List of works - Miguel Maestro

1β,25-Dihydroxyvitamin D3: A new vitamin D metabolite in human serum

scientific article published on 10 February 2017

25 S-Adamantyl-23-yne-26,27-dinor-1α,25-dihydroxyvitamin D3: Synthesis, Tissue Selective Biological Activities, and X-ray Crystal Structural Analysis of Its Vitamin D Receptor Complex

scientific article published on 23 July 2018

26,26,26,27,27,27-Hexadeuterated-1,25-Dihydroxyvitamin D3 (1,25D-d6) As Adjuvant of Chemotherapy in Breast Cancer Cell Lines.

scientific article published on 27 December 2013

A 4-hydroxypyrrolidine-catalyzed mannich reaction of aldehydes: control of anti-selectivity by hydrogen bonding assisted by Brønsted acids.

scientific article published in May 2010

A new approach to 19-nor-A-ring phosphine oxide for the convergent synthesis of 19-nor-calcitriol

scientific article published on 31 August 2016

A novel V(IV)O-pyrimidinone complex: synthesis, solution speciation and human serum protein binding

scientific article published in September 2013

A short practical approach to 24R,25-dihydroxyvitamin D3.

scientific article published on 10 April 2010

Alkynoates as a source of reactive alkylinides for aldehyde addition reactions

scientific article published on 01 June 2001

An efficient convergent synthesis of 1α,25-dihydroxy-3-epi-vitamin D2.

scientific article published on 16 October 2014

An efficient synthesis of 1α,25-dihydroxy-20-epi-vitamin D3.

scientific article published on 06 February 2013

An unprecedented hybrid scorpionate/cyclopentadienyl ligand

scientific article published on 01 February 2004

Aromatic-Based Design of Highly Active and Noncalcemic Vitamin D Receptor Agonists

scientific article published on 22 May 2018

Base-dependent stereodivergent intramolecular aza-Michael reaction: asymmetric synthesis of 1,3-disubstituted isoindolines.

scientific article published on 12 July 2013

Boron trifluoride-induced, new stereospecific rearrangements of chiral epoxy ethers. Ready access to enantiopure 4-(diarylmethyl)-1,3-dioxolanes and 4,5-disubstituted tetrahydrobenzo[c]oxepin-4-ols

scientific article published in February 2006

Carborane-based design of a potent vitamin D receptor agonist.

scientific article published on 27 October 2015

Clinical utility of simultaneous quantitation of 25-hydroxyvitamin D and 24,25-dihydroxyvitamin D by LC-MS/MS involving derivatization with DMEQ-TAD

scientific article

Combined effects of diamines and carboxylate bridges on structural and magnetic properties of a series of polynuclear copper(II) complexes with 1,1-cyclobutanedicarboxylic acid

scientific article published on 01 October 2006

Conjugate addition of nitroalkanes to an acrylate equivalent. Stereocontrol at C-alpha of the nitro group through double catalytic activation

scientific article published on 01 September 2009

Design, synthesis, evaluation, and structure of vitamin D analogues with furan side chains

scientific article

Enantio- and diastereoselective organocatalytic α-alkylation of aldehydes with 3-substituted 2-(bromomethyl)acrylates

scientific article published on 14 December 2011

Equilibria between metallosupramolecular squares and triangles with the new rigid linker 1,4-bis(4-pyridyl)tetrafluorobenzene. Experimental and theoretical study of the structural dependence of NMR data

scientific article

Evidence of desulfurization in the oxidative cyclization of thiosemicarbazones. Conversion to 1,3,4-oxadiazole derivatives.

