List of works - Luca Gonsalvi

(Pentamethylcyclopentadienyl)iridium-PTA (PTA = 1,3,5-Triaza-7-phosphaadamantane) Complexes and Their Application in Catalytic Water Phase Carbon Dioxide Hydrogenation

scholarly article by Mikael Erlandsson et al published February 2008 in European Journal of Inorganic Chemistry

A Ligand-Driven Geometry Switch in Octahedral and Trigonal-Bipyramidal Iron Complexes Containing (H)PNO and PNN Ligands

A snapshot of P4 tetrahedron opening: Rh- and Ir-mediated activation of white phosphorus

scientific article published on 01 June 2006

Acid-base interaction between transition-metal hydrides: dihydrogen bonding and dihydrogen evolution

scientific article published on 29 December 2010

Amino-phosphanes in RhI-Catalyzed Hydroformylation: Hemilabile Behavior of P,N Ligands under High CO Pressure and Catalytic Properties

Aqueous phase carbon dioxide and bicarbonate hydrogenation catalyzed by cyclopentadienyl ruthenium complexes

Bifunctional metallodendrimers based on AB5 derivatives of cyclotriphosphazene as core and P,N ligands as terminal functions

Carbon dioxide hydrogenation catalysed by well-defined Mn(i) PNP pincer hydride complexes.

scientific article published on 4 May 2017

Coordination chemistry of 1,3,5-triaza-7-phosphaadamantane (PTA)

article published in 2004

Counterion-dependent deuteration of pentamethylcyclopentadiene in water-soluble cationic Rh(III) complexes assisted by PTA.

scientific article published on 2 March 2010

Cyclopentadienyl ruthenium(II) complexes with bridging alkynylphosphine ligands: synthesis and electrochemical studies.

scientific article published in November 2009

Diastereomerically enriched analogues of the water-soluble phosphine PTA. Synthesis of phenyl(1,3,5-triaza-7-phosphatricyclo[3.3.1.1(3,7)]dec-6-yl)methanol (PZA) and the sulfide PZA(S) and X-ray crystal structures of the oxide PZA(O) and [Cp*IrCl(2)

scientific article published on 11 December 2007

Dynamic behaviour of Ru and Ru–Pt complexes containing tetrahedro-P4 ligand

scientific article published on 24 August 2011

Experimental Evidence of Phosphine Oxide Generation in Solution and Trapping by Ruthenium Complexes ⬇️

scientific article published on April 28, 2011

Formic acid dehydrogenation catalysed by ruthenium complexes bearing the tripodal ligands triphos and NP3.

scientific article published on 4 December 2012

Grafting of water-soluble phosphines to dendrimers and their use in catalysis: positive dendritic effects in aqueous media

scientific article published on 20 April 2009

Heterobimetallic cooperation mediates the transformation of white phosphorus into zwitterionic catena-phosphonium(+)diphosphenide(-) ligands

scientific article published on 01 January 2008

Homogenous catalytic hydrogenation of bicarbonate with water soluble aryl phosphine ligands

In Vitro Evaluation of Rhodium and Osmium RAPTA Analogues: The Case for Organometallic Anticancer Drugs Not Based on Ruthenium

scholarly article by Antoine Dorcier et al published August 2006 in Organometallics

Influence of Structural Variation on the Anticancer Activity of RAPTA-Type Complexes: ptn versus pta

Mechanistic studies on NaHCO3 hydrogenation and HCOOH dehydrogenation reactions catalysed by a Fe(II) linear tetraphosphine complex

scientific article published on 15 December 2017

NMR studies on the novel heterobimetallic complexes [M(dppm)(Ph(2)PCH(2)PPh(2)PPPP) {Pt(PPh3)2}]OTf (M = Rh, Ir) derived from the stepwise activation of white phosphorus.

scientific article

New Class of Half-Sandwich Ruthenium(II) Arene Complexes Bearing the Water-Soluble CAP Ligand as an in Vitro Anticancer Agent

scientific article published on 26 April 2017

New Wind in Old Sails: Novel Applications of Triphos-based Transition Metal Complexes as Homogeneous Catalysts for Small Molecules and Renewables Activation

scientific article published in January 2015

Novel synthetic pathways for bis(acyl)phosphine oxide photoinitiators

scientific article published on 04 July 2012

Number of terminal groups versus generation of the dendrimer, which criteria influence the catalytic properties?

