesis ofd- andl-Carbocyclic Nucleosides via Rhodium-Catalyzed Asymmetric Hydroacylation as the Key Step

scientific article published on 25 September 2008

The reaction of pyranoside 2-uloses with DAST revised. Synthesis of 1-fluoro-ketofuranosyl fluorides and their reactivity with alcohols

Tridentate chiral NPN ligands based on bis(oxazolines) and their use in Pd-catalyzed enantioselective allylic substitution in molecular and ionic liquids

Tuning the Selectivity in the Hydrogenation of Aromatic Ketones Catalyzed by Similar Ruthenium and Rhodium Nanoparticles

Tuning the Stereoelectronic Properties of 1-Sulfanylhex-1-enitols for the Sequential Stereoselective Synthesis of 2-Deoxy-2-iodo-β-d-allopyranosides

scientific article published on 21 March 2014

List of works by Sergio Castillón

A new and efficient catalytic method for synthesizing isocyanates from carbamates

A phosphine-free Pd catalyst for the selective double carbonylation of aryl iodides

Advances in the enantioselective synthesis of carbocyclic nucleosides.

An Efficient and General Enantioselective Synthesis of Sphingosine, Phythosphingosine, and 4-Substituted Derivatives†

An efficient method for the synthesis of enantiopure phosphine–imidazoline ligands: application to the Ir-catalyzed hydrogenation of imines

An expeditious and efficient procedure for the synthesis of unsaturated acyclonucleosides of Z configuration related to D4T.

An outstanding palladium system containing a C2-symmetrical phosphite ligand for enantioselective allylic substitution processes

Asymmetric Hydroformylation

Asymmetric hydroformylation of styrene by rhodium(I) catalysts with chiral ligands containing sulfur donors

Asymmetric hydroformylation of styrene using a rhodium catalyst with BDPP as the chiral ligand

Asymmetric hydroformylation of styrene using dithiolato bridged dirhodium catalyst with BDPP as chiral ligand

Asymmetric sulfur ylide based enantioselective synthesis of D-erythro-sphingosine.

C1 and C2-symmetric carbohydrate phosphorus ligands in asymmetric catalysis

C1-Symmetric Diphosphite Ligands Derived from Carbohydrates: Influence of Structural Modifications on the Rhodium-Catalyzed Asymmetric Hydroformylation of Styrene

C1-Symmetric carbohydrate diphosphite ligands for asymmetric Pd-allylic alkylation reactions. Study of the key Pd-allyl intermediates ⬇️

C2-symmetric diphosphinite ligands derived from carbohydrates. The strong influence of remote stereocenters on asymmetric rhodium-catalyzed hydrogenation

Carbohydrate derivative ligands in asymmetric catalysis

Carbohydrate-derived 1,3-diphosphite ligands as chiral nanoparticle stabilizers: promising catalytic systems for asymmetric hydrogenation.

Changing the Palladium Coordination to Phosphinoimidazolines with a Remote Triazole Substituent

Chemo-, regio-, and stereoselective silver-catalyzed aziridination of dienes: scope, mechanistic studies, and ring-opening reactions

Chiral Diphosphite‐Modified Rhodium(0) Nanoparticles: Catalyst Reservoir for Styrene Hydroformylation

Colloidal Ru, Co and Fe-nanoparticles. Synthesis and application as nanocatalysts in the Fischer–Tropsch process

Computational insight into the reaction intermediates in the glycosylation reaction assisted by donor heteroatoms.

Conformationally-Locked N-Glycosides with Selective β-Glucosidase Inhibitory Activity: Identification of a New Non-Iminosugar-Type Pharmacological Chaperone for Gaucher Disease

Conformationally-locked N-glycosides: Exploiting long-range non-glycone interactions in the design of pharmacological chaperones for Gaucher disease

Correlation between Hydrocarbon Product Distribution and Solvent Composition in the Fischer–Tropsch Synthesis Catalyzed by Colloidal Cobalt Nanoparticles

Designing an effective approach for obtaining methylenecarboxylate analogues of adenophostin A. Preliminary results

Diphosphite ligands derived from carbohydrates as stabilizers for ruthenium nanoparticles: promising catalytic systems in arene hydrogenation

Effect of pH on catalyst activity and selectivity in the aqueous Fischer–Tropsch synthesis catalyzed by cobalt nanoparticles

Efficient recycling of a chiral palladium catalytic system for asymmetric allylic substitutions in ionic liquid

Efficient silver-catalyzed regio- and stereospecific aziridination of dienes

Enantioselective Formal Synthesis of Nectrisine Using a Palladium-Catalyzed Asymmetric Allylic Amination and Cross-Metathesis as Key Steps

Enantioselective Synthesis of 3-Heterosubstituted-2-amino-1-ols by Sequential Metal-Free Diene Aziridination/Kinetic Resolution

Enantioselective Synthesis of Aminodiols by Sequential Rh-Catalysed Oxyamination/Kinetic Resolution. Expanding the Substrate Scope of Amidine-Based Catalysis

Enhanced regioselectivity in palladium-catalysed asymmetric methoxycarbonylation of styrene using phosphetanes as chiral ligands

Fe-Catalyzed Olefin Epoxidation with Tridentate Non-Heme Ligands and Hydrogen Peroxide as the Oxidant

Fluorinated triazole-containing sphingosine analogues. Syntheses and in vitro evaluation as SPHK inhibitors

