List of works - Yoshihiro Miyake

A 3-pyridyl-5,15-diazaporphyrin nickel(II) complex as a bidentate metalloligand for transition metals

scientific article published on 22 October 2014

A DFT study on the reaction pathways for carbon-carbon bond-forming reactions between propargylic alcohols and alkenes or ketones catalyzed by thiolate-bridged diruthenium complexes.

scientific article

A molybdenum complex bearing PNP-type pincer ligands leads to the catalytic reduction of dinitrogen into ammonia

scientific article (publication date: 5 December 2010)

Asymmetric synthesis of epoxides from aromatic aldehydes and benzyl halides catalyzed by C2 symmetric optically active sulfides having a binaphthyl skeleton

Bi-TTF, bis-TTF, and related TTF oligomers

scientific article

Catalytic Cycloisomerization of 1,5-Enynes to 1,3-Cyclohexadienes via Ruthenium Vinylidene Intermediates

scientific article published on 01 January 2009

Complexation of 2,7-diazapyrene with boron for structural and electronic tuning

scientific article published on 07 January 2021

Cooperative Catalytic Reactions Using Distinct Transition-Metal Catalysts: Ruthenium- and Copper-Catalyzed Enantioselective Propargylic Alkylation

scientific article published on 01 February 2012

Cooperative Catalytic Reactions Using Organocatalysts and Transition Metal Catalysts: Enantioselective Propargylic Alkylation of Propargylic Esters with Aldehydes

scientific article published on 11 January 2011

Cooperative catalytic reactions using organocatalysts and transition-metal catalysts: enantioselective propargylic alkylation of propargylic alcohols with aldehydes

scientific article

Copper-Catalyzed Enantioselective Propargylic Amination of Nonaromatic Propargylic Esters with Amines

scientific article published on 07 April 2011

Copper-Catalyzed Enantioselective Propargylic Amination of Propargylic Esters with Amines: Copper−Allenylidene Complexes as Key Intermediates

scientific article published on 01 August 2010

Copper-Catalyzed Nucleophilic Trifluoromethylation of Allylic Halides: A Simple Approach to Allylic Trifluoromethylation

scientific article published on 10 September 2012

Copper-catalyzed asymmetric propargylic substitution reactions of propargylic acetates with amines

scientific article published in January 2008

Copper-catalyzed nucleophilic trifluoromethylation of benzylic chlorides

scientific article published on 26 June 2014

Copper-catalyzed nucleophilic trifluoromethylation of propargylic halides

scientific article published on 01 September 2013

Design and preparation of a chiral ligand based on a pseudorotaxane skeleton: application to rhodium-catalyzed enantioselective hydrogenation of enamides

scientific article published on 10 October 2007

Design and preparation of molybdenum-dinitrogen complexes with ferrocenyldiphosphine and pentamethylcyclopentadienyl moieties as auxiliary ligands

scientific article

Diazachlorin and diazabacteriochlorin for one- and two-photon photodynamic therapy

scientific article published on 01 December 2018

Direct sp3CH Amination of Nitrogen-Containing Benzoheterocycles Mediated by Visible-Light-Photoredox Catalysts

scientific article published on 13 November 2012

Diversity-oriented synthesis of tetrathia[8]circulenes by sequential C-H borylation and annulation

scientific article published on 7 October 2015

Efficient construction of biaryls and macrocyclic cyclophanes via electron-transfer oxidation of Lipshutz cuprates

scientific article published on 01 August 2006

Enantioface-selective palladium-catalyzed silaboration of allenes via double asymmetric induction.

scientific article published in September 2003

Enantioselective Ring-Opening Reactions of Racemic Ethynyl Epoxides via Copper−Allenylidene Intermediates: Efficient Approach to Chiral β-Amino Alcohols

scientific article published on 01 October 2009

Enantioselective alkylation of β-keto phosphonates by direct use of diaryl methanols as electrophiles

scientific article published on 01 October 2012

Hetero[8]circulenes: synthetic progress and intrinsic properties

scientific article published on 10 December 2020

Iron(III) 5,15-Diazaporphyrin Catalysts for the Direct Oxidation of C(sp3)-H Bonds

scientific article published on 14 October 2020

Iron-catalysed transformation of molecular dinitrogen into silylamine under ambient conditions

scientific article published in Nature Communications

Long-distance ferromagnetic coupling through spin polarization in a linear heterotrinuclear iron(III)-copper(II)-iron(III) complex derived from 5-ferrocenyl-2-aminotropone

scientific article published on 16 October 2008

Molybdenum-Catalyzed Transformation of Molecular Dinitrogen into Silylamine: Experimental and DFT Study on the Remarkable Role of Ferrocenyldiphosphine Ligands

scholarly article by Hiromasa Tanaka et al published 16 March 2011 in Journal of the American Chemical Society

