List of works - Antonio Antiñolo

Activation of a CNXylyl ancillary ligand in the reaction of electron-deficient alkynes with a phosphido niobocene complex

scientific article published on 09 February 2006

Advances in the chemistry of bis-cyclopentadienyl hydride derivatives of niobium and tantalum

scholarly article by Antonio Antiñolo et al published October 1999 in Coordination Chemistry Reviews

An unprecedented hybrid scorpionate/cyclopentadienyl ligand

scientific article published on 01 February 2004

Asymmetric niobium guanidinates as intermediates in the catalytic guanylation of amines

scientific article published on 16 April 2013

Carbodiimides as catalysts for the reduction of CO2 with boranes

scientific article published on 01 May 2018

Design of new heteroscorpionate ligands and their coordinative ability toward Group 4 transition metals; an efficient synthetic route to obtain enantiopure ligands

scientific article published on 17 July 2006

Dialkylboron guanidinates: syntheses, structures and carbodiimide de-insertion reactions

scientific article published on 06 September 2016

Facile Synthesis of Alkynyl− and Vinylidene−Niobocene Complexes. Unexpected η1-Vinylidene−η2-Alkyne Isomerization

scientific article published in May 2000

First complexes of scandium and yttrium with NNO and NNS heteroscorpionate ligands.

scientific article published in July 2005

Guanidines: from classical approaches to efficient catalytic syntheses.

scientific article published on 14 March 2014

Heteroscorpionate ligands based on bis(pyrazol-1-yl)methane: design and coordination chemistry.

scientific article published on 2 April 2004

Highly diastereoselective nucleophilic addition to myrtenal. Straightforward synthesis of an enantiopure scorpionate ligand

scientific article published on 21 September 2007

Insertion reactions of small unsaturated molecules in the N-B bonds of boron guanidinates

scientific article published on 24 July 2017

Lewis base character of the phosphorus atom in phosphanido-niobocene complexes. Synthesis of new early-early homo- and heterobimetallic entities

scientific article published on 04 February 2011

Lithium, titanium, and zirconium complexes with novel amidinate scorpionate ligands

scientific article published on 03 February 2007

Mixed amido-/imido-/guanidinato niobium complexes: synthesis and the effect of ligands on insertion reactions.

scientific article published in December 2014

New Niobocene Alkyne Complexes: Synthesis and Characterization of Neutral and Cationic Niobium Complexes with Functionalized Alkynes. X-ray Crystal Structure of [Nb(η5-C5H4SiMe3)2(Cl)(η2(C,C)-R1C⋮CR2)] (R1= C⋮CPh, R2= Ph (2b); R1= CH2CHC(CH3)2,

scientific article published in March 1999

New complexes of zirconium(IV) and hafnium(IV) with heteroscorpionate ligands and the hydrolysis of such complexes to give a zirconium cluster

scientific article published on 01 February 2004

Niobocene Alkyne Complexes: Synthesis and Characterization of Neutral and Cationic d2Metal Alkyne Derivatives. X-ray Crystal Structure of [Nb(η5-C5H4SiMe3)2(η2(C,C)-HC⋮CPh)(CH2Ph)]

article published in 1997

Nitric oxide binding and photodelivery based on ruthenium(II) complexes of 4-arylazo-3,5-dimethylpyrazole

scientific article

Oxo- and imido-alkoxide vanadium complexes as precatalysts for the guanylation of aromatic amines

scientific article published on 07 June 2010

Ph2PCH2CH2B(C8H14) and Its Formaldehyde Adduct as Catalysts for the Reduction of CO2 with Hydroboranes

scientific article published on 25 June 2020

Polymerization of Ethylene by the Electrophilic Heteroscorpionate-Containing Complexes [TiCl 3 (bdmpza)] and [TiCl 2 (bdmpza){O(CH 2 ) 4 Cl}] (bdmpza = Bis(3,5-dimethylpyrazol-1-yl)acetate)

scientific article published on 11 May 2001

Preparation of new monoanionic "scorpionate" ligands: synthesis and structural characterization of titanium(IV) complexes bearing this class of ligand

scientific article published on 01 October 2002

Reactions of alkynes with phosphido niobocenes: a combined experimental and theoretical study.

scientific article published on 11 January 2010

Reactions of an Osmium(IV)-Hydroxo Complex with Amino-Boranes: Formation of Boroxide Derivatives

scholarly article by Antonio Antiñolo et al published 21 November 2018 in Organometallics

Reactivity of N-Phosphinoguanidines of the Formula (HNR)(Ph2PNR)C(NAr) toward Main Group Metal Alkyls: Facile Ligand Rearrangement from N-Phosphinoguanidinates to Phosphinimine-Amidinates

scientific article published on 01 October 2020

Ruthenium Complexes of the Scorpionate Ligand Bis(3,5-dimethylpyrazol-1-yl)dithioacetate and the Effect of Nitric Oxide Coordination

Selective Three-Component Coupling for CO2 Chemical Fixation to Boron Guanidinato Compounds

scientific article published on 27 June 2018

Simple ZnEt2 as a catalyst in carbodiimide hydroalkynylation: structural and mechanistic studies

scientific article published on 19 September 2017

Structural and Mechanistic Insights into s-Block Bimetallic Catalysis: Sodium Magnesiate-Catalyzed Guanylation of Amines

scientific article published on 27 October 2016

Synthesis and reactivity of alkynyl niobocene complexes

scientific article published in March 2003

Titanium and niobium imido complexes stabilized by heteroscorpionate ligands

scientific article published on 28 October 2004

Tris(pentafluorophenyl)borane as an efficient catalyst in the guanylation reaction of amines

scientific article published on 01 June 2016

Unexpected mild C-N bond cleavage mediated by guanidine coordination to a niobium iminocarbamoyl complex.