List of works - Nicolai Cramer

2-(Trifluoromethyl)indoles via Pd(0)-Catalyzed C(sp(3))-H Functionalization of Trifluoroacetimidoyl Chlorides

scientific article published on 7 April 2016

A 1,3,2-Diazaphospholene-Catalyzed Reductive Claisen Rearrangement

scientific article published on 16 May 2019

A Bulky Chiral N-Heterocyclic Carbene Nickel Catalyst Enables Enantioselective C-H Functionalizations of Indoles and Pyrroles

scientific article published on 03 July 2019

A Readily Accessible Class of Chiral Cp Ligands and their Application in RuII -Catalyzed Enantioselective Syntheses of Dihydrobenzoindoles.

scientific article published on 12 March 2018

A tunable class of chiral Cp ligands for enantioselective rhodium(III)-catalyzed C-H allylations of benzamides

scientific article

A β-Carbon elimination strategy for convenient in situ access to cyclopentadienyl metal complexes.

scientific article published on 24 August 2017

Access to P- and Axially Chiral Biaryl Phosphine Oxides by Enantioselective Cpx IrIII -Catalyzed C-H Arylations

scientific article published on 29 August 2018

Access to sultams by rhodium(III)-catalyzed directed C-H activation

scientific article published on 23 September 2012

Access to β-lactams by enantioselective palladium(0)-catalyzed C(sp3)-H alkylation.

scientific article published in July 2014

An Enantioselective Cpx Rh(III)-Catalyzed C-H Functionalization/Ring-Opening Route to Chiral Cyclopentenylamines

scientific article published on 25 January 2019

Aromatic homologation by non-chelate-assisted Rh(III)-catalyzed C-H functionalization of arenes with alkynes

scientific article published on 19 February 2014

Asymmetric Alkenyl C-H Functionalization by Cpx RhIII forms 2H-Pyrrol-2-ones through [4+1]-Annulation of Acryl Amides and Allenes

scientific article published on 28 October 2019

Asymmetric Catalysis Powered by Chiral Cyclopentadienyl Ligands.

scientific article published on 10 February 2016

Asymmetric synthesis of isoindolones by chiral cyclopentadienyl-rhodium(III)-catalyzed C-H functionalizations

scientific article published on 10 June 2014

Asymmetric transformations via C-C bond cleavage

scientific article published in January 2014

Axially Chiral Dibenzazepinones by a Palladium(0)-Catalyzed Atropo-enantioselective C-H Arylation

scientific article published on 23 July 2018

Biomimetic synthesis of (+)-ledene, (+)-viridiflorol, (-)-palustrol, (+)-spathulenol, and psiguadial A, C, and D via the platform terpene (+)-bicyclogermacrene

scientific article published on 27 May 2014

Catalysis: Gold unleashes the power of three.

scientific article published in January 2015

Catalytic Asymmetric Functionalization of Inert Bonds and Synthesis of Bioactive Natural Products ⬇️

scientific article published on 01 January 2011

Catalytic C-C Bond Activations via Oxidative Addition to Transition Metals

scientific article published on 05 June 2015

Catalytic Enantioselective Functionalizations of C-H Bonds by Chiral Iridium Complexes

scientific article published on 08 September 2020

Catalytic Enantioselective Transformations Involving C-H Bond Cleavage by Transition-Metal Complexes.

