Search filters

List of works by Bas de Bruin

'Carbene radicals' in Co(II)(por)-catalyzed olefin cyclopropanation.

scientific article published on August 2010

2-Rhodaoxetanes: Their Formation of Oxidation of [RhI(ethene)]+ and Their Reactivity upon Protonation

scientific article published on 01 January 2000

3-Methylindole-Based Tripodal Tetraphosphine Ruthenium Complexes in N2 Coordination and Reduction and Formic Acid Dehydrogenation

article published in 2017

A Diolefin Diamide Rhodium(I) Complex and Its One-Electron Oxidation Resulting in a Two-Center, Three-Electron Rh-N Bond

article

A Mechanistic Study of Direct Activation of Allylic Alcohols in Palladium Catalyzed Amination Reactions

A Self-Assembled Molecular Cage for Substrate-Selective Epoxidation Reactions in Aqueous Media

article published in 2016

A Stable Aminyl Radical Coordinated to Cobalt.

scientific article

A different route to functional polyolefins: olefin-carbene copolymerisation.

scientific article published on 30 January 2013

A low-valent dinuclear ruthenium diazadiene complex catalyzes the oxidation of dihydrogen and reversible hydrogenation of quinones

scientific article published on 15 November 2018

A platinum(II) metallonitrene with a triplet ground state

scientific article published on 24 August 2020

Accessing the CpArNi(I) Synthon: Reactions with N-Heterocyclic Carbenes, TEMPO, Sulfur, and Selenium

Activation of Carbon Monoxide by (Me3tpa)Rh and (Me3tpa)Ir

Activation of H2 by a highly distorted RhII complex with a new C3-symmetric tripodal tetraphosphine ligand

Amidation of [RhI(ethene)]+ via a 2-Rhodaoxetane

scholarly article by Bas de Bruin et al published 15 January 1999 in Angewandte Chemie

Amido-bridged dinuclear rhodium(I) complexes by deprotonation of mononuclear rhodium(I) amine complexes

scholarly article by Bas de Bruin et al published September 2002 in Inorganica Chimica Acta

Amino olefin nickel(i) and nickel(0) complexes as dehydrogenation catalysts for amine boranes

scholarly article by Matthias Vogt et al published 2011 in Chemical Science

Amplified Vibrational Circular Dichroism as a Probe of Local Biomolecular Structure

article

An iridium(iii/iv/v) redox series featuring a terminal imido complex with triplet ground state.

scientific article

Application of [Co(Corrole)]- Complexes in Ring-Closing C-H Amination of Aliphatic Azides via Nitrene Radical Intermediates

Aqueous Phase Separation Behavior of Highly Syndiotactic, High Molecular Weight Polymers with Densely Packed Hydroxy-Containing Side Groups

scientific article published on 11 September 2018

Aryldiazonium Salts as Nitrogen-Based Lewis Acids: Facile Synthesis of Tuneable Azophosphonium Salts

scientific article published on 20 August 2018

Balance between Metal and Ligand Reduction in Diiminepyridine Complexes of Ti

Base-free production of H2 by dehydrogenation of formic acid using an iridium-bisMETAMORPhos complex

scientific article published on 19 July 2013

Beyond classical reactivity patterns: hydroformylation of vinyl and allyl arenes to valuable β- and γ-aldehyde intermediates using supramolecular catalysis.

scientific article published on 2 June 2014

Binuclear [(cod)(Cl)Ir(bpi)Ir(cod)]+for Catalytic Water Oxidation

Bioinspired nonheme iron complexes derived from an extended series of N,N,O-ligated BAIP ligands

scientific article published on 10 June 2013

Bridging methylene addition to the disulfur ligands of an iron-sulfur cluster compound. X-ray structure of [Fe4(.mu.3-S)2((.mu.3-S2)CH2(.mu.3-S2))(C5H4Me)4]2+ (FeCl4)2-

article

C-H Activation of Benzene by a Photoactivated Ni(II)(azide): Formation of a Transient Nickel Nitrido Complex