Novel electron-transfer oxidation of Lipshutz cuprates with 1,4-benzoquinones: an efficient homo-coupling reaction of aryl halides and its application to the construction of macrocyclic systems

scientific article published on 01 December 2004

Preparation and reactivity of molybdenum–dinitrogen complexes bearing an arsenic-containing ANA-type pincer ligand

scientific article published on 01 October 2013

Regioselective Oxidative Ring Cleavage of Antiaromatic Nickel(II) Norcorrole to Dialkoxybis(dipyrrin)s

scientific article published on 04 April 2019

Regioselective Oxidative Ring Cleavage of Antiaromatic Nickel(II) Norcorrole to Dialkoxybis(dipyrrin)s

scientific article published on 15 May 2019

Remarkable effect of N-substituent on enantioselective ruthenium-catalyzed propargylation of indoles with propargylic alcohols

scientific article published on 29 November 2007

Ruthenium-catalyzed enantioselective carbon-carbon bond forming reaction via allenylidene-ene process: synthetic approach to chiral heterocycles such as chromane, thiochromane, and 1,2,3,4-tetrahydroquinoline derivatives

scientific article published on 22 July 2008

Ruthenium-catalyzed enantioselective propargylation of aromatic compounds with propargylic alcohols via allenylidene intermediates

scientific article published in January 2007

Ruthenium-catalyzed propargylic reduction of propargylic alcohols with silanes

scientific article published in July 2006

Ruthenium-catalyzed reactions of 1-cyclopropyl-2-propyn-1-ols with anilines and water via allenylidene intermediates: selective preparation of tri- and tetrasubstituted conjugated enynes.

scientific article published on 29 March 2007

Ruthenium-catalyzed sequential reactions: deracemization of secondary benzylic alcohols

scientific article published in March 2007

Ruthenium-catalyzed vinylic substitution reactions with nucleophiles via butatrienylidene intermediates

scientific article

Ruthenium-triggered ring opening of ethynylcyclopropanes: [3+2] cycloaddition with aldehydes and aldimines involving metal allenylidene intermediates.

scientific article

Selective α-arylation of α,β-unsaturated imides mediated by a visible light photoredox catalyst.

scientific article published in August 2017

Site-Selective N-Methylation of 5,15-Diazaporphyrins: Reactive Cationic Porphyrinoids that Provide Isoporphyrin Analogues

scientific article published on 06 February 2020

Soluble and Planar 2,9-Diazaperopyrenes through Reductive Aromatization of Perylene Diimides: Tunable Emission and Aggregation Behaviors

scientific article published on 17 July 2019

Structural, electronic and magnetic properties of Cu(II) complexes of 2-substituted tropones bearing a ferrocenyl group at 5-position

scientific article published on 11 January 2010

Structures of the Heme Acquisition Protein HasA with Iron(III)-5,15-Diphenylporphyrin and Derivatives Thereof as an Artificial Prosthetic Group.

scientific article

Synthesis and Functionalization of Porphyrins through Organometallic Methodologies

scientific article

Synthesis and Photodynamics of Tetragermatetrathia[8]circulene

scientific article published on 27 December 2017

Synthesis of Tetraaza[8]circulenes from Tetrathia[8]circulenes through an SNAr-Based Process

scientific article published on 10 May 2017

Synthesis of Tetrasilatetrathia[8]circulenes by a Fourfold Intramolecular Dehydrogenative Silylation of C-H Bonds

scientific article published on 28 March 2017

Synthesis of nitrogen heterocycles via α-aminoalkyl radicals generated from α-silyl secondary amines under visible light irradiation

scientific article published in August 2014

Synthetic Utilization of α-Aminoalkyl Radicals and Related Species in Visible Light Photoredox Catalysis