scientific article published on 17 February 2017

Catalytic enantioselective reductive Eschenmoser-Claisen rearrangements

scientific article published on 25 January 2024

Chiral 1,3,2-Diazaphospholenes as Catalytic Molecular Hydrides for Enantioselective Conjugate Reductions

scientific article published on 20 February 2018

Chiral Cationic Cp(x)Ru(II) Complexes for Enantioselective Yne-Enone Cyclizations

scientific article published on 15 September 2015

Chiral Cp-rhodium(III)-catalyzed asymmetric hydroarylations of 1,1-disubstituted alkenes

scientific article published on 6 December 2013

Chiral Cyclopentadienyl Cobalt(III) Complexes Enable Highly Enantioselective 3d-Metal-Catalyzed C-H Functionalizations

scientific article published on 27 March 2019

Chiral Cyclopentadienyls: Enabling Ligands for Asymmetric Rh(III)-Catalyzed C-H Functionalizations

scientific article

Chiral Monodentate Phosphines and Bulky Carboxylic Acids: Cooperative Effects in Palladium‐Catalyzed Enantioselective C(sp3)–H Functionalization ⬇️

scientific article published on 03 February 2012

Chiral N-Heterocyclic Carbene Ligand Enabled Nickel(0)-Catalyzed Enantioselective Three-Component Couplings as Direct Access to Silylated Indanols

scientific article published on 21 June 2016

Chiral cyclopentadienyl Rh-catalyzed enantioselective cyclopropanation of electron-deficient olefins enable rapid access to UPF-648 and oxylipin natural products

scientific article published on 17 January 2019

Chiral cyclopentadienyl iridium(III) complexes promote enantioselective cycloisomerizations giving fused cyclopropanes

scientific article published on 27 August 2015

Chiral cyclopentadienyl ligands as stereocontrolling element in asymmetric C-H functionalization.

scientific article published in October 2012

Chiral γ-Lactams by Enantioselective Palladium(0)-Catalyzed Cyclopropane Functionalizations.

scientific article published on 12 August 2015

Concise total synthesis of (+/-)-marcfortine B.

scientific article published on 22 February 2007

Cooperative Effects between Chiral Cpx -Iridium(III) Catalysts and Chiral Carboxylic Acids in Enantioselective C-H Amidations of Phosphine Oxides

scientific article

Cyclobutanes in catalysis

scientific article published on 26 July 2011

Desymmetrizations of meso-tert-norbornenols by rhodium(I)-catalyzed enantioselective retro-allylations

scientific article published on 31 August 2010

Diaminophosphine oxide ligand enabled asymmetric nickel-catalyzed hydrocarbamoylations of alkenes

scientific article published on 02 August 2013

Divergent Asymmetric Synthesis of Polycyclic Compounds via Vinyl Triazenes

scientific article published on 11 July 2017

Divergent Synthesis of Densely Substituted Arenes and Pyridines via Cyclotrimerization Reactions of Alkynyl Triazenes

scientific article published on 24 June 2019

Efficient Kinetic Resolution of Sulfur-Stereogenic Sulfoximines by Exploiting CpX RhIII -Catalyzed C-H Functionalization

scientific article published on 24 May 2019

Enantioselective Access to 1H-Isoindoles with Quaternary Stereogenic Centers by Palladium(0)-Catalyzed C-H Functionalization

scientific article published on 19 September 2018

Enantioselective Access to S-Chiral 1,2-Benzothiazines by CpxRh(III) Catalyzed C-H Functionalization of Sulfoximines

scientific article published on 26 October 2018

Enantioselective Access to Spirocyclic Sultams by Chiral Cp(x) -Rhodium(III)-Catalyzed Annulations

scientific article published on 11 January 2016

Enantioselective C-C bond activation of allenyl cyclobutanes: access to cyclohexenones with quaternary stereogenic centers

scientific article published on 01 January 2008

Enantioselective C-H Functionalization-Addition Sequence Delivers Densely Substituted 3-Azabicyclo[3.1.0]hexanes.

scientific article

Enantioselective C-H arylation strategy for functionalized dibenzazepinones with quaternary stereocenters.

scientific article published on 19 June 2013

Enantioselective Iron-Catalyzed Cross-[4+4]-Cycloaddition of 1,3-Dienes Provides Chiral Cyclooctadienes

scientific article published on 11 November 2020

Enantioselective Rhodium(I)‐Catalyzed [3+2] Annulations of Aromatic Ketimines Induced by Directed CH Activations ⬇️

scientific article published on 04 October 2011

Enantioselective Rhodium-catalyzed C-C Bond Activation of Cyclobutanones.