scientific article

C1 polymerisation and related C-C bond forming 'carbene insertion' reactions

scientific article published on 03 December 2009

Carbene insertion into transition metal–carbon bonds: a new tool for catalytic C–C bond formation

article

Carbene radicals in cobalt(II)-porphyrin-catalysed carbene carbonylation reactions; a catalytic approach to ketenes

scientific article

Carbon-carbon bond activation of 2,2,6,6-tetramethyl-piperidine-1-oxyl by a Rh(II) metalloradical: a combined experimental and theoretical study

scientific article published on 19 January 2008

Carbonyl Complexes of Rhodium with N-Donor Ligands: Factors Determining the Formation of Terminal versus Bridging Carbonyls

scholarly article by Wojciech I. Dzik et al published 12 April 2010 in Organometallics

Catalyst recycling via specific non-covalent adsorption on modified silicas

scientific article published on 4 January 2013

Catalytic 1,2-dihydronaphthalene and E-aryl-diene synthesis via CoIII-Carbene radical and o-quinodimethane intermediates.

scientific article

Catalytic Dibenzocyclooctene Synthesis via Cobalt(III)-Carbene Radical and ortho-Quinodimethane Intermediates

scientific article published on 20 November 2017

Catalytic Synthesis of 2H-Chromenes

article

Catalytic Synthesis of Indolines by Hydrogen Atom Transfer to Cobalt(III)-Carbene Radicals

scientific article

Catalytic Synthesis of N-Heterocycles via Direct C(sp3)-H Amination Using an Air-Stable Iron(III) Species with a Redox-Active Ligand

scientific article

Characterization of Porphyrin-Co(III)-'Nitrene Radical' Species Relevant in Catalytic Nitrene Transfer Reactions

scientific article published on 16 April 2015

Charge-Delocalized κ2C,N-NHC-Amine Complexes of Rhodium, Iridium, and Ruthenium

scholarly article by Eveline Jansen et al published 22 May 2014 in Organometallics

Cheap and Diastereoselective ß-Lactam Formation

Chloride-Triggered Disproportionation of a Mononuclear RhII(nbd) Species to RhI(nbd) and RhIII(η1-norbornenyl) Complexes: Possibilities for Wacker Type Mono-oxygenation of Norbornadiene to Norbornenone

article

Chromatographic examination of the chemical composition and sequence distribution of copolymers from ethyl and benzyl diazoacetate

article

Closed-shell and open-shell square-planar iridium nitrido complexes

scholarly article by Markus G. Scheibel et al published 3 June 2012 in Nature Chemistry

Co(III)-Carbene Radical Approach to Substituted 1H-Indenes

scientific article published on 24 June 2016

Cobalt-Porphyrin-Catalysed Intramolecular Ring-Closing C-H Amination of Aliphatic Azides: A Nitrene-Radical Approach to Saturated Heterocycles

scientific article published on 23 March 2017

Complexes with nitrogen-centered radical ligands: classification, spectroscopic features, reactivity, and catalytic applications

scientific article

Computed Propagation and Termination Steps in [(Cycloocta-2,6-dien-1-yl)RhIII(polymeryl)]+ Catalyzed Carbene Polymerization Reactions

Controlled Synthesis of Functional Copolymers with Blocky Architectures via Carbene Polymerization

article by Nicole M. G. Franssen et al published 18 April 2012 in Macromolecules

Convenient Transfer Semihydrogenation Methodology for Alkynes Using a PdII-NHC Precatalyst

Cooperative Double Deprotonation of Bis(2-picolyl)amine Leading to Unexpected Bimetallic Mixed Valence (M–I, MI) Rhodium and Iridium Complexes

scholarly article by Cristina Tejel et al published 15 August 2011 in Inorganic Chemistry

Coordination of 3‐Methylindole‐Based Tripodal Tetraphosphine Ligands to Iron(+II), Cobalt(+II), and Nickel(+II) and Investigations of their Subsequent Two‐Electron Reduction.

