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List of works by Donald J. Darensbourg

(Salen)CrIIIX catalysts for the copolymerization of carbon dioxide and epoxides: role of the initiator and cocatalyst.

scientific article published in March 2004

(Tetramethyltetraazaannulene)chromium chloride: a highly active catalyst for the alternating copolymerization of epoxides and carbon dioxide

scientific article published on 13 June 2007

A convenient synthesis of cis-Mo(CO)4L2 derivatives (L = Group 5a ligand) and a qualitative study of their thermal reactivity toward ligand dissociation

A kinetic study of the ring-opening process in tungsten carbonyl complexes containing hemilabile metallodithiolate ligands

scientific article published in January 2006

A one-pot synthesis of a triblock copolymer from propylene oxide/carbon dioxide and lactide: intermediacy of polyol initiators

scientific article published on 14 August 2013

A phase separable polycarbonate polymerization catalyst

scientific article

Acrylic acid derivatives of group 8 metal carbonyls: a structural and kinetic study

scientific article published on 24 April 2013

Aluminum salen complexes and tetrabutylammonium salts: a binary catalytic system for production of polycarbonates from CO2 and cyclohexene oxide

scientific article published in March 2005

Amino Acid Complexes of Metal Carbonyls: Mechanistic Aspects of the CO-Labilizing Ability of Glycinate Ligands in Zero-Valent Chromium and Tungsten Derivatives

scientific article published on 01 August 1997

An experimental and theoretical investigation of the carbon dioxide insertion process into the tungsten-nitrogen bond of an anionic W(0) complex

scientific article published in April 2001

An exploration of the coupling reactions of epoxides and carbon dioxide catalyzed by tetramethyltetraazaannulene chromium(III) derivatives: formation of copolymers versus cyclic carbonates

scientific article

Analysis of an Organometallic Iron Site Model for the Heterodimetallic Unit of [NiFe]Hydrogenase

scientific article published in 1997

Anionic group 6 hydrides and carboxylates as homogeneous catalysts for reduction of aldehydes and ketones

scientific article published in 1986

Bis(triphenylphosphine)copper(I) Complexes of Orotate and L-Dihydroorotate

scientific article published on 01 November 1998

Carbon dioxide/epoxide coupling reactions utilizing Lewis base adducts of zinc halides as catalysts. Cyclic carbonate versus polycarbonate production

scientific article published in January 2003

Carbon monoxide induced reductive elimination of disulfide in an N-heterocyclic carbene (NHC)/thiolate dinitrosyl iron complex (DNIC).

scientific article published on 23 May 2013

Characterization of steric and electronic properties of NiN2S2 complexes as S-donor metallodithiolate ligands

scientific article

Chemistry of Carbon Dioxide Relevant to Its Utilization: A Personal Perspective ⬇️

scientific article published on October 25, 2010

Chromium, molybdenum and tungsten

scholarly article by Donald J. Darensbourg et al published December 1974 in Journal of Organometallic Chemistry

Chromium, molybdenum and tungsten

Chromium, molybdenum, and tungsten

scholarly article by Jim D. Atwood et al published December 1981 in Journal of Organometallic Chemistry

Cobalt catalysts for the coupling of CO2 and epoxides to provide polycarbonates and cyclic carbonates.

scientific article published on 22 August 2011

Comparative kinetic studies of the copolymerization of cyclohexene oxide and propylene oxide with carbon dioxide in the presence of chromium salen derivatives. In situ FTIR measurements of copolymer vs cyclic carbonate production

scientific article

Construction of Versatile and Functional Nanostructures Derived from CO2 -based Polycarbonates

scientific article published on 15 July 2015

Construction of ultrastable porphyrin Zr metal-organic frameworks through linker elimination

scientific article published on 31 October 2013

Coordination Chemistry, Structure, and Reactivity of Thiouracil Derivatives of Tungsten(0) Hexacarbonyl: A Theoretical and Experimental Investigation into the Chelation/Dechelation of Thiouracil via CO Loss and Addition

scientific article published on 01 October 1999

Coordinatively Unsaturated Derivatives of Group 6 Metal Carbonyls Containing the pi-Donating Ligand 3,5-Di-tert-butylcatecholate

scientific article published on 01 March 1996

Coordinatively and Electronically Unsaturated Tungsten(0) Carbonyl Complexes Stabilized by pi-Donating Amido Ligands

scientific article published on 01 March 1996

Copolymerization of CO2 and epoxides catalyzed by metal salen complexes

scientific article published in November 2004

Copolymerization of epoxides and carbon dioxide. Evidence supporting the lack of dual catalysis at a single metal site.

