Search filters

List of works by Wonwoo Nam

A High-Valent Manganese(IV)-Oxo-Cerium(IV) Complex and Its Enhanced Oxidizing Reactivity

scientific article published on 24 September 2019

A Manganese(V)-Oxo Complex: Synthesis by Dioxygen Activation and Enhancement of Its Oxidizing Power by Binding Scandium Ion.

scientific article published on 16 June 2016

A Manganese(V)-Oxo Tetraamido Macrocyclic Ligand (TAML) Cation Radical Complex: Synthesis, Characterization, and Reactivity Studies

scientific article published on 19 November 2018

A Mononuclear Nonheme Iron(III)-Peroxo Complex Binding Redox-Inactive Metal Ions

scientific article

A Mononuclear Nonheme Iron(IV)-Amido Complex Relevant for the Compound II Chemistry of Cytochrome P450

scientific article published on 20 December 2018

A Mononuclear Nonheme Iron(V)-Imido Complex.

scientific article published on 19 June 2017

A Mononuclear Nonheme Manganese(III)-Aqua Complex as a New Active Oxidant in Hydrogen Atom Transfer Reactions

scientific article published on 02 October 2018

A biomimetic ferric hydroperoxo porphyrin intermediate

scientific article published on 01 March 2010

A chromium(III)-superoxo complex in oxygen atom transfer reactions as a chemical model of cysteine dioxygenase

scientific article published on 26 June 2012

A cobalt(ii) iminoiodane complex and its scandium adduct: mechanistic promiscuity in hydrogen atom abstraction reactions

scientific article published on 28 July 2016

A ferric-cyanide-bridged one-dimensional dirhodium complex with (18-crown-6)potassium cations

scientific article published in March 2001

A fluorescence turn-on H2O2 probe exhibits lysosome-localized fluorescence signals

scientific article published on 26 April 2012

A highly active zinc catalyst for the controlled polymerization of lactide

scientific article

A highly efficient non-heme manganese complex in oxygenation reactions

scientific article published on 20 September 2007

A highly reactive mononuclear non-heme manganese(IV)-oxo complex that can activate the strong C-H bonds of alkanes

scientific article published on 29 November 2011

A highly selective fluorescent chemosensor for Pb2+.

scientific article published in July 2005

A mononuclear non-heme high-spin iron(III)-hydroperoxo complex as an active oxidant in sulfoxidation reactions.

scientific article

A mononuclear non-heme manganese(IV)-oxo complex binding redox-inactive metal ions.

scientific article

A mononuclear nonheme cobalt(iii)-hydroperoxide complex with an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions

scientific article published on 18 May 2016

A mononuclear nonheme {FeNO}6 complex: synthesis and structural and spectroscopic characterization

scientific article published on 20 July 2018

A nonheme manganese(IV)-oxo species generated in photocatalytic reaction using water as an oxygen source.

scientific article

A theoretical study into a trans-dioxo Mn(V) porphyrin complex that does not follow the oxygen rebound mechanism in C-H bond activation reactions

scientific article published on 01 January 2016

A thiolate-ligated nonheme oxoiron(IV) complex relevant to cytochrome P450

scientific article published on 27 October 2005

A two-state reactivity rationale for counterintuitive axial ligand effects on the C-H activation reactivity of nonheme FeIV=O oxidants

scientific article

Accelerated cerebral ischemic injury by activated macrophages/microglia after lipopolysaccharide microinjection into rat corpus callosum

scientific article published in April 2005

Achieving One-Electron Oxidation of a Mononuclear Nonheme Iron(V)-Imido Complex.

scientific article published on 29 September 2017

Acid-induced mechanism change and overpotential decrease in dioxygen reduction catalysis with a dinuclear copper complex

scientific article published on 26 February 2013

Acid-promoted hydride transfer from an NADH analogue to a Cr(III)-superoxo complex <i>via</i> a proton-coupled hydrogen atom transfer

scientific article published on 17 December 2020

Activation of hydrocarbon C-H bonds by iodosylbenzene: how does it compare with iron(IV)-oxo oxidants?

scientific article published on 03 February 2009

An "end-on" chromium(III)-superoxo complex: crystallographic and spectroscopic characterization and reactivity in C-H bond activation of hydrocarbons

scientific article published on 01 May 2010

An FeIV=O complex of a tetradentate tripodal nonheme ligand

scholarly article

An autocatalytic radical chain pathway in formation of an iron(IV)-oxo complex by oxidation of an iron(II) complex with dioxygen and isopropanol

scientific article published in March 2013

An isoelectronic NO dioxygenase reaction using a nonheme iron(III)-peroxo complex and nitrosonium ion.

