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List of works by Hiroaki Kotani

A Ruthenium(III)-Oxyl Complex Bearing Strong Radical Character.

scientific article

An efficient fluorescence sensor for superoxide with an acridinium ion-linked porphyrin triad.

scientific article

Binding of scandium ions to metalloporphyrin-flavin complexes for long-lived charge separation

scientific article

Contrasting effects of axial ligands on electron-transfer versus proton-coupled electron-transfer reactions of nonheme oxoiron(IV) complexes

scientific article published in January 2010

Cooperative Effects of Heterodinuclear IrIII-MII Complexes on Catalytic H2 Evolution from Formic Acid Dehydrogenation in Water

scientific article published on 10 July 2020

Correction to "Efficient Photocatalytic CO2 Reduction by a Ni(II) Complex Having Pyridine Pendants through Capturing a Mg2+ Ion as a Lewis-Acid Cocatalyst"

scientific article published on 19 May 2020

Crystal structure of a metal ion-bound oxoiron(IV) complex and implications for biological electron transfer.

scientific article published on 11 July 2010

Cupric superoxo-mediated intermolecular C-H activation chemistry

scientific article

Determination of the structural features of a long-lived electron-transfer state of 9-mesityl-10-methylacridinium ion.

scientific article

Dioxygen/Hydrogen Peroxide Interconversion Using Redox Couples of Saddle-Distorted Porphyrins and Isophlorins

scientific article published on 27 March 2019

Efficient Photocatalytic CO2 Reduction by a Ni(II) Complex Having Pyridine Pendants through Capturing a Mg2+ Ion as a Lewis-Acid Cocatalyst

scientific article published on 02 December 2019

Efficient photocatalytic proton-coupled electron-transfer reduction of O2 using a saddle-distorted porphyrin as a photocatalyst

scientific article published on 01 April 2019

Electron- and hydride-transfer reactivity of an isolable manganese(V)-oxo complex

scientific article published on 10 January 2011

Electron-transfer properties of an efficient nonheme iron oxidation catalyst with a tetradentate bispidine ligand

scientific article published on 01 March 2010

Electron-transfer reduction of dinuclear copper peroxo and bis-μ-oxo complexes leading to the catalytic four-electron reduction of dioxygen to water

scientific article published on 3 January 2012

Electron-transfer state of 9-mesityl-10-methylacridinium ion with a much longer lifetime and higher energy than that of the natural photosynthetic reaction center

scientific article published in February 2004

Enhancement of 4-electron O2 reduction by a Cu(ii)-pyridylamine complex via protonation of a pendant pyridine in the second coordination sphere in water

scientific article published on 01 September 2015

Formation and characterization of a reactive chromium(v)-oxo complex: mechanistic insight into hydrogen-atom transfer reactions.

scientific article

Formation of a Ruthenium(V)-Imido Complex and the Reactivity in Substrate Oxidation in Water through the Nitrogen Non-Rebound Mechanism

scientific article published on 25 September 2019

Formation of a long-lived electron-transfer state of a naphthalene–quinolinium ion dyad and the π-dimer radical cation

scientific article published on January 1, 2012

Fundamental electron-transfer and proton-coupled electron-transfer properties of Ru(iv)-oxo complexes

scientific article published on 22 July 2019

Fundamental electron-transfer properties of non-heme oxoiron(IV) complexes

scientific article published on 18 December 2007

High-valent manganese(v)-oxo porphyrin complexes in hydride transfer reactions

scientific article published on 19 December 2008

Highly efficient photocatalytic oxygenation reactions using water as an oxygen source

scientific article published on 28 November 2010

Homogeneous Photocatalytic Water Oxidation with a Dinuclear Co(III)-Pyridylmethylamine Complex.

scientific article published on 21 January 2016

Homogeneous catalytic O2 reduction to water by a cytochrome c oxidase model with trapping of intermediates and mechanistic insights

scientific article

Importance of the Reactant-State Potentials of Chromium(V)-Oxo Complexes to Determine the Reactivity in Hydrogen-Atom Transfer Reactions

article

Intermediate-Spin Iron(III) Complexes Having a Redox-Noninnocent Macrocyclic Tetraamido Ligand.