scientific article published in March 2002

Gold catalyzed stereoselective tandem hydroamination-formal aza-Diels-Alder reaction of propargylic amino esters

scientific article published on 10 January 2013

Gold-catalyzed intramolecular hydroamination of o-alkynylbenzyl carbamates: a route to chiral fluorinated isoindoline and isoquinoline derivatives

scientific article published on 29 January 2013

Highly enantioselective conjugate additions of aldehydes to vinyl sulfones

scientific article published on 01 January 2009

Innovative Three-Step Microwave-Promoted Synthesis of N-Propargyltetrahydroquinoline and 1,2,3-Triazole Derivatives as a Potential Factor Xa (FXa) Inhibitors: Drug Design, Synthesis, and Biological Evaluation

scientific article published on 23 January 2020

Intramolecular Michael reaction of tert-butylsulfinyl ketimines: asymmetric synthesis of 3-substituted indanones

scientific article published on 23 November 2011

Magnetic properties of cyano-bridged Ln3+-M3+ complexes. Part I: trinuclear complexes (Ln3+ = La, Ce, Pr, Nd, Sm; M3+ = FeLS, Co) with bpy as blocking ligand

scientific article published in October 2005

Magnetism of cyano-bridged Ln3+-M3+ complexes. Part II: one-dimensional complexes (Ln3+ = Eu, Tb, Dy, Ho, Er, Tm; M3+ = Fe or Co) with bpy as blocking ligand

scientific article published in October 2005

Magnetism of cyano-bridged hetero-one-dimensional Ln3+-M3+ complexes (Ln3+ = Sm, Gd, Yb; M3+ = FeLS, Co).

scientific article published in August 2003

N-(Diazoacetyl)oxazolidin-2-thiones as sulfur-donor reagents: asymmetric synthesis of thiiranes from aldehydes

scientific article published on 26 September 2012

New oxamato-bridged trinuclear Cu(II)-Cu(II)-Cu(II) complexes with hydrogen-bond supramolecular structures: synthesis and magneto-structural studies

scientific article published in October 2002

New oxamidato-bridged Cu(II)-Ni(II) complexes: supramolecular structures with thiocyanate ligands and hydrogen bonds. Magnetostructural studies: DFT calculations

scientific article published in December 2002

Novel synthetic approach to 1alpha,25-dihydroxyvitamin D3 and analogues.

scientific article

Oxamato-bridged trinuclear NiIICuIINiII complexes: a new (NiIICuIINiII)2 hexanuclear complex and supramolecular structures. Characterization and magnetic properties

scientific article published in May 2003

Oxazoline-mediated interannular cyclopalladation of ferrocene: chiral palladium(II) catalysts for the enantioselective Aza-Claisen rearrangement

scientific article published on 01 March 2005

Pd-catalyzed carbocyclization-Negishi cross-coupling cascade: a novel approach to 1alpha,25-dihydroxyvitamin D3 and analogues

scientific article published on 01 December 2005

Phosphine-substrate recognition through the C-H...O hydrogen bond: application to the asymmetric Pauson-Khand reaction

scientific article published in October 2005

Pit-1 inhibits BRCA1 and sensitizes human breast tumors to cisplatin and vitamin D treatment

scientific article

PuPHOS: a synthetically useful chiral bidentate ligand for the intermolecular Pauson-Khand reaction.

scientific article published in November 2004

Quantitative analytical method to evaluate the metabolism of vitamin D.

scientific article published on 7 January 2015

Reversing the stereoselectivity of the intermolecular Pauson-Khand reaction: formation of endo-fused norbornadiene adducts

scientific article published on 01 April 2002

Self-assembly of ligands designed for the building of a new type of [2 x 2] metallic grid. anion encapsulation and diffusion NMR spectroscopy

scientific article published on 2 October 2007

Stereoselective Palladium-Catalyzed Approach to Vitamin D3 Derivatives in Protic Medium.

scientific article published on 14 December 2017

Stereoselective synthesis of 1β,25-Dihydroxyvitamin D3 and its 26,27-hexadeuterated derivative

scientific article published on 09 September 2015

Structure, magnetic properties and nuclease activity of pyridine-2-carbaldehyde thiosemicarbazonecopper(II) complexes

scientific article published in July 2008

Synthesis and biological activity of the dihydrotachysterol2 metabolite 25-hydroxydihydrotachysterol2.

scientific article

Synthesis and biological evaluation of 1α,25-dihydroxyvitamin D₃ analogues with a long side chain at C12 and short C17 side chains.