scientific article

Anionic ligand effect on the nature of epoxidizing intermediates in iron porphyrin complex-catalyzed epoxidation reactions

scientific article published in July 2002

Aromatic hydroxylation of anthracene derivatives by a chromium(iii)-superoxo complex via proton-coupled electron transfer

scientific article published on 01 July 2019

Augmented death in immunostimulated astrocytes deprived of glucose: inhibition by an iron porphyrin FeTMPyP.

scientific article published in January 2001

Autocatalytic formation of an iron(IV)-oxo complex via scandium ion-promoted radical chain autoxidation of an iron(II) complex with dioxygen and tetraphenylborate

scientific article published on 21 May 2014

Axial ligand effects on the geometric and electronic structures of nonheme oxoiron(IV) complexes

scientific article published on 20 August 2008

Axial ligand substituted nonheme FeIV=O complexes: observation of near-UV LMCT bands and Fe=O Raman vibrations.

scientific article

Axial ligand tuning of a nonheme iron(IV)-oxo unit for hydrogen atom abstraction

scholarly article

Bioinspired chemical inversion of L-amino acids to D-amino acids

scientific article published on 01 February 2007

Blockade of peroxynitrite-mediated astrocyte death by manganese(III)-cyclam

scientific article

Brønsted acid-promoted C-H bond cleavage via electron transfer from toluene derivatives to a protonated nonheme iron(IV)-oxo complex with no kinetic isotope effect

scientific article published on 25 March 2013

Catalytic Four-Electron Reduction of Dioxygen by Ferrocene Derivatives with a Nonheme Iron(III) TAML Complex

scientific article published on 10 December 2020

Catalytic four-electron reduction of O2 via rate-determining proton-coupled electron transfer to a dinuclear cobalt-μ-1,2-peroxo complex.

scientific article

Catalytic oxidation of alkanes by iron bispidine complexes and dioxygen: oxygen activation versus autoxidation

scientific article published on 01 January 2014

Chromium(IV)–Peroxo Complex Formation and Its Nitric Oxide Dioxygenase Reactivity ⬇️

scientific article published on September 10, 2012

Cobalt analogs of Ru-based water oxidation catalysts: overcoming thermodynamic instability and kinetic lability to achieve electrocatalytic O2 evolution

scholarly article by Matthew L. Rigsby et al published 2012 in Chemical Science

Combined experimental and theoretical approach to understand the reactivity of a mononuclear Cu(II)-hydroperoxo complex in oxygenation reactions

scientific article

Combined experimental and theoretical study on aromatic hydroxylation by mononuclear nonheme iron(IV)-oxo complexes

scientific article published on 20 April 2007

Comparison of high-spin and low-spin nonheme Fe(III)-OOH complexes in O-O bond homolysis and H-atom abstraction reactivities

scientific article published on 14 February 2013

Contrasting effects of axial ligands on electron-transfer versus proton-coupled electron-transfer reactions of nonheme oxoiron(IV) complexes

scientific article published in January 2010

Correlating DFT-calculated energy barriers to experiments in nonheme octahedral Fe(IV)O species

scientific article published on 19 June 2012

Crystal structure of a metal ion-bound oxoiron(IV) complex and implications for biological electron transfer.

scientific article published on 11 July 2010

Crystallographic and Spectroscopic Characterization of a Nonheme Fe(IV)&cjs0811;O Complex

scientific article published in Science

Crystallographic and spectroscopic characterization and reactivities of a mononuclear non-haem iron(III)-superoxo complex

scientific article published on 16 December 2014

Cyclometalated iridium(III) complexes for phosphorescence sensing of biological metal ions.

scientific article

Demonstration of the heterolytic O-O bond cleavage of putative nonheme iron(II)-OOH(R) complexes for Fenton and enzymatic reactions

scientific article published on 10 June 2014

Determination of Spin Inversion Probability, H-Tunneling Correction, and Regioselectivity in the Two-State Reactivity of Nonheme Iron(IV)-Oxo Complexes

scientific article

Dioxygen Activation and O-O Bond Formation Reactions by Manganese Corroles.

