List of works - Carlos C. Romão

(Eta2-alkyne)methyl(dioxo)rhenium complexes as aldehyde-olefination catalysts

scientific article published in March 2003

A contribution to the rational design of Ru(CO)3Cl2L complexes for in vivo delivery of CO

scientific article

A novel carbon monoxide-releasing molecule fully protects mice from severe malaria

scientific article published on 12 December 2011

Activation of B-H bonds by an oxo-rhenium complex

scientific article published on 23 October 2008

An N-Acetyl Cysteine Ruthenium Tricarbonyl Conjugate Enables Simultaneous Release of CO and Ablation of Reactive Oxygen Species

scientific article

An artificial CO-releasing metalloprotein built by histidine-selective metallation

scientific article published on 01 March 2015

CORM-3 reactivity toward proteins: the crystal structure of a Ru(II) dicarbonyl-lysozyme complex

scientific article

Catalytic olefin epoxidation with cyclopentadienyl–molybdenum complexes in room temperature ionic liquids

article published in 2005

Catalyzing Aldehyde Hydrosilylation with a Molybdenum(VI) Complex: A Density Functional Theory Study

scientific article published on 01 January 2007

Cation Exchange Strategy for the Encapsulation of a Photoactive CO-Releasing Organometallic Molecule into Anionic Porous Frameworks

scientific article published on 11 June 2016

Characterization of a versatile organometallic pro-drug (CORM) for experimental CO based therapeutics

scientific article

Chemoselective Sulfide and Sulfoxide Oxidations by CpMo(CO)3Cl/HOOR: a DFT Mechanistic Study

Comparing spectroscopic and electrochemical properties of complexes of type Cp’M(η 3 -C 3 H 5 )(CO) 2 (Cp’ = Cp, Ind, Flu): A complementary experimental and DFT study

Cyanide–isocyanide isomers in polynuclear complexes. Reactivity and theoretical studies

Cyclopentadienyl molybdenum dicarbonyl η3-allyl complexes as catalyst precursors for olefin epoxidation. Crystal structures of Cp′Mo(CO)2(η3-C3H5) (Cp′ = η5-C5H4Me, η5-C5Me5)

Developing drug molecules for therapy with carbon monoxide.

scientific article published on 20 February 2012

Dioxomolybdenum(vi) complexes as catalysts for the hydrosilylation of aldehydes and ketones

scientific article published on 23 February 2006

Encapsulation of Cyano(cyclopentadienyl) Complexes of Iron with β-cyclodextrin

Encapsulation of sodium nimesulide and precursors in beta-cyclodextrin

scientific article published in March 2003

Epoxidation of cyclooctene catalyzed by dioxomolybdenum(VI) complexes in ionic liquids

article published in 2004

Exocyclic coordination of the η3-fluorenyl, η3-cyclopenta[def]phenanthrenyl and η3-8,9-dihydrocyclopenta[def]phenanthrenyl anions: X-ray crystal structures, NMR fluxionality and theoretical studies

Generation of Carbon Monoxide Releasing Molecules (CO-RMs) as Drug Candidates for the Treatment of Acute Liver Injury: Targeting of CO-RMs to the Liver

Heterometallic complexes involving iron(II) and rhenium(VII) centers connected by mu-oxido bridges

scientific article published on 8 October 2009

Highly Efficient Reduction of Sulfoxides with the System Borane/Oxo-rhenium Complexes†

scholarly article by Ana C. Fernandes et al published 8 November 2010 in Organometallics

Highly chemo- and regioselective reduction of aromatic nitro compounds using the system silane/oxo-rhenium complexes.

scientific article published in September 2009

Hydrogen activation by high-valent oxo-molybdenum(vi) and -rhenium(vii) and -(v) compounds

scientific article published on 27 February 2008

Incorporation of a (Cyclopentadienyl)molybdenum Oxo Complex in MCM-41 and Its Use as a Catalyst for Olefin Epoxidation

Indenyl ring slippage in crown thioether complexes [IndMo(CO)2L]+ and C-S activation of trithiacyclononane: experimental and theoretical studies.

scientific article published on 16 August 2011

Inhibition of Nitric Oxide–Stimulated Vasorelaxation by Carbon Monoxide-Releasing Molecules

scientific article published on 01 November 2011

Interactions of Omeprazole and Precursors withbeta-Cyclodextrin Host Molecules

article

Intercalation of a molybdenum η3-allyl dicarbonyl complex in a layered double hydroxide and catalytic performance in olefin epoxidation

article

Ligand Dependence of the Indenyl Ring Slippage in [(η5-Ind)MoL2(CO)2]0,+Complexes: Experimental and Theoretical Studies