scientific article

Enantioselective assembly of the benzo[d]xanthene tetracyclic core of anti-influenza active natural products

scientific article published on 01 April 2010

Enantioselective metal-catalyzed activation of strained rings

scientific article published on 10 June 2009

Enantioselective palladium(0)-catalyzed intramolecular cyclopropane functionalization: access to dihydroquinolones, dihydroisoquinolones and the BMS-791325 ring system.

scientific article published on 17 June 2015

Enantioselective palladium-catalyzed direct arylations at ambient temperature: access to indanes with quaternary stereocenters

scientific article published on 01 January 2009

Enantioselective rhodium-catalyzed C-C bond activations.

scientific article

Enantioselective synthesis of indanols from tert-cyclobutanols using a rhodium-catalyzed C-C/C-H activation sequence

scientific article published on 01 January 2009

Enantioselective total synthesis of cylindramide

scientific article published on 01 January 2005

Exploitation of Unconventional Electrophiles in Enantioselective Pd(0)-Catalyzed C-H Functionalizations

scientific article published on 01 April 2019

Heteroatom Nucleophile Induced C–C Fragmentations to Access Functionalized Allenes ⬇️

scientific article published on 01 January 2012

Heteroatom‐Nucleophile‐Induced CC Fragmentations: Synthesis of Allenes and Entry to Domino Reactions ⬇️

scientific article published on November 15, 2010

Highly enantioselective rhodium(I)-catalyzed activation of enantiotopic cyclobutanone C-C bonds

scientific article published on 12 February 2014

Highly enantioselective rhodium(I)-catalyzed carbonyl carboacylations initiated by C-C bond activation

scientific article published on 14 July 2014

Intermolecular Palladium(0)-Catalyzed Atropo-enantioselective C-H Arylation of Heteroarenes

scientific article published on 27 January 2020

Iridium-catalyzed acid-assisted asymmetric hydrogenation of oximes to hydroxylamines

scientific article published on 01 June 2020

Ligand-controlled regiodivergent nickel-catalyzed annulation of pyridones

scientific article published on 06 November 2014

Ligand-controlled regiodivergent pathways of rhodium(III)-catalyzed dihydroisoquinolone synthesis: experimental and computational studies of different cyclopentadienyl ligands.

scientific article published on 3 October 2014

Mild complexation protocol for chiral CpRh and Ir complexes suitable for catalysis

scientific article published on 31 October 2018

Neutral chiral cyclopentadienyl Ru(ii)Cl catalysts enable enantioselective [2+2]-cycloadditions

scientific article

Nickel(0)-catalyzed enantioselective annulations of alkynes and arylenoates enabled by a chiral NHC ligand: efficient access to cyclopentenones

scientific article published on 24 September 2014

Nickel-Catalyzed Enantioselective Pyridone C-H Functionalizations Enabled by a Bulky N-Heterocyclic Carbene Ligand

scientific article published on 20 March 2018

One-Step Multigram-Scale Biomimetic Synthesis of Psiguadial B.

scientific article

Palladium(0)-catalyzed enantioselective C-H arylation of cyclopropanes: efficient access to functionalized tetrahydroquinolines

scientific article published on 19 November 2012

Palladium-catalyzed arylative ring-opening reactions of norbornenols: entry to highly substituted cyclohexenes, quinolines, and tetrahydroquinolines

scientific article published on 01 June 2010

Preparation of UDP-galacturonic acid using UDP-sugar pyrophosphorylase

scientific article published on 15 March 2006

Regiodivergent cyclobutanone cleavage: switching selectivity with different Lewis acids

scientific article published on 04 December 2014

Rhodium(I)-catalyzed enantioselective activation of cyclobutanols: formation of cyclohexane derivatives with quaternary stereogenic centers

scientific article published in March 2010

Rhodium(III)-Catalyzed Cyclopropane C-H/C-C Activation Sequence Provides Diastereoselective Access to α-Alkoxylated γ-Lactams

scientific article published on 17 June 2020

Rhodium(III)-Catalyzed Enantiotopic C-H Activation Enables Access to P-Chiral Cyclic Phosphinamides.