scientific article published on 22 October 2017

Dioxygen Activation by a Macrocyclic Copper Complex Leads to a Cu2O2 Core with Unexpected Structure and Reactivity

scientific article published on 26 February 2016

Dioxygen Activation by a Non-Heme Iron(II) Complex: Theoretical Study toward Understanding Ferric-Superoxo Complexes

scientific article published on 28 February 2012

Dioxygen activation and catalytic aerobic oxidation by a mononuclear nonheme iron(II) complex

scientific article published in March 2005

Dioxygen activation by a non-heme iron(II) complex: formation of an iron(IV)-oxo complex via C-H activation by a putative iron(III)-superoxo species

scientific article published on 01 August 2010

Dioxygen activation by mononuclear nonheme iron(II) complexes generates iron-oxygen intermediates in the presence of an NADH analogue and proton

scientific article published on 01 October 2009

Direct evidence for an iron(IV)-oxo porphyrin pi-cation radical as an active oxidant in catalytic oxygenation reactions

scientific article published on 03 January 2008

Direct evidence for oxygen-atom exchange between nonheme oxoiron(IV) complexes and isotopically labeled water

scientific article published on 01 April 2004

Double action: toward phosphorescence ratiometric sensing of chromium ion

scientific article published on 20 April 2012

Effect of anionic axial ligands on the formation of oxoiron(IV) porphyrin intermediates

scientific article published on 01 November 2000

Effect of porphyrin ligands on the regioselective dehydrogenation versus epoxidation of olefins by oxoiron(IV) mimics of cytochrome P450.

scientific article published in October 2009

Effects of proton acceptors on formation of a non-heme iron(IV)-oxo complex via proton-coupled electron transfer

scientific article published on 4 March 2013

Efficient Epoxidation of Styrene Derivatives by a Nonheme Iron(IV)-Oxo Complex via Proton-Coupled Electron Transfer with Triflic Acid

scientific article published on 26 May 2015

Electron-Transfer and Redox Reactivity of High-Valent Iron Imido and Oxo Complexes with the Formal Oxidation States of Five and Six

scientific article published on 18 February 2020

Electron-transfer properties of a nonheme manganese(IV)-oxo complex acting as a stronger one-electron oxidant than the iron(IV)-oxo analogue

scientific article published on 05 October 2012

Enantioselective recognition of 1,2-amino alcohols by reversible formation of imines with resonance-assisted hydrogen bonds.

scientific article

Enhanced Electron Transfer Reactivity of a Nonheme Iron(IV)-Imido Complex as Compared to the Iron(IV)-Oxo Analogue

scientific article published on 17 February 2016

Enhanced Electron-Transfer Reactivity of a Long-Lived Photoexcited State of a Cobalt-Oxygen Complex

scientific article published on 22 August 2018

Enhanced electron-transfer reactivity of nonheme manganese(IV)-oxo complexes by binding scandium ions.

scientific article published on 06 June 2013

Enhanced reactivities of iron(IV)-oxo porphyrin pi-cation radicals in oxygenation reactions by electron-donating axial ligands

scientific article published in October 2009

Evidence for an alternative to the oxygen rebound mechanism in C-H bond activation by non-heme Fe(IV)O complexes

scientific article published on 06 December 2012

Experiment and theory reveal the fundamental difference between two-state and single-state reactivity patterns in nonheme Fe(IV)=O versus Ru(IV)=O oxidants

scientific article published on 01 January 2008

Experimental and theoretical evidence for nonheme iron(III) alkylperoxo species as sluggish oxidants in oxygenation reactions.

scientific article published in January 2007

Factors Controlling the Chemoselectivity in the Oxidation of Olefins by Nonheme Manganese(IV)-Oxo Complexes

scientific article published on 27 July 2016

Factors That Control Catalytic Two- versus Four-Electron Reduction of Dioxygen by Copper Complexes ⬇️

scientific article published on April 12, 2012

Factors That Control the Reactivity of Cobalt(III)-Nitrosyl Complexes in Nitric Oxide Transfer and Dioxygenation Reactions: A Combined Experimental and Theoretical Investigation

scientific article published on 24 May 2016

Factors affecting the catalytic epoxidation of olefins by iron porphyrin complexes and H2O2 in protic solvents

scientific article published in October 2003

First direct evidence for stereospecific olefin epoxidation and alkane hydroxylation by an oxoiron(IV) porphyrin complex

scientific article

First success of catalytic epoxidation of olefins by an electron-rich iron(III) porphyrin complex and H2O2: imidazole effect on the activation of H2O2 by iron porphyrin complexes in aprotic solvent

scientific article published on 01 July 2000

Flexibility of inorganic tennis ball structures inducing anion selectivity

scientific article

Fluorescence ratiometric zinc sensors based on controlled energy transfer

Fluorescent zinc sensor with minimized proton-induced interferences: photophysical mechanism for fluorescence turn-on response and detection of endogenous free zinc ions.