scientific article

Cover Feature: Exogenous Ligand‐Free Nickel‐Catalyzed Carboxylate O ‐Arylation: Insight into Ni I /Ni III Cycles (ChemCatChem 18/2022)

scientific article published on 25 August 2022

Cross-linking polyethylene through carbenes

scientific article published on 01 November 2019

Dehydrative cross-coupling reactions of allylic alcohols with olefins

scientific article published on 11 August 2014

Dehydrogenation of formic acid by Ir-bisMETAMORPhos complexes: experimental and computational insight into the role of a cooperative ligand

scientific article published on 22 October 2014

Deprotonation Induced Ligand Oxidation in a Ni(II) Complex of a Redox Noninnocent N(1)-(2-Aminophenyl)benzene-1,2-diamine and Its Use in Catalytic Alcohol Oxidation

scientific article published on 7 June 2016

Deprotonation induced ligand-to-metal electron transfer: synthesis of a mixed-valence Rh(-I,I) dinuclear compound and its reaction with dioxygen

scientific article published on 11 April 2008

Developing Synthetic Approaches with Non-Innocent Metalloligands: Easy Access to IrI/Pd0 and IrI/Pd0/IrI Cores

scientific article published on 17 August 2011

Diastereoselective Radical-Type Cyclopropanation of Electron-Deficient Alkenes Mediated by the Highly Active Cobalt(II) Tetramethyltetraaza[14]annulene Catalyst

scientific article published on 24 April 2017

Dibenzo[b,f]phosphepines: Novel Phosphane–Olefin Ligands for Transition Metals

article

Difluorocarbene transfer from a cobalt complex to an electron-deficient alkene

scientific article published on 5 April 2017

Dinuclear palladium complexes with two ligand-centered radicals and a single bridging ligand: subtle tuning of magnetic properties

scientific article published on 3 March 2015

Dioxygen Activation by a Mononuclear IrII–Ethene Complex

scholarly article by Bas de Bruin et al published 17 June 2002 in Angewandte Chemie

Direct probing of photoinduced electron transfer in a self-assembled biomimetic [2Fe2S]-hydrogenase complex using ultrafast vibrational spectroscopy

scientific article published on 26 April 2014

Disproportionation of RhII(cod) to RhI(cod) and RhIII(cycloocta-2,5-dien-1-yl): Hydrogen Atom Transfer vs Electron and Proton Transfer

article published in 2003

Dynamic Combinatorial Chemistry: The Unexpected Choice of Receptors by Guest Molecules

scholarly article by Bas de Bruin et al published 21 April 2006 in Angewandte Chemie International Edition

Dynamic ligand reactivity in a rhodium pincer complex

scientific article

EPR Spectroscopy as a Tool in Homogeneous Catalysis Research

scholarly article by Monalisa Goswami et al published 4 August 2015 in Topics in Catalysis

Effector responsive hydroformylation catalysis

scientific article published on 19 June 2019

Efficient Copper-Catalyzed Multicomponent Synthesis of N-Acyl Amidines via Acyl Nitrenes

scientific article published on 10 September 2019

Electrocatalytic Azide Oxidation Mediated by a Rh(PNP) Pincer Complex

scientific article published on 12 September 2017

Electromeric rhodium radical complexes

scientific article

Electronic Selectivity Tuning in Titanium(III)-Catalyzed Acetylene Cross-Dimerization Reactions

scholarly article by Gennady V. Oshovsky et al published 28 November 2011 in Organometallics

Electronic Structure and Magnetic Anisotropy of an Unsaturated Cyclopentadienyl Iron(I) Complex with 15 Valence Electrons

scientific article published on 30 May 2017

Electronically Asynchronous Transition States for C–N Bond Formation by Electrophilic [Co III (TAML)] -Nitrene Radical Complexes Involving Substrate-to-Ligand Single-Electron Transfer and a Cobalt-Centered Spin Shuttle

scientific article published on 12 June 2020

Encapsulated cobalt-porphyrin as a catalyst for size-selective radical-type cyclopropanation reactions

scientific article published on 24 March 2014

Encapsulation of Metalloporphyrins in a Self-Assembled Cubic M8L6Cage: A New Molecular Flask for Cobalt-Porphyrin-Catalysed Radical-Type Reactions

scientific article published on 02 July 2013

Enhanced reactivity of 2-rhodaoxetanes through a labile acetonitrile ligand

scientific article

Exchange of organic radicals with organo-cobalt complexes formed in the living radical polymerization of vinyl acetate

scientific article

Exchanging conformations of a hydroformylation catalyst structurally characterized using two-dimensional vibrational spectroscopy.