Loading and delivery of sertraline using inorganic micro and mesoporous materials

scientific article published on 05 December 2006

Methylisocyanide derivatives of molybdenocene and tungstenocene: preparation, reactivity and electronic structure: crystal structures of [(η5-C5H5)2WBr(CNMe)]Br and [(η5-C5H5)2{N(H)CH3}][BF4]2· CH3CN

Molybdenum(vi) catalysts obtained from η3-allyl dicarbonyl precursors: Synthesis, characterization and catalytic performance in cyclooctene epoxidation

scientific article published on 02 February 2012

Mononuclear and Binuclear Cyclopentadienyl Oxo Molybdenum and Tungsten Complexes: Syntheses and Applications in Olefin Epoxidation Catalysis

Nuclear magnetic resonance studies of sulfur inversion in bis(cyclopentadienyl)-molybdenum and -tungsten complexes with dithioethers

Nucleophilic and electrophilic reactions of C5 cyclo-polyenes coordinated to the [CpMoL2]n+ fragment (n = 1,2; L = 1/2dppe, PMe3, P(OMe)3, CO)

Octahedral bipyridine and bipyrimidine dioxomolybdenum(VI) complexes: characterization, application in catalytic epoxidation, and density functional mechanistic study

scientific article

Olefin epoxidation with tert-butyl hydroperoxide catalyzed by MoO2X2L complexes: a DFT mechanistic study

scientific article published on 20 January 2006

One-pot preparation of a novel CO-releasing material based on a CO-releasing molecule@metal-organic framework system.

scientific article published on 2 June 2017

Oxorhenium complexes as aldehyde-olefination catalysts

scientific article published in December 2004

Phase equilibria of haloalkanes dissolved in ethylsulfate- or ethylsulfonate-based ionic liquids.

scientific article published in June 2010

Photochemistry of Methyltrioxorhenium Revisited: A DFT/TD-DFT and CASSCF/MS-CASPT2 Theoretical Study

Prevention of clinical and histological signs of proteolipid protein (PLP)-induced experimental allergic encephalomyelitis (EAE) in mice by the water-soluble carbon monoxide-releasing molecule (CORM)-A1.

scientific article

Reaction of Spiro[2.4]hepta-4,6-diene with Molybdenum(II) Indenyl Compounds: Effects of Substitution in the Indenyl Ligand

Rhenium(VII) Oxo and Imido Complexes: Synthesis, Structures, and Applications

scientific article published on 01 December 1997

Ring Slippage vs Charge Transfer in the Reductive Chemistry of [IndMo(CO)2(α-diimine)]+Cations

Ring-Functionalized Molybdenocene Complexes

Selective and mild oxidation of sulfides to sulfoxides or sulfones using H2O2 and Cp′Mo(CO)3Cl as catalysts

article published in 2008

Spontaneous CO release from Ru(II)(CO)2-protein complexes in aqueous solution, cells, and mice

scientific article published on 4 December 2014

Stepwise hapticity changes in sequential one-electron redox reactions of indenyl-molybdenum complexes: combined electrochemical, ESR, X-ray, and theoretical studies

scientific article published in October 2001

Structural preferences of cyclopentadienyl and indenyl rings in iridium(I) carbene complexes

scholarly article by Martina Prinz et al published October 2006 in Journal of Organometallic Chemistry

Studies on molybdenocene derivatives: Reactions of [Cp2Mo(η2-NCMe)] and preparation of alkyl hydride complexes. Crystal structure of [Cp2Mo(PMe3)]

scientific article published in February 1993

Synthesis and catalytic application of octahedral lewis base adducts of dichloro and dialkyl dioxotungsten(VI).

scientific article published in August 2002

Synthesis and reactivity of molybdenocene isocyanide complexes; crystal structure of (η5-C5H5)2MoCNtBu

Synthesis of ferrocenyldiimine metal carbonyl complexes and an investigation of the Mo adduct encapsulated in cyclodextrin

Synthesis, characterization and antitumor activity of 1,2-disubstituted ferrocenes and cyclodextrin inclusion complexes

article published in 2008

Synthesis, characterization and catalytic studies of bis(chloro)dioxomolybdenum(VI)-chiral diimine complexes