Octahedral RuII Complexes with [PNO] Hydrazonic Ligands: Synthesis, Structure, Reactivity and Catalytic Activity in the Addition of Benzoic Acid to Alkynes

On the protonation of ruthenium-PTA complexes in water. X-ray crystal structure of RuCl4(PTAH)2·4 H2O (PTA=1,3,5-triaza-7-phosphaadamantane)

P4 activation by late-transition metal complexes

scientific article published on 01 July 2010

Rationalization of the inhibition activity of structurally related organometallic compounds against the drug target cathepsin B by DFT.

scientific article published on 14 May 2010

Recent Advances in Metal Catalyst Design for CO2 Hydroboration to C1 Derivatives

scientific article published in 2021

Selective ruthenium-catalyzed oxidation of 1,2:4,5-di-O-isopropylidene- beta-D-fructopyranose and other alcohols with NaOCl

scientific article published on 01 May 2002

Solution and solid-state dynamics of metal-coordinated white phosphorus

scientific article

Stabilization of the triphosphallyl ligand η3-P3{P(O)H} at iridium via alkaline activation of P4.

scientific article

Stable, water-soluble Pta-based Ru-Ag organometallic polymers

scientific article published on 01 April 2005

Steric and electronic effects on the reactivity of rh and ir complexes containing P-S, P-P, and P-O ligands. Implications for the effects of chelate ligands in catalysis.

scientific article published in November 2002

Synthesis and characterization of terminal [Re(XCO)(CO)2(triphos)] (X=N, P): isocyanate versus phosphaethynolate complexes

scientific article published on 28 September 2012

Synthesis of new enantiomerically enriched beta-Hydroxy-gamma-amino phosphines by selective transformation of naturally occurring amino acids

scientific article

Synthesis, catalytic properties and biological activity of new water soluble ruthenium cyclopentadienyl PTA complexes [(C5R5)RuCl(PTA)2] (R = H, Me; PTA = 1,3,5-triaza-7-phosphaadamantane).

scientific article published on January 2003

Transfer hydrogenation of ketones catalyzed by surface-active ruthenium and rhodium complexes in water.

scientific article published on 12 December 2013

Water soluble ruthenium cyclopentadienyl and aminocyclopentadienyl PTA complexes as catalysts for selective hydrogenation of α,β-unsaturated substrates (PTA=1,3,5-triaza-7-phosphaadamantane)

article published in 2004

Water-Soluble Silver(I) Complexes Featuring the Hemilabile 3,7-Dimethyl-1,3,5-triaza-7-phosphabicyclo[3.3.1]nonane Ligand: Synthesis, Characterization, and Antimicrobial Activity.

scientific article

List of works by Luca Gonsalvi

(Pentamethylcyclopentadienyl)iridium-PTA (PTA = 1,3,5-Triaza-7-phosphaadamantane) Complexes and Their Application in Catalytic Water Phase Carbon Dioxide Hydrogenation

A Ligand-Driven Geometry Switch in Octahedral and Trigonal-Bipyramidal Iron Complexes Containing (H)PNO and PNN Ligands

A snapshot of P4 tetrahedron opening: Rh- and Ir-mediated activation of white phosphorus

Acid-base interaction between transition-metal hydrides: dihydrogen bonding and dihydrogen evolution

Amino-phosphanes in RhI-Catalyzed Hydroformylation: Hemilabile Behavior of P,N Ligands under High CO Pressure and Catalytic Properties

Aqueous phase carbon dioxide and bicarbonate hydrogenation catalyzed by cyclopentadienyl ruthenium complexes

Bifunctional metallodendrimers based on AB5 derivatives of cyclotriphosphazene as core and P,N ligands as terminal functions

Carbon dioxide hydrogenation catalysed by well-defined Mn(i) PNP pincer hydride complexes.

Coordination chemistry of 1,3,5-triaza-7-phosphaadamantane (PTA)

Counterion-dependent deuteration of pentamethylcyclopentadiene in water-soluble cationic Rh(III) complexes assisted by PTA.

Cyclopentadienyl ruthenium(II) complexes with bridging alkynylphosphine ligands: synthesis and electrochemical studies.