scientific article published on 20 November 2013

Exogenous Ligand‐Free Nickel‐Catalyzed Carboxylate O ‐Arylation: Insight into Ni I /Ni III Cycles**

scientific article published on 11 August 2022

Experimental evidence for cobalt(III)-carbene radicals: key intermediates in cobalt(II)-based metalloradical cyclopropanation.

scientific article

Facile synthesis and versatile reactivity of an unusual cyclometalated rhodium(I) pincer complex

scientific article

Formation of Ethylene-Bridged Dinuclear IrIIISpecies via M−C Coupling of IrIIand IrII(ethene)

article published in 2002

Formation of a paramagnetic Al complex and extrusion of Fe during the reaction of (diiminepyridine)Fe with AlR3 (R = Me, Et).

scientific article

Front Cover: [Co(MeTAA)] Metalloradical Catalytic Route to Ketenes via Carbonylation of Carbene Radicals (Eur. J. Inorg. Chem. 20-21/2018)

Functional Models for Rhodium-Mediated Olefin-Oxygenation Catalysis

article

Gas-phase reactions of an iridium(I) complex with dioxygen – Comparison to solution-phase reactivity

scholarly article by Simone Thewissen et al published March 2006 in International Journal of Mass Spectrometry

Germanium(iii) corrole complex: reactivity and mechanistic studies of visible-light promoted N–H bond activations

article

Highly enantioselective hydroformylation of dihydrofurans catalyzed by hybrid phosphine-phosphonite rhodium complexes

scientific article published on 18 January 2010

Highly selective asymmetric Rh-catalyzed hydroformylation of heterocyclic olefins.

scientific article published on 3 April 2012

Homogeneously catalysed conversion of aqueous formaldehyde to H2 and carbonate

scientific article

Homoleptic diphosphacyclobutadiene complexes [M(η(4)-P2C2R2)2]x- (M = Fe, Co; x = 0, 1).

scientific article published on December 2010

Homolytic N-H activation of ammonia: hydrogen transfer of parent iridium ammine, amide, imide, and nitride species

scientific article

How Solvent Affects C-H Activation and Hydrogen Production Pathways in Homogeneous Ru-Catalyzed Methanol Dehydrogenation Reactions

Hydroformylation of 1-Octene Mediated by the Cobalt Complex [CoH(dchpf)(CO)2]

scholarly article by Alexander M. Kluwer et al published 12 September 2016 in Topics in Catalysis

Hydrogen-atom transfer in open-shell organometallic chemistry: the reactivity of Rh(II)(cod) and Ir(II)(cod) radicals

scientific article published on January 2007

Hydrogen-atom transfer in reactions of organic radicals with [Co(II)(por)]* (por = porphyrinato) and in subsequent addition of [Co(H)(por)] to olefins

scientific article

Hydrogen-bond-assisted activation of allylic alcohols for palladium-catalyzed coupling reactions

scientific article published on 16 January 2014

Hydrogenation of carboxylic acids with a homogeneous cobalt catalyst

scientific article published in October 2015

Instability of Square Planar N3-Ligand Iridium(I) Ethene Complexes

scholarly article by Simone Thewissen et al published November 2005 in Organometallics

Interconversion of Phosphinyl Radical and Phosphinidene Complexes by Proton Coupled Electron Transfer

scientific article published on 01 April 2019

Intervalent bis(mu-aziridinato)M(II)--M(I) complexes (M=Rh,Ir): delocalized metallo-radicals or delocalized aminyl radicals?

scientific article

Intramolecular redox-active ligand-to-substrate single-electron transfer: radical reactivity with a palladium(II) complex

scientific article published on 17 June 2014

Investigating the Active Species in a [(R‐SN(H)S‐R)CrCl 3 ] Ethene Trimerization System: Mononuclear or Dinuclear?