scientific article published on 9 August 2016

Systematic Synthesis of Tetrathia[8]circulenes: The Influence of Peripheral Substituents on the Structures and Properties in Solution and Solid States

scientific article published on 26 August 2019

The reductive aromatization of naphthalene diimide: a versatile platform for 2,7-diazapyrenes

scientific article published on 01 May 2018

Visible light-mediated oxidative decarboxylation of arylacetic acids into benzyl radicals: addition to electron-deficient alkenes by using photoredox catalysts ⬇️

scientific article published on September 14, 2013

Visible-Light-Mediated Utilization of α-Aminoalkyl Radicals: Addition to Electron-Deficient Alkenes Using Photoredox Catalysts

article

Visible-light-mediated addition of α-aminoalkyl radicals generated from α-silylamines to α,β-unsaturated carbonyl compounds

article

Visible-light-mediated addition of α-aminoalkyl radicals to [60]fullerene by using photoredox catalysts

scientific article published on 2 April 2014

List of works by Yoshihiro Miyake

A 3-pyridyl-5,15-diazaporphyrin nickel(II) complex as a bidentate metalloligand for transition metals

A DFT study on the reaction pathways for carbon-carbon bond-forming reactions between propargylic alcohols and alkenes or ketones catalyzed by thiolate-bridged diruthenium complexes.

A molybdenum complex bearing PNP-type pincer ligands leads to the catalytic reduction of dinitrogen into ammonia

Asymmetric synthesis of epoxides from aromatic aldehydes and benzyl halides catalyzed by C2 symmetric optically active sulfides having a binaphthyl skeleton

Bi-TTF, bis-TTF, and related TTF oligomers

Catalytic Cycloisomerization of 1,5-Enynes to 1,3-Cyclohexadienes via Ruthenium Vinylidene Intermediates

Complexation of 2,7-diazapyrene with boron for structural and electronic tuning

Cooperative Catalytic Reactions Using Distinct Transition-Metal Catalysts: Ruthenium- and Copper-Catalyzed Enantioselective Propargylic Alkylation

Cooperative Catalytic Reactions Using Organocatalysts and Transition Metal Catalysts: Enantioselective Propargylic Alkylation of Propargylic Esters with Aldehydes

Cooperative catalytic reactions using organocatalysts and transition-metal catalysts: enantioselective propargylic alkylation of propargylic alcohols with aldehydes

Copper-Catalyzed Enantioselective Propargylic Amination of Nonaromatic Propargylic Esters with Amines

Copper-Catalyzed Enantioselective Propargylic Amination of Propargylic Esters with Amines: Copper−Allenylidene Complexes as Key Intermediates

Copper-Catalyzed Nucleophilic Trifluoromethylation of Allylic Halides: A Simple Approach to Allylic Trifluoromethylation

Copper-catalyzed asymmetric propargylic substitution reactions of propargylic acetates with amines

Copper-catalyzed nucleophilic trifluoromethylation of benzylic chlorides

Copper-catalyzed nucleophilic trifluoromethylation of propargylic halides

Design and preparation of a chiral ligand based on a pseudorotaxane skeleton: application to rhodium-catalyzed enantioselective hydrogenation of enamides

Design and preparation of molybdenum-dinitrogen complexes with ferrocenyldiphosphine and pentamethylcyclopentadienyl moieties as auxiliary ligands

Diazachlorin and diazabacteriochlorin for one- and two-photon photodynamic therapy

Direct sp3CH Amination of Nitrogen-Containing Benzoheterocycles Mediated by Visible-Light-Photoredox Catalysts

Diversity-oriented synthesis of tetrathia[8]circulenes by sequential C-H borylation and annulation

Efficient construction of biaryls and macrocyclic cyclophanes via electron-transfer oxidation of Lipshutz cuprates

Enantioface-selective palladium-catalyzed silaboration of allenes via double asymmetric induction.