Diastereomerically enriched analogues of the water-soluble phosphine PTA. Synthesis of phenyl(1,3,5-triaza-7-phosphatricyclo[3.3.1.1(3,7)]dec-6-yl)methanol (PZA) and the sulfide PZA(S) and X-ray crystal structures of the oxide PZA(O) and [Cp*IrCl(2)

Dynamic behaviour of Ru and Ru–Pt complexes containing tetrahedro-P4 ligand

Experimental Evidence of Phosphine Oxide Generation in Solution and Trapping by Ruthenium Complexes ⬇️

Formic acid dehydrogenation catalysed by ruthenium complexes bearing the tripodal ligands triphos and NP3.

Grafting of water-soluble phosphines to dendrimers and their use in catalysis: positive dendritic effects in aqueous media

Heterobimetallic cooperation mediates the transformation of white phosphorus into zwitterionic catena-phosphonium(+)diphosphenide(-) ligands

Homogenous catalytic hydrogenation of bicarbonate with water soluble aryl phosphine ligands

In Vitro Evaluation of Rhodium and Osmium RAPTA Analogues: The Case for Organometallic Anticancer Drugs Not Based on Ruthenium

Influence of Structural Variation on the Anticancer Activity of RAPTA-Type Complexes: ptn versus pta

Mechanistic studies on NaHCO3 hydrogenation and HCOOH dehydrogenation reactions catalysed by a Fe(II) linear tetraphosphine complex

NMR studies on the novel heterobimetallic complexes [M(dppm)(Ph(2)PCH(2)PPh(2)PPPP) {Pt(PPh3)2}]OTf (M = Rh, Ir) derived from the stepwise activation of white phosphorus.

New Class of Half-Sandwich Ruthenium(II) Arene Complexes Bearing the Water-Soluble CAP Ligand as an in Vitro Anticancer Agent

New Wind in Old Sails: Novel Applications of Triphos-based Transition Metal Complexes as Homogeneous Catalysts for Small Molecules and Renewables Activation

Novel synthetic pathways for bis(acyl)phosphine oxide photoinitiators

Number of terminal groups versus generation of the dendrimer, which criteria influence the catalytic properties?

Octahedral RuII Complexes with [PNO] Hydrazonic Ligands: Synthesis, Structure, Reactivity and Catalytic Activity in the Addition of Benzoic Acid to Alkynes

On the protonation of ruthenium-PTA complexes in water. X-ray crystal structure of RuCl4(PTAH)2·4 H2O (PTA=1,3,5-triaza-7-phosphaadamantane)

P4 activation by late-transition metal complexes

Rationalization of the inhibition activity of structurally related organometallic compounds against the drug target cathepsin B by DFT.

Recent Advances in Metal Catalyst Design for CO2 Hydroboration to C1 Derivatives

Selective ruthenium-catalyzed oxidation of 1,2:4,5-di-O-isopropylidene- beta-D-fructopyranose and other alcohols with NaOCl

Solution and solid-state dynamics of metal-coordinated white phosphorus

Stabilization of the triphosphallyl ligand η3-P3{P(O)H} at iridium via alkaline activation of P4.

Stable, water-soluble Pta-based Ru-Ag organometallic polymers

Steric and electronic effects on the reactivity of rh and ir complexes containing P-S, P-P, and P-O ligands. Implications for the effects of chelate ligands in catalysis.

Synthesis and characterization of terminal [Re(XCO)(CO)2(triphos)] (X=N, P): isocyanate versus phosphaethynolate complexes

Synthesis of new enantiomerically enriched beta-Hydroxy-gamma-amino phosphines by selective transformation of naturally occurring amino acids

Synthesis, catalytic properties and biological activity of new water soluble ruthenium cyclopentadienyl PTA complexes [(C5R5)RuCl(PTA)2] (R = H, Me; PTA = 1,3,5-triaza-7-phosphaadamantane).

Transfer hydrogenation of ketones catalyzed by surface-active ruthenium and rhodium complexes in water.

Water soluble ruthenium cyclopentadienyl and aminocyclopentadienyl PTA complexes as catalysts for selective hydrogenation of α,β-unsaturated substrates (PTA=1,3,5-triaza-7-phosphaadamantane)

Water-Soluble Silver(I) Complexes Featuring the Hemilabile 3,7-Dimethyl-1,3,5-triaza-7-phosphabicyclo[3.3.1]nonane Ligand: Synthesis, Characterization, and Antimicrobial Activity.