scientific article published on 12 December 2019

IrII(ethene): metal or carbon radical?

scientific article

IrII(ethene): metal or carbon radical? Part II: oxygenation via iridium or direct oxygenation at ethene?

scientific article

Iron-Catalyzed/Mediated C-N Bond Formation: Competition between Substrate Amination and Ligand Amination

scientific article published on 14 January 2019

Ligand Design in Rh(diene)-Mediated “Carbene” Polymerization; Efficient Synthesis of High-Mass, Highly Stereoregular, and Fully Functionalized Carbon-Chain Polymers

Ligand Redox Noninnocence in [CoIII(TAML)]0/- Complexes Affects Nitrene Formation

scientific article published on 30 December 2019

Ligand denticity controls enantiomeric preference in DNA-based asymmetric catalysis

scientific article published on 23 January 2012

Ligand effects on the hydrogenation of biomass-inspired substrates with bifunctional Ru, Ir, and Rh complexes

scientific article published in September 2013

Ligand oxidation of a deprotonated bis(picolyl)amine Ir(I)(cod) complex

scientific article published in January 2008

Ligand- and Metal-Based Reactivity of a Neutral Ruthenium Diolefin Diazadiene Complex; The Innocent, the Guilty, and the Suspicious

scientific article published on 17 January 2018

Ligand-Mediated Spin-State Changes in a Cobalt-Dipyrrin-Bisphenol Complex

scientific article published on 20 August 2020

Ligand-centred reactivity of bis(picolyl)amine iridium: sequential deprotonation, oxidation and oxygenation of a "non-innocent" ligand

scientific article

Ligand-controlled magnetic interactions in Mn(4) clusters

scientific article published in December 2009

Ligands that Store and Release Electrons during Catalysis

scientific article published on 04 March 2011

Localized Mixed-Valence and Redox Activity within a Triazole-Bridged Dinucleating Ligand upon Coordination to Palladium

scientific article published on 17 August 2016

Low-Valence Anionic α-Diimine Iron Complexes: Synthesis, Characterization, and Catalytic Hydroboration Studies

scientific article published on 20 October 2020

Low-Valent Iron Mono-Diazadiene Compounds: Electronic Structure and Catalytic Application

Low-valent iron: an Fe(i) ate compound as a building block for a linear trinuclear Fe cluster

scientific article published on 01 September 2015

Mechanism of cobalt(II) porphyrin-catalyzed C-H amination with organic azides: radical nature and H-atom abstraction ability of the key cobalt(III)-nitrene intermediates.

scientific article published on 18 July 2011

Mechanism of the Dehydrogenative Phenothiazination of Phenols

scientific article published on 25 July 2018

Mechanistic investigations into the cyclopropanation of electron-deficient alkenes with ethyl diazoacetate using [Co(MeTAA)]

scholarly article by Andrei Chirila et al published May 2018 in Journal of Catalysis

Metal-Catalysed Azidation of Organic Molecules

scientific article published on 22 December 2016

Metal-to-ligand electron transfer in diiminopyridine complexes of Mn-Zn. A theoretical study.

scientific article published in August 2001

Metalloradical Reactivity of RuI and Ru0 Stabilized by an Indole-Based Tripodal Tetraphosphine Ligand

scientific article published on 30 August 2017

Metalloradical approach to 2H-chromenes.

scientific article published on 08 January 2014

Metalloradical-Catalyzed Selective 1,2-Rh-H Insertion into the Aliphatic Carbon–Carbon Bond of Cyclooctane

Molecular Golf Balls: Vesicles from Bowl-Shaped Host Molecules

scholarly article by Albertus P. H. J. Schenning et al published 2 September 1994 in Angewandte Chemie International Edition

Molecular and Electronic Structures of Bis(pyridine-2,6-diimine)metal Complexes [ML2](PF6)n(n= 0, 1, 2, 3; M = Mn, Fe, Co, Ni, Cu, Zn)†

scientific article (publication date: June 2000)

Multitechnique Approach to Reveal the Mechanism of Copper(II)-Catalyzed Arylation Reactions