General Method for Synthesizing Pyranoid Glycals.A New Route to Allal and Gulal Derivatives

Heterogenization of Pd–NHC complexes onto a silica support and their application in Suzuki–Miyaura coupling under batch and continuous flow conditions

Highlights of Transition Metal-Catalyzed Asymmetric Hydrogenation of Imines

Highlights of the Rh-catalysed asymmetric hydroformylation of alkenes using phosphorus donor ligands

Highly Efficient Rhodium Catalysts for the Asymmetric Hydroformylation of Vinyl and Allyl Ethers usingC1-Symmetrical Diphosphite Ligands

Highly Selective Palladium-Catalysed Aminocarbonylation of Aryl Iodides using a Bulky Diphosphine Ligand

Highly efficient and stereoselective synthesis of beta-glycolipids

Hydroformylation of allyl ethers. A study of the regioselectivity using rhodium catalysts

Hydroformylation of glucal derivatives with rhodium catalysts. Crucial influence of the auxiliary ligand tris(ortho-tert-butylphenyl) phosphite

Insights into CO/styrene copolymerization by using Pd(II) catalysts containing modular pyridine-imidazoline ligands

Ir(I) complexes with oxazoline-thioether ligands: nucleophilic attack of pyridine on coordinated 1,5-cyclooctadiene and application as catalysts in imine hydrogenation

Modular Synthesis of Functionalisable Alkoxy-Tethered N-Heterocyclic Carbene Ligands and an Active Catalyst for Buchwald-Hartwig Aminations

Montmorillonite K10 as a suitable co-catalyst for atom economy in chelation-assisted intermolecular hydroacylation

New Chiral P-N Ligands for the Regio- and Stereoselective Pd-Catalyzed Dimerization of Styrene

New alkyl derivatives phosphine sulfonate (P–O) ligands. Catalytic activity in Pd-catalysed Suzuki–Miyaura reactions in water

New camphor-derived sulfur chiral controllers: Synthesis of (2R-exo)-10-methylthio-2-bornanethiol and (2R-exo)-2,10-bis(methylthio)bornane

New chiral diphosphites derived from substituted 9,10-dihydroanthracene. Applications in asymmetric catalytic processes

New dithiolate-bridged rhodium complexes

NewC2-Symmetric Diphosphite Ligands Derived from Carbohydrates: Effect of the Remote Stereocenters on Asymmetric Catalysis

Norbornene Bidentate Ligands: Coordination Chemistry and Enantioselective Catalytic Applications

Novel Polymer Stabilized Water Soluble Ru-Nanoparticles as Aqueous Colloidal Fischer–Tropsch Catalysts

Oxidative carbonylation of aniline with new cobalt catalytic systems

Palladium Catalytic Species Containing Chiral Phosphites: Towards a Discrimination between Molecular and Colloidal Catalysts

Palladium-catalyzed allylic amination: a powerful tool for the enantioselective synthesis of acyclic nucleoside phosphonates

Pd-catalysed mono- and dicarbonylation of aryl iodides: insights into the mechanism and the selectivity

Phosphine ligands in the palladium-catalysed methoxycarbonylation of ethene: insights into the catalytic cycle through an HP NMR spectroscopic study

Phosphine-free Suzuki-Miyaura cross-coupling in aqueous media enables access to 2-C-aryl-glycosides

Preparation, structure and reactivity of dinuclear aminothiolate-bridged iridium complexes

Recent advances in the glycosylation of sphingosines and ceramides.

Recycling of allylic alkylation Pd catalysts containing phosphine-imidazoline ligands in ionic liquids

Rhodium-catalyzed regio- and stereoselective oxyamination of dienes via tandem aziridination/ring-opening of dienyl carbamates

Rhodium-diphosphite catalysed hydroformylation of allylbenzene and propenylbenzene derivatives

Ruthenium-catalyzed cross-metathesis with electron-rich phenyl vinyl sulfide enables access to 2,3-dideoxy-d-ribopyranose ring system donors

Selective catalytic deuteration of phosphorus ligands using ruthenium nanoparticles: a new approach to gain information on ligand coordination

Selective hydrogenation of α,β-unsaturated oxosteroids with homogeneous rhodium catalysts

Sequential Directed Epoxydation-Acidolysis from Glycals with MCPBA. A Flexible Approach to Protected Glycosyl Donors

Soluble transition-metal nanoparticles-catalysed hydrogenation of arenes ⬇️

Stannyl ceramides as efficient acceptors for synthesising β-galactosyl ceramides

Stereoselective Synthesis of 2‘,3‘-Dideoxy-3‘-fluoro-2‘-phenylselenenyl- β-nucleosides from Phenyl 1-Seleno-α-arabino-furanosides through Consecutive 1,2-Migration and Glycosylation under Mitsunobu Conditions. A New Entry to 2‘,3‘-Dideo

Stereoselective synthesis of 2-deoxy-2-iodo-glycosides from furanoses. A new route to 2-deoxy-glycosides and 2-deoxy-oligosaccharides of ribo and xylo configuration.

Strategies for the Immobilization of Homogeneous Catalysts and Their Use in the Synthesis of Carbamates

Studies on the Zn(II)-mediated electrophilic selenocyclization and elimination of 3,4-O-isopropylidene-protected hydroxyalkenyl sulfides: synthesis of a 2-phenylselenenyl glycal