scientific article

Formation, stability, and reactivity of a mononuclear nonheme oxoiron(IV) complex in aqueous solution

scientific article published on 27 January 2005

Fuel Production from Seawater and Fuel Cells Using Seawater.

scientific article

Fundamental differences of substrate hydroxylation by high-valent iron(IV)-oxo models of cytochrome P450.

scientific article published in July 2009

Fundamental electron-transfer properties of non-heme oxoiron(IV) complexes

scientific article published on 18 December 2007

High conversion of olefins to cis-diols by non-heme iron catalysts and H2O2

scientific article published on 01 June 2002

High-Spin Mn(V)-Oxo Intermediate in Nonheme Manganese Complex-Catalyzed Alkane Hydroxylation Reaction: Experimental and Theoretical Approach

scientific article published on 17 October 2019

High-valent iron(IV)-oxo complexes of heme and non-heme ligands in oxygenation reactions

scientific article

High-valent manganese(v)-oxo porphyrin complexes in hydride transfer reactions

scientific article published on 19 December 2008

High-valent metal-oxo intermediates in energy demanding processes: from dioxygen reduction to water splitting

scientific article

Highly Reactive Manganese(IV)-Oxo Porphyrins Showing Temperature-Dependent Reversed Electronic Effect in C-H Bond Activation Reactions

scientific article published on 26 July 2019

Highly efficient photocatalytic oxygenation reactions using water as an oxygen source

scientific article published on 28 November 2010

Highly reactive nonheme iron(III) iodosylarene complexes in alkane hydroxylation and sulfoxidation reactions

scientific article published on 12 May 2014

Highly stereoselective directed reactions and an efficient synthesis of azafuranoses from a chiral aziridine

scientific article published in June 2013

Homogeneous and Heterogeneous Photocatalytic Water Oxidation by Persulfate

scientific article published on 17 February 2016

How axial ligands control the reactivity of high-valent iron(IV)-oxo porphyrin pi-cation radicals in alkane hydroxylation: a computational study

scientific article published on 3 March 2006

How does the axial ligand of cytochrome P450 biomimetics influence the regioselectivity of aliphatic versus aromatic hydroxylation?

scientific article

Hydride transfer from NADH analogues to a nonheme manganese(IV)-oxo complex via rate-determining electron transfer.

scientific article published in November 2014

Hydrogen Atom Transfer Reactions of Mononuclear Nonheme Metal-Oxygen Intermediates

scientific article published on 04 September 2018

Hydrogen atom abstraction and hydride transfer reactions by iron(IV)-oxo porphyrins

scientific article published on 01 January 2008

Hydrogen-atom abstraction reactions by manganese(V)- and manganese(IV)-oxo porphyrin complexes in aqueous solution

scientific article published in November 2009

Identification of an "end-on" nickel-superoxo adduct, [Ni(tmc)(O2)]+

scientific article published on 01 November 2006

Intercalation of bulky Delta,Delta- and Lambda,Lambda-bis-Ru(II) complex between DNA base pairs

scientific article published on 26 June 2008

Intermetal oxygen atom transfer from an Fe(V)O complex to a Mn(III) complex: an experimental and theoretical approach.

scientific article published on 17 October 2016

Interplay of Experiment and Theory in Elucidating Mechanisms of Oxidation Reactions by a Nonheme Ru(IV)O Complex

scientific article published on 29 June 2015

Investigating Superoxide Transfer through a μ-1,2-O2 Bridge between Nonheme Ni(III)-Peroxo and Mn(II) Species by DFT Methods to Bridge Theoretical and Experimental Views

scientific article published on 30 June 2014

Iron porphyrins anchored to a thermosensitive polymeric core-shell nanosphere as a thermotropic catalyst

scientific article published on 21 June 2005

Isolation and structural characterization of the elusive 1:1 adduct of hydrazine and carbon dioxide

scientific article published on 15 September 2011

Lewis Acid Coupled Electron Transfer of Metal-Oxygen Intermediates

scientific article published on 25 September 2015

Ligand topology effect on the reactivity of a mononuclear nonheme iron(IV)-oxo complex in oxygenation reactions

scientific article published on 15 July 2011

Long-Lived Photoexcited State of a Mn(IV)-Oxo Complex Binding Scandium Ions That is Capable of Hydroxylating Benzene

scientific article published on 15 June 2018

Manganese complex-catalyzed oxidation and oxidative kinetic resolution of secondary alcohols by hydrogen peroxide.