N-Atom transfer via thermal or photolytic activation of a Co-azido complex with a PNP pincer ligand.

scientific article

New routes toward metallated methanofullerene terdentate bisaminoaryl ligands

New tetracobalt cluster compounds for electrocatalytic proton reduction: syntheses, structures, and reactivity

scientific article published on 29 January 2015

Nickel-Alkyl Complexes with a Reactive PNC-Pincer Ligand.

scientific article

Nitrene Radical Intermediates in Catalytic Synthesis

scientific article published on 4 July 2017

Non-innocent ligands

scientific article

Nucleophilicity and P-C Bond Formation Reactions of a Terminal Phosphanido Iridium Complex

scientific article published on 22 December 2015

Olefin hydrogenation using diimine pyridine complexes of Co and Rh

scholarly article by Quinten Knijnenburg et al published May 2005 in Journal of Molecular Catalysis A

On the "tertiary structure" of poly-carbenes; self-assembly of sp3-carbon-based polymers into liquid-crystalline aggregates

scientific article published on 12 July 2013

Open-Shell Organometallic [MII(dbcot(bislutidylamine)]2+Complexes (M = Rh, Ir): Unexpected Base-Assisted Reduction of the Metal Instead of Amine Ligand Deprotonation

Open-shell rhodium and iridium species in (catalytic) oxygenation reactions

article

Oxidation of RhI(olefin) Fragments to 2-Rhoda(III)oxetanes

Oxidation of Rhodium-Olefin Complexes via 2-Rhodaoxetanes ⬇️

PhD thesis at Radboud University

Paramagnetic (Alkene)Rh and (Alkene)Ir Complexes: Metal or Ligand Radicals?

Pd-CatalyzedZ-Selective Semihydrogenation of Alkynes: Determining the Type of Active Species

article

Pd-mediated carbenepolymerisation: activity of palladium(ii) versus low-valent palladium

scholarly article by Nicole M. G. Franssen et al published 2011 in Polymer Chemistry

Phosphorus Analogues of [Ni(bpy)2]: Synthesis and Application in Carbon-Halogen Bond Activation

scientific article published on 02 July 2020

Photo- and Thermal Isomerization of (TP)Fe(CO)Cl2 [TP = Bis(2-diphenylphosphinophenyl)phenylphosphine]

article

Photolytic N2Splitting: A Road to Sustainable NH3Production?

scientific article published on 07 November 2014

Pincer ligands with an all-phosphorus donor set: subtle differences between rhodium and palladium.

scientific article published on 7 July 2011

Porphyrin Co(III)-Nitrene Radical Mediated Pathway for Synthesis of o-Aminoazobenzenes

scientific article published in May 2018

Porphyrin Cobalt(III) "Nitrene Radical" Reactivity; Hydrogen Atom Transfer from Ortho-YH Substituents to the Nitrene Moiety of Cobalt-Bound Aryl Nitrene Intermediates (Y = O, NH).

scientific article published on 20 February 2016

Propagation and termination steps in Rh-mediated carbene polymerisation using diazomethane

article

Publisher Correction: A platinum(II) metallonitrene with a triplet ground state

scientific article published on 16 December 2020

Pump–probe XAS investigation of the triplet state of an Ir photosensitizer with chromenopyridinone ligands

scientific article published on 01 July 2018

P–C dichotomy: divergent iron(−I)-mediated alkyne and phosphaalkyne cycloligomerisations

article

Radical-type Reactions Controlled by Cobalt: From Carbene Radical Reactivity to the Catalytic Intermediacy of Reactive o-Quinodimethanes

scholarly article by Bas de Bruin & Colet te Grotenhuis published 19 July 2018 in Synlett

Rational Optimization of Supramolecular Catalysts for the Rhodium-Catalyzed Asymmetric Hydrogenation Reaction.

scientific article

Reactivity of Dinitrogen Bound to Mid- and Late-Transition-Metal Centers

article by Nitesh Khoenkhoen et al published 20 January 2015 in European Journal of Inorganic Chemistry

Reactivity of Me-pma RhIand IrIComplexes upon Deprotonation and Their Application in Catalytic Carbene Carbonylation Reactions