Enantioselective Ring-Opening Reactions of Racemic Ethynyl Epoxides via Copper−Allenylidene Intermediates: Efficient Approach to Chiral β-Amino Alcohols

Enantioselective alkylation of β-keto phosphonates by direct use of diaryl methanols as electrophiles

Hetero[8]circulenes: synthetic progress and intrinsic properties

Iron(III) 5,15-Diazaporphyrin Catalysts for the Direct Oxidation of C(sp3)-H Bonds

Iron-catalysed transformation of molecular dinitrogen into silylamine under ambient conditions

Long-distance ferromagnetic coupling through spin polarization in a linear heterotrinuclear iron(III)-copper(II)-iron(III) complex derived from 5-ferrocenyl-2-aminotropone

Molybdenum-Catalyzed Transformation of Molecular Dinitrogen into Silylamine: Experimental and DFT Study on the Remarkable Role of Ferrocenyldiphosphine Ligands

Novel electron-transfer oxidation of Lipshutz cuprates with 1,4-benzoquinones: an efficient homo-coupling reaction of aryl halides and its application to the construction of macrocyclic systems

Preparation and reactivity of molybdenum–dinitrogen complexes bearing an arsenic-containing ANA-type pincer ligand

Regioselective Oxidative Ring Cleavage of Antiaromatic Nickel(II) Norcorrole to Dialkoxybis(dipyrrin)s

Regioselective Oxidative Ring Cleavage of Antiaromatic Nickel(II) Norcorrole to Dialkoxybis(dipyrrin)s

Remarkable effect of N-substituent on enantioselective ruthenium-catalyzed propargylation of indoles with propargylic alcohols

Ruthenium-catalyzed enantioselective carbon-carbon bond forming reaction via allenylidene-ene process: synthetic approach to chiral heterocycles such as chromane, thiochromane, and 1,2,3,4-tetrahydroquinoline derivatives

Ruthenium-catalyzed enantioselective propargylation of aromatic compounds with propargylic alcohols via allenylidene intermediates

Ruthenium-catalyzed propargylic reduction of propargylic alcohols with silanes

Ruthenium-catalyzed reactions of 1-cyclopropyl-2-propyn-1-ols with anilines and water via allenylidene intermediates: selective preparation of tri- and tetrasubstituted conjugated enynes.

Ruthenium-catalyzed sequential reactions: deracemization of secondary benzylic alcohols

Ruthenium-catalyzed vinylic substitution reactions with nucleophiles via butatrienylidene intermediates

Ruthenium-triggered ring opening of ethynylcyclopropanes: [3+2] cycloaddition with aldehydes and aldimines involving metal allenylidene intermediates.

Selective α-arylation of α,β-unsaturated imides mediated by a visible light photoredox catalyst.

Site-Selective N-Methylation of 5,15-Diazaporphyrins: Reactive Cationic Porphyrinoids that Provide Isoporphyrin Analogues

Soluble and Planar 2,9-Diazaperopyrenes through Reductive Aromatization of Perylene Diimides: Tunable Emission and Aggregation Behaviors

Structural, electronic and magnetic properties of Cu(II) complexes of 2-substituted tropones bearing a ferrocenyl group at 5-position

Structures of the Heme Acquisition Protein HasA with Iron(III)-5,15-Diphenylporphyrin and Derivatives Thereof as an Artificial Prosthetic Group.

Synthesis and Functionalization of Porphyrins through Organometallic Methodologies

Synthesis and Photodynamics of Tetragermatetrathia[8]circulene

Synthesis of Tetraaza[8]circulenes from Tetrathia[8]circulenes through an SNAr-Based Process

Synthesis of Tetrasilatetrathia[8]circulenes by a Fourfold Intramolecular Dehydrogenative Silylation of C-H Bonds

Synthesis of nitrogen heterocycles via α-aminoalkyl radicals generated from α-silyl secondary amines under visible light irradiation

Synthetic Utilization of α-Aminoalkyl Radicals and Related Species in Visible Light Photoredox Catalysis

Systematic Synthesis of Tetrathia[8]circulenes: The Influence of Peripheral Substituents on the Structures and Properties in Solution and Solid States

The reductive aromatization of naphthalene diimide: a versatile platform for 2,7-diazapyrenes

Visible light-mediated oxidative decarboxylation of arylacetic acids into benzyl radicals: addition to electron-deficient alkenes by using photoredox catalysts ⬇️

Visible-Light-Mediated Utilization of α-Aminoalkyl Radicals: Addition to Electron-Deficient Alkenes Using Photoredox Catalysts

Visible-light-mediated addition of α-aminoalkyl radicals generated from α-silylamines to α,β-unsaturated carbonyl compounds

Visible-light-mediated addition of α-aminoalkyl radicals to [60]fullerene by using photoredox catalysts