The Carbon monoxide releasing molecule ALF-186 mediates anti-inflammatory and neuroprotective effects via the soluble guanylate cyclase ß1 in rats' retinal ganglion cells after ischemia and reperfusion injury

scientific article

The nature of the indenyl effect

scientific article published in February 2002

The role of cyclopentadienyl versus indenyl in Mo(II) spirodiene complexes reactivity: A DFT mechanistic study

article published in 2010

[MoO2Cl2] as catalyst for hydrosilylation of aldehydes and ketones

scientific article

cis-Di-μ-oxido-bis-[(N,N-diethyl-dithio-carbamato-κS,S')oxidomolybdenum(V)](Mo-Mo) tetra-hydro-furan monosolvate.

scientific article published on 29 January 2011

β-Cyclodextrin and permethylated β-cyclodextrin inclusion compounds of a cyclopentadienyl molybdenum tricarbonyl complex and their use as cyclooctene epoxidation catalyst precursors

List of works by Carlos C. Romão

(Eta2-alkyne)methyl(dioxo)rhenium complexes as aldehyde-olefination catalysts

A contribution to the rational design of Ru(CO)3Cl2L complexes for in vivo delivery of CO

A novel carbon monoxide-releasing molecule fully protects mice from severe malaria

Activation of B-H bonds by an oxo-rhenium complex

An N-Acetyl Cysteine Ruthenium Tricarbonyl Conjugate Enables Simultaneous Release of CO and Ablation of Reactive Oxygen Species

An artificial CO-releasing metalloprotein built by histidine-selective metallation

CORM-3 reactivity toward proteins: the crystal structure of a Ru(II) dicarbonyl-lysozyme complex

Catalytic olefin epoxidation with cyclopentadienyl–molybdenum complexes in room temperature ionic liquids

Catalyzing Aldehyde Hydrosilylation with a Molybdenum(VI) Complex: A Density Functional Theory Study

Cation Exchange Strategy for the Encapsulation of a Photoactive CO-Releasing Organometallic Molecule into Anionic Porous Frameworks

Characterization of a versatile organometallic pro-drug (CORM) for experimental CO based therapeutics

Chemoselective Sulfide and Sulfoxide Oxidations by CpMo(CO)3Cl/HOOR: a DFT Mechanistic Study

Comparing spectroscopic and electrochemical properties of complexes of type Cp’M(η 3 -C 3 H 5 )(CO) 2 (Cp’ = Cp, Ind, Flu): A complementary experimental and DFT study

Cyanide–isocyanide isomers in polynuclear complexes. Reactivity and theoretical studies

Cyclopentadienyl molybdenum dicarbonyl η3-allyl complexes as catalyst precursors for olefin epoxidation. Crystal structures of Cp′Mo(CO)2(η3-C3H5) (Cp′ = η5-C5H4Me, η5-C5Me5)

Developing drug molecules for therapy with carbon monoxide.

Dioxomolybdenum(vi) complexes as catalysts for the hydrosilylation of aldehydes and ketones

Encapsulation of Cyano(cyclopentadienyl) Complexes of Iron with β-cyclodextrin

Encapsulation of sodium nimesulide and precursors in beta-cyclodextrin

Epoxidation of cyclooctene catalyzed by dioxomolybdenum(VI) complexes in ionic liquids

Exocyclic coordination of the η3-fluorenyl, η3-cyclopenta[def]phenanthrenyl and η3-8,9-dihydrocyclopenta[def]phenanthrenyl anions: X-ray crystal structures, NMR fluxionality and theoretical studies

Generation of Carbon Monoxide Releasing Molecules (CO-RMs) as Drug Candidates for the Treatment of Acute Liver Injury: Targeting of CO-RMs to the Liver

Heterometallic complexes involving iron(II) and rhenium(VII) centers connected by mu-oxido bridges

Highly Efficient Reduction of Sulfoxides with the System Borane/Oxo-rhenium Complexes†

Highly chemo- and regioselective reduction of aromatic nitro compounds using the system silane/oxo-rhenium complexes.

Hydrogen activation by high-valent oxo-molybdenum(vi) and -rhenium(vii) and -(v) compounds

Incorporation of a (Cyclopentadienyl)molybdenum Oxo Complex in MCM-41 and Its Use as a Catalyst for Olefin Epoxidation

Indenyl ring slippage in crown thioether complexes [IndMo(CO)2L]+ and C-S activation of trithiacyclononane: experimental and theoretical studies.

