List of works by Miguel A Sierra

1,2,3-Triazolium-Derived Mesoionic Carbene Ligands Bearing Chiral Sulfur-Based Moieties: Synthesis, Catalytic Properties, and Their Role in Chirality Transfer

scientific article published on 07 August 2019

2-Azetidinones as Precursors of Pincer Ligands: Preparation, Structure, and Spectroscopic Properties of CC'N-Osmium Complexes.

scientific article published on 29 October 2015

A DFT study of the ambiphilic nature of arylpalladium species in intramolecular cyclization reactions

scientific article published on 01 February 2011

A click approach to polymetallic chromium(0) and tungsten(0) Fischer-carbene complexes and their use in the synthesis of functionalized polymetallic metal-carbene complexes

scientific article published on 30 November 2012

A straightforward synthesis of tetrameric estrone-based macrocycles

scientific article published on 23 July 2008

Alkyne−Co2(CO)6Complexes in the Synthesis of Fused Tricyclic β-Lactam and Azetidine Systems†,1

scientific article published on 01 October 1998

An Entry to Mixed NHC-Fischer Carbene Complexes and Zwitterionic Group 6 Metal Alkenyls

scientific article published on 26 July 2016

Azole Assisted C–H Bond Activation Promoted by an Osmium-Polyhydride: Discerning between N and NH

scientific article published on 5 May 2015

Bio-Organometallic Derivatives of Antibacterial Drugs

scientific article published on 18 March 2019

Biological activity of Fe(III) aquo-complexes towards ferric chelate reductase (FCR)

scientific article published on 07 February 2012

C-branched chiral (racemic) macrocyclic amino acids: structure of their Ni(II), Zn(II) and Cu(II) complexes

scientific article published on 08 August 2011

C8K-promoted self-condensation and self-condensation-cycloisomerization reactions of alpha,beta-unsaturated Fischer carbene complexes

scientific article published on 01 September 2002

Catalytic transmetalation from group 6 Fischer carbene complexes: an emerging powerful tool in organic synthesis

scientific article published on 01 January 2005

Central (S) to Central (M=Ir, Rh) to Planar (Metallocene, M=Fe, Ru) Chirality Transfer Using Sulfoxide-Substituted Mesoionic Carbene Ligands: Synthesis of Bimetallic Planar Chiral Metallocenes

scientific article published on 13 September 2019

Chelated Assisted Metal-Mediated N–H Bond Activation of β-Lactams: Preparation of Irida-, Rhoda-, Osma-, and Ruthenatrinems

scientific article published in April 2014

Chelating agents related to ethylenediamine bis(2-hydroxyphenyl)acetic acid (EDDHA): synthesis, characterization, and equilibrium studies of the free ligands and their Mg2+, Ca2+, Cu2+, and Fe3+ chelates.

scientific article published in August 2003

Chiral Sulfur Functional Groups as Definers of the Chirality at the Metal in Ir and Rh Half-Sandwich Complexes: A Combined CD/X-ray Study

scientific article published on 27 July 2017

Cobalt-mediated approach for the synthesis of terpene-based hybrids.

scientific article published on July 2003

Computational and experimental studies on the mechanism of the photochemical carbonylation of group 6 Fischer carbene complexes

scientific article published on 01 October 2005

Control over the E/Z selectivity of the catalytic dimerization of group 6 (Fischer) metal carbene complexes

scientific article published on 14 January 2013

Control over the chemoselectivity of Pd-catalyzed cyclization reactions of (2-iodoanilino)carbonyl compounds

scientific article published on 04 April 2012

Cu-catalyzed synthesis of symmetric group 6 (Fischer) bis-carbene complexes

scientific article published on 10 January 2008

DFT study on the Diels-Alder cycloaddition between alkenyl-M(0) (M = Cr, W) carbene complexes and neutral 1,3-dienes

scientific article

Deeper insight into the mechanism of the reaction of photogenerated metallaketenes and imines.