scientific article

Cyanide Docking and Linkage Isomerism in Models for the Artificial [FeFe]-Hydrogenase Maturation Process

scientific article published on 27 July 2018

Cyclohexene oxide/CO2 copolymerization catalyzed by chromium(III) salen complexes and N-methylimidazole: effects of varying salen ligand substituents and relative cocatalyst loading

scientific article published in September 2004

Displacement kinetics of eta(2)-bound furan and 2,3-dihydrofuran from Mn and Cr centers: evidence for the partial dearomatization of the furan ligand.

scientific article published in August 2009

Effective, selective coupling of propylene oxide and carbon dioxide to poly(propylene carbonate) using (salen)CrN3 catalysts

scientific article published in June 2005

Estimating the strength of the M-H-B interaction: a kinetic approach

scientific article published in May 2013

Facile reduction of carbon dioxide by anionic Group 6b metal hydrides. Chemistry relevant to catalysis of the water-gas shift reaction

scientific article published in 1981

Hammett correlations as test of mechanism of CO-induced disulfide elimination from dinitrosyl iron complexes

Intramolecular ligand rearrangements in anionic group 6 metal pentacarbonyl hydride derivatives

Investigations into the coupling of cyclohexene oxide and carbon disulfide catalyzed by (salen)CrCl. Selectivity for the production of copolymers vs. cyclic thiocarbonates

scientific article published on 18 August 2009

Ligand additivity in the valence photoelectron spectroscopy of phosphine-substituted molybdenum carbonyls

scholarly article by Bruce E. Bursten et al published December 1984 in Inorganic Chemistry

Ligand substitution from the (eta5-DMP)Mn(CO)2(Solv) [DMP = 2,5-dimethylpyrrole, Solv = solvent] complexes: to ring slip or not to ring slip?

scientific article published on August 2010

Light-enhanced displacement of methyl acrylate from iron carbonyl: investigation of the reactive intermediate via rapid-scan Fourier transform infrared and computational studies.

scientific article

Making plastics from carbon dioxide: salen metal complexes as catalysts for the production of polycarbonates from epoxides and CO2.

scientific article

Manganese(III) Schiff base complexes: chemistry relevant to the copolymerization of epoxides and carbon dioxide

scientific article published on 19 June 2007

Mechanism of CO Displacement from an Unusually Labile Rhenium Complex: An Experimental and Theoretical Investigation ⬇️

scientific article published on November 15, 2012

Mechanistic aspects of the copolymerization reaction of carbon dioxide and epoxides, using a chiral salen chromium chloride catalyst

scientific article published in June 2002

Mechanistic insight into the initiation step of the coupling reaction of oxetane or epoxides and CO2 catalyzed by (salen)CrX complexes

scientific article published on 27 September 2008

Mechanistic studies of the copolymerization reaction of aziridines and carbon monoxide to produce poly-beta-peptoids

scientific article published in October 2004

Mechanistic studies of the copolymerization reaction of oxetane and carbon dioxide to provide aliphatic polycarbonates catalyzed by (Salen)CrX complexes

scientific article published on 29 April 2008

Metal salen derivatives as catalysts for the alternating copolymerization of oxetanes and carbon dioxide to afford polycarbonates

scientific article published in May 2006

Metal-Templated, Tight Loop Conformation of a Cys-X-Cys Biomimetic Assembles a Dimanganese Complex

scientific article published on 21 January 2020

N2S2Ni Metallothiolates as a Class of Ligands that Support Organometallic and Bioorganometallic Reactivity

scientific article published on 01 February 2005

Perfectly Alternating and Regioselective Copolymerization of Carbonyl Sulfide and Epoxides by Metal-Free Lewis Pairs

scientific article published on 26 April 2017

Perfectly alternating copolymerization of CO2 and epichlorohydrin using cobalt(III)-based catalyst systems

scientific article published on 6 September 2011

Preparation of a stereospecifically carbon-13 monoxide-labeled [(.mu.-H)[Mo(CO)5]2]- species and analysis of its carbonyl stretching vibrational modes

Reaction of (Cy3P)2Ni(H)(CH3) with carbon dioxide. Formation of an hydridonickel formate complex, HNi(O2CH)(Cy3P)2

scientific article published in 1987

Reactions of transition metal carbonyls with organolithium compounds. II. Prediction of nucleophilic attack at carbon and resultant stereochemistry

Responses of the Fe(CN)2(CO) Unit to Electronic Changes as Related to Its Role in [NiFe]Hydrogenase

article

Ring-opening polymerization of cyclic esters and trimethylene carbonate catalyzed by aluminum half-salen complexes

scientific article published on 15 June 2011

Ring-opening polymerization of lactides catalyzed by natural amino-acid based zinc catalysts

scientific article published in March 2010

Role of the cocatalyst in the copolymerization of CO2 and cyclohexene oxide utilizing chromium salen complexes

scientific article

Salen Metal Complexes as Catalysts for the Synthesis of Polycarbonates from Cyclic Ethers and Carbon Dioxide