scientific article

Manganese displacement from Zinpyr-1 allows zinc detection by fluorescence microscopy and magnetic resonance imaging

scientific article

Manganese substituted Compound I of cytochrome P450 biomimetics: a comparative reactivity study of Mn(V)-oxo versus Mn(IV)-oxo species

scientific article published on 07 January 2011

Manganese(V)-oxo corroles in hydride-transfer reactions.

scientific article published on 11 October 2010

Mechanism and fluorescence application of electrochromism in photochromic dithienylcyclopentene

scientific article published on 26 April 2012

Mechanisms of catalytic reduction of CO with heme and nonheme metal complexes

scientific article published on 02 July 2018

Mechanistic Insight into the Nitric Oxide Dioxygenation Reaction of Nonheme Iron(III)-Superoxo and Manganese(IV)-Peroxo Complexes.

scientific article published on 4 September 2016

Mechanistic borderline of one-step hydrogen atom transfer versus stepwise Sc(3+)-coupled electron transfer from benzyl alcohol derivatives to a non-heme iron(IV)-oxo complex

scientific article published on 6 September 2012

Mechanistic insight into alcohol oxidation by high-valent iron-oxo complexes of heme and nonheme ligands

scientific article published in July 2005

Mechanistic insight into the aromatic hydroxylation by high-valent iron(IV)-oxo porphyrin pi-cation radical complexes

scientific article published on 10 July 2007

Mechanistic insight into the hydroxylation of alkanes by a nonheme iron(V)-oxo complex

scientific article published on 01 May 2014

Mechanistic insights into hydride-transfer and electron-transfer reactions by a manganese(IV)-oxo porphyrin complex

scientific article published in December 2009

Mechanistic insights into the C-H bond activation of hydrocarbons by chromium(IV) oxo and chromium(III) superoxo complexes.

scientific article published on 3 December 2013

Mechanistic insights into the reactions of hydride transfer versus hydrogen atom transfer by a trans-dioxoruthenium(VI) complex

scientific article published on 01 April 2015

Mechanistic insights into the reversible formation of iodosylarene-iron porphyrin complexes in the reactions of oxoiron(IV) porphyrin pi-cation radicals and iodoarenes: equilibrium, epoxidizing intermediate, and oxygen exchange.

scientific article

Metal ion effect on the switch of mechanism from direct oxygen transfer to metal ion-coupled electron transfer in the sulfoxidation of thioanisoles by a non-heme iron(IV)-oxo complex

scientific article published on 16 March 2011

Metal ion-coupled electron transfer of a nonheme oxoiron(IV) complex: remarkable enhancement of electron-transfer rates by Sc3+

scientific article published on 15 December 2010

Methoxy[meso-5,10,15,20-tetrakis-(2,6-difluorophenyl)porphyrinato]-iron(III), [Fe(TDFPP)(OCH3)].

scientific article

Mn(III)-Iodosylarene Porphyrins as an Active Oxidant in Oxidation Reactions: Synthesis, Characterization, and Reactivity Studies

scientific article published on 06 August 2018

Mononuclear Metal–O2 Complexes Bearing Macrocyclic N-Tetramethylated Cyclam Ligands ⬇️

scientific article published on May 21, 2012

Mononuclear Nonheme High-Spin (S=2) versus Intermediate-Spin (S=1) Iron(IV)-Oxo Complexes in Oxidation Reactions

scientific article published on 6 June 2016

Mononuclear Nonheme High-Spin Iron(III)-Acylperoxo Complexes in Olefin Epoxidation and Alkane Hydroxylation Reactions

scientific article published on 27 January 2016

Mononuclear Nonheme Iron(III)-Iodosylarene and High-Valent Iron-Oxo Complexes in Olefin Epoxidation Reactions

scientific article

Mononuclear manganese-peroxo and bis(μ-oxo)dimanganese complexes bearing a common N-methylated macrocyclic ligand

scientific article published on 11 September 2013

Mononuclear nonheme ferric-peroxo complex in aldehyde deformylation

scientific article published on 10 August 2005

Mononuclear nonheme iron(IV)-oxo and manganese(IV)-oxo complexes in oxidation reactions: experimental results prove theoretical prediction

scientific article published on 01 August 2015

Mutable Properties of Nonheme Iron(III)-Iodosylarene Complexes Result in the Elusive Multiple-Oxidant Mechanism

scientific article

Non-heme manganese catalysts for on-demand production of chlorine dioxide in water and under mild conditions

scientific article published on 24 February 2014

Nonheme FeIVO complexes that can oxidize the C-H bonds of cyclohexane at room temperature.