scientific article

Rhodium(III)/copper(II)-promoted trans-selective heteroaryl acyloxylation of alkynes: stereodefined access to trans-enol esters

scientific article published on 03 November 2014

Rhodium-catalyzed C-C bond cleavage: construction of acyclic methyl substituted quaternary stereogenic centers.

scientific article published in April 2010

Rhodium-catalyzed dynamic kinetic asymmetric transformations of racemic allenes by the [3+2] annulation of aryl ketimines

scientific article published on 16 August 2013

Synthesis and biological properties of cylindramide derivatives: evidence for calcium-dependent cytotoxicity of tetramic acid lactams

scientific article published on October 2008

Synthesis of Fijiolide A via an Atropselective Paracyclophane Formation

scientific article published on 24 August 2015

Synthesis of functionalized spiroindolines via palladium-catalyzed methine C-H arylation

scientific article published on 01 March 2013

TADDOL-based phosphorus(III)-ligands in enantioselective Pd(0)-catalysed C-H functionalisations

scientific article published on 29 October 2015

Tailored trisubstituted chiral Cp x RhIII catalysts for kinetic resolutions of phosphinic amides.

scientific article

Teaching enantioselectivity to C-H bond functionalizations: initial steps of a rather long shot

scientific article published in January 2012

The 44 th EUCHEMS Conference on Stereochemistry (Bürgenstock Conference 2009)

The 4th Young Faculty Meeting - Science and Funding in its Different Varieties

scientific article

Total Synthesis of Fijiolide A.

scientific article published in April 2016

Total synthesis and NMR investigations of cylindramide

scientific article published in March 2006

syn‐Selective Rhodium(I)‐Catalyzed Allylations of Ketimines Proceeding through a Directed CH Activation/Allene Addition Sequence ⬇️

scientific article published on October 25, 2010

List of works by Nicolai Cramer

2-(Trifluoromethyl)indoles via Pd(0)-Catalyzed C(sp(3))-H Functionalization of Trifluoroacetimidoyl Chlorides

A 1,3,2-Diazaphospholene-Catalyzed Reductive Claisen Rearrangement

A Bulky Chiral N-Heterocyclic Carbene Nickel Catalyst Enables Enantioselective C-H Functionalizations of Indoles and Pyrroles

A Readily Accessible Class of Chiral Cp Ligands and their Application in RuII -Catalyzed Enantioselective Syntheses of Dihydrobenzoindoles.

A tunable class of chiral Cp ligands for enantioselective rhodium(III)-catalyzed C-H allylations of benzamides

A β-Carbon elimination strategy for convenient in situ access to cyclopentadienyl metal complexes.

Access to P- and Axially Chiral Biaryl Phosphine Oxides by Enantioselective Cpx IrIII -Catalyzed C-H Arylations

Access to sultams by rhodium(III)-catalyzed directed C-H activation

Access to β-lactams by enantioselective palladium(0)-catalyzed C(sp3)-H alkylation.

An Enantioselective Cpx Rh(III)-Catalyzed C-H Functionalization/Ring-Opening Route to Chiral Cyclopentenylamines

Aromatic homologation by non-chelate-assisted Rh(III)-catalyzed C-H functionalization of arenes with alkynes

Asymmetric Alkenyl C-H Functionalization by Cpx RhIII forms 2H-Pyrrol-2-ones through [4+1]-Annulation of Acryl Amides and Allenes

Asymmetric Catalysis Powered by Chiral Cyclopentadienyl Ligands.