scientific article published on 24 September 2008

Desulfinylation of Ag(I) Sulfinyl Mesoionic Carbenes: Preparation of C-Unsubstituted Au(I)-1,2,3-Triazole Carbene Complexes

scientific article published on 30 January 2017

Di- and polymetallic heteroatom stabilized (Fischer) metal carbene complexes

scientific article published on 01 October 2000

Divergent pathways in the reaction of Fischer carbenes and palladium

scientific article published on 27 March 2007

Diversity oriented synthesis of hispanane-like terpene derivatives from (R)-(+)-sclareolide.

scientific article published in June 2005

Do ν(CO) stretching frequencies in metal carbonyl complexes unequivocally correlate with the intrinsic electron-donicity of ancillary ligands?

scientific article published on 05 May 2011

Dyotropic reactions: mechanisms and synthetic applications

scientific article published on 01 December 2009

Effect of a κ1-Bonded-M-1,2,3-triazole (M = Co, Ru) on the Structure and Reactivity of Group 6 Alkoxy (Fischer) Carbenes

scientific article published on 10 February 2017

Effect of the metal fragment in the thermal cycloaddition between alkynyl metal(0) Fischer carbene complexes and nitrones

scientific article published on 01 August 2006

Effect of the tether on the Mg(II), Ca(II), Cu(II) and Fe(III) stability constants and pM values of chelating agents related to EDDHA.

scientific article published on 8 October 2004

Electronic structure of alkoxychromium(0) carbene complexes: a joint TD-DFT/experimental study

scientific article published on 15 May 2008

Electrospray mass spectra of group 6 (Fischer) carbenes in the presence of electron-donor compounds.

scientific article

Facile deferration of commercial fertilizers containing iron chelates for their NMR analysis.

scientific article published in June 2009

First Insertions of Carbene Ligands into Ge-N and Si-N Bonds.

scientific article

Fischer carbene complexes: beautiful playgrounds to study single electron transfer (SET) reactions.

scientific article published on January 2007

Gold Sulfinyl Mesoionic Carbenes: Synthesis, Structure, and Catalytic Activity.

scientific article

Gold(I)-Catalyzed Cycloisomerization-Dimerization Cascade of Benzene-Tethered 1,6-Enynes

scientific article published on 26 June 2017

In-plane aromaticity in double group transfer reactions

scientific article published on 01 February 2007

Intramolecular Pd(0)-catalyzed reactions of (2-iodoanilino)-aldehydes: a joint experimental-computational study

scientific article published on 05 November 2012

Kinetic isotope effects in the study of organometallic reaction mechanisms

scientific article published on 05 May 2011

Light-induced aminocarbene to imine dyotropic rearrangement in a chromium(0) center: an unprecedented reaction pathway

scientific article published on 01 August 2003

Mechanistic Insight into the Facilitation of β-Lactam Fragmentation through Metal Assistance

Metal-tuned photochemistry of metallocene-substituted chromium(0)-carbene complexes

scientific article published on 01 January 2009

Mono- and Bimetallic Alkynyl Metallocenes and Half-Sandwich Complexes: A Simple and Versatile Synthetic Approach.

scientific article

Mono- and Bimetallic Zwitterionic Chromium(0) and Tungsten(0) Allenyls

scientific article published on 8 May 2015

Mono- and dinuclear osmium N,N'-di- and tetraphenylbipyridyls and extended bipyridyls. Synthesis, structure and electrochemistry

scientific article published on 4 January 2013

Multicomponent Synthesis of Pyran-2-ylidene Chromium(0) and Tungsten(0) Fischer Carbene Complexes

scientific article published on 12 April 2010

Multiple C−H Bond Activation of Phenyl-Substituted Pyrimidines and Triazines Promoted by an Osmium Polyhydride: Formation of Osmapolycycles with Three, Five, and Eight Fused Rings

scientific article published on 22 February 2010

Nature of impurities in fertilizers containing EDDHMA/Fe(3+), EDDHSA/Fe(3+), and EDDCHA/Fe(3+) chelates

scientific article published in January 2002

New Pd-catalyzed tandem cyclization processes on group 6 bis-carbene complexes

scientific article published in September 2002

New Platinum-Catalysed Dihydroalkoxylation of Allenes

scientific article published on 7 September 2010

On the Use of Metal Purine Derivatives (M=Ir, Rh) for the Selective Labeling of Nucleosides and Nucleotides