scientific article

Nonheme iron(II) complexes of macrocyclic ligands in the generation of oxoiron(IV) complexes and the catalytic epoxidation of olefins

scientific article published on 03 February 2006

Nonheme iron-oxo and -superoxo reactivities: O2 binding and spin inversion probability matter

scientific article published on 17 January 2012

Nonheme oxoiron(IV) complexes of tris(2-pyridylmethyl)amine with cis-monoanionic ligands

scientific article published in August 2006

Nuclear Resonance Vibrational Spectroscopic Definition of Peroxy Intermediates in Nonheme Iron Sites

scientific article

Oxidative N-dealkylation reactions by oxoiron(IV) complexes of nonheme and heme ligands

scientific article published on 01 January 2007

Oxidative properties of a nonheme Ni(II)(O2) complex: Reactivity patterns for C-H activation, aromatic hydroxylation and heteroatom oxidation

scientific article published on 02 September 2011

Oxidizing intermediates in cytochrome P450 model reactions

scientific article published on 30 July 2004

Oxoiron(IV) porphyrin pi-cation radical complexes with a chameleon behavior in cytochrome P450 model reactions

scientific article published on 13 April 2005

Oxygen-atom transfer between mononuclear nonheme iron(IV)-oxo and iron(II) complexes

scientific article published on 01 June 2006

Parallel mechanistic studies on the counterion effect of manganese salen and porphyrin complexes on olefin epoxidation by iodosylarenes

scientific article published in February 2005

Phosphorescent Sensor for Robust Quantification of Copper(II) Ion ⬇️

scientific article published on July 12, 2011

Phosphorescent Zinc Probe for Reversible Turn-On Detection with Bathochromically Shifted Emission

scientific article published on 5 October 2015

Phosphorescent sensor for biological mobile zinc.

scientific article

Photocatalytic Hydrogen Evolution from Plastoquinol Analogues as a Potential Functional Model of Photosystem I

scientific article published on 07 October 2020

Photocatalytic Oxygenation Reactions Using Water and Dioxygen

scientific article published on 25 July 2019

Photocatalytic Oxygenation Reactions with a Cobalt Porphyrin Complex Using Water as an Oxygen Source and Dioxygen as an Oxidant

scientific article published on 30 May 2019

Photocatalytic generation of a non-heme oxoiron(IV) complex with water as an oxygen source

scientific article published on 18 February 2011

Photocatalytic oxidation of benzene to phenol using dioxygen as an oxygen source and water as an electron source in the presence of a cobalt catalyst.

scientific article published on 21 August 2017

Photodriven Oxidation of Water by Plastoquinone Analogs with a Nonheme Iron Catalyst

scientific article published on 15 April 2019

Photoelectrocatalysis to Improve Cycloreversion Quantum Yields of Photochromic Dithienylethene Compounds

scientific article published on 13 November 2012

Photofunctional triplet excited states of cyclometalated Ir(iii) complexes: beyond electroluminescence ⬇️

scientific article published on July 16, 2012

Predictive studies of H-atom abstraction reactions by an iron(IV)-oxo corrole cation radical oxidant

scientific article published on 01 March 2012

Properties and reactivities of nonheme iron(IV)-oxo versus iron(V)-oxo: long-range electron transfer versus hydrogen atom abstraction

scientific article published in November 2014

Proton-Promoted and Anion-Enhanced Epoxidation of Olefins by Hydrogen Peroxide in the Presence of Nonheme Manganese Catalysts.

scientific article published on 31 December 2015

Proton-promoted disproportionation of iron(v)-imido TAML to iron(v)-imido TAML cation radical and iron(iv) TAML

scientific article published on 21 August 2020

Proton-promoted oxygen atom transfer vs proton-coupled electron transfer of a non-heme iron(IV)-oxo complex

scientific article published on 16 February 2012

Protonation Equilibrium and Hydrogen Production by a Dinuclear Cobalt–Hydride Complex Reduced by Cobaltocene with Trifluoroacetic Acid

scientific article published on 01 October 2013

Reactions of Co(III)-nitrosyl complexes with superoxide and their mechanistic insights

scientific article published on 25 March 2015

Reactions of a chromium(III)-superoxo complex and nitric oxide that lead to the formation of chromium(IV)-oxo and chromium(III)-nitrito complexes

scientific article published on 30 September 2013

Reactivities of mononuclear non-heme iron intermediates including evidence that iron(III)-hydroperoxo species is a sluggish oxidant.