Reactivity of a Ruthenium-Carbonyl Complex in the Methanol Dehydrogenation Reaction

scientific article published on 18 August 2016

Reactivity of a mononuclear iridium(I) species bearing a terminal phosphido fragment embedded in a triphosphorus ligand.

scientific article published on 29 January 2013

Redox Non-Innocent Ligands: Versatile New Tools to Control Catalytic Reactions

Redox Noninnocence of Carbene Ligands: Carbene Radicals in (Catalytic) C−C Bond Formation

scientific article (publication date: 17 October 2011)

Redox-Active Bis(phenolate) N-Heterocyclic Carbene [OCO] Pincer Ligands Support Cobalt Electron Transfer Series Spanning Four Oxidation States.

scientific article

Redox-active ligand-induced homolytic bond activation

scientific article

Reductive Elimination at an Ortho-Metalated Iridium(III) Hydride Bearing a Tripodal Tetraphosphorus Ligand

scholarly article by Yann Gloaguen et al published 12 July 2013 in Organometallics

Remote Supramolecular Control of Catalyst Selectivity in the Hydroformylation of Alkenes

scientific article published on 01 January 2011

Reversible Redox Chemistry and Catalytic C(sp(3))-H Amination Reactivity of a Paramagnetic Pd Complex Bearing a Redox-Active o-Aminophenol-Derived NNO Pincer Ligand

scientific article

Rh-Mediated C1-Polymerization: Copolymers from Diazoesters and Sulfoxonium Ylides

Rh-Mediated Carbene Polymerization: from Multistep Catalyst Activation to Alcohol-Mediated Chain-Transfer

Rh-Mediated Polymerization of Carbenes: Mechanism and Stereoregulation

scientific article published in 2007

Rhodium(0) metalloradicals in binuclear C-H activation

scientific article

Rhodium(I) mediated arylation of aldehydes with arylboronic acids under base and water free conditions: A computational study☆

article published in 2010

Rhodium-Catalyzed Asymmetric Hydroformylation with Taddol-Based IndolPhos Ligands

scholarly article by Jeroen Wassenaar et al published 28 June 2010 in Organometallics

Rhodium-Mediated Stereoselective Polymerization of “Carbenes”

article

Rhodium-Mediated Stereospecific Carbene Polymerization: From Homopolymers to Random and Block Copolymers

article

Rhodium-P,O-bidentate coordinated ureaphosphine ligands for asymmetric hydrogenation reactions

scientific article published on 6 January 2010

Role of the ligand and activator in selective Cr–PNP ethene tri- and tetramerization catalysts – a spectroscopic study

scientific article published in 2020

Role of β-H Elimination in Rhodium-Mediated Carbene Insertion Polymerization

Selective C-C coupling of Ir-ethene and Ir-carbenoid radicals

scientific article published in January 2008

Selective Co-Encapsulation Inside an M6 L4 Cage

scientific article published on 14 September 2016

Selective Oxidation of [RhI(cod)]+ by H2O2 and O2

Selective P4 Activation by a Highly Reduced Cobaltate: Synthesis of Dicobalt Tetraphosphido Complexes.

scientific article published on 21 September 2016

Selective P4 activation by an organometallic nickel(i) radical: formation of a dinuclear nickel(ii) tetraphosphide and related di- and trichalcogenides

article

Snapshots of a Reversible Metal-Ligand Two-Electron Transfer Step Involving Compounds Related by Multiple Types of Isomerism

article

Spin density distribution in mononuclear Rh(0) complexes: A combined experimental and DFT study

Spontaneous disproportionation of rhodium(i) bisoxazolinates to rhodium(ii)Electronic supplementary information (ESI) available: synthetic procedures (including 1H NMR, 13C NMR and elemental analysis data), EPR spectrum and cyclic voltammogram. See h

scientific article published on 01 January 2002

Stereospecific Carbene Polymerization with Oxygenated Rh(diene) Species ⬇️

scientific article published on April 12, 2012

Strong Binding of Paraquat and Polymeric Paraquat Derivatives by Basket-Shaped Hosts