Sequestering CO2 for Short-Term Storage in MOFs: Copolymer Synthesis with Oxiranes

article published in 2014

Solid-state structures of zinc(II) benzoate complexes. Catalyst precursors for the coupling of carbon dioxide and epoxides

scientific article published in February 2002

Solution and solid-state structural studies of epoxide adducts of cadmium phenoxides. Chemistry relevant to epoxide activation for ring-opening reactions

scientific article

Solution and solid-state structures of phosphine adducts of monomeric zinc bisphenoxide complexes. Importance of these derivatives in CO2/epoxide copolymerization processes

scientific article published on 01 April 2000

Spectroscopic studies of some carbene pentacarbonyl complexes of chromium(0) and tungsten(0)

Structural Diversity in Monomeric Cadmium Phenoxides

scientific article published on 01 December 1997

Structural and Spectroscopic Studies of 16-Electron, Unsaturated Derivatives of Low-Valent, Group 6 Carbonyl Complexes Containing pi-Donor Ligands

scientific article published on 01 October 1999

Studies of the carbon dioxide and epoxide coupling reaction in the presence of fluorinated manganese(III) acacen complexes: kinetics of epoxide ring-opening

scientific article published on 26 April 2008

Studies using tributylphosphine oxide as a carbon monoxide labilizing ligand in the synthesis of metal carbonyl complexes highly enriched in carbon-13 monoxide

Switchable-polarity solvents prepared with a single liquid component

scientific article

Syntheses, Structures, and Binding Constants of Cyclic Ether and Thioether Adducts of Soluble Cadmium(II) Carboxylates. Intermediates in the Homopolymerization of Oxiranes and Thiiranes and in Carbon Dioxide Coupling Processes

scientific article published on 01 May 1997

Synthesis and X-ray Structure of the Novel Aluminum Complex [{eta(3)-HB(3-Phpz)(2)(5-Phpz)}(2)Al][AlCl(4)]. Catalysis of CO(2)/Propylene Oxide to Propylene Carbonate by the AlCl(4)(-) Anion

scientific article published on 01 April 1996

Synthesis and characterization of a monocyanide-bridged bimetallic iron(II) and copper(I) complex

scientific article published on 01 December 2001

Synthesis and structural characterization of double metal cyanides of iron and zinc: catalyst precursors for the copolymerization of carbon dioxide and epoxides

scientific article published in December 2003

Synthesis and structures of nickel and palladium salicylaldiminato 1,3,5-triaza-7-phosphaadamantane (PTA) complexes.

scientific article

Synthesis of metal carbonyl complexes highly enriched in carbon-13: utilization of the carbon monoxide-labilizing ability of (n-Bu)3P:O

scientific article published in 1980

Synthesis of poly(indene carbonate) from indene oxide and carbon dioxide--a polycarbonate with a rigid backbone

scientific article published in November 2011

Synthetic Metallodithiolato Ligands as Pendant Bases in [FeIFeI], [FeI[Fe(NO)]II], and [(μ-H)FeIIFeII] Complexes

scientific article published on 21 February 2020

Tandem metal-coordination copolymerization and organocatalytic ring-opening polymerization via water to synthesize diblock copolymers of styrene oxide/CO2 and lactide

scientific article published on 9 October 2012

The Reversible Insertion Reaction of Carbon Dioxide with the W(CO)(5)OH(-) Anion. Isolation and Characterization of the Resulting Bicarbonate Complex [PPN][W(CO)(5)O(2)COH]

scientific article published on 01 July 1996

The copolymerization of carbon dioxide and [2-(3,4-epoxycyclohexyl)ethyl]trimethoxysilane catalyzed by (salen)CrCl. Formation of a CO2 soluble polycarbonate

scientific article published in July 2003

Thermal and photochemical reactivity of manganese tricarbonyl and tetracarbonyl complexes with a bulky diazabutadiene ligand

scientific article published on 01 April 2014

Toward the design of double metal cyanides for the copolymerization of CO(2) and epoxides

scientific article published on 01 December 2001

Tricyclohexylphosphine derivatives of bis(2,6-difluorophenoxide)cadmium: a solution and solid-state NMR study

scientific article published in July 2001

Trigonal-Planar Zinc(II) and Cadmium(II) Tris(phenoxide) Complexes

scientific article published on 01 March 1999

X-Ray crystal structures of five-coordinate (salen)MnN3 derivatives and their binding abilities towards epoxides: chemistry relevant to the epoxide-CO2 copolymerization process

scientific article

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