scientific article

Reactivity Patterns of (Protonated) Compound II and Compound I of Cytochrome P450: Which is the Better Oxidant?

scientific article published on 10 March 2017

Reactivity comparison of high-valent iron(IV)-oxo complexes bearing N-tetramethylated cyclam ligands with different ring size

scientific article published on 16 April 2013

Reactivity of a cobalt(III)-peroxo complex in oxidative nucleophilic reactions

scientific article

Redox Reactivity of a Mononuclear Manganese-Oxo Complex Binding Calcium Ion and Other Redox-Inactive Metal Ions

scientific article published on 09 January 2019

Redox-inactive metal ions modulate the reactivity and oxygen release of mononuclear non-haem iron(III)-peroxo complexes

scientific article

Regioselective Oxybromination of Benzene and Its Derivatives by Bromide Anion with a Mononuclear Nonheme Mn(IV)-Oxo Complex

scientific article published on 14 October 2019

Regioselectivity of aliphatic versus aromatic hydroxylation by a nonheme iron(II)-superoxo complex

scientific article published on 17 January 2012

Remarkable Acid Catalysis in Proton-Coupled Electron-Transfer Reactions of a Chromium(III)-Superoxo Complex

scientific article published on 29 June 2018

Reversible O-O bond cleavage and formation between Mn(IV)-peroxo and Mn(V)-oxo corroles

scientific article published on 01 October 2010

Reversible formation of iodosylbenzene-iron porphyrin intermediates in the reaction of oxoiron(IV) porphyrin pi-cation radicals and iodobenzene

scientific article published in January 2003

Scandium ion-enhanced oxidative dimerization and N-demethylation of N,N-dimethylanilines by a non-heme iron(IV)-oxo complex.

scientific article published on 19 October 2011

Selective Oxygenation of Cyclohexene by Dioxygen via an Iron(V)-Oxo Complex-Autocatalyzed Reaction.

scientific article published on 19 April 2017

Self-hydroxylation of perbenzoic acids at a nonheme iron(II) center

scientific article

Sequential electron-transfer and proton-transfer pathways in hydride-transfer reactions from dihydronicotinamide adenine dinucleotide analogues to non-heme oxoiron(IV) complexes and p-chloranil. Detection of radical cations of NADH analogues in acid

scientific article

Singly Unified Driving Force Dependence of Outer-Sphere Electron-Transfer Pathways of Nonheme Manganese(IV)-Oxo Complexes in the Absence and Presence of Lewis Acids

scientific article published on 07 October 2019

Small Reorganization Energy for Ligand-Centered Electron-Transfer Reduction of Compound I to Compound II in a Heme Model Study

scientific article published on 11 June 2019

Solar-Driven Production of Hydrogen Peroxide from Water and Dioxygen.

scientific article published on 3 November 2017

Spectroscopic and computational characterization of CuII-OOR (R = H or cumyl) complexes bearing a Me6-tren ligand

scientific article published on 24 January 2011

Spectroscopic capture and reactivity of a low-spin cobalt(IV)-oxo complex stabilized by binding redox-inactive metal ions.

scientific article published on 31 July 2014

Spectroscopic characterization and reactivity studies of a mononuclear nonheme Mn(III)-hydroperoxo complex.

scientific article

Status of reactive non-heme metal-oxygen intermediates in chemical and enzymatic reactions.

scientific article published on 29 September 2014

Structural characterization and remarkable axial ligand effect on the nucleophilic reactivity of a nonheme manganese(III)-peroxo complex

scientific article published on 01 January 2009

Structural insights into nonheme alkylperoxoiron(III) and oxoiron(IV) intermediates by X-ray absorption spectroscopy

scientific article published on 01 December 2004

Structure and spin state of nonheme FeIVO complexes depending on temperature: predictive insights from DFT calculations and experiments

scientific article published on 30 May 2017

Sulfur versus iron oxidation in an iron-thiolate model complex

scientific article

Switchover of the Mechanism between Electron Transfer and Hydrogen-Atom Transfer for a Protonated Manganese(IV)-Oxo Complex by Changing Only the Reaction Temperature

scientific article published on 18 May 2016

Synthesis of azines in solid state: reactivity of solid hydrazine with aldehydes and ketones

scientific article published on 17 November 2011

Synthesis, characterization, and reactivity of cobalt(III)-oxygen complexes bearing a macrocyclic N-tetramethylated cyclam ligand.