scientific article published on 23 February 2014

On the structure and spin states of Fe(III)-EDDHA complexes

scientific article published on 01 July 2006

Pd-catalyzed inter- and intramolecular carbene transfer from group 6 metal-carbene complexes

scientific article published in February 2001

Photochemical access to tetra- and pentacyclic terpene-like products from R-(+)-sclareolide

scientific article published in August 2003

Photochemistry of group 6 Fischer carbene complexes: beyond the photocarbonylation reaction

scientific article published on 25 April 2011

Pi-stacking effect on levoglucosenone derived internal chiral auxiliaries. A case of complete enantioselectivity inversion on the Diels-Alder reaction

scientific article published on 17 July 2008

Platinum-catalysed bisindolylation of allenes: a complementary alternative to gold catalysis

scientific article published on 13 March 2012

Reduction of cyclic group 6 Fischer carbene complexes: a case of exquisite regioselectivity

scientific article published on 01 May 2003

Regio- and diastereoselective stepwise [8 + 3]-Cycloaddition reaction between tropone derivatives and donor-acceptor cyclopropanes

scientific article published on 16 September 2013

Regioselective and stepwise [8 + 2] cycloaddition reaction between alkynyl-Fischer carbene complexes and tropothione

scientific article published on 16 July 2012

Remote Control by π-Conjugation of the Emissive Properties of Fischer Carbene-BODIPY Dyads.

scientific article published on 3 March 2016

Reversible Carbene Insertion into a Ge-N Bond and Insights into CO and Carbene Substitution Reactions Involving Amidinatogermylenes and Fischer Carbene Complexes

scientific article published on 27 December 2018

Sequential Reactions of Alkynes on an Iridium(III) Single Site.

scientific article published on 25 April 2017

Silver(I)-Catalyzed Addition of Phenols to Alkyne Cobalt Cluster Stabilized Carbocations

scientific article published on 17 May 2016

Stereoelectronic effects on type I 1,2-dyotropic rearrangements in vicinal dibromides

scientific article published on 01 August 2006

Stereoselective Synthesis of 3-Substituted 4-(Formyloxy)-2-azetidinones by the Unusual Baeyer−Villiger Reaction of β-Lactam Aldehydes. Scope and Synthetic Applications

scientific article published on 01 December 1996

Steroid Derived Mesoionic Gold and Silver Mono- and Polymetallic Carbenes

scientific article published on 24 November 2015

Structure and Fertilizer Properties of Byproducts Formed in the Synthesis of EDDHA

scientific article published on 01 June 2006

Structure and photoreactivity of stable zwitterionic group 6 metal allenyls

scientific article published in 2013

Study of the ESI-mass spectrometry ionization mechanism of Fischer carbene complexes.

scientific article published in June 2005

Sulfur Groups Improve the Performance of Triazole- and Triazolium-Based Interaction Units in Anion Binding.

scientific article published on 20 February 2017

Synthesis and Electrochemical Properties of Novel Tetrametallic Macrocyclic Fischer Carbene Complexes

scientific article published on April 17, 2003

Synthesis and characterisation of [6]-azaosmahelicenes: the first d4-heterometallahelicenes

scientific article published on 20 April 2012

Synthesis and chemical characterization of the novel agronomically relevant pentadentate chelate 2-(2-((2-hydroxybenzyl)amino)ethylamino)-2-(2-hydroxyphenyl)acetic acid (DCHA).

scientific article published in July 2010

Synthesis and properties of mononuclear group 10 alkoxy-biscarbene complexes

scientific article published in January 2009

Synthesis of Oxaspiranic Compounds through [3 + 2] Annulation of Cyclopropenones and Donor–Acceptor Cyclopropanes

scientific article published on 29 December 2014

Synthesis of a pH dependent covalent imprinted polymer able to recognize organotin species

scientific article published on 22 November 2005

Synthesis of alpha-onoceradiene-like terpene dimers by intermolecular metathesis processes

scientific article published on 01 February 2006

Synthesis of ferrocene tethered open and macrocyclic bis-beta-lactams and bis-beta-amino acid derivatives