scientific article published on 16 March 2018

Mechanistic Insight into Dioxygen Evolution from Diastereomeric μ-Peroxo Dinuclear Co(III) Complexes Based on Stoichiometric Electron-Transfer Oxidation

scientific article published on 27 February 2019

Mechanistic Insight into Synergistic Catalysis of Olefin Hydrogenation by a Hetero-Dinuclear RuII-CoII Complex with Adjacent Reaction Sites

scientific article published on 09 August 2019

Mechanistic Insights into C-H Oxidations by Ruthenium(III)-Pterin Complexes: Impact of Basicity of the Pterin Ligand and Electron Acceptability of the Metal Center on the Transition States

scientific article published on 12 July 2016

Mechanistic Insights into Homogeneous Electrocatalytic and Photocatalytic Hydrogen Evolution Catalyzed by High-Spin Ni(II) Complexes with S2N2-Type Tetradentate Ligands

scientific article published on 30 May 2018

Mechanistic insights into hydride-transfer and electron-transfer reactions by a manganese(IV)-oxo porphyrin complex

scientific article published in December 2009

Metal ion-coupled electron transfer of a nonheme oxoiron(IV) complex: remarkable enhancement of electron-transfer rates by Sc3+

scientific article published on 15 December 2010

Misleading effects of impurities derived from the extremely long-lived electron-transfer state of 9-mesityl-10-methylacridinium ion.

scientific article

Photocatalytic generation of a non-heme oxoiron(IV) complex with water as an oxygen source

scientific article published on 18 February 2011

Photocatalytic hydrogen evolution under highly basic conditions by using Ru nanoparticles and 2-phenyl-4-(1-naphthyl)quinolinium ion.

scientific article

Photocatalytic hydrogen evolution using a Ru(II)-bound heteroaromatic ligand as a reactive site

scientific article published on 19 November 2020

Photocatalytic oxygenation of anthracenes and olefins with dioxygen via selective radical coupling using 9-mesityl-10-methylacridinium ion as an effective electron-transfer photocatalyst

scientific article published in December 2004

Photoelectrochemical properties of supramolecular composite of fullerene nanoclusters and 9-mesityl-10-carboxymethylacridinium ion on SnO2.

scientific article published in September 2004

Photoinduced Electron Transfer in 9-Substituted 10-Methylacridinium Ions

scientific article published on 4 November 2016

Production of an ultra-long-lived charge-separated state in a zinc chlorin-C60 dyad by one-step photoinduced electron transfer

scientific article published in February 2004

Reactivity of a Ru(III)-hydroxo complex in substrate oxidation in water

scientific article published on 01 December 2014

Redox-Noninnocent Behavior of Tris(2-pyridylmethyl)amine Bound to a Lewis Acidic Rh(III) Ion Induced by C-H Deprotonation

scientific article published on 24 August 2015

Response: Why had long-lived electron-transfer states of donor-substituted 10-methylacridinium ions been overlooked? Formation of the dimer radical cations detected in the near-IR region

scientific article published on 8 July 2008

Selective catalytic 2e--oxidation of organic substrates by an FeII complex having an N-heterocyclic carbene ligand in water

scientific article published on 27 July 2020

Sequential electron-transfer and proton-transfer pathways in hydride-transfer reactions from dihydronicotinamide adenine dinucleotide analogues to non-heme oxoiron(IV) complexes and p-chloranil. Detection of radical cations of NADH analogues in acid

scientific article

Size- and shape-dependent activity of metal nanoparticles as hydrogen-evolution catalysts: mechanistic insights into photocatalytic hydrogen evolution

scientific article published on 30 January 2011

Synthesis and photodynamics of 9-mesitylacridinium ion-modified gold nanoclusters

scientific article published on August 2010

Tetranuclear Ruthenium(II) Complex with a Dinucleating Ligand Forming Multi-Mixed-Valence States

scientific article published on 20 November 2014

Viologen-modified platinum clusters acting as an efficient catalyst in photocatalytic hydrogen evolution

scientific article

Visible-Light-Driven Photocatalytic CO2 Reduction by a Ni(II) Complex Bearing a Bioinspired Tetradentate Ligand for Selective CO Production.

scientific article published on 28 April 2017