Asymmetric synthesis of isoindolones by chiral cyclopentadienyl-rhodium(III)-catalyzed C-H functionalizations

Asymmetric transformations via C-C bond cleavage

Axially Chiral Dibenzazepinones by a Palladium(0)-Catalyzed Atropo-enantioselective C-H Arylation

Biomimetic synthesis of (+)-ledene, (+)-viridiflorol, (-)-palustrol, (+)-spathulenol, and psiguadial A, C, and D via the platform terpene (+)-bicyclogermacrene

Catalysis: Gold unleashes the power of three.

Catalytic Asymmetric Functionalization of Inert Bonds and Synthesis of Bioactive Natural Products ⬇️

Catalytic C-C Bond Activations via Oxidative Addition to Transition Metals

Catalytic Enantioselective Functionalizations of C-H Bonds by Chiral Iridium Complexes

Catalytic Enantioselective Transformations Involving C-H Bond Cleavage by Transition-Metal Complexes.

Catalytic enantioselective reductive Eschenmoser-Claisen rearrangements

Chiral 1,3,2-Diazaphospholenes as Catalytic Molecular Hydrides for Enantioselective Conjugate Reductions

Chiral Cationic Cp(x)Ru(II) Complexes for Enantioselective Yne-Enone Cyclizations

Chiral Cp-rhodium(III)-catalyzed asymmetric hydroarylations of 1,1-disubstituted alkenes

Chiral Cyclopentadienyl Cobalt(III) Complexes Enable Highly Enantioselective 3d-Metal-Catalyzed C-H Functionalizations

Chiral Cyclopentadienyls: Enabling Ligands for Asymmetric Rh(III)-Catalyzed C-H Functionalizations

Chiral Monodentate Phosphines and Bulky Carboxylic Acids: Cooperative Effects in Palladium‐Catalyzed Enantioselective C(sp3)–H Functionalization ⬇️

Chiral N-Heterocyclic Carbene Ligand Enabled Nickel(0)-Catalyzed Enantioselective Three-Component Couplings as Direct Access to Silylated Indanols

Chiral cyclopentadienyl Rh-catalyzed enantioselective cyclopropanation of electron-deficient olefins enable rapid access to UPF-648 and oxylipin natural products

Chiral cyclopentadienyl iridium(III) complexes promote enantioselective cycloisomerizations giving fused cyclopropanes

Chiral cyclopentadienyl ligands as stereocontrolling element in asymmetric C-H functionalization.

Chiral γ-Lactams by Enantioselective Palladium(0)-Catalyzed Cyclopropane Functionalizations.

Concise total synthesis of (+/-)-marcfortine B.

Cooperative Effects between Chiral Cpx -Iridium(III) Catalysts and Chiral Carboxylic Acids in Enantioselective C-H Amidations of Phosphine Oxides

Cyclobutanes in catalysis

Desymmetrizations of meso-tert-norbornenols by rhodium(I)-catalyzed enantioselective retro-allylations

Diaminophosphine oxide ligand enabled asymmetric nickel-catalyzed hydrocarbamoylations of alkenes

Divergent Asymmetric Synthesis of Polycyclic Compounds via Vinyl Triazenes

Divergent Synthesis of Densely Substituted Arenes and Pyridines via Cyclotrimerization Reactions of Alkynyl Triazenes

Efficient Kinetic Resolution of Sulfur-Stereogenic Sulfoximines by Exploiting CpX RhIII -Catalyzed C-H Functionalization

Enantioselective Access to 1H-Isoindoles with Quaternary Stereogenic Centers by Palladium(0)-Catalyzed C-H Functionalization

Enantioselective Access to S-Chiral 1,2-Benzothiazines by CpxRh(III) Catalyzed C-H Functionalization of Sulfoximines

Enantioselective Access to Spirocyclic Sultams by Chiral Cp(x) -Rhodium(III)-Catalyzed Annulations

Enantioselective C-C bond activation of allenyl cyclobutanes: access to cyclohexenones with quaternary stereogenic centers

Enantioselective C-H Functionalization-Addition Sequence Delivers Densely Substituted 3-Azabicyclo[3.1.0]hexanes.