scientific article

Synthesis and characterization of heterodinuclear Ln(3+)-Fe3+ and Ln(3+)-Co3+ complexes, bridged by cyanide ligand (Ln3+ = lanthanide ions). Nature of the magnetic interaction in the Ln(3+)-Fe3+ complexes

scientific article published on 01 January 2003

Synthesis and characterization of metallodendritic palladium-biscarbene complexes derived from 1,1'-methylenebis(1,2,4-triazole)

scientific article published on 07 March 2011

Synthesis of 28,28,28-trideutero-25-hydroxydihydrotachysterol2

scientific article published on 19 September 2018

Synthesis of Side-Chain Locked Analogs of 1α,25-Dihydroxyvitamin D3 Bearing a C17 Methyl Group

scientific article published on 13 April 2018

Synthesis of highly condensed polycyclic carbohydrates by reaction of a spirocyclic enamino sulfonate derived from d-xylofuranose with bifunctional reagents.

scientific article published on 14 November 2007

Synthesis of nonadeuterated 1α,25-dihydroxyvitamin D2.

scientific article

Synthesis of two carboxylic haptens for raising antibodies to 25-hydroxyvitamin D3 and 1alpha,25-dihydroxyvitamin D3

scientific article published on 18 January 2007

Synthesis, Crystal Structure, and Magnetic Studies of One-Dimensional Cyano-Bridged Ln3+−Cr3+Complexes with bpy as a Blocking Ligand

scientific article published on 01 October 2006

Synthesis, characterization, and magnetic properties of self-assembled compounds based on discrete homotrinuclear complexes of Cu(II).

scientific article published in June 2001

Synthesis, crystal structure, and magnetic studies of oxo-centered trinuclear chromium(III) complexes: [Cr(3)(mu(3)-O)(mu(2)-PhCOO)(6)(H(2)O)(3)]NO(3). 4H(2)O.2CH(3)OH, a case of spin-frustrated system, and [Cr(3)(mu(3)-O)- (mu(2)-PhCOO)(2)(mu(2)-OC

scientific article published on 16 November 2007

Synthesis, structure, and biological activity of des-side chain analogues of 1α,25-dihydroxyvitamin D3 with substituents at C18

scientific article

THE MAIN NONPOLAR CHLOROPHYLL c FROM EMILIANIA HUXLEYI (PRYMNESIOPHYCEAE) IS A CHLOROPHYLL c 2 -MONOGALACTOSYLDIACYLGLYCERIDE ESTER: A MASS SPECTROMETRY STUDY

scientific article published on 01 June 2000

Total synthesis of 1α,25-dihydroxyvitamin D3 (calcitriol) through a Si-assisted allylic substitution

scientific article

Total synthesis of 1α,25-dihydroxyvitamin D3 analogs modified at the side chain and D-ring

scientific article published on 01 June 2018

Vitamin D receptor 2016: novel ligands and structural insights.

scientific article

X-ray diffraction, solution structure, and computational studies on derivatives of (3-sec-butyl-2,3-dihydro-1H-isoquinolin-4-ylidene)acetic acid: compounds with activity as calpain inhibitors.

scientific article published in January 2010

List of works by Miguel Maestro

1β,25-Dihydroxyvitamin D3: A new vitamin D metabolite in human serum

25 S-Adamantyl-23-yne-26,27-dinor-1α,25-dihydroxyvitamin D3: Synthesis, Tissue Selective Biological Activities, and X-ray Crystal Structural Analysis of Its Vitamin D Receptor Complex

26,26,26,27,27,27-Hexadeuterated-1,25-Dihydroxyvitamin D3 (1,25D-d6) As Adjuvant of Chemotherapy in Breast Cancer Cell Lines.

A 4-hydroxypyrrolidine-catalyzed mannich reaction of aldehydes: control of anti-selectivity by hydrogen bonding assisted by Brønsted acids.

A new approach to 19-nor-A-ring phosphine oxide for the convergent synthesis of 19-nor-calcitriol

A novel V(IV)O-pyrimidinone complex: synthesis, solution speciation and human serum protein binding

A short practical approach to 24R,25-dihydroxyvitamin D3.

Alkynoates as a source of reactive alkylinides for aldehyde addition reactions

An efficient convergent synthesis of 1α,25-dihydroxy-3-epi-vitamin D2.