scientific article published on 02 September 2009

Synthesis of ferrocene-substituted 2-azetidinones

scientific article published in December 2001

Synthesis of highly functionalized macrocycles by the peripheral functionalization of macrocyclic diimines

scientific article published on 01 November 2006

Synthesis of new bioorganometallic Ir- and Rh-complexes having β-lactam containing ligands

scientific article published on 01 January 2014

Synthesis of o,p-EDDHA and its detection as the main impurity in o,o-EDDHA commercial iron chelates

scientific article published in October 2002

Synthesis of polymetallic macrocyclic terpene-derived hybrids

scientific article published on 20 January 2006

Synthesis of terpene and steroid dimers and trimers having cyclobutadienyl-Co and aromatic tethers

scientific article published on 04 May 2007

Synthesis, structure, and electronic properties of extended π-conjugated Group 6 Fischer alkoxy-bis(carbene) complexes.

scientific article

The "click" reaction involving metal azides, metal alkynes, or both: an exploration into multimetal structures

scientific article published on 18 February 2013

The Gold(I)- and Silver(I)-Catalyzed Nicholas Reaction

scientific article published in February 2013

The Intramolecular Aldol Condensation Route to Fused Bi- and Tricyclic β-Lactams1,2

scientific article published on 01 October 1996

The Selective Synthesis of Metallanucleosides and Metallanucleotides: A New Tool for the Functionalization of Nucleic Acids

scientific article published on 30 August 2012

The assembly of macrocyclic bis- and tetra-beta-lactams with embedded platinum or palladium square-planar centers

scientific article published on 01 July 2009

The asymmetric synthesis of novel tin-functionalized carbapenam systems through radical cyclization of enyne β-lactams

The electronic structure and photochemistry of group 6 bimetallic (Fischer) carbene complexes: beyond the photocarbonylation reaction.

scientific article published in June 2010

The mechanism of the ketene-imine (staudinger) reaction in its centennial: still an unsolved problem?

scientific article published on 29 July 2008

The nicholas approach to natural product hybrids

scientific article published on 01 August 2006

The photochemical reaction of vinylaziridines and vinylazetidines with chromium(0) and molybdenum(0) (Fischer) carbene complexes.

scientific article published on 16 December 2013

The photochemical reactivity of the "photo-inert" tungsten (Fischer) carbene complexes

scientific article published on 01 December 2005

The sequential building of chiral macrocyclic bis-beta-lactams by double staudinger-Cu-catalyzed azide-alkyne cycloadditions.

scientific article published in February 2010

Towards a general synthesis of 3-metal-substituted β-lactams

scientific article published on 18 July 2013

Transmetalation reactions from Fischer carbene complexes to late transition metals: a DFT study

scientific article published on 01 January 2008

Trapping intermediates in an [8 + 2] cycloaddition reaction with the help of DFT calculations

scientific article published on 11 May 2011

Triazole vs. triazolium carbene ligands in the site-selective cyclometallation of o-carboranes by M(iii) (M = Ir, Rh) complexes

scientific article published in 2018

Triazole-Containing [FeFe] Hydrogenase Mimics: Synthesis and Electrocatalytic Behavior

scientific article published on 13 November 2019

Tuning the photophysical properties of BODIPY molecules by π-conjugation with Fischer carbene complexes.

scientific article

Two Types of σ-Allenyl Complexes from Reactions of Silylenes and Germylenes with Chromium Fischer Alkynyl(alkoxy)carbenes

scientific article published on 27 May 2019

Two versatile and parallel approaches to highly symmetrical open and closed natural product-based structures

scientific article published on 01 March 2010

Understanding of the mode of action of Fe(III)-EDDHA as iron chlorosis corrector based on its photochemical and redox behavior

scientific article published on 01 October 2005

Unexpected Reaction Pathways Leading to Thiodiglycol During the Degradation of Long-Chain Sulfur Mustards

scientific article published on 02 October 2018

Unexpected Zwitterionic Allenyls from Silylenes and a Fischer Alkynylcarbene: A Remarkable Silylene-Promoted Rearrangement

scientific article published on 16 January 2019

Unexpected reaction pathways in the reaction of alkoxyalkynylchromium(0) carbenes with aromatic dinucleophiles.

scientific article published in October 2003