Structure and reactivity of a unique Y-shaped tricoordinate bis(silyl)platinum(II)-NHC complex

scientific article published in January 2009

Sulfonamido−Phosphoramidite Ligands in Cooperative Dinuclear Hydrogenation Catalysis

article published in 2009

Supramolecular NHC ligands: on the influence of Zn(II)-templates on the activity of Rh(I)(cod) complexes in 'carbene polymerization'.

scientific article published on 7 September 2009

Synthesis and Electronic Structure of Dissymmetrical, Naphthalene-Bridged Sandwich Complexes [Cp′Fe(μ-C10H8)MCp*]x (x = 0, +1; M = Fe, Ru; Cp′ = η5-C5H2-1,2,4-tBu3; Cp* = η5-C5Me5)

article

Synthesis and Reactivity of Ester-Functionalized 5-Membered RhI-κ2-C,O-Chelates and Their Relevance in Rh(cod)-Mediated Carbene Polymerization

Synthesis and reactivity of a transient, terminal nitrido complex of rhodium.

scientific article

Synthesis of functional 'polyolefins': state of the art and remaining challenges

scientific article published on July 2013

Synthesis, aggregation, and binding behavior of synthetic amphiphilic receptors

scientific article

Synthesis, electronic structure and redox properties of the diruthenium sandwich complexes [Cp*Ru(μ-C10H8)RuCp*]x (x = 0, 1+; Cp* = C5Me5; C10H8 = naphthalene)

article

Terminal phosphanido rhodium complexes mediating catalytic P-P and P-C bond formation

scientific article

The Organometallic Chemistry of Rh-, Ir-, Pd-, and Pt-Based Radicals: Higher Valent Species

article

The radical mechanism of cobalt(II) porphyrin-catalyzed olefin aziridination and the importance of cooperative H-bonding.

scientific article published on 11 April 2011

Three-Coordinate Rhodium Complexes in Low Oxidation States

scientific article published on 19 February 2020

Transition Metal Catalysis Controlled by Hydrogen Bonding in the Second Coordination Sphere

scientific article published in 2022

Transition Metal-Free Cleavage of CO.

scientific article

Transition metal catalysis in confined spaces

scientific article

Uncatalyzed Oxidative C-H Amination of 9,10-Dihydro-9-Heteroanthracenes: A Mechanistic Study

scientific article published on 29 March 2019

Unraveling the electronic structures of low-valent naphthalene and anthracene iron complexes: X-ray, spectroscopic, and density functional theory studies

scientific article

Unusual Stereochemistry in Complexes of the Form [RhH(CO)2(PPri3)2]†

Ureaphosphanes as Hybrid, Anionic or Supramolecular Bidentate Ligands for Asymmetric Hydrogenation Reactions

Versatile new C(3)-symmetric tripodal tetraphosphine ligands; structural flexibility to stabilize Cu(I) and Rh(I) species and tune their reactivity

scientific article published in July 2010

Visible-light-induced addition of carboxymethanide to styrene from monochloroacetic acid

scientific article published on 16 March 2020

Water Splitting by Cooperative Catalysis

scientific article published on 01 January 2009

Well-Defined BisMETAMORPhos PdI–PdI Complex: Synthesis, Structural Characterization, and Reactivity

article

[Co(MeTAA)] Metalloradical Catalytic Route to Ketenes via Carbonylation of Carbene Radicals

[Co(TPP)]-Catalyzed Formation of Substituted Piperidines

scientific article published on 01 April 2019

[Cp(Ar)Ni{Ga(nacnac)}]: An Open-Shell Nickel(I) Complex Supported by a Gallium(I) Carbenoid (Cp(Ar) = C5(C6H4-4-Et)5, nacnac = HC[C(Me)N-(C6H3)-2,6-iPr2]2).

scientific article

[Ni(cod)2][Al(OR(F))4], a Source for Naked Nickel(I) Chemistry

scientific article published on 13 October 2015

‘Carbene Radicals’ in CoII(por)-Catalyzed Olefin Cyclopropanation

scientific article published in 2010

Paulina is supported by:

About Paulina

Help