An efficient synthesis of 1α,25-dihydroxy-20-epi-vitamin D3.

An unprecedented hybrid scorpionate/cyclopentadienyl ligand

Aromatic-Based Design of Highly Active and Noncalcemic Vitamin D Receptor Agonists

Base-dependent stereodivergent intramolecular aza-Michael reaction: asymmetric synthesis of 1,3-disubstituted isoindolines.

Boron trifluoride-induced, new stereospecific rearrangements of chiral epoxy ethers. Ready access to enantiopure 4-(diarylmethyl)-1,3-dioxolanes and 4,5-disubstituted tetrahydrobenzo[c]oxepin-4-ols

Carborane-based design of a potent vitamin D receptor agonist.

Clinical utility of simultaneous quantitation of 25-hydroxyvitamin D and 24,25-dihydroxyvitamin D by LC-MS/MS involving derivatization with DMEQ-TAD

Combined effects of diamines and carboxylate bridges on structural and magnetic properties of a series of polynuclear copper(II) complexes with 1,1-cyclobutanedicarboxylic acid

Conjugate addition of nitroalkanes to an acrylate equivalent. Stereocontrol at C-alpha of the nitro group through double catalytic activation

Design, synthesis, evaluation, and structure of vitamin D analogues with furan side chains

Enantio- and diastereoselective organocatalytic α-alkylation of aldehydes with 3-substituted 2-(bromomethyl)acrylates

Equilibria between metallosupramolecular squares and triangles with the new rigid linker 1,4-bis(4-pyridyl)tetrafluorobenzene. Experimental and theoretical study of the structural dependence of NMR data

Evidence of desulfurization in the oxidative cyclization of thiosemicarbazones. Conversion to 1,3,4-oxadiazole derivatives.

Gold catalyzed stereoselective tandem hydroamination-formal aza-Diels-Alder reaction of propargylic amino esters

Gold-catalyzed intramolecular hydroamination of o-alkynylbenzyl carbamates: a route to chiral fluorinated isoindoline and isoquinoline derivatives

Highly enantioselective conjugate additions of aldehydes to vinyl sulfones

Innovative Three-Step Microwave-Promoted Synthesis of N-Propargyltetrahydroquinoline and 1,2,3-Triazole Derivatives as a Potential Factor Xa (FXa) Inhibitors: Drug Design, Synthesis, and Biological Evaluation

Intramolecular Michael reaction of tert-butylsulfinyl ketimines: asymmetric synthesis of 3-substituted indanones

Magnetic properties of cyano-bridged Ln3+-M3+ complexes. Part I: trinuclear complexes (Ln3+ = La, Ce, Pr, Nd, Sm; M3+ = FeLS, Co) with bpy as blocking ligand

Magnetism of cyano-bridged Ln3+-M3+ complexes. Part II: one-dimensional complexes (Ln3+ = Eu, Tb, Dy, Ho, Er, Tm; M3+ = Fe or Co) with bpy as blocking ligand

Magnetism of cyano-bridged hetero-one-dimensional Ln3+-M3+ complexes (Ln3+ = Sm, Gd, Yb; M3+ = FeLS, Co).

N-(Diazoacetyl)oxazolidin-2-thiones as sulfur-donor reagents: asymmetric synthesis of thiiranes from aldehydes

New oxamato-bridged trinuclear Cu(II)-Cu(II)-Cu(II) complexes with hydrogen-bond supramolecular structures: synthesis and magneto-structural studies

New oxamidato-bridged Cu(II)-Ni(II) complexes: supramolecular structures with thiocyanate ligands and hydrogen bonds. Magnetostructural studies: DFT calculations

Novel synthetic approach to 1alpha,25-dihydroxyvitamin D3 and analogues.