Inhibition of Nitric Oxide–Stimulated Vasorelaxation by Carbon Monoxide-Releasing Molecules

Interactions of Omeprazole and Precursors withbeta-Cyclodextrin Host Molecules

Intercalation of a molybdenum η3-allyl dicarbonyl complex in a layered double hydroxide and catalytic performance in olefin epoxidation

Ligand Dependence of the Indenyl Ring Slippage in [(η5-Ind)MoL2(CO)2]0,+Complexes: Experimental and Theoretical Studies

Loading and delivery of sertraline using inorganic micro and mesoporous materials

Methylisocyanide derivatives of molybdenocene and tungstenocene: preparation, reactivity and electronic structure: crystal structures of [(η5-C5H5)2WBr(CNMe)]Br and [(η5-C5H5)2{N(H)CH3}][BF4]2· CH3CN

Molybdenum(vi) catalysts obtained from η3-allyl dicarbonyl precursors: Synthesis, characterization and catalytic performance in cyclooctene epoxidation

Mononuclear and Binuclear Cyclopentadienyl Oxo Molybdenum and Tungsten Complexes: Syntheses and Applications in Olefin Epoxidation Catalysis

Nuclear magnetic resonance studies of sulfur inversion in bis(cyclopentadienyl)-molybdenum and -tungsten complexes with dithioethers

Nucleophilic and electrophilic reactions of C5 cyclo-polyenes coordinated to the [CpMoL2]n+ fragment (n = 1,2; L = 1/2dppe, PMe3, P(OMe)3, CO)

Octahedral bipyridine and bipyrimidine dioxomolybdenum(VI) complexes: characterization, application in catalytic epoxidation, and density functional mechanistic study

Olefin epoxidation with tert-butyl hydroperoxide catalyzed by MoO2X2L complexes: a DFT mechanistic study

One-pot preparation of a novel CO-releasing material based on a CO-releasing molecule@metal-organic framework system.

Oxorhenium complexes as aldehyde-olefination catalysts

Phase equilibria of haloalkanes dissolved in ethylsulfate- or ethylsulfonate-based ionic liquids.

Photochemistry of Methyltrioxorhenium Revisited: A DFT/TD-DFT and CASSCF/MS-CASPT2 Theoretical Study

Prevention of clinical and histological signs of proteolipid protein (PLP)-induced experimental allergic encephalomyelitis (EAE) in mice by the water-soluble carbon monoxide-releasing molecule (CORM)-A1.

Reaction of Spiro[2.4]hepta-4,6-diene with Molybdenum(II) Indenyl Compounds: Effects of Substitution in the Indenyl Ligand

Rhenium(VII) Oxo and Imido Complexes: Synthesis, Structures, and Applications

Ring Slippage vs Charge Transfer in the Reductive Chemistry of [IndMo(CO)2(α-diimine)]+Cations

Ring-Functionalized Molybdenocene Complexes

Selective and mild oxidation of sulfides to sulfoxides or sulfones using H2O2 and Cp′Mo(CO)3Cl as catalysts

Spontaneous CO release from Ru(II)(CO)2-protein complexes in aqueous solution, cells, and mice

Stepwise hapticity changes in sequential one-electron redox reactions of indenyl-molybdenum complexes: combined electrochemical, ESR, X-ray, and theoretical studies

Structural preferences of cyclopentadienyl and indenyl rings in iridium(I) carbene complexes

Studies on molybdenocene derivatives: Reactions of [Cp2Mo(η2-NCMe)] and preparation of alkyl hydride complexes. Crystal structure of [Cp2Mo(PMe3)]

Synthesis and catalytic application of octahedral lewis base adducts of dichloro and dialkyl dioxotungsten(VI).

Synthesis and reactivity of molybdenocene isocyanide complexes; crystal structure of (η5-C5H5)2MoCNtBu

Synthesis of ferrocenyldiimine metal carbonyl complexes and an investigation of the Mo adduct encapsulated in cyclodextrin

Synthesis, characterization and antitumor activity of 1,2-disubstituted ferrocenes and cyclodextrin inclusion complexes

Synthesis, characterization and catalytic studies of bis(chloro)dioxomolybdenum(VI)-chiral diimine complexes

The Carbon monoxide releasing molecule ALF-186 mediates anti-inflammatory and neuroprotective effects via the soluble guanylate cyclase ß1 in rats' retinal ganglion cells after ischemia and reperfusion injury

The nature of the indenyl effect

The role of cyclopentadienyl versus indenyl in Mo(II) spirodiene complexes reactivity: A DFT mechanistic study

[MoO2Cl2] as catalyst for hydrosilylation of aldehydes and ketones

cis-Di-μ-oxido-bis-[(N,N-diethyl-dithio-carbamato-κS,S')oxidomolybdenum(V)](Mo-Mo) tetra-hydro-furan monosolvate.

β-Cyclodextrin and permethylated β-cyclodextrin inclusion compounds of a cyclopentadienyl molybdenum tricarbonyl complex and their use as cyclooctene epoxidation catalyst precursors