Enantioselective C-H arylation strategy for functionalized dibenzazepinones with quaternary stereocenters.

Enantioselective Iron-Catalyzed Cross-[4+4]-Cycloaddition of 1,3-Dienes Provides Chiral Cyclooctadienes

Enantioselective Rhodium(I)‐Catalyzed [3+2] Annulations of Aromatic Ketimines Induced by Directed CH Activations ⬇️

Enantioselective Rhodium-catalyzed C-C Bond Activation of Cyclobutanones.

Enantioselective assembly of the benzo[d]xanthene tetracyclic core of anti-influenza active natural products

Enantioselective metal-catalyzed activation of strained rings

Enantioselective palladium(0)-catalyzed intramolecular cyclopropane functionalization: access to dihydroquinolones, dihydroisoquinolones and the BMS-791325 ring system.

Enantioselective palladium-catalyzed direct arylations at ambient temperature: access to indanes with quaternary stereocenters

Enantioselective rhodium-catalyzed C-C bond activations.

Enantioselective synthesis of indanols from tert-cyclobutanols using a rhodium-catalyzed C-C/C-H activation sequence

Enantioselective total synthesis of cylindramide

Exploitation of Unconventional Electrophiles in Enantioselective Pd(0)-Catalyzed C-H Functionalizations

Heteroatom Nucleophile Induced C–C Fragmentations to Access Functionalized Allenes ⬇️

Heteroatom‐Nucleophile‐Induced CC Fragmentations: Synthesis of Allenes and Entry to Domino Reactions ⬇️

Highly enantioselective rhodium(I)-catalyzed activation of enantiotopic cyclobutanone C-C bonds

Highly enantioselective rhodium(I)-catalyzed carbonyl carboacylations initiated by C-C bond activation

Intermolecular Palladium(0)-Catalyzed Atropo-enantioselective C-H Arylation of Heteroarenes

Iridium-catalyzed acid-assisted asymmetric hydrogenation of oximes to hydroxylamines

Ligand-controlled regiodivergent nickel-catalyzed annulation of pyridones

Ligand-controlled regiodivergent pathways of rhodium(III)-catalyzed dihydroisoquinolone synthesis: experimental and computational studies of different cyclopentadienyl ligands.

Mild complexation protocol for chiral CpRh and Ir complexes suitable for catalysis

Neutral chiral cyclopentadienyl Ru(ii)Cl catalysts enable enantioselective [2+2]-cycloadditions

Nickel(0)-catalyzed enantioselective annulations of alkynes and arylenoates enabled by a chiral NHC ligand: efficient access to cyclopentenones

Nickel-Catalyzed Enantioselective Pyridone C-H Functionalizations Enabled by a Bulky N-Heterocyclic Carbene Ligand

One-Step Multigram-Scale Biomimetic Synthesis of Psiguadial B.

Palladium(0)-catalyzed enantioselective C-H arylation of cyclopropanes: efficient access to functionalized tetrahydroquinolines

Palladium-catalyzed arylative ring-opening reactions of norbornenols: entry to highly substituted cyclohexenes, quinolines, and tetrahydroquinolines

Preparation of UDP-galacturonic acid using UDP-sugar pyrophosphorylase

Regiodivergent cyclobutanone cleavage: switching selectivity with different Lewis acids

Rhodium(I)-catalyzed enantioselective activation of cyclobutanols: formation of cyclohexane derivatives with quaternary stereogenic centers

Rhodium(III)-Catalyzed Cyclopropane C-H/C-C Activation Sequence Provides Diastereoselective Access to α-Alkoxylated γ-Lactams

Rhodium(III)-Catalyzed Enantiotopic C-H Activation Enables Access to P-Chiral Cyclic Phosphinamides.