Oxamato-bridged trinuclear NiIICuIINiII complexes: a new (NiIICuIINiII)2 hexanuclear complex and supramolecular structures. Characterization and magnetic properties

Oxazoline-mediated interannular cyclopalladation of ferrocene: chiral palladium(II) catalysts for the enantioselective Aza-Claisen rearrangement

Pd-catalyzed carbocyclization-Negishi cross-coupling cascade: a novel approach to 1alpha,25-dihydroxyvitamin D3 and analogues

Phosphine-substrate recognition through the C-H...O hydrogen bond: application to the asymmetric Pauson-Khand reaction

Pit-1 inhibits BRCA1 and sensitizes human breast tumors to cisplatin and vitamin D treatment

PuPHOS: a synthetically useful chiral bidentate ligand for the intermolecular Pauson-Khand reaction.

Quantitative analytical method to evaluate the metabolism of vitamin D.

Reversing the stereoselectivity of the intermolecular Pauson-Khand reaction: formation of endo-fused norbornadiene adducts

Self-assembly of ligands designed for the building of a new type of [2 x 2] metallic grid. anion encapsulation and diffusion NMR spectroscopy

Stereoselective Palladium-Catalyzed Approach to Vitamin D3 Derivatives in Protic Medium.

Stereoselective synthesis of 1β,25-Dihydroxyvitamin D3 and its 26,27-hexadeuterated derivative

Structure, magnetic properties and nuclease activity of pyridine-2-carbaldehyde thiosemicarbazonecopper(II) complexes

Synthesis and biological activity of the dihydrotachysterol2 metabolite 25-hydroxydihydrotachysterol2.

Synthesis and biological evaluation of 1α,25-dihydroxyvitamin D₃ analogues with a long side chain at C12 and short C17 side chains.

Synthesis and characterization of heterodinuclear Ln(3+)-Fe3+ and Ln(3+)-Co3+ complexes, bridged by cyanide ligand (Ln3+ = lanthanide ions). Nature of the magnetic interaction in the Ln(3+)-Fe3+ complexes

Synthesis and characterization of metallodendritic palladium-biscarbene complexes derived from 1,1'-methylenebis(1,2,4-triazole)

Synthesis of 28,28,28-trideutero-25-hydroxydihydrotachysterol2

Synthesis of Side-Chain Locked Analogs of 1α,25-Dihydroxyvitamin D3 Bearing a C17 Methyl Group

Synthesis of highly condensed polycyclic carbohydrates by reaction of a spirocyclic enamino sulfonate derived from d-xylofuranose with bifunctional reagents.

Synthesis of nonadeuterated 1α,25-dihydroxyvitamin D2.

Synthesis of two carboxylic haptens for raising antibodies to 25-hydroxyvitamin D3 and 1alpha,25-dihydroxyvitamin D3

Synthesis, Crystal Structure, and Magnetic Studies of One-Dimensional Cyano-Bridged Ln3+−Cr3+Complexes with bpy as a Blocking Ligand

Synthesis, characterization, and magnetic properties of self-assembled compounds based on discrete homotrinuclear complexes of Cu(II).

Synthesis, crystal structure, and magnetic studies of oxo-centered trinuclear chromium(III) complexes: [Cr(3)(mu(3)-O)(mu(2)-PhCOO)(6)(H(2)O)(3)]NO(3). 4H(2)O.2CH(3)OH, a case of spin-frustrated system, and [Cr(3)(mu(3)-O)- (mu(2)-PhCOO)(2)(mu(2)-OC

Synthesis, structure, and biological activity of des-side chain analogues of 1α,25-dihydroxyvitamin D3 with substituents at C18

THE MAIN NONPOLAR CHLOROPHYLL c FROM EMILIANIA HUXLEYI (PRYMNESIOPHYCEAE) IS A CHLOROPHYLL c 2 -MONOGALACTOSYLDIACYLGLYCERIDE ESTER: A MASS SPECTROMETRY STUDY

Total synthesis of 1α,25-dihydroxyvitamin D3 (calcitriol) through a Si-assisted allylic substitution

Total synthesis of 1α,25-dihydroxyvitamin D3 analogs modified at the side chain and D-ring

Vitamin D receptor 2016: novel ligands and structural insights.

X-ray diffraction, solution structure, and computational studies on derivatives of (3-sec-butyl-2,3-dihydro-1H-isoquinolin-4-ylidene)acetic acid: compounds with activity as calpain inhibitors.