scientific article published on 03 September 2013

Synthetic control over photoinduced electron transfer in phosphorescence zinc sensors.

scientific article

Synthetic mononuclear nonheme iron-oxygen intermediates

scientific article

Temperature-independent catalytic two-electron reduction of dioxygen by ferrocenes with a copper(II) tris[2-(2-pyridyl)ethyl]amine catalyst in the presence of perchloric acid.

scientific article published on 8 February 2013

The Axial Ligand Effect on Aliphatic and Aromatic Hydroxylation by Non‐heme Iron(IV)–oxo Biomimetic Complexes ⬇️

scientific article published on November 24, 2010

The Fe(III)(H2O2) Complex as a Highly Efficient Oxidant in Sulfoxidation Reactions: Revival of an Underrated Oxidant in Cytochrome P450.

scientific article published on 8 May 2013

The effect and influence of cis-ligands on the electronic and oxidizing properties of nonheme oxoiron biomimetics. A density functional study

scientific article published in December 2008

Theoretical predictions of a highly reactive non-heme Fe(IV)=O complex with a high-spin ground state.

scientific article published on 18 May 2010

To rebound or dissociate? This is the mechanistic question in C-H hydroxylation by heme and nonheme metal-oxo complexes.

scientific article published on 21 December 2015

Trapping of a Highly Reactive Oxoiron(IV) Complex in the Catalytic Epoxidation of Olefins by Hydrogen Peroxide

article published in 2019

Tuning Electron-Transfer Reactivity of a Chromium(III)-Superoxo Complex Enabled by Calcium Ion and Other Redox-Inactive Metal Ions

scientific article published on 18 December 2019

Tuning reactivity and mechanism in oxidation reactions by mononuclear nonheme iron(IV)-oxo complexes

scientific article published on 13 February 2014

Tuning the Reactivity of Chromium(III)-Superoxo Species by Coordinating Axial Ligands

scientific article published on 21 October 2015

Tuning the Redox Properties of a Nonheme Iron(III)-Peroxo Complex Binding Redox-Inactive Zinc Ions by Water Molecules.

scientific article

Tuning the intermolecular dative interactions by altering the ligand planarity and counter cations in vanadyl(IV) complexes.

scientific article

Tunneling Controls the Reaction Pathway in the Deformylation of Aldehydes by a Nonheme Iron(III)-Hydroperoxo Complex: Hydrogen Atom Abstraction versus Nucleophilic Addition

scientific article published on 02 May 2019

Tunneling Effect That Changes the Reaction Pathway from Epoxidation to Hydroxylation in the Oxidation of Cyclohexene by a Compound I Model of Cytochrome P450.

scientific article published on 16 March 2017

Unified Mechanism of Oxygen Atom Transfer and Hydrogen Atom Transfer Reactions with a Triflic Acid-Bound Nonheme Manganese(IV)–Oxo Complex via Outer-Sphere Electron Transfer

scientific article published on 15 January 2019

Unified view of oxidative C-H bond cleavage and sulfoxidation by a nonheme iron(IV)-oxo complex via Lewis acid-promoted electron transfer

scientific article published on 7 March 2014

Unprecedented Reactivities of Highly Reactive Manganese(III)-Iodosylarene Porphyrins in Oxidation Reactions

scientific article published on 13 November 2020

Water as an oxygen source in the generation of mononuclear nonheme iron(IV) oxo complexes

scientific article published in January 2009

Water as an oxygen source: synthesis, characterization, and reactivity studies of a mononuclear nonheme manganese(IV) oxo complex

scientific article published on 01 October 2010

Water oxidation catalysis with nonheme iron complexes under acidic and basic conditions: homogeneous or heterogeneous?

scientific article

[Fe(IV)═O(TBC)(CH3CN)]2+: comparative reactivity of iron(IV)-oxo species with constrained equatorial cyclam ligation.

scientific article

[Mn(tmc)(O2)]+: a side-on peroxido manganese(III) complex bearing a non-heme ligand

scientific article published on 01 January 2007

Paulina is supported by